Colloidal Processing and Ionic Conductivity of Fine-Grained Cupric-Oxide-Doped Tetragonal Zirconia
CuO-doped tetragonal ZrO2 (3-mol%-Y2O3-doped tetragonal zirconia, 3Y-TZ) green bodies were consolidated from zirconia slurries with Cu2+ by a pressure filtration method. The slurries were prepared by dispersing 3Y-TZ powder in a solution of [NH4OH + NH3NO3] = 0.1M at pH 11 and adding an appropriate...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Sakka, Yoshio [verfasserIn] Ozawa, Kiyoshi [verfasserIn] Uchikoshi, Tetsuo [verfasserIn] |
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| Format: |
E-Artikel |
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| Erschienen: |
Westerville, Ohio: American Ceramics Society ; 2001 |
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| Schlagwörter: |
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| Umfang: |
Online-Ressource |
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| Reproduktion: |
2004 ; Blackwell Publishing Journal Backfiles 1879-2005 |
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| Übergeordnetes Werk: |
In: Journal of the American Ceramic Society - American Ceramic Society ; GKD-ID: 6113X, Oxford [u.a.] : Wiley-Blackwell, 1918, 84(2001), 9, Seite 0 |
| Übergeordnetes Werk: |
volume:84 ; year:2001 ; number:9 ; pages:0 |
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| DOI / URN: |
10.1111/j.1151-2916.2001.tb00972.x |
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| 520 | |a CuO-doped tetragonal ZrO2 (3-mol%-Y2O3-doped tetragonal zirconia, 3Y-TZ) green bodies were consolidated from zirconia slurries with Cu2+ by a pressure filtration method. The slurries were prepared by dispersing 3Y-TZ powder in a solution of [NH4OH + NH3NO3] = 0.1M at pH 11 and adding an appropriate amount of Cu(NO3)·3H2O solution. Green bodies with narrow pore-size distribution were obtained after cold isostatically pressing the pressure-filtrated bodies. Small amounts of CuO-doped samples were densified fully at 1200°C. The size of a grain of 0.16-mol%-CuO-doped 3Y-TZ sintered at 1200°C was 84 nm. Bulk and grain-boundary conductivities are measured by a complex impedance method. The bulk conductivity of the CuO-doped 3Y-TZ was almost equal to the undoped one, but the grain-boundary conductivity decreased with CuO addition. | ||
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10.1111/j.1151-2916.2001.tb00972.x doi (DE-627)NLEJ243464746 DE-627 ger DE-627 rakwb Sakka, Yoshio verfasserin aut Colloidal Processing and Ionic Conductivity of Fine-Grained Cupric-Oxide-Doped Tetragonal Zirconia Westerville, Ohio American Ceramics Society 2001 Online-Ressource nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier CuO-doped tetragonal ZrO2 (3-mol%-Y2O3-doped tetragonal zirconia, 3Y-TZ) green bodies were consolidated from zirconia slurries with Cu2+ by a pressure filtration method. The slurries were prepared by dispersing 3Y-TZ powder in a solution of [NH4OH + NH3NO3] = 0.1M at pH 11 and adding an appropriate amount of Cu(NO3)·3H2O solution. Green bodies with narrow pore-size distribution were obtained after cold isostatically pressing the pressure-filtrated bodies. Small amounts of CuO-doped samples were densified fully at 1200°C. The size of a grain of 0.16-mol%-CuO-doped 3Y-TZ sintered at 1200°C was 84 nm. Bulk and grain-boundary conductivities are measured by a complex impedance method. The bulk conductivity of the CuO-doped 3Y-TZ was almost equal to the undoped one, but the grain-boundary conductivity decreased with CuO addition. 2004 Blackwell Publishing Journal Backfiles 1879-2005 |2004|||||||||| zirconia: tetragonal polycrystals Ozawa, Kiyoshi verfasserin aut Uchikoshi, Tetsuo verfasserin aut Hiraga, Keijiro oth In American Ceramic Society ; GKD-ID: 6113X Journal of the American Ceramic Society Oxford [u.a.] : Wiley-Blackwell, 1918 84(2001), 9, Seite 0 Online-Ressource (DE-627)NLEJ243927835 (DE-600)2008170-4 1551-2916 nnns volume:84 year:2001 number:9 pages:0 http://dx.doi.org/10.1111/j.1151-2916.2001.tb00972.x text/html Verlag Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-DJB GBV_NL_ARTICLE AR 84 2001 9 0 |
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10.1111/j.1151-2916.2001.tb00972.x doi (DE-627)NLEJ243464746 DE-627 ger DE-627 rakwb Sakka, Yoshio verfasserin aut Colloidal Processing and Ionic Conductivity of Fine-Grained Cupric-Oxide-Doped Tetragonal Zirconia Westerville, Ohio American Ceramics Society 2001 Online-Ressource nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier CuO-doped tetragonal ZrO2 (3-mol%-Y2O3-doped tetragonal zirconia, 3Y-TZ) green bodies were consolidated from zirconia slurries with Cu2+ by a pressure filtration method. The slurries were prepared by dispersing 3Y-TZ powder in a solution of [NH4OH + NH3NO3] = 0.1M at pH 11 and adding an appropriate amount of Cu(NO3)·3H2O solution. Green bodies with narrow pore-size distribution were obtained after cold isostatically pressing the pressure-filtrated bodies. Small amounts of CuO-doped samples were densified fully at 1200°C. The size of a grain of 0.16-mol%-CuO-doped 3Y-TZ sintered at 1200°C was 84 nm. Bulk and grain-boundary conductivities are measured by a complex impedance method. The bulk conductivity of the CuO-doped 3Y-TZ was almost equal to the undoped one, but the grain-boundary conductivity decreased with CuO addition. 2004 Blackwell Publishing Journal Backfiles 1879-2005 |2004|||||||||| zirconia: tetragonal polycrystals Ozawa, Kiyoshi verfasserin aut Uchikoshi, Tetsuo verfasserin aut Hiraga, Keijiro oth In American Ceramic Society ; GKD-ID: 6113X Journal of the American Ceramic Society Oxford [u.a.] : Wiley-Blackwell, 1918 84(2001), 9, Seite 0 Online-Ressource (DE-627)NLEJ243927835 (DE-600)2008170-4 1551-2916 nnns volume:84 year:2001 number:9 pages:0 http://dx.doi.org/10.1111/j.1151-2916.2001.tb00972.x text/html Verlag Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-DJB GBV_NL_ARTICLE AR 84 2001 9 0 |
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10.1111/j.1151-2916.2001.tb00972.x doi (DE-627)NLEJ243464746 DE-627 ger DE-627 rakwb Sakka, Yoshio verfasserin aut Colloidal Processing and Ionic Conductivity of Fine-Grained Cupric-Oxide-Doped Tetragonal Zirconia Westerville, Ohio American Ceramics Society 2001 Online-Ressource nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier CuO-doped tetragonal ZrO2 (3-mol%-Y2O3-doped tetragonal zirconia, 3Y-TZ) green bodies were consolidated from zirconia slurries with Cu2+ by a pressure filtration method. The slurries were prepared by dispersing 3Y-TZ powder in a solution of [NH4OH + NH3NO3] = 0.1M at pH 11 and adding an appropriate amount of Cu(NO3)·3H2O solution. Green bodies with narrow pore-size distribution were obtained after cold isostatically pressing the pressure-filtrated bodies. Small amounts of CuO-doped samples were densified fully at 1200°C. The size of a grain of 0.16-mol%-CuO-doped 3Y-TZ sintered at 1200°C was 84 nm. Bulk and grain-boundary conductivities are measured by a complex impedance method. The bulk conductivity of the CuO-doped 3Y-TZ was almost equal to the undoped one, but the grain-boundary conductivity decreased with CuO addition. 2004 Blackwell Publishing Journal Backfiles 1879-2005 |2004|||||||||| zirconia: tetragonal polycrystals Ozawa, Kiyoshi verfasserin aut Uchikoshi, Tetsuo verfasserin aut Hiraga, Keijiro oth In American Ceramic Society ; GKD-ID: 6113X Journal of the American Ceramic Society Oxford [u.a.] : Wiley-Blackwell, 1918 84(2001), 9, Seite 0 Online-Ressource (DE-627)NLEJ243927835 (DE-600)2008170-4 1551-2916 nnns volume:84 year:2001 number:9 pages:0 http://dx.doi.org/10.1111/j.1151-2916.2001.tb00972.x text/html Verlag Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-DJB GBV_NL_ARTICLE AR 84 2001 9 0 |
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10.1111/j.1151-2916.2001.tb00972.x doi (DE-627)NLEJ243464746 DE-627 ger DE-627 rakwb Sakka, Yoshio verfasserin aut Colloidal Processing and Ionic Conductivity of Fine-Grained Cupric-Oxide-Doped Tetragonal Zirconia Westerville, Ohio American Ceramics Society 2001 Online-Ressource nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier CuO-doped tetragonal ZrO2 (3-mol%-Y2O3-doped tetragonal zirconia, 3Y-TZ) green bodies were consolidated from zirconia slurries with Cu2+ by a pressure filtration method. The slurries were prepared by dispersing 3Y-TZ powder in a solution of [NH4OH + NH3NO3] = 0.1M at pH 11 and adding an appropriate amount of Cu(NO3)·3H2O solution. Green bodies with narrow pore-size distribution were obtained after cold isostatically pressing the pressure-filtrated bodies. Small amounts of CuO-doped samples were densified fully at 1200°C. The size of a grain of 0.16-mol%-CuO-doped 3Y-TZ sintered at 1200°C was 84 nm. Bulk and grain-boundary conductivities are measured by a complex impedance method. The bulk conductivity of the CuO-doped 3Y-TZ was almost equal to the undoped one, but the grain-boundary conductivity decreased with CuO addition. 2004 Blackwell Publishing Journal Backfiles 1879-2005 |2004|||||||||| zirconia: tetragonal polycrystals Ozawa, Kiyoshi verfasserin aut Uchikoshi, Tetsuo verfasserin aut Hiraga, Keijiro oth In American Ceramic Society ; GKD-ID: 6113X Journal of the American Ceramic Society Oxford [u.a.] : Wiley-Blackwell, 1918 84(2001), 9, Seite 0 Online-Ressource (DE-627)NLEJ243927835 (DE-600)2008170-4 1551-2916 nnns volume:84 year:2001 number:9 pages:0 http://dx.doi.org/10.1111/j.1151-2916.2001.tb00972.x text/html Verlag Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-DJB GBV_NL_ARTICLE AR 84 2001 9 0 |
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10.1111/j.1151-2916.2001.tb00972.x doi (DE-627)NLEJ243464746 DE-627 ger DE-627 rakwb Sakka, Yoshio verfasserin aut Colloidal Processing and Ionic Conductivity of Fine-Grained Cupric-Oxide-Doped Tetragonal Zirconia Westerville, Ohio American Ceramics Society 2001 Online-Ressource nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier CuO-doped tetragonal ZrO2 (3-mol%-Y2O3-doped tetragonal zirconia, 3Y-TZ) green bodies were consolidated from zirconia slurries with Cu2+ by a pressure filtration method. The slurries were prepared by dispersing 3Y-TZ powder in a solution of [NH4OH + NH3NO3] = 0.1M at pH 11 and adding an appropriate amount of Cu(NO3)·3H2O solution. Green bodies with narrow pore-size distribution were obtained after cold isostatically pressing the pressure-filtrated bodies. Small amounts of CuO-doped samples were densified fully at 1200°C. The size of a grain of 0.16-mol%-CuO-doped 3Y-TZ sintered at 1200°C was 84 nm. Bulk and grain-boundary conductivities are measured by a complex impedance method. The bulk conductivity of the CuO-doped 3Y-TZ was almost equal to the undoped one, but the grain-boundary conductivity decreased with CuO addition. 2004 Blackwell Publishing Journal Backfiles 1879-2005 |2004|||||||||| zirconia: tetragonal polycrystals Ozawa, Kiyoshi verfasserin aut Uchikoshi, Tetsuo verfasserin aut Hiraga, Keijiro oth In American Ceramic Society ; GKD-ID: 6113X Journal of the American Ceramic Society Oxford [u.a.] : Wiley-Blackwell, 1918 84(2001), 9, Seite 0 Online-Ressource (DE-627)NLEJ243927835 (DE-600)2008170-4 1551-2916 nnns volume:84 year:2001 number:9 pages:0 http://dx.doi.org/10.1111/j.1151-2916.2001.tb00972.x text/html Verlag Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-DJB GBV_NL_ARTICLE AR 84 2001 9 0 |
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colloidal processing and ionic conductivity of fine-grained cupric-oxide-doped tetragonal zirconia |
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Colloidal Processing and Ionic Conductivity of Fine-Grained Cupric-Oxide-Doped Tetragonal Zirconia |
| abstract |
CuO-doped tetragonal ZrO2 (3-mol%-Y2O3-doped tetragonal zirconia, 3Y-TZ) green bodies were consolidated from zirconia slurries with Cu2+ by a pressure filtration method. The slurries were prepared by dispersing 3Y-TZ powder in a solution of [NH4OH + NH3NO3] = 0.1M at pH 11 and adding an appropriate amount of Cu(NO3)·3H2O solution. Green bodies with narrow pore-size distribution were obtained after cold isostatically pressing the pressure-filtrated bodies. Small amounts of CuO-doped samples were densified fully at 1200°C. The size of a grain of 0.16-mol%-CuO-doped 3Y-TZ sintered at 1200°C was 84 nm. Bulk and grain-boundary conductivities are measured by a complex impedance method. The bulk conductivity of the CuO-doped 3Y-TZ was almost equal to the undoped one, but the grain-boundary conductivity decreased with CuO addition. |
| abstractGer |
CuO-doped tetragonal ZrO2 (3-mol%-Y2O3-doped tetragonal zirconia, 3Y-TZ) green bodies were consolidated from zirconia slurries with Cu2+ by a pressure filtration method. The slurries were prepared by dispersing 3Y-TZ powder in a solution of [NH4OH + NH3NO3] = 0.1M at pH 11 and adding an appropriate amount of Cu(NO3)·3H2O solution. Green bodies with narrow pore-size distribution were obtained after cold isostatically pressing the pressure-filtrated bodies. Small amounts of CuO-doped samples were densified fully at 1200°C. The size of a grain of 0.16-mol%-CuO-doped 3Y-TZ sintered at 1200°C was 84 nm. Bulk and grain-boundary conductivities are measured by a complex impedance method. The bulk conductivity of the CuO-doped 3Y-TZ was almost equal to the undoped one, but the grain-boundary conductivity decreased with CuO addition. |
| abstract_unstemmed |
CuO-doped tetragonal ZrO2 (3-mol%-Y2O3-doped tetragonal zirconia, 3Y-TZ) green bodies were consolidated from zirconia slurries with Cu2+ by a pressure filtration method. The slurries were prepared by dispersing 3Y-TZ powder in a solution of [NH4OH + NH3NO3] = 0.1M at pH 11 and adding an appropriate amount of Cu(NO3)·3H2O solution. Green bodies with narrow pore-size distribution were obtained after cold isostatically pressing the pressure-filtrated bodies. Small amounts of CuO-doped samples were densified fully at 1200°C. The size of a grain of 0.16-mol%-CuO-doped 3Y-TZ sintered at 1200°C was 84 nm. Bulk and grain-boundary conductivities are measured by a complex impedance method. The bulk conductivity of the CuO-doped 3Y-TZ was almost equal to the undoped one, but the grain-boundary conductivity decreased with CuO addition. |
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Colloidal Processing and Ionic Conductivity of Fine-Grained Cupric-Oxide-Doped Tetragonal Zirconia |
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Ozawa, Kiyoshi Uchikoshi, Tetsuo Hiraga, Keijiro |
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