Intrinsically Formed Trivalent Titanium Ions in Sol–Gel Titania
Electron paramagnetic resonance (EPR) room-temperature observation of trivalent titanium in sol–gel titania has been reported. This unprecedented detection of stable paramagnetic signals in this titania, which was treated at 200°–800°C, occurred regardless of whether the atmosphere was reducing, ine...
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| Autor*in: |
Muñoz, Eduardo [verfasserIn] Boldú, José L. [verfasserIn] Andrade, Eduardo [verfasserIn] |
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| Format: |
E-Artikel |
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| Erschienen: |
Westerville, Ohio: American Ceramics Society ; 2001 |
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| Schlagwörter: |
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| Umfang: |
Online-Ressource |
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| Reproduktion: |
2004 ; Blackwell Publishing Journal Backfiles 1879-2005 |
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| Übergeordnetes Werk: |
In: Journal of the American Ceramic Society - American Ceramic Society ; GKD-ID: 6113X, Oxford [u.a.] : Wiley-Blackwell, 1918, 84(2001), 2, Seite 0 |
| Übergeordnetes Werk: |
volume:84 ; year:2001 ; number:2 ; pages:0 |
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| DOI / URN: |
10.1111/j.1151-2916.2001.tb00667.x |
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NLEJ243467524 |
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| 520 | |a Electron paramagnetic resonance (EPR) room-temperature observation of trivalent titanium in sol–gel titania has been reported. This unprecedented detection of stable paramagnetic signals in this titania, which was treated at 200°–800°C, occurred regardless of whether the atmosphere was reducing, inert, or oxidating. The possibility that the paramagnetic signals may originate from an metal impurity other than titanium was completely excluded by analyzing the samples using three different ion-beam-analysis techniques: Rutherford backscattering spectroscopy, particle-induced X-ray emission resonance, and energy-recoil detection analysis. The paramagnetic signals appeared at precisely the temperature range of the sample dehydroxylation, which suggests a mechanism for explaining these Ti3+ EPR spectra. | ||
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10.1111/j.1151-2916.2001.tb00667.x doi (DE-627)NLEJ243467524 DE-627 ger DE-627 rakwb Muñoz, Eduardo verfasserin aut Intrinsically Formed Trivalent Titanium Ions in Sol–Gel Titania Westerville, Ohio American Ceramics Society 2001 Online-Ressource nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Electron paramagnetic resonance (EPR) room-temperature observation of trivalent titanium in sol–gel titania has been reported. This unprecedented detection of stable paramagnetic signals in this titania, which was treated at 200°–800°C, occurred regardless of whether the atmosphere was reducing, inert, or oxidating. The possibility that the paramagnetic signals may originate from an metal impurity other than titanium was completely excluded by analyzing the samples using three different ion-beam-analysis techniques: Rutherford backscattering spectroscopy, particle-induced X-ray emission resonance, and energy-recoil detection analysis. The paramagnetic signals appeared at precisely the temperature range of the sample dehydroxylation, which suggests a mechanism for explaining these Ti3+ EPR spectra. 2004 Blackwell Publishing Journal Backfiles 1879-2005 |2004|||||||||| titanium oxide Boldú, José L. verfasserin aut Andrade, Eduardo verfasserin aut Novaro, Octavio oth Bokhimi, Xi. oth López, Tessy oth Gómez, Ricardo oth In American Ceramic Society ; GKD-ID: 6113X Journal of the American Ceramic Society Oxford [u.a.] : Wiley-Blackwell, 1918 84(2001), 2, Seite 0 Online-Ressource (DE-627)NLEJ243927835 (DE-600)2008170-4 1551-2916 nnns volume:84 year:2001 number:2 pages:0 http://dx.doi.org/10.1111/j.1151-2916.2001.tb00667.x text/html Verlag Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-DJB GBV_NL_ARTICLE AR 84 2001 2 0 |
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10.1111/j.1151-2916.2001.tb00667.x doi (DE-627)NLEJ243467524 DE-627 ger DE-627 rakwb Muñoz, Eduardo verfasserin aut Intrinsically Formed Trivalent Titanium Ions in Sol–Gel Titania Westerville, Ohio American Ceramics Society 2001 Online-Ressource nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Electron paramagnetic resonance (EPR) room-temperature observation of trivalent titanium in sol–gel titania has been reported. This unprecedented detection of stable paramagnetic signals in this titania, which was treated at 200°–800°C, occurred regardless of whether the atmosphere was reducing, inert, or oxidating. The possibility that the paramagnetic signals may originate from an metal impurity other than titanium was completely excluded by analyzing the samples using three different ion-beam-analysis techniques: Rutherford backscattering spectroscopy, particle-induced X-ray emission resonance, and energy-recoil detection analysis. The paramagnetic signals appeared at precisely the temperature range of the sample dehydroxylation, which suggests a mechanism for explaining these Ti3+ EPR spectra. 2004 Blackwell Publishing Journal Backfiles 1879-2005 |2004|||||||||| titanium oxide Boldú, José L. verfasserin aut Andrade, Eduardo verfasserin aut Novaro, Octavio oth Bokhimi, Xi. oth López, Tessy oth Gómez, Ricardo oth In American Ceramic Society ; GKD-ID: 6113X Journal of the American Ceramic Society Oxford [u.a.] : Wiley-Blackwell, 1918 84(2001), 2, Seite 0 Online-Ressource (DE-627)NLEJ243927835 (DE-600)2008170-4 1551-2916 nnns volume:84 year:2001 number:2 pages:0 http://dx.doi.org/10.1111/j.1151-2916.2001.tb00667.x text/html Verlag Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-DJB GBV_NL_ARTICLE AR 84 2001 2 0 |
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10.1111/j.1151-2916.2001.tb00667.x doi (DE-627)NLEJ243467524 DE-627 ger DE-627 rakwb Muñoz, Eduardo verfasserin aut Intrinsically Formed Trivalent Titanium Ions in Sol–Gel Titania Westerville, Ohio American Ceramics Society 2001 Online-Ressource nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Electron paramagnetic resonance (EPR) room-temperature observation of trivalent titanium in sol–gel titania has been reported. This unprecedented detection of stable paramagnetic signals in this titania, which was treated at 200°–800°C, occurred regardless of whether the atmosphere was reducing, inert, or oxidating. The possibility that the paramagnetic signals may originate from an metal impurity other than titanium was completely excluded by analyzing the samples using three different ion-beam-analysis techniques: Rutherford backscattering spectroscopy, particle-induced X-ray emission resonance, and energy-recoil detection analysis. The paramagnetic signals appeared at precisely the temperature range of the sample dehydroxylation, which suggests a mechanism for explaining these Ti3+ EPR spectra. 2004 Blackwell Publishing Journal Backfiles 1879-2005 |2004|||||||||| titanium oxide Boldú, José L. verfasserin aut Andrade, Eduardo verfasserin aut Novaro, Octavio oth Bokhimi, Xi. oth López, Tessy oth Gómez, Ricardo oth In American Ceramic Society ; GKD-ID: 6113X Journal of the American Ceramic Society Oxford [u.a.] : Wiley-Blackwell, 1918 84(2001), 2, Seite 0 Online-Ressource (DE-627)NLEJ243927835 (DE-600)2008170-4 1551-2916 nnns volume:84 year:2001 number:2 pages:0 http://dx.doi.org/10.1111/j.1151-2916.2001.tb00667.x text/html Verlag Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-DJB GBV_NL_ARTICLE AR 84 2001 2 0 |
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10.1111/j.1151-2916.2001.tb00667.x doi (DE-627)NLEJ243467524 DE-627 ger DE-627 rakwb Muñoz, Eduardo verfasserin aut Intrinsically Formed Trivalent Titanium Ions in Sol–Gel Titania Westerville, Ohio American Ceramics Society 2001 Online-Ressource nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Electron paramagnetic resonance (EPR) room-temperature observation of trivalent titanium in sol–gel titania has been reported. This unprecedented detection of stable paramagnetic signals in this titania, which was treated at 200°–800°C, occurred regardless of whether the atmosphere was reducing, inert, or oxidating. The possibility that the paramagnetic signals may originate from an metal impurity other than titanium was completely excluded by analyzing the samples using three different ion-beam-analysis techniques: Rutherford backscattering spectroscopy, particle-induced X-ray emission resonance, and energy-recoil detection analysis. The paramagnetic signals appeared at precisely the temperature range of the sample dehydroxylation, which suggests a mechanism for explaining these Ti3+ EPR spectra. 2004 Blackwell Publishing Journal Backfiles 1879-2005 |2004|||||||||| titanium oxide Boldú, José L. verfasserin aut Andrade, Eduardo verfasserin aut Novaro, Octavio oth Bokhimi, Xi. oth López, Tessy oth Gómez, Ricardo oth In American Ceramic Society ; GKD-ID: 6113X Journal of the American Ceramic Society Oxford [u.a.] : Wiley-Blackwell, 1918 84(2001), 2, Seite 0 Online-Ressource (DE-627)NLEJ243927835 (DE-600)2008170-4 1551-2916 nnns volume:84 year:2001 number:2 pages:0 http://dx.doi.org/10.1111/j.1151-2916.2001.tb00667.x text/html Verlag Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-DJB GBV_NL_ARTICLE AR 84 2001 2 0 |
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10.1111/j.1151-2916.2001.tb00667.x doi (DE-627)NLEJ243467524 DE-627 ger DE-627 rakwb Muñoz, Eduardo verfasserin aut Intrinsically Formed Trivalent Titanium Ions in Sol–Gel Titania Westerville, Ohio American Ceramics Society 2001 Online-Ressource nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier Electron paramagnetic resonance (EPR) room-temperature observation of trivalent titanium in sol–gel titania has been reported. This unprecedented detection of stable paramagnetic signals in this titania, which was treated at 200°–800°C, occurred regardless of whether the atmosphere was reducing, inert, or oxidating. The possibility that the paramagnetic signals may originate from an metal impurity other than titanium was completely excluded by analyzing the samples using three different ion-beam-analysis techniques: Rutherford backscattering spectroscopy, particle-induced X-ray emission resonance, and energy-recoil detection analysis. The paramagnetic signals appeared at precisely the temperature range of the sample dehydroxylation, which suggests a mechanism for explaining these Ti3+ EPR spectra. 2004 Blackwell Publishing Journal Backfiles 1879-2005 |2004|||||||||| titanium oxide Boldú, José L. verfasserin aut Andrade, Eduardo verfasserin aut Novaro, Octavio oth Bokhimi, Xi. oth López, Tessy oth Gómez, Ricardo oth In American Ceramic Society ; GKD-ID: 6113X Journal of the American Ceramic Society Oxford [u.a.] : Wiley-Blackwell, 1918 84(2001), 2, Seite 0 Online-Ressource (DE-627)NLEJ243927835 (DE-600)2008170-4 1551-2916 nnns volume:84 year:2001 number:2 pages:0 http://dx.doi.org/10.1111/j.1151-2916.2001.tb00667.x text/html Verlag Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-DJB GBV_NL_ARTICLE AR 84 2001 2 0 |
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Electron paramagnetic resonance (EPR) room-temperature observation of trivalent titanium in sol–gel titania has been reported. This unprecedented detection of stable paramagnetic signals in this titania, which was treated at 200°–800°C, occurred regardless of whether the atmosphere was reducing, inert, or oxidating. The possibility that the paramagnetic signals may originate from an metal impurity other than titanium was completely excluded by analyzing the samples using three different ion-beam-analysis techniques: Rutherford backscattering spectroscopy, particle-induced X-ray emission resonance, and energy-recoil detection analysis. The paramagnetic signals appeared at precisely the temperature range of the sample dehydroxylation, which suggests a mechanism for explaining these Ti3+ EPR spectra. |
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Electron paramagnetic resonance (EPR) room-temperature observation of trivalent titanium in sol–gel titania has been reported. This unprecedented detection of stable paramagnetic signals in this titania, which was treated at 200°–800°C, occurred regardless of whether the atmosphere was reducing, inert, or oxidating. The possibility that the paramagnetic signals may originate from an metal impurity other than titanium was completely excluded by analyzing the samples using three different ion-beam-analysis techniques: Rutherford backscattering spectroscopy, particle-induced X-ray emission resonance, and energy-recoil detection analysis. The paramagnetic signals appeared at precisely the temperature range of the sample dehydroxylation, which suggests a mechanism for explaining these Ti3+ EPR spectra. |
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Electron paramagnetic resonance (EPR) room-temperature observation of trivalent titanium in sol–gel titania has been reported. This unprecedented detection of stable paramagnetic signals in this titania, which was treated at 200°–800°C, occurred regardless of whether the atmosphere was reducing, inert, or oxidating. The possibility that the paramagnetic signals may originate from an metal impurity other than titanium was completely excluded by analyzing the samples using three different ion-beam-analysis techniques: Rutherford backscattering spectroscopy, particle-induced X-ray emission resonance, and energy-recoil detection analysis. The paramagnetic signals appeared at precisely the temperature range of the sample dehydroxylation, which suggests a mechanism for explaining these Ti3+ EPR spectra. |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">NLEJ243467524</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20210707181505.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">120427s2001 xx |||||o 00| ||und c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1111/j.1151-2916.2001.tb00667.x</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)NLEJ243467524</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Muñoz, Eduardo</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Intrinsically Formed Trivalent Titanium Ions in Sol–Gel Titania</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">Westerville, Ohio</subfield><subfield code="b">American Ceramics Society</subfield><subfield code="c">2001</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">z</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zu</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Electron paramagnetic resonance (EPR) room-temperature observation of trivalent titanium in sol–gel titania has been reported. This unprecedented detection of stable paramagnetic signals in this titania, which was treated at 200°–800°C, occurred regardless of whether the atmosphere was reducing, inert, or oxidating. The possibility that the paramagnetic signals may originate from an metal impurity other than titanium was completely excluded by analyzing the samples using three different ion-beam-analysis techniques: Rutherford backscattering spectroscopy, particle-induced X-ray emission resonance, and energy-recoil detection analysis. The paramagnetic signals appeared at precisely the temperature range of the sample dehydroxylation, which suggests a mechanism for explaining these Ti3+ EPR spectra.</subfield></datafield><datafield tag="533" ind1=" " ind2=" "><subfield code="d">2004</subfield><subfield code="f">Blackwell Publishing Journal Backfiles 1879-2005</subfield><subfield code="7">|2004||||||||||</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">titanium oxide</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Boldú, José L.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Andrade, Eduardo</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Novaro, Octavio</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Bokhimi, Xi.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">López, Tessy</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Gómez, Ricardo</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">In</subfield><subfield code="a">American Ceramic Society ; GKD-ID: 6113X</subfield><subfield code="t">Journal of the American Ceramic Society</subfield><subfield code="d">Oxford [u.a.] : Wiley-Blackwell, 1918</subfield><subfield code="g">84(2001), 2, Seite 0</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)NLEJ243927835</subfield><subfield code="w">(DE-600)2008170-4</subfield><subfield code="x">1551-2916</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:84</subfield><subfield code="g">year:2001</subfield><subfield code="g">number:2</subfield><subfield code="g">pages:0</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">http://dx.doi.org/10.1111/j.1151-2916.2001.tb00667.x</subfield><subfield code="q">text/html</subfield><subfield code="x">Verlag</subfield><subfield code="z">Deutschlandweit zugänglich</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">ZDB-1-DJB</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_NL_ARTICLE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">84</subfield><subfield code="j">2001</subfield><subfield code="e">2</subfield><subfield code="h">0</subfield></datafield></record></collection>
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