Origin of the Difference in Phase Transition Behavior betweenTwoType of All-Organic Radical Liquid Crystals
We have synthesized two types of all-organic radical liquid crystalline (LC) compounds,trans-2-alkoxyphenyl-5-[4-(4-alkoxybenzenecarbonyloxy)phenyl]-2,5-dimethylpyrrolidine-1-oxy(1) and 4-alkoxyphenyl trans-4-[5-(4-alkoxyphenyl)-2,5-dimethylpyrrolidine-1-oxy-2-yl]benzoate(2) and have fully character...
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| Autor*in: |
Uchida, Yoshiaki [verfasserIn] |
|---|
| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
s.l. Stafa-Zurich, Switzerland: 2008 |
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| Anmerkung: |
https://getinfo.de/app/details?id=transtech:doi~10.4028%252Fwww.scientific.net%252FAST.55.42 |
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| Umfang: |
Online-Ressource (4 pages) |
| Reproduktion: |
Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008 |
|---|---|
| Übergeordnetes Werk: |
In: Advances in science and technology - [S.l.] : Scientific.Net, 1984, Vol. 55 (Sept. 2008), p. 42-45 |
| Übergeordnetes Werk: |
volume:55 ; year:2008 ; pages:42-45 |
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10.4028/www.scientific.net/AST.55.42 |
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| 520 | |a We have synthesized two types of all-organic radical liquid crystalline (LC) compounds,trans-2-alkoxyphenyl-5-[4-(4-alkoxybenzenecarbonyloxy)phenyl]-2,5-dimethylpyrrolidine-1-oxy(1) and 4-alkoxyphenyl trans-4-[5-(4-alkoxyphenyl)-2,5-dimethylpyrrolidine-1-oxy-2-yl]benzoate(2) and have fully characterized their LC properties. Although the only difference in the molecularstructure between 1 and 2 is the orientation of a binding group connecting the core portion and oneside-chain (-OCO- and -COO- for 1 and 2), the racemic or enantiomerically enriched 2 showed anSmA phase, or SmA* and TGBA* phases, which were not observed for 1, besides N and SmC, or N*and SmC* phases, respectively. Here we discuss the origin of these differences on the basis of theircrystal structures determined by X-ray crystallographic analysis | ||
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10.4028/www.scientific.net/AST.55.42 doi (DE-627)NLEJ238392317 DE-627 ger DE-627 rakwb eng Uchida, Yoshiaki verfasserin aut Origin of the Difference in Phase Transition Behavior betweenTwoType of All-Organic Radical Liquid Crystals s.l. Stafa-Zurich, Switzerland 2008 Online-Ressource (4 pages) nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier https://getinfo.de/app/details?id=transtech:doi~10.4028%252Fwww.scientific.net%252FAST.55.42 We have synthesized two types of all-organic radical liquid crystalline (LC) compounds,trans-2-alkoxyphenyl-5-[4-(4-alkoxybenzenecarbonyloxy)phenyl]-2,5-dimethylpyrrolidine-1-oxy(1) and 4-alkoxyphenyl trans-4-[5-(4-alkoxyphenyl)-2,5-dimethylpyrrolidine-1-oxy-2-yl]benzoate(2) and have fully characterized their LC properties. Although the only difference in the molecularstructure between 1 and 2 is the orientation of a binding group connecting the core portion and oneside-chain (-OCO- and -COO- for 1 and 2), the racemic or enantiomerically enriched 2 showed anSmA phase, or SmA* and TGBA* phases, which were not observed for 1, besides N and SmC, or N*and SmC* phases, respectively. Here we discuss the origin of these differences on the basis of theircrystal structures determined by X-ray crystallographic analysis Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008 Tamura, Rui oth Ikuma, Naohiko oth Shimono, Satoshi oth Takahashi, Hiroki oth Yamauchi, Jun oth In Advances in science and technology [S.l.] : Scientific.Net, 1984 Vol. 55 (Sept. 2008), p. 42-45 Online-Ressource (DE-627)NLEJ237794942 (DE-600)2413130-1 1662-0356 volume:55 year:2008 pages:42-45 https://www.tib.eu/de/openurl/search/?pid=doi:10.4028/www.scientific.net/AST.55.42 text/html Deutschlandweit zugänglich Volltext https://doi.org//10.4028/www.scientific.net/AST.55.42 text/html Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-SNT GBV_NL_ARTICLE AR 55 2008 42-45 Vol. 55 (Sept. 2008), p. 42-45 |
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10.4028/www.scientific.net/AST.55.42 doi (DE-627)NLEJ238392317 DE-627 ger DE-627 rakwb eng Uchida, Yoshiaki verfasserin aut Origin of the Difference in Phase Transition Behavior betweenTwoType of All-Organic Radical Liquid Crystals s.l. Stafa-Zurich, Switzerland 2008 Online-Ressource (4 pages) nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier https://getinfo.de/app/details?id=transtech:doi~10.4028%252Fwww.scientific.net%252FAST.55.42 We have synthesized two types of all-organic radical liquid crystalline (LC) compounds,trans-2-alkoxyphenyl-5-[4-(4-alkoxybenzenecarbonyloxy)phenyl]-2,5-dimethylpyrrolidine-1-oxy(1) and 4-alkoxyphenyl trans-4-[5-(4-alkoxyphenyl)-2,5-dimethylpyrrolidine-1-oxy-2-yl]benzoate(2) and have fully characterized their LC properties. Although the only difference in the molecularstructure between 1 and 2 is the orientation of a binding group connecting the core portion and oneside-chain (-OCO- and -COO- for 1 and 2), the racemic or enantiomerically enriched 2 showed anSmA phase, or SmA* and TGBA* phases, which were not observed for 1, besides N and SmC, or N*and SmC* phases, respectively. Here we discuss the origin of these differences on the basis of theircrystal structures determined by X-ray crystallographic analysis Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008 Tamura, Rui oth Ikuma, Naohiko oth Shimono, Satoshi oth Takahashi, Hiroki oth Yamauchi, Jun oth In Advances in science and technology [S.l.] : Scientific.Net, 1984 Vol. 55 (Sept. 2008), p. 42-45 Online-Ressource (DE-627)NLEJ237794942 (DE-600)2413130-1 1662-0356 volume:55 year:2008 pages:42-45 https://www.tib.eu/de/openurl/search/?pid=doi:10.4028/www.scientific.net/AST.55.42 text/html Deutschlandweit zugänglich Volltext https://doi.org//10.4028/www.scientific.net/AST.55.42 text/html Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-SNT GBV_NL_ARTICLE AR 55 2008 42-45 Vol. 55 (Sept. 2008), p. 42-45 |
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10.4028/www.scientific.net/AST.55.42 doi (DE-627)NLEJ238392317 DE-627 ger DE-627 rakwb eng Uchida, Yoshiaki verfasserin aut Origin of the Difference in Phase Transition Behavior betweenTwoType of All-Organic Radical Liquid Crystals s.l. Stafa-Zurich, Switzerland 2008 Online-Ressource (4 pages) nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier https://getinfo.de/app/details?id=transtech:doi~10.4028%252Fwww.scientific.net%252FAST.55.42 We have synthesized two types of all-organic radical liquid crystalline (LC) compounds,trans-2-alkoxyphenyl-5-[4-(4-alkoxybenzenecarbonyloxy)phenyl]-2,5-dimethylpyrrolidine-1-oxy(1) and 4-alkoxyphenyl trans-4-[5-(4-alkoxyphenyl)-2,5-dimethylpyrrolidine-1-oxy-2-yl]benzoate(2) and have fully characterized their LC properties. Although the only difference in the molecularstructure between 1 and 2 is the orientation of a binding group connecting the core portion and oneside-chain (-OCO- and -COO- for 1 and 2), the racemic or enantiomerically enriched 2 showed anSmA phase, or SmA* and TGBA* phases, which were not observed for 1, besides N and SmC, or N*and SmC* phases, respectively. Here we discuss the origin of these differences on the basis of theircrystal structures determined by X-ray crystallographic analysis Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008 Tamura, Rui oth Ikuma, Naohiko oth Shimono, Satoshi oth Takahashi, Hiroki oth Yamauchi, Jun oth In Advances in science and technology [S.l.] : Scientific.Net, 1984 Vol. 55 (Sept. 2008), p. 42-45 Online-Ressource (DE-627)NLEJ237794942 (DE-600)2413130-1 1662-0356 volume:55 year:2008 pages:42-45 https://www.tib.eu/de/openurl/search/?pid=doi:10.4028/www.scientific.net/AST.55.42 text/html Deutschlandweit zugänglich Volltext https://doi.org//10.4028/www.scientific.net/AST.55.42 text/html Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-SNT GBV_NL_ARTICLE AR 55 2008 42-45 Vol. 55 (Sept. 2008), p. 42-45 |
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10.4028/www.scientific.net/AST.55.42 doi (DE-627)NLEJ238392317 DE-627 ger DE-627 rakwb eng Uchida, Yoshiaki verfasserin aut Origin of the Difference in Phase Transition Behavior betweenTwoType of All-Organic Radical Liquid Crystals s.l. Stafa-Zurich, Switzerland 2008 Online-Ressource (4 pages) nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier https://getinfo.de/app/details?id=transtech:doi~10.4028%252Fwww.scientific.net%252FAST.55.42 We have synthesized two types of all-organic radical liquid crystalline (LC) compounds,trans-2-alkoxyphenyl-5-[4-(4-alkoxybenzenecarbonyloxy)phenyl]-2,5-dimethylpyrrolidine-1-oxy(1) and 4-alkoxyphenyl trans-4-[5-(4-alkoxyphenyl)-2,5-dimethylpyrrolidine-1-oxy-2-yl]benzoate(2) and have fully characterized their LC properties. Although the only difference in the molecularstructure between 1 and 2 is the orientation of a binding group connecting the core portion and oneside-chain (-OCO- and -COO- for 1 and 2), the racemic or enantiomerically enriched 2 showed anSmA phase, or SmA* and TGBA* phases, which were not observed for 1, besides N and SmC, or N*and SmC* phases, respectively. Here we discuss the origin of these differences on the basis of theircrystal structures determined by X-ray crystallographic analysis Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008 Tamura, Rui oth Ikuma, Naohiko oth Shimono, Satoshi oth Takahashi, Hiroki oth Yamauchi, Jun oth In Advances in science and technology [S.l.] : Scientific.Net, 1984 Vol. 55 (Sept. 2008), p. 42-45 Online-Ressource (DE-627)NLEJ237794942 (DE-600)2413130-1 1662-0356 volume:55 year:2008 pages:42-45 https://www.tib.eu/de/openurl/search/?pid=doi:10.4028/www.scientific.net/AST.55.42 text/html Deutschlandweit zugänglich Volltext https://doi.org//10.4028/www.scientific.net/AST.55.42 text/html Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-SNT GBV_NL_ARTICLE AR 55 2008 42-45 Vol. 55 (Sept. 2008), p. 42-45 |
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10.4028/www.scientific.net/AST.55.42 doi (DE-627)NLEJ238392317 DE-627 ger DE-627 rakwb eng Uchida, Yoshiaki verfasserin aut Origin of the Difference in Phase Transition Behavior betweenTwoType of All-Organic Radical Liquid Crystals s.l. Stafa-Zurich, Switzerland 2008 Online-Ressource (4 pages) nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier https://getinfo.de/app/details?id=transtech:doi~10.4028%252Fwww.scientific.net%252FAST.55.42 We have synthesized two types of all-organic radical liquid crystalline (LC) compounds,trans-2-alkoxyphenyl-5-[4-(4-alkoxybenzenecarbonyloxy)phenyl]-2,5-dimethylpyrrolidine-1-oxy(1) and 4-alkoxyphenyl trans-4-[5-(4-alkoxyphenyl)-2,5-dimethylpyrrolidine-1-oxy-2-yl]benzoate(2) and have fully characterized their LC properties. Although the only difference in the molecularstructure between 1 and 2 is the orientation of a binding group connecting the core portion and oneside-chain (-OCO- and -COO- for 1 and 2), the racemic or enantiomerically enriched 2 showed anSmA phase, or SmA* and TGBA* phases, which were not observed for 1, besides N and SmC, or N*and SmC* phases, respectively. Here we discuss the origin of these differences on the basis of theircrystal structures determined by X-ray crystallographic analysis Scientific.Net: Materials Science & Technology / Trans Tech Publications Archiv 1984-2008 Tamura, Rui oth Ikuma, Naohiko oth Shimono, Satoshi oth Takahashi, Hiroki oth Yamauchi, Jun oth In Advances in science and technology [S.l.] : Scientific.Net, 1984 Vol. 55 (Sept. 2008), p. 42-45 Online-Ressource (DE-627)NLEJ237794942 (DE-600)2413130-1 1662-0356 volume:55 year:2008 pages:42-45 https://www.tib.eu/de/openurl/search/?pid=doi:10.4028/www.scientific.net/AST.55.42 text/html Deutschlandweit zugänglich Volltext https://doi.org//10.4028/www.scientific.net/AST.55.42 text/html Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-SNT GBV_NL_ARTICLE AR 55 2008 42-45 Vol. 55 (Sept. 2008), p. 42-45 |
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Origin of the Difference in Phase Transition Behavior betweenTwoType of All-Organic Radical Liquid Crystals |
| abstract |
We have synthesized two types of all-organic radical liquid crystalline (LC) compounds,trans-2-alkoxyphenyl-5-[4-(4-alkoxybenzenecarbonyloxy)phenyl]-2,5-dimethylpyrrolidine-1-oxy(1) and 4-alkoxyphenyl trans-4-[5-(4-alkoxyphenyl)-2,5-dimethylpyrrolidine-1-oxy-2-yl]benzoate(2) and have fully characterized their LC properties. Although the only difference in the molecularstructure between 1 and 2 is the orientation of a binding group connecting the core portion and oneside-chain (-OCO- and -COO- for 1 and 2), the racemic or enantiomerically enriched 2 showed anSmA phase, or SmA* and TGBA* phases, which were not observed for 1, besides N and SmC, or N*and SmC* phases, respectively. Here we discuss the origin of these differences on the basis of theircrystal structures determined by X-ray crystallographic analysis https://getinfo.de/app/details?id=transtech:doi~10.4028%252Fwww.scientific.net%252FAST.55.42 |
| abstractGer |
We have synthesized two types of all-organic radical liquid crystalline (LC) compounds,trans-2-alkoxyphenyl-5-[4-(4-alkoxybenzenecarbonyloxy)phenyl]-2,5-dimethylpyrrolidine-1-oxy(1) and 4-alkoxyphenyl trans-4-[5-(4-alkoxyphenyl)-2,5-dimethylpyrrolidine-1-oxy-2-yl]benzoate(2) and have fully characterized their LC properties. Although the only difference in the molecularstructure between 1 and 2 is the orientation of a binding group connecting the core portion and oneside-chain (-OCO- and -COO- for 1 and 2), the racemic or enantiomerically enriched 2 showed anSmA phase, or SmA* and TGBA* phases, which were not observed for 1, besides N and SmC, or N*and SmC* phases, respectively. Here we discuss the origin of these differences on the basis of theircrystal structures determined by X-ray crystallographic analysis https://getinfo.de/app/details?id=transtech:doi~10.4028%252Fwww.scientific.net%252FAST.55.42 |
| abstract_unstemmed |
We have synthesized two types of all-organic radical liquid crystalline (LC) compounds,trans-2-alkoxyphenyl-5-[4-(4-alkoxybenzenecarbonyloxy)phenyl]-2,5-dimethylpyrrolidine-1-oxy(1) and 4-alkoxyphenyl trans-4-[5-(4-alkoxyphenyl)-2,5-dimethylpyrrolidine-1-oxy-2-yl]benzoate(2) and have fully characterized their LC properties. Although the only difference in the molecularstructure between 1 and 2 is the orientation of a binding group connecting the core portion and oneside-chain (-OCO- and -COO- for 1 and 2), the racemic or enantiomerically enriched 2 showed anSmA phase, or SmA* and TGBA* phases, which were not observed for 1, besides N and SmC, or N*and SmC* phases, respectively. Here we discuss the origin of these differences on the basis of theircrystal structures determined by X-ray crystallographic analysis https://getinfo.de/app/details?id=transtech:doi~10.4028%252Fwww.scientific.net%252FAST.55.42 |
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| title_short |
Origin of the Difference in Phase Transition Behavior betweenTwoType of All-Organic Radical Liquid Crystals |
| url |
https://www.tib.eu/de/openurl/search/?pid=doi:10.4028/www.scientific.net/AST.55.42 https://doi.org//10.4028/www.scientific.net/AST.55.42 |
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| author2 |
Tamura, Rui Ikuma, Naohiko Shimono, Satoshi Takahashi, Hiroki Yamauchi, Jun |
| author2Str |
Tamura, Rui Ikuma, Naohiko Shimono, Satoshi Takahashi, Hiroki Yamauchi, Jun |
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10.4028/www.scientific.net/AST.55.42 |
| up_date |
2024-07-06T05:01:38.069Z |
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7.402647 |