Formation of radical pairs in the photolysis of 2, 6-di(tert-butyl)-l,4-benzoquinonediazide in single crystals of 2,6-di(tert-butyl)-4-methylphenol
Abstract In the photolysis of single crystals of 2,6-di(tert-butyl)-4-methylphenol with the addition of 2,4-di(tert-butyl)-l,4-benzoquinonediazide it was found that they form carbenes and radical pairs with r1=6.0 å, which are secondary products of the photolysis of the quinonediazide and which form...
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1991 |
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| Umfang: |
4 |
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| Reproduktion: |
Springer Online Journal Archives 1860-2002 |
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| Übergeordnetes Werk: |
in: Russian chemical bulletin - 1952, 40(1991) vom: März, Seite 483-486 |
| Übergeordnetes Werk: |
volume:40 ; year:1991 ; month:03 ; pages:483-486 ; extent:4 |
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NLEJ192200305 |
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| 245 | 1 | 0 | |a Formation of radical pairs in the photolysis of 2, 6-di(tert-butyl)-l,4-benzoquinonediazide in single crystals of 2,6-di(tert-butyl)-4-methylphenol |
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| 520 | |a Abstract In the photolysis of single crystals of 2,6-di(tert-butyl)-4-methylphenol with the addition of 2,4-di(tert-butyl)-l,4-benzoquinonediazide it was found that they form carbenes and radical pairs with r1=6.0 å, which are secondary products of the photolysis of the quinonediazide and which form as a result of transfer of a hydrogen atom from the phenol to the carbene. The high thermal stability of these radical pairs makes it possible to use them as two-spin probes. Also found were radical products that are annealed by light with wavelength greater than 560 nm and are hypothetically classified as ion-radical pairs with rav=8.9 å. | ||
| 533 | |f Springer Online Journal Archives 1860-2002 | ||
| 700 | 1 | |a Lazarev, G. G. |4 oth | |
| 700 | 1 | |a Kuskov, V. L. |4 oth | |
| 700 | 1 | |a Lebedev, Ya. S. |4 oth | |
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(DE-627)NLEJ192200305 DE-627 ger DE-627 rakwb eng Formation of radical pairs in the photolysis of 2, 6-di(tert-butyl)-l,4-benzoquinonediazide in single crystals of 2,6-di(tert-butyl)-4-methylphenol 1991 4 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Abstract In the photolysis of single crystals of 2,6-di(tert-butyl)-4-methylphenol with the addition of 2,4-di(tert-butyl)-l,4-benzoquinonediazide it was found that they form carbenes and radical pairs with r1=6.0 å, which are secondary products of the photolysis of the quinonediazide and which form as a result of transfer of a hydrogen atom from the phenol to the carbene. The high thermal stability of these radical pairs makes it possible to use them as two-spin probes. Also found were radical products that are annealed by light with wavelength greater than 560 nm and are hypothetically classified as ion-radical pairs with rav=8.9 å. Springer Online Journal Archives 1860-2002 Lazarev, G. G. oth Kuskov, V. L. oth Lebedev, Ya. S. oth in Russian chemical bulletin 1952 40(1991) vom: März, Seite 483-486 (DE-627)NLEJ188989994 (DE-600)2037677-7 1573-9171 nnns volume:40 year:1991 month:03 pages:483-486 extent:4 http://dx.doi.org/10.1007/BF00957980 GBV_USEFLAG_U ZDB-1-SOJ GBV_NL_ARTICLE AR 40 1991 3 483-486 4 |
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(DE-627)NLEJ192200305 DE-627 ger DE-627 rakwb eng Formation of radical pairs in the photolysis of 2, 6-di(tert-butyl)-l,4-benzoquinonediazide in single crystals of 2,6-di(tert-butyl)-4-methylphenol 1991 4 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Abstract In the photolysis of single crystals of 2,6-di(tert-butyl)-4-methylphenol with the addition of 2,4-di(tert-butyl)-l,4-benzoquinonediazide it was found that they form carbenes and radical pairs with r1=6.0 å, which are secondary products of the photolysis of the quinonediazide and which form as a result of transfer of a hydrogen atom from the phenol to the carbene. The high thermal stability of these radical pairs makes it possible to use them as two-spin probes. Also found were radical products that are annealed by light with wavelength greater than 560 nm and are hypothetically classified as ion-radical pairs with rav=8.9 å. Springer Online Journal Archives 1860-2002 Lazarev, G. G. oth Kuskov, V. L. oth Lebedev, Ya. S. oth in Russian chemical bulletin 1952 40(1991) vom: März, Seite 483-486 (DE-627)NLEJ188989994 (DE-600)2037677-7 1573-9171 nnns volume:40 year:1991 month:03 pages:483-486 extent:4 http://dx.doi.org/10.1007/BF00957980 GBV_USEFLAG_U ZDB-1-SOJ GBV_NL_ARTICLE AR 40 1991 3 483-486 4 |
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(DE-627)NLEJ192200305 DE-627 ger DE-627 rakwb eng Formation of radical pairs in the photolysis of 2, 6-di(tert-butyl)-l,4-benzoquinonediazide in single crystals of 2,6-di(tert-butyl)-4-methylphenol 1991 4 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Abstract In the photolysis of single crystals of 2,6-di(tert-butyl)-4-methylphenol with the addition of 2,4-di(tert-butyl)-l,4-benzoquinonediazide it was found that they form carbenes and radical pairs with r1=6.0 å, which are secondary products of the photolysis of the quinonediazide and which form as a result of transfer of a hydrogen atom from the phenol to the carbene. The high thermal stability of these radical pairs makes it possible to use them as two-spin probes. Also found were radical products that are annealed by light with wavelength greater than 560 nm and are hypothetically classified as ion-radical pairs with rav=8.9 å. Springer Online Journal Archives 1860-2002 Lazarev, G. G. oth Kuskov, V. L. oth Lebedev, Ya. S. oth in Russian chemical bulletin 1952 40(1991) vom: März, Seite 483-486 (DE-627)NLEJ188989994 (DE-600)2037677-7 1573-9171 nnns volume:40 year:1991 month:03 pages:483-486 extent:4 http://dx.doi.org/10.1007/BF00957980 GBV_USEFLAG_U ZDB-1-SOJ GBV_NL_ARTICLE AR 40 1991 3 483-486 4 |
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(DE-627)NLEJ192200305 DE-627 ger DE-627 rakwb eng Formation of radical pairs in the photolysis of 2, 6-di(tert-butyl)-l,4-benzoquinonediazide in single crystals of 2,6-di(tert-butyl)-4-methylphenol 1991 4 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Abstract In the photolysis of single crystals of 2,6-di(tert-butyl)-4-methylphenol with the addition of 2,4-di(tert-butyl)-l,4-benzoquinonediazide it was found that they form carbenes and radical pairs with r1=6.0 å, which are secondary products of the photolysis of the quinonediazide and which form as a result of transfer of a hydrogen atom from the phenol to the carbene. The high thermal stability of these radical pairs makes it possible to use them as two-spin probes. Also found were radical products that are annealed by light with wavelength greater than 560 nm and are hypothetically classified as ion-radical pairs with rav=8.9 å. Springer Online Journal Archives 1860-2002 Lazarev, G. G. oth Kuskov, V. L. oth Lebedev, Ya. S. oth in Russian chemical bulletin 1952 40(1991) vom: März, Seite 483-486 (DE-627)NLEJ188989994 (DE-600)2037677-7 1573-9171 nnns volume:40 year:1991 month:03 pages:483-486 extent:4 http://dx.doi.org/10.1007/BF00957980 GBV_USEFLAG_U ZDB-1-SOJ GBV_NL_ARTICLE AR 40 1991 3 483-486 4 |
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(DE-627)NLEJ192200305 DE-627 ger DE-627 rakwb eng Formation of radical pairs in the photolysis of 2, 6-di(tert-butyl)-l,4-benzoquinonediazide in single crystals of 2,6-di(tert-butyl)-4-methylphenol 1991 4 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Abstract In the photolysis of single crystals of 2,6-di(tert-butyl)-4-methylphenol with the addition of 2,4-di(tert-butyl)-l,4-benzoquinonediazide it was found that they form carbenes and radical pairs with r1=6.0 å, which are secondary products of the photolysis of the quinonediazide and which form as a result of transfer of a hydrogen atom from the phenol to the carbene. The high thermal stability of these radical pairs makes it possible to use them as two-spin probes. Also found were radical products that are annealed by light with wavelength greater than 560 nm and are hypothetically classified as ion-radical pairs with rav=8.9 å. Springer Online Journal Archives 1860-2002 Lazarev, G. G. oth Kuskov, V. L. oth Lebedev, Ya. S. oth in Russian chemical bulletin 1952 40(1991) vom: März, Seite 483-486 (DE-627)NLEJ188989994 (DE-600)2037677-7 1573-9171 nnns volume:40 year:1991 month:03 pages:483-486 extent:4 http://dx.doi.org/10.1007/BF00957980 GBV_USEFLAG_U ZDB-1-SOJ GBV_NL_ARTICLE AR 40 1991 3 483-486 4 |
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Formation of radical pairs in the photolysis of 2, 6-di(tert-butyl)-l,4-benzoquinonediazide in single crystals of 2,6-di(tert-butyl)-4-methylphenol |
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Formation of radical pairs in the photolysis of 2, 6-di(tert-butyl)-l,4-benzoquinonediazide in single crystals of 2,6-di(tert-butyl)-4-methylphenol |
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Formation of radical pairs in the photolysis of 2, 6-di(tert-butyl)-l,4-benzoquinonediazide in single crystals of 2,6-di(tert-butyl)-4-methylphenol |
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formation of radical pairs in the photolysis of 2, 6-di(tert-butyl)-l,4-benzoquinonediazide in single crystals of 2,6-di(tert-butyl)-4-methylphenol |
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Formation of radical pairs in the photolysis of 2, 6-di(tert-butyl)-l,4-benzoquinonediazide in single crystals of 2,6-di(tert-butyl)-4-methylphenol |
| abstract |
Abstract In the photolysis of single crystals of 2,6-di(tert-butyl)-4-methylphenol with the addition of 2,4-di(tert-butyl)-l,4-benzoquinonediazide it was found that they form carbenes and radical pairs with r1=6.0 å, which are secondary products of the photolysis of the quinonediazide and which form as a result of transfer of a hydrogen atom from the phenol to the carbene. The high thermal stability of these radical pairs makes it possible to use them as two-spin probes. Also found were radical products that are annealed by light with wavelength greater than 560 nm and are hypothetically classified as ion-radical pairs with rav=8.9 å. |
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Abstract In the photolysis of single crystals of 2,6-di(tert-butyl)-4-methylphenol with the addition of 2,4-di(tert-butyl)-l,4-benzoquinonediazide it was found that they form carbenes and radical pairs with r1=6.0 å, which are secondary products of the photolysis of the quinonediazide and which form as a result of transfer of a hydrogen atom from the phenol to the carbene. The high thermal stability of these radical pairs makes it possible to use them as two-spin probes. Also found were radical products that are annealed by light with wavelength greater than 560 nm and are hypothetically classified as ion-radical pairs with rav=8.9 å. |
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Abstract In the photolysis of single crystals of 2,6-di(tert-butyl)-4-methylphenol with the addition of 2,4-di(tert-butyl)-l,4-benzoquinonediazide it was found that they form carbenes and radical pairs with r1=6.0 å, which are secondary products of the photolysis of the quinonediazide and which form as a result of transfer of a hydrogen atom from the phenol to the carbene. The high thermal stability of these radical pairs makes it possible to use them as two-spin probes. Also found were radical products that are annealed by light with wavelength greater than 560 nm and are hypothetically classified as ion-radical pairs with rav=8.9 å. |
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Formation of radical pairs in the photolysis of 2, 6-di(tert-butyl)-l,4-benzoquinonediazide in single crystals of 2,6-di(tert-butyl)-4-methylphenol |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">NLEJ192200305</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230506163903.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">070526s1991 xx |||||o 00| ||eng c</controlfield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)NLEJ192200305</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Formation of radical pairs in the photolysis of 2, 6-di(tert-butyl)-l,4-benzoquinonediazide in single crystals of 2,6-di(tert-butyl)-4-methylphenol</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">1991</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">4</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">z</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zu</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract In the photolysis of single crystals of 2,6-di(tert-butyl)-4-methylphenol with the addition of 2,4-di(tert-butyl)-l,4-benzoquinonediazide it was found that they form carbenes and radical pairs with r1=6.0 å, which are secondary products of the photolysis of the quinonediazide and which form as a result of transfer of a hydrogen atom from the phenol to the carbene. The high thermal stability of these radical pairs makes it possible to use them as two-spin probes. Also found were radical products that are annealed by light with wavelength greater than 560 nm and are hypothetically classified as ion-radical pairs with rav=8.9 å.</subfield></datafield><datafield tag="533" ind1=" " ind2=" "><subfield code="f">Springer Online Journal Archives 1860-2002</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lazarev, G. G.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kuskov, V. L.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Lebedev, Ya. S.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">in</subfield><subfield code="t">Russian chemical bulletin</subfield><subfield code="d">1952</subfield><subfield code="g">40(1991) vom: März, Seite 483-486</subfield><subfield code="w">(DE-627)NLEJ188989994</subfield><subfield code="w">(DE-600)2037677-7</subfield><subfield code="x">1573-9171</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:40</subfield><subfield code="g">year:1991</subfield><subfield code="g">month:03</subfield><subfield code="g">pages:483-486</subfield><subfield code="g">extent:4</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">http://dx.doi.org/10.1007/BF00957980</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">ZDB-1-SOJ</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_NL_ARTICLE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">40</subfield><subfield code="j">1991</subfield><subfield code="c">3</subfield><subfield code="h">483-486</subfield><subfield code="g">4</subfield></datafield></record></collection>
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