Ionic conductivity and lithium electrode stability in Hydrin: LiBF4 elastomers
Abstract Three commercial elastomers, Hydrin C, Hydrin H and Hydrin T, which contain ethylene oxide and epichlorohydrin repeat units, have been investigated as polymer electrolytes in contact with lithium electrode. The influence of polyethylene glycol and fine particles of zeolite on ionic conducti...
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1994 |
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| Umfang: |
7 |
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| Reproduktion: |
Springer Online Journal Archives 1860-2002 |
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| Übergeordnetes Werk: |
in: Journal of applied electrochemistry - 1971, 24(1994) vom: Okt., Seite 1066-1072 |
| Übergeordnetes Werk: |
volume:24 ; year:1994 ; month:10 ; pages:1066-1072 ; extent:7 |
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NLEJ193305364 |
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| 245 | 1 | 0 | |a Ionic conductivity and lithium electrode stability in Hydrin: LiBF4 elastomers |
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| 520 | |a Abstract Three commercial elastomers, Hydrin C, Hydrin H and Hydrin T, which contain ethylene oxide and epichlorohydrin repeat units, have been investigated as polymer electrolytes in contact with lithium electrode. The influence of polyethylene glycol and fine particles of zeolite on ionic conductivity of Hydrin-LiBF4 electrolytes and the exchange current density of the lithium electrode reaction has been studied by using impedance spectroscopy and cyclic voltammetry. The specific conductivity of the elastomeric electrolyte is about 10−5 S cm−1 at room temperature when polyethylene glycol is present. But the mechanical stability of the film is less. The addition of zeolite particles to the elastomers also improves the specific conductivity. When present in low concentrations, the zeolite particles show catalytic effect on the electrochemical reaction at lithium electrode at ambient temperature. The lithium electrode reaction is reversible and the electrolyte possesses good electrochemical stability. | ||
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| 700 | 1 | |a Marsh, R. A. |4 oth | |
| 700 | 1 | |a Kumar, B. |4 oth | |
| 700 | 1 | |a Sircar, A. K. |4 oth | |
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(DE-627)NLEJ193305364 DE-627 ger DE-627 rakwb eng Ionic conductivity and lithium electrode stability in Hydrin: LiBF4 elastomers 1994 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Abstract Three commercial elastomers, Hydrin C, Hydrin H and Hydrin T, which contain ethylene oxide and epichlorohydrin repeat units, have been investigated as polymer electrolytes in contact with lithium electrode. The influence of polyethylene glycol and fine particles of zeolite on ionic conductivity of Hydrin-LiBF4 electrolytes and the exchange current density of the lithium electrode reaction has been studied by using impedance spectroscopy and cyclic voltammetry. The specific conductivity of the elastomeric electrolyte is about 10−5 S cm−1 at room temperature when polyethylene glycol is present. But the mechanical stability of the film is less. The addition of zeolite particles to the elastomers also improves the specific conductivity. When present in low concentrations, the zeolite particles show catalytic effect on the electrochemical reaction at lithium electrode at ambient temperature. The lithium electrode reaction is reversible and the electrolyte possesses good electrochemical stability. Springer Online Journal Archives 1860-2002 Munichandraiah, N. oth Scanlon, L. G. oth Marsh, R. A. oth Kumar, B. oth Sircar, A. K. oth in Journal of applied electrochemistry 1971 24(1994) vom: Okt., Seite 1066-1072 (DE-627)NLEJ188992626 (DE-600)1491094-9 1572-8838 nnns volume:24 year:1994 month:10 pages:1066-1072 extent:7 http://dx.doi.org/10.1007/BF00241200 GBV_USEFLAG_U ZDB-1-SOJ GBV_NL_ARTICLE AR 24 1994 10 1066-1072 7 |
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(DE-627)NLEJ193305364 DE-627 ger DE-627 rakwb eng Ionic conductivity and lithium electrode stability in Hydrin: LiBF4 elastomers 1994 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Abstract Three commercial elastomers, Hydrin C, Hydrin H and Hydrin T, which contain ethylene oxide and epichlorohydrin repeat units, have been investigated as polymer electrolytes in contact with lithium electrode. The influence of polyethylene glycol and fine particles of zeolite on ionic conductivity of Hydrin-LiBF4 electrolytes and the exchange current density of the lithium electrode reaction has been studied by using impedance spectroscopy and cyclic voltammetry. The specific conductivity of the elastomeric electrolyte is about 10−5 S cm−1 at room temperature when polyethylene glycol is present. But the mechanical stability of the film is less. The addition of zeolite particles to the elastomers also improves the specific conductivity. When present in low concentrations, the zeolite particles show catalytic effect on the electrochemical reaction at lithium electrode at ambient temperature. The lithium electrode reaction is reversible and the electrolyte possesses good electrochemical stability. Springer Online Journal Archives 1860-2002 Munichandraiah, N. oth Scanlon, L. G. oth Marsh, R. A. oth Kumar, B. oth Sircar, A. K. oth in Journal of applied electrochemistry 1971 24(1994) vom: Okt., Seite 1066-1072 (DE-627)NLEJ188992626 (DE-600)1491094-9 1572-8838 nnns volume:24 year:1994 month:10 pages:1066-1072 extent:7 http://dx.doi.org/10.1007/BF00241200 GBV_USEFLAG_U ZDB-1-SOJ GBV_NL_ARTICLE AR 24 1994 10 1066-1072 7 |
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(DE-627)NLEJ193305364 DE-627 ger DE-627 rakwb eng Ionic conductivity and lithium electrode stability in Hydrin: LiBF4 elastomers 1994 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Abstract Three commercial elastomers, Hydrin C, Hydrin H and Hydrin T, which contain ethylene oxide and epichlorohydrin repeat units, have been investigated as polymer electrolytes in contact with lithium electrode. The influence of polyethylene glycol and fine particles of zeolite on ionic conductivity of Hydrin-LiBF4 electrolytes and the exchange current density of the lithium electrode reaction has been studied by using impedance spectroscopy and cyclic voltammetry. The specific conductivity of the elastomeric electrolyte is about 10−5 S cm−1 at room temperature when polyethylene glycol is present. But the mechanical stability of the film is less. The addition of zeolite particles to the elastomers also improves the specific conductivity. When present in low concentrations, the zeolite particles show catalytic effect on the electrochemical reaction at lithium electrode at ambient temperature. The lithium electrode reaction is reversible and the electrolyte possesses good electrochemical stability. Springer Online Journal Archives 1860-2002 Munichandraiah, N. oth Scanlon, L. G. oth Marsh, R. A. oth Kumar, B. oth Sircar, A. K. oth in Journal of applied electrochemistry 1971 24(1994) vom: Okt., Seite 1066-1072 (DE-627)NLEJ188992626 (DE-600)1491094-9 1572-8838 nnns volume:24 year:1994 month:10 pages:1066-1072 extent:7 http://dx.doi.org/10.1007/BF00241200 GBV_USEFLAG_U ZDB-1-SOJ GBV_NL_ARTICLE AR 24 1994 10 1066-1072 7 |
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(DE-627)NLEJ193305364 DE-627 ger DE-627 rakwb eng Ionic conductivity and lithium electrode stability in Hydrin: LiBF4 elastomers 1994 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Abstract Three commercial elastomers, Hydrin C, Hydrin H and Hydrin T, which contain ethylene oxide and epichlorohydrin repeat units, have been investigated as polymer electrolytes in contact with lithium electrode. The influence of polyethylene glycol and fine particles of zeolite on ionic conductivity of Hydrin-LiBF4 electrolytes and the exchange current density of the lithium electrode reaction has been studied by using impedance spectroscopy and cyclic voltammetry. The specific conductivity of the elastomeric electrolyte is about 10−5 S cm−1 at room temperature when polyethylene glycol is present. But the mechanical stability of the film is less. The addition of zeolite particles to the elastomers also improves the specific conductivity. When present in low concentrations, the zeolite particles show catalytic effect on the electrochemical reaction at lithium electrode at ambient temperature. The lithium electrode reaction is reversible and the electrolyte possesses good electrochemical stability. Springer Online Journal Archives 1860-2002 Munichandraiah, N. oth Scanlon, L. G. oth Marsh, R. A. oth Kumar, B. oth Sircar, A. K. oth in Journal of applied electrochemistry 1971 24(1994) vom: Okt., Seite 1066-1072 (DE-627)NLEJ188992626 (DE-600)1491094-9 1572-8838 nnns volume:24 year:1994 month:10 pages:1066-1072 extent:7 http://dx.doi.org/10.1007/BF00241200 GBV_USEFLAG_U ZDB-1-SOJ GBV_NL_ARTICLE AR 24 1994 10 1066-1072 7 |
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(DE-627)NLEJ193305364 DE-627 ger DE-627 rakwb eng Ionic conductivity and lithium electrode stability in Hydrin: LiBF4 elastomers 1994 7 nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Abstract Three commercial elastomers, Hydrin C, Hydrin H and Hydrin T, which contain ethylene oxide and epichlorohydrin repeat units, have been investigated as polymer electrolytes in contact with lithium electrode. The influence of polyethylene glycol and fine particles of zeolite on ionic conductivity of Hydrin-LiBF4 electrolytes and the exchange current density of the lithium electrode reaction has been studied by using impedance spectroscopy and cyclic voltammetry. The specific conductivity of the elastomeric electrolyte is about 10−5 S cm−1 at room temperature when polyethylene glycol is present. But the mechanical stability of the film is less. The addition of zeolite particles to the elastomers also improves the specific conductivity. When present in low concentrations, the zeolite particles show catalytic effect on the electrochemical reaction at lithium electrode at ambient temperature. The lithium electrode reaction is reversible and the electrolyte possesses good electrochemical stability. Springer Online Journal Archives 1860-2002 Munichandraiah, N. oth Scanlon, L. G. oth Marsh, R. A. oth Kumar, B. oth Sircar, A. K. oth in Journal of applied electrochemistry 1971 24(1994) vom: Okt., Seite 1066-1072 (DE-627)NLEJ188992626 (DE-600)1491094-9 1572-8838 nnns volume:24 year:1994 month:10 pages:1066-1072 extent:7 http://dx.doi.org/10.1007/BF00241200 GBV_USEFLAG_U ZDB-1-SOJ GBV_NL_ARTICLE AR 24 1994 10 1066-1072 7 |
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ionic conductivity and lithium electrode stability in hydrin: libf4 elastomers |
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Ionic conductivity and lithium electrode stability in Hydrin: LiBF4 elastomers |
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Abstract Three commercial elastomers, Hydrin C, Hydrin H and Hydrin T, which contain ethylene oxide and epichlorohydrin repeat units, have been investigated as polymer electrolytes in contact with lithium electrode. The influence of polyethylene glycol and fine particles of zeolite on ionic conductivity of Hydrin-LiBF4 electrolytes and the exchange current density of the lithium electrode reaction has been studied by using impedance spectroscopy and cyclic voltammetry. The specific conductivity of the elastomeric electrolyte is about 10−5 S cm−1 at room temperature when polyethylene glycol is present. But the mechanical stability of the film is less. The addition of zeolite particles to the elastomers also improves the specific conductivity. When present in low concentrations, the zeolite particles show catalytic effect on the electrochemical reaction at lithium electrode at ambient temperature. The lithium electrode reaction is reversible and the electrolyte possesses good electrochemical stability. |
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Abstract Three commercial elastomers, Hydrin C, Hydrin H and Hydrin T, which contain ethylene oxide and epichlorohydrin repeat units, have been investigated as polymer electrolytes in contact with lithium electrode. The influence of polyethylene glycol and fine particles of zeolite on ionic conductivity of Hydrin-LiBF4 electrolytes and the exchange current density of the lithium electrode reaction has been studied by using impedance spectroscopy and cyclic voltammetry. The specific conductivity of the elastomeric electrolyte is about 10−5 S cm−1 at room temperature when polyethylene glycol is present. But the mechanical stability of the film is less. The addition of zeolite particles to the elastomers also improves the specific conductivity. When present in low concentrations, the zeolite particles show catalytic effect on the electrochemical reaction at lithium electrode at ambient temperature. The lithium electrode reaction is reversible and the electrolyte possesses good electrochemical stability. |
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Abstract Three commercial elastomers, Hydrin C, Hydrin H and Hydrin T, which contain ethylene oxide and epichlorohydrin repeat units, have been investigated as polymer electrolytes in contact with lithium electrode. The influence of polyethylene glycol and fine particles of zeolite on ionic conductivity of Hydrin-LiBF4 electrolytes and the exchange current density of the lithium electrode reaction has been studied by using impedance spectroscopy and cyclic voltammetry. The specific conductivity of the elastomeric electrolyte is about 10−5 S cm−1 at room temperature when polyethylene glycol is present. But the mechanical stability of the film is less. The addition of zeolite particles to the elastomers also improves the specific conductivity. When present in low concentrations, the zeolite particles show catalytic effect on the electrochemical reaction at lithium electrode at ambient temperature. The lithium electrode reaction is reversible and the electrolyte possesses good electrochemical stability. |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">NLEJ193305364</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20210707205109.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">070526s1994 xx |||||o 00| ||eng c</controlfield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)NLEJ193305364</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Ionic conductivity and lithium electrode stability in Hydrin: LiBF4 elastomers</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">1994</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">7</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">z</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zu</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract Three commercial elastomers, Hydrin C, Hydrin H and Hydrin T, which contain ethylene oxide and epichlorohydrin repeat units, have been investigated as polymer electrolytes in contact with lithium electrode. The influence of polyethylene glycol and fine particles of zeolite on ionic conductivity of Hydrin-LiBF4 electrolytes and the exchange current density of the lithium electrode reaction has been studied by using impedance spectroscopy and cyclic voltammetry. The specific conductivity of the elastomeric electrolyte is about 10−5 S cm−1 at room temperature when polyethylene glycol is present. But the mechanical stability of the film is less. The addition of zeolite particles to the elastomers also improves the specific conductivity. When present in low concentrations, the zeolite particles show catalytic effect on the electrochemical reaction at lithium electrode at ambient temperature. The lithium electrode reaction is reversible and the electrolyte possesses good electrochemical stability.</subfield></datafield><datafield tag="533" ind1=" " ind2=" "><subfield code="f">Springer Online Journal Archives 1860-2002</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Munichandraiah, N.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Scanlon, L. G.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Marsh, R. A.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kumar, B.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Sircar, A. K.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">in</subfield><subfield code="t">Journal of applied electrochemistry</subfield><subfield code="d">1971</subfield><subfield code="g">24(1994) vom: Okt., Seite 1066-1072</subfield><subfield code="w">(DE-627)NLEJ188992626</subfield><subfield code="w">(DE-600)1491094-9</subfield><subfield code="x">1572-8838</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:24</subfield><subfield code="g">year:1994</subfield><subfield code="g">month:10</subfield><subfield code="g">pages:1066-1072</subfield><subfield code="g">extent:7</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">http://dx.doi.org/10.1007/BF00241200</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">ZDB-1-SOJ</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_NL_ARTICLE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">24</subfield><subfield code="j">1994</subfield><subfield code="c">10</subfield><subfield code="h">1066-1072</subfield><subfield code="g">7</subfield></datafield></record></collection>
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