Thermal Decomposition of Titanium Alkoxide and Silicate Ester in Organic Solvent: A New Method for Synthesizing Large-Surface-Area, Silica-Modified Titanium(IV) Oxide of High Thermal Stability
Silica-modified titanium oxide (S-TiO2) powders that have an anatase structure were synthesized via the thermal decomposition of mixtures of titanium(IV) isopropoxide (TIP) and tetramethyl orthosilicate (TMOS) in toluene at 300°C. These S-TiO2 materials had high rutile-transformation temperatures an...
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| Autor*in: |
Kominami, Hiroshi [verfasserIn] Kohno, Masaaki [verfasserIn] Matsunaga, Yukino [verfasserIn] |
|---|
| Format: |
E-Artikel |
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| Erschienen: |
Westerville, Ohio: American Ceramics Society ; 2001 |
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| Schlagwörter: |
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| Umfang: |
Online-Ressource |
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| Reproduktion: |
2004 ; Blackwell Publishing Journal Backfiles 1879-2005 |
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| Übergeordnetes Werk: |
In: Journal of the American Ceramic Society - American Ceramic Society ; GKD-ID: 6113X, Oxford [u.a.] : Wiley-Blackwell, 1918, 84(2001), 5, Seite 0 |
| Übergeordnetes Werk: |
volume:84 ; year:2001 ; number:5 ; pages:0 |
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| DOI / URN: |
10.1111/j.1151-2916.2001.tb00811.x |
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NLEJ243466471 |
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| 520 | |a Silica-modified titanium oxide (S-TiO2) powders that have an anatase structure were synthesized via the thermal decomposition of mixtures of titanium(IV) isopropoxide (TIP) and tetramethyl orthosilicate (TMOS) in toluene at 300°C. These S-TiO2 materials had high rutile-transformation temperatures and maintained large surface areas at elevated temperatures (550°–1000°C). For example, the product that was prepared from a 9:1 TIP:TMOS mixture transformed to rutile at ∼1100°C and possessed a surface area of 160 m2/g, even after calcination at 800°C for 1 h. | ||
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10.1111/j.1151-2916.2001.tb00811.x doi (DE-627)NLEJ243466471 DE-627 ger DE-627 rakwb Kominami, Hiroshi verfasserin aut Thermal Decomposition of Titanium Alkoxide and Silicate Ester in Organic Solvent: A New Method for Synthesizing Large-Surface-Area, Silica-Modified Titanium(IV) Oxide of High Thermal Stability Westerville, Ohio American Ceramics Society 2001 Online-Ressource nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Silica-modified titanium oxide (S-TiO2) powders that have an anatase structure were synthesized via the thermal decomposition of mixtures of titanium(IV) isopropoxide (TIP) and tetramethyl orthosilicate (TMOS) in toluene at 300°C. These S-TiO2 materials had high rutile-transformation temperatures and maintained large surface areas at elevated temperatures (550°–1000°C). For example, the product that was prepared from a 9:1 TIP:TMOS mixture transformed to rutile at ∼1100°C and possessed a surface area of 160 m2/g, even after calcination at 800°C for 1 h. 2004 Blackwell Publishing Journal Backfiles 1879-2005 |2004|||||||||| titanium oxide Kohno, Masaaki verfasserin aut Matsunaga, Yukino verfasserin aut Kera, Yoshiya oth In American Ceramic Society ; GKD-ID: 6113X Journal of the American Ceramic Society Oxford [u.a.] : Wiley-Blackwell, 1918 84(2001), 5, Seite 0 Online-Ressource (DE-627)NLEJ243927835 (DE-600)2008170-4 1551-2916 nnns volume:84 year:2001 number:5 pages:0 http://dx.doi.org/10.1111/j.1151-2916.2001.tb00811.x text/html Verlag Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-DJB GBV_NL_ARTICLE AR 84 2001 5 0 |
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10.1111/j.1151-2916.2001.tb00811.x doi (DE-627)NLEJ243466471 DE-627 ger DE-627 rakwb Kominami, Hiroshi verfasserin aut Thermal Decomposition of Titanium Alkoxide and Silicate Ester in Organic Solvent: A New Method for Synthesizing Large-Surface-Area, Silica-Modified Titanium(IV) Oxide of High Thermal Stability Westerville, Ohio American Ceramics Society 2001 Online-Ressource nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Silica-modified titanium oxide (S-TiO2) powders that have an anatase structure were synthesized via the thermal decomposition of mixtures of titanium(IV) isopropoxide (TIP) and tetramethyl orthosilicate (TMOS) in toluene at 300°C. These S-TiO2 materials had high rutile-transformation temperatures and maintained large surface areas at elevated temperatures (550°–1000°C). For example, the product that was prepared from a 9:1 TIP:TMOS mixture transformed to rutile at ∼1100°C and possessed a surface area of 160 m2/g, even after calcination at 800°C for 1 h. 2004 Blackwell Publishing Journal Backfiles 1879-2005 |2004|||||||||| titanium oxide Kohno, Masaaki verfasserin aut Matsunaga, Yukino verfasserin aut Kera, Yoshiya oth In American Ceramic Society ; GKD-ID: 6113X Journal of the American Ceramic Society Oxford [u.a.] : Wiley-Blackwell, 1918 84(2001), 5, Seite 0 Online-Ressource (DE-627)NLEJ243927835 (DE-600)2008170-4 1551-2916 nnns volume:84 year:2001 number:5 pages:0 http://dx.doi.org/10.1111/j.1151-2916.2001.tb00811.x text/html Verlag Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-DJB GBV_NL_ARTICLE AR 84 2001 5 0 |
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10.1111/j.1151-2916.2001.tb00811.x doi (DE-627)NLEJ243466471 DE-627 ger DE-627 rakwb Kominami, Hiroshi verfasserin aut Thermal Decomposition of Titanium Alkoxide and Silicate Ester in Organic Solvent: A New Method for Synthesizing Large-Surface-Area, Silica-Modified Titanium(IV) Oxide of High Thermal Stability Westerville, Ohio American Ceramics Society 2001 Online-Ressource nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Silica-modified titanium oxide (S-TiO2) powders that have an anatase structure were synthesized via the thermal decomposition of mixtures of titanium(IV) isopropoxide (TIP) and tetramethyl orthosilicate (TMOS) in toluene at 300°C. These S-TiO2 materials had high rutile-transformation temperatures and maintained large surface areas at elevated temperatures (550°–1000°C). For example, the product that was prepared from a 9:1 TIP:TMOS mixture transformed to rutile at ∼1100°C and possessed a surface area of 160 m2/g, even after calcination at 800°C for 1 h. 2004 Blackwell Publishing Journal Backfiles 1879-2005 |2004|||||||||| titanium oxide Kohno, Masaaki verfasserin aut Matsunaga, Yukino verfasserin aut Kera, Yoshiya oth In American Ceramic Society ; GKD-ID: 6113X Journal of the American Ceramic Society Oxford [u.a.] : Wiley-Blackwell, 1918 84(2001), 5, Seite 0 Online-Ressource (DE-627)NLEJ243927835 (DE-600)2008170-4 1551-2916 nnns volume:84 year:2001 number:5 pages:0 http://dx.doi.org/10.1111/j.1151-2916.2001.tb00811.x text/html Verlag Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-DJB GBV_NL_ARTICLE AR 84 2001 5 0 |
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10.1111/j.1151-2916.2001.tb00811.x doi (DE-627)NLEJ243466471 DE-627 ger DE-627 rakwb Kominami, Hiroshi verfasserin aut Thermal Decomposition of Titanium Alkoxide and Silicate Ester in Organic Solvent: A New Method for Synthesizing Large-Surface-Area, Silica-Modified Titanium(IV) Oxide of High Thermal Stability Westerville, Ohio American Ceramics Society 2001 Online-Ressource nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Silica-modified titanium oxide (S-TiO2) powders that have an anatase structure were synthesized via the thermal decomposition of mixtures of titanium(IV) isopropoxide (TIP) and tetramethyl orthosilicate (TMOS) in toluene at 300°C. These S-TiO2 materials had high rutile-transformation temperatures and maintained large surface areas at elevated temperatures (550°–1000°C). For example, the product that was prepared from a 9:1 TIP:TMOS mixture transformed to rutile at ∼1100°C and possessed a surface area of 160 m2/g, even after calcination at 800°C for 1 h. 2004 Blackwell Publishing Journal Backfiles 1879-2005 |2004|||||||||| titanium oxide Kohno, Masaaki verfasserin aut Matsunaga, Yukino verfasserin aut Kera, Yoshiya oth In American Ceramic Society ; GKD-ID: 6113X Journal of the American Ceramic Society Oxford [u.a.] : Wiley-Blackwell, 1918 84(2001), 5, Seite 0 Online-Ressource (DE-627)NLEJ243927835 (DE-600)2008170-4 1551-2916 nnns volume:84 year:2001 number:5 pages:0 http://dx.doi.org/10.1111/j.1151-2916.2001.tb00811.x text/html Verlag Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-DJB GBV_NL_ARTICLE AR 84 2001 5 0 |
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10.1111/j.1151-2916.2001.tb00811.x doi (DE-627)NLEJ243466471 DE-627 ger DE-627 rakwb Kominami, Hiroshi verfasserin aut Thermal Decomposition of Titanium Alkoxide and Silicate Ester in Organic Solvent: A New Method for Synthesizing Large-Surface-Area, Silica-Modified Titanium(IV) Oxide of High Thermal Stability Westerville, Ohio American Ceramics Society 2001 Online-Ressource nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Silica-modified titanium oxide (S-TiO2) powders that have an anatase structure were synthesized via the thermal decomposition of mixtures of titanium(IV) isopropoxide (TIP) and tetramethyl orthosilicate (TMOS) in toluene at 300°C. These S-TiO2 materials had high rutile-transformation temperatures and maintained large surface areas at elevated temperatures (550°–1000°C). For example, the product that was prepared from a 9:1 TIP:TMOS mixture transformed to rutile at ∼1100°C and possessed a surface area of 160 m2/g, even after calcination at 800°C for 1 h. 2004 Blackwell Publishing Journal Backfiles 1879-2005 |2004|||||||||| titanium oxide Kohno, Masaaki verfasserin aut Matsunaga, Yukino verfasserin aut Kera, Yoshiya oth In American Ceramic Society ; GKD-ID: 6113X Journal of the American Ceramic Society Oxford [u.a.] : Wiley-Blackwell, 1918 84(2001), 5, Seite 0 Online-Ressource (DE-627)NLEJ243927835 (DE-600)2008170-4 1551-2916 nnns volume:84 year:2001 number:5 pages:0 http://dx.doi.org/10.1111/j.1151-2916.2001.tb00811.x text/html Verlag Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-DJB GBV_NL_ARTICLE AR 84 2001 5 0 |
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Thermal Decomposition of Titanium Alkoxide and Silicate Ester in Organic Solvent: A New Method for Synthesizing Large-Surface-Area, Silica-Modified Titanium(IV) Oxide of High Thermal Stability titanium oxide |
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Thermal Decomposition of Titanium Alkoxide and Silicate Ester in Organic Solvent: A New Method for Synthesizing Large-Surface-Area, Silica-Modified Titanium(IV) Oxide of High Thermal Stability |
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Silica-modified titanium oxide (S-TiO2) powders that have an anatase structure were synthesized via the thermal decomposition of mixtures of titanium(IV) isopropoxide (TIP) and tetramethyl orthosilicate (TMOS) in toluene at 300°C. These S-TiO2 materials had high rutile-transformation temperatures and maintained large surface areas at elevated temperatures (550°–1000°C). For example, the product that was prepared from a 9:1 TIP:TMOS mixture transformed to rutile at ∼1100°C and possessed a surface area of 160 m2/g, even after calcination at 800°C for 1 h. |
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Silica-modified titanium oxide (S-TiO2) powders that have an anatase structure were synthesized via the thermal decomposition of mixtures of titanium(IV) isopropoxide (TIP) and tetramethyl orthosilicate (TMOS) in toluene at 300°C. These S-TiO2 materials had high rutile-transformation temperatures and maintained large surface areas at elevated temperatures (550°–1000°C). For example, the product that was prepared from a 9:1 TIP:TMOS mixture transformed to rutile at ∼1100°C and possessed a surface area of 160 m2/g, even after calcination at 800°C for 1 h. |
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Silica-modified titanium oxide (S-TiO2) powders that have an anatase structure were synthesized via the thermal decomposition of mixtures of titanium(IV) isopropoxide (TIP) and tetramethyl orthosilicate (TMOS) in toluene at 300°C. These S-TiO2 materials had high rutile-transformation temperatures and maintained large surface areas at elevated temperatures (550°–1000°C). For example, the product that was prepared from a 9:1 TIP:TMOS mixture transformed to rutile at ∼1100°C and possessed a surface area of 160 m2/g, even after calcination at 800°C for 1 h. |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">NLEJ243466471</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20210707181457.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">120427s2001 xx |||||o 00| ||und c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1111/j.1151-2916.2001.tb00811.x</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)NLEJ243466471</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Kominami, Hiroshi</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Thermal Decomposition of Titanium Alkoxide and Silicate Ester in Organic Solvent: A New Method for Synthesizing Large-Surface-Area, Silica-Modified Titanium(IV) Oxide of High Thermal Stability</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">Westerville, Ohio</subfield><subfield code="b">American Ceramics Society</subfield><subfield code="c">2001</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">z</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zu</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Silica-modified titanium oxide (S-TiO2) powders that have an anatase structure were synthesized via the thermal decomposition of mixtures of titanium(IV) isopropoxide (TIP) and tetramethyl orthosilicate (TMOS) in toluene at 300°C. These S-TiO2 materials had high rutile-transformation temperatures and maintained large surface areas at elevated temperatures (550°–1000°C). 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7.3990107 |