Enthalpy characteristics of dilute solutions of amides in acetonitrile
Abstract The enthalpy of mixing of formamide,N-methylformamide,N,N-dimethylformamide, and hexamethylphosphoric triamide with MeCN was measured in the 283–328 K range. The enthalpic coefficients of the binary and ternary interactions between the amide molecules are calculated within the framework of...
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| Autor*in: |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1993 |
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| Umfang: |
6 |
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| Reproduktion: |
Springer Online Journal Archives 1860-2002 |
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| Übergeordnetes Werk: |
in: Russian chemical bulletin - 1952, 42(1993) vom: Okt., Seite 1652-1657 |
| Übergeordnetes Werk: |
volume:42 ; year:1993 ; month:10 ; pages:1652-1657 ; extent:6 |
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NLEJ192209140 |
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| 520 | |a Abstract The enthalpy of mixing of formamide,N-methylformamide,N,N-dimethylformamide, and hexamethylphosphoric triamide with MeCN was measured in the 283–328 K range. The enthalpic coefficients of the binary and ternary interactions between the amide molecules are calculated within the framework of the McMillan-Mayer theory. The contributions to the enthalpy of dissolution due to cavity formation in the solvent (Δcav H 0) and due to solute-solvent interaction (Δint H 0) were determined. The enthalpies of specific and nonspecific solvation of amides in MeCN were calculated. The main contribution to the enthalpy of solvation of formamide andN-methylformamide is from specific interactions, while forN,N-dimethylformamide and hexamethylphosphoric triamide it is from nonspecific interactions. The values obtained are compared with those for solutions of the amides mentioned in water and methanol. | ||
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| 700 | 1 | |a Kolker, A. M. |4 oth | |
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(DE-627)NLEJ192209140 DE-627 ger DE-627 rakwb eng Enthalpy characteristics of dilute solutions of amides in acetonitrile 1993 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Abstract The enthalpy of mixing of formamide,N-methylformamide,N,N-dimethylformamide, and hexamethylphosphoric triamide with MeCN was measured in the 283–328 K range. The enthalpic coefficients of the binary and ternary interactions between the amide molecules are calculated within the framework of the McMillan-Mayer theory. The contributions to the enthalpy of dissolution due to cavity formation in the solvent (Δcav H 0) and due to solute-solvent interaction (Δint H 0) were determined. The enthalpies of specific and nonspecific solvation of amides in MeCN were calculated. The main contribution to the enthalpy of solvation of formamide andN-methylformamide is from specific interactions, while forN,N-dimethylformamide and hexamethylphosphoric triamide it is from nonspecific interactions. The values obtained are compared with those for solutions of the amides mentioned in water and methanol. Springer Online Journal Archives 1860-2002 Kulikov, M. V. oth Kolker, A. M. oth in Russian chemical bulletin 1952 42(1993) vom: Okt., Seite 1652-1657 (DE-627)NLEJ188989994 (DE-600)2037677-7 1573-9171 nnns volume:42 year:1993 month:10 pages:1652-1657 extent:6 http://dx.doi.org/10.1007/BF00697033 GBV_USEFLAG_U ZDB-1-SOJ GBV_NL_ARTICLE AR 42 1993 10 1652-1657 6 |
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(DE-627)NLEJ192209140 DE-627 ger DE-627 rakwb eng Enthalpy characteristics of dilute solutions of amides in acetonitrile 1993 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Abstract The enthalpy of mixing of formamide,N-methylformamide,N,N-dimethylformamide, and hexamethylphosphoric triamide with MeCN was measured in the 283–328 K range. The enthalpic coefficients of the binary and ternary interactions between the amide molecules are calculated within the framework of the McMillan-Mayer theory. The contributions to the enthalpy of dissolution due to cavity formation in the solvent (Δcav H 0) and due to solute-solvent interaction (Δint H 0) were determined. The enthalpies of specific and nonspecific solvation of amides in MeCN were calculated. The main contribution to the enthalpy of solvation of formamide andN-methylformamide is from specific interactions, while forN,N-dimethylformamide and hexamethylphosphoric triamide it is from nonspecific interactions. The values obtained are compared with those for solutions of the amides mentioned in water and methanol. Springer Online Journal Archives 1860-2002 Kulikov, M. V. oth Kolker, A. M. oth in Russian chemical bulletin 1952 42(1993) vom: Okt., Seite 1652-1657 (DE-627)NLEJ188989994 (DE-600)2037677-7 1573-9171 nnns volume:42 year:1993 month:10 pages:1652-1657 extent:6 http://dx.doi.org/10.1007/BF00697033 GBV_USEFLAG_U ZDB-1-SOJ GBV_NL_ARTICLE AR 42 1993 10 1652-1657 6 |
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(DE-627)NLEJ192209140 DE-627 ger DE-627 rakwb eng Enthalpy characteristics of dilute solutions of amides in acetonitrile 1993 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Abstract The enthalpy of mixing of formamide,N-methylformamide,N,N-dimethylformamide, and hexamethylphosphoric triamide with MeCN was measured in the 283–328 K range. The enthalpic coefficients of the binary and ternary interactions between the amide molecules are calculated within the framework of the McMillan-Mayer theory. The contributions to the enthalpy of dissolution due to cavity formation in the solvent (Δcav H 0) and due to solute-solvent interaction (Δint H 0) were determined. The enthalpies of specific and nonspecific solvation of amides in MeCN were calculated. The main contribution to the enthalpy of solvation of formamide andN-methylformamide is from specific interactions, while forN,N-dimethylformamide and hexamethylphosphoric triamide it is from nonspecific interactions. The values obtained are compared with those for solutions of the amides mentioned in water and methanol. Springer Online Journal Archives 1860-2002 Kulikov, M. V. oth Kolker, A. M. oth in Russian chemical bulletin 1952 42(1993) vom: Okt., Seite 1652-1657 (DE-627)NLEJ188989994 (DE-600)2037677-7 1573-9171 nnns volume:42 year:1993 month:10 pages:1652-1657 extent:6 http://dx.doi.org/10.1007/BF00697033 GBV_USEFLAG_U ZDB-1-SOJ GBV_NL_ARTICLE AR 42 1993 10 1652-1657 6 |
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(DE-627)NLEJ192209140 DE-627 ger DE-627 rakwb eng Enthalpy characteristics of dilute solutions of amides in acetonitrile 1993 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Abstract The enthalpy of mixing of formamide,N-methylformamide,N,N-dimethylformamide, and hexamethylphosphoric triamide with MeCN was measured in the 283–328 K range. The enthalpic coefficients of the binary and ternary interactions between the amide molecules are calculated within the framework of the McMillan-Mayer theory. The contributions to the enthalpy of dissolution due to cavity formation in the solvent (Δcav H 0) and due to solute-solvent interaction (Δint H 0) were determined. The enthalpies of specific and nonspecific solvation of amides in MeCN were calculated. The main contribution to the enthalpy of solvation of formamide andN-methylformamide is from specific interactions, while forN,N-dimethylformamide and hexamethylphosphoric triamide it is from nonspecific interactions. The values obtained are compared with those for solutions of the amides mentioned in water and methanol. Springer Online Journal Archives 1860-2002 Kulikov, M. V. oth Kolker, A. M. oth in Russian chemical bulletin 1952 42(1993) vom: Okt., Seite 1652-1657 (DE-627)NLEJ188989994 (DE-600)2037677-7 1573-9171 nnns volume:42 year:1993 month:10 pages:1652-1657 extent:6 http://dx.doi.org/10.1007/BF00697033 GBV_USEFLAG_U ZDB-1-SOJ GBV_NL_ARTICLE AR 42 1993 10 1652-1657 6 |
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(DE-627)NLEJ192209140 DE-627 ger DE-627 rakwb eng Enthalpy characteristics of dilute solutions of amides in acetonitrile 1993 6 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Abstract The enthalpy of mixing of formamide,N-methylformamide,N,N-dimethylformamide, and hexamethylphosphoric triamide with MeCN was measured in the 283–328 K range. The enthalpic coefficients of the binary and ternary interactions between the amide molecules are calculated within the framework of the McMillan-Mayer theory. The contributions to the enthalpy of dissolution due to cavity formation in the solvent (Δcav H 0) and due to solute-solvent interaction (Δint H 0) were determined. The enthalpies of specific and nonspecific solvation of amides in MeCN were calculated. The main contribution to the enthalpy of solvation of formamide andN-methylformamide is from specific interactions, while forN,N-dimethylformamide and hexamethylphosphoric triamide it is from nonspecific interactions. The values obtained are compared with those for solutions of the amides mentioned in water and methanol. Springer Online Journal Archives 1860-2002 Kulikov, M. V. oth Kolker, A. M. oth in Russian chemical bulletin 1952 42(1993) vom: Okt., Seite 1652-1657 (DE-627)NLEJ188989994 (DE-600)2037677-7 1573-9171 nnns volume:42 year:1993 month:10 pages:1652-1657 extent:6 http://dx.doi.org/10.1007/BF00697033 GBV_USEFLAG_U ZDB-1-SOJ GBV_NL_ARTICLE AR 42 1993 10 1652-1657 6 |
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enthalpy characteristics of dilute solutions of amides in acetonitrile |
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Enthalpy characteristics of dilute solutions of amides in acetonitrile |
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Abstract The enthalpy of mixing of formamide,N-methylformamide,N,N-dimethylformamide, and hexamethylphosphoric triamide with MeCN was measured in the 283–328 K range. The enthalpic coefficients of the binary and ternary interactions between the amide molecules are calculated within the framework of the McMillan-Mayer theory. The contributions to the enthalpy of dissolution due to cavity formation in the solvent (Δcav H 0) and due to solute-solvent interaction (Δint H 0) were determined. The enthalpies of specific and nonspecific solvation of amides in MeCN were calculated. The main contribution to the enthalpy of solvation of formamide andN-methylformamide is from specific interactions, while forN,N-dimethylformamide and hexamethylphosphoric triamide it is from nonspecific interactions. The values obtained are compared with those for solutions of the amides mentioned in water and methanol. |
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Abstract The enthalpy of mixing of formamide,N-methylformamide,N,N-dimethylformamide, and hexamethylphosphoric triamide with MeCN was measured in the 283–328 K range. The enthalpic coefficients of the binary and ternary interactions between the amide molecules are calculated within the framework of the McMillan-Mayer theory. The contributions to the enthalpy of dissolution due to cavity formation in the solvent (Δcav H 0) and due to solute-solvent interaction (Δint H 0) were determined. The enthalpies of specific and nonspecific solvation of amides in MeCN were calculated. The main contribution to the enthalpy of solvation of formamide andN-methylformamide is from specific interactions, while forN,N-dimethylformamide and hexamethylphosphoric triamide it is from nonspecific interactions. The values obtained are compared with those for solutions of the amides mentioned in water and methanol. |
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Abstract The enthalpy of mixing of formamide,N-methylformamide,N,N-dimethylformamide, and hexamethylphosphoric triamide with MeCN was measured in the 283–328 K range. The enthalpic coefficients of the binary and ternary interactions between the amide molecules are calculated within the framework of the McMillan-Mayer theory. The contributions to the enthalpy of dissolution due to cavity formation in the solvent (Δcav H 0) and due to solute-solvent interaction (Δint H 0) were determined. The enthalpies of specific and nonspecific solvation of amides in MeCN were calculated. The main contribution to the enthalpy of solvation of formamide andN-methylformamide is from specific interactions, while forN,N-dimethylformamide and hexamethylphosphoric triamide it is from nonspecific interactions. The values obtained are compared with those for solutions of the amides mentioned in water and methanol. |
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