Mullite Decomposition Kinetics and Melt Stabilization in the Temperature Range 1900—2000°C
An investigation of the mullite decomposition mechanism and kinetics in the temperature range 1900—2000°C was conducted. SEM-EDS and XRD analysis showed that the decomposition of mullite in this temperature range was primarily caused by the presence of carbon from furnace components. A reaction mech...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Xiao, Zhijun [verfasserIn] Mitchell, Brian S. [verfasserIn] |
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| Format: |
E-Artikel |
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| Erschienen: |
Westerville, Ohio: American Ceramics Society ; 2000 |
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| Schlagwörter: |
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| Umfang: |
Online-Ressource |
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| Reproduktion: |
2004 ; Blackwell Publishing Journal Backfiles 1879-2005 |
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| Übergeordnetes Werk: |
In: Journal of the American Ceramic Society - American Ceramic Society ; GKD-ID: 6113X, Oxford [u.a.] : Wiley-Blackwell, 1918, 83(2000), 4, Seite 0 |
| Übergeordnetes Werk: |
volume:83 ; year:2000 ; number:4 ; pages:0 |
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| DOI / URN: |
10.1111/j.1151-2916.2000.tb01271.x |
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| 520 | |a An investigation of the mullite decomposition mechanism and kinetics in the temperature range 1900—2000°C was conducted. SEM-EDS and XRD analysis showed that the decomposition of mullite in this temperature range was primarily caused by the presence of carbon from furnace components. A reaction mechanism, in which gas-phase SiO2 reacts with carbon to form SiO and CO, is proposed; both IR analysis and kinetic studies support the proposed mechanism. The decomposition was completely suppressed by the introduction of a modified crucible assembly and the addition of excess SiO2 to the reaction system. A mullite melt of stable composition was thus obtained, setting the groundwork for inviscid melt spinning mullite fiber making process development. | ||
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10.1111/j.1151-2916.2000.tb01271.x doi (DE-627)NLEJ243472293 DE-627 ger DE-627 rakwb Xiao, Zhijun verfasserin aut Mullite Decomposition Kinetics and Melt Stabilization in the Temperature Range 1900—2000°C Westerville, Ohio American Ceramics Society 2000 Online-Ressource nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier An investigation of the mullite decomposition mechanism and kinetics in the temperature range 1900—2000°C was conducted. SEM-EDS and XRD analysis showed that the decomposition of mullite in this temperature range was primarily caused by the presence of carbon from furnace components. A reaction mechanism, in which gas-phase SiO2 reacts with carbon to form SiO and CO, is proposed; both IR analysis and kinetic studies support the proposed mechanism. The decomposition was completely suppressed by the introduction of a modified crucible assembly and the addition of excess SiO2 to the reaction system. A mullite melt of stable composition was thus obtained, setting the groundwork for inviscid melt spinning mullite fiber making process development. 2004 Blackwell Publishing Journal Backfiles 1879-2005 |2004|||||||||| mullite Mitchell, Brian S. verfasserin aut In American Ceramic Society ; GKD-ID: 6113X Journal of the American Ceramic Society Oxford [u.a.] : Wiley-Blackwell, 1918 83(2000), 4, Seite 0 Online-Ressource (DE-627)NLEJ243927835 (DE-600)2008170-4 1551-2916 nnns volume:83 year:2000 number:4 pages:0 http://dx.doi.org/10.1111/j.1151-2916.2000.tb01271.x text/html Verlag Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-DJB GBV_NL_ARTICLE AR 83 2000 4 0 |
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10.1111/j.1151-2916.2000.tb01271.x doi (DE-627)NLEJ243472293 DE-627 ger DE-627 rakwb Xiao, Zhijun verfasserin aut Mullite Decomposition Kinetics and Melt Stabilization in the Temperature Range 1900—2000°C Westerville, Ohio American Ceramics Society 2000 Online-Ressource nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier An investigation of the mullite decomposition mechanism and kinetics in the temperature range 1900—2000°C was conducted. SEM-EDS and XRD analysis showed that the decomposition of mullite in this temperature range was primarily caused by the presence of carbon from furnace components. A reaction mechanism, in which gas-phase SiO2 reacts with carbon to form SiO and CO, is proposed; both IR analysis and kinetic studies support the proposed mechanism. The decomposition was completely suppressed by the introduction of a modified crucible assembly and the addition of excess SiO2 to the reaction system. A mullite melt of stable composition was thus obtained, setting the groundwork for inviscid melt spinning mullite fiber making process development. 2004 Blackwell Publishing Journal Backfiles 1879-2005 |2004|||||||||| mullite Mitchell, Brian S. verfasserin aut In American Ceramic Society ; GKD-ID: 6113X Journal of the American Ceramic Society Oxford [u.a.] : Wiley-Blackwell, 1918 83(2000), 4, Seite 0 Online-Ressource (DE-627)NLEJ243927835 (DE-600)2008170-4 1551-2916 nnns volume:83 year:2000 number:4 pages:0 http://dx.doi.org/10.1111/j.1151-2916.2000.tb01271.x text/html Verlag Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-DJB GBV_NL_ARTICLE AR 83 2000 4 0 |
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10.1111/j.1151-2916.2000.tb01271.x doi (DE-627)NLEJ243472293 DE-627 ger DE-627 rakwb Xiao, Zhijun verfasserin aut Mullite Decomposition Kinetics and Melt Stabilization in the Temperature Range 1900—2000°C Westerville, Ohio American Ceramics Society 2000 Online-Ressource nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier An investigation of the mullite decomposition mechanism and kinetics in the temperature range 1900—2000°C was conducted. SEM-EDS and XRD analysis showed that the decomposition of mullite in this temperature range was primarily caused by the presence of carbon from furnace components. A reaction mechanism, in which gas-phase SiO2 reacts with carbon to form SiO and CO, is proposed; both IR analysis and kinetic studies support the proposed mechanism. The decomposition was completely suppressed by the introduction of a modified crucible assembly and the addition of excess SiO2 to the reaction system. A mullite melt of stable composition was thus obtained, setting the groundwork for inviscid melt spinning mullite fiber making process development. 2004 Blackwell Publishing Journal Backfiles 1879-2005 |2004|||||||||| mullite Mitchell, Brian S. verfasserin aut In American Ceramic Society ; GKD-ID: 6113X Journal of the American Ceramic Society Oxford [u.a.] : Wiley-Blackwell, 1918 83(2000), 4, Seite 0 Online-Ressource (DE-627)NLEJ243927835 (DE-600)2008170-4 1551-2916 nnns volume:83 year:2000 number:4 pages:0 http://dx.doi.org/10.1111/j.1151-2916.2000.tb01271.x text/html Verlag Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-DJB GBV_NL_ARTICLE AR 83 2000 4 0 |
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10.1111/j.1151-2916.2000.tb01271.x doi (DE-627)NLEJ243472293 DE-627 ger DE-627 rakwb Xiao, Zhijun verfasserin aut Mullite Decomposition Kinetics and Melt Stabilization in the Temperature Range 1900—2000°C Westerville, Ohio American Ceramics Society 2000 Online-Ressource nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier An investigation of the mullite decomposition mechanism and kinetics in the temperature range 1900—2000°C was conducted. SEM-EDS and XRD analysis showed that the decomposition of mullite in this temperature range was primarily caused by the presence of carbon from furnace components. A reaction mechanism, in which gas-phase SiO2 reacts with carbon to form SiO and CO, is proposed; both IR analysis and kinetic studies support the proposed mechanism. The decomposition was completely suppressed by the introduction of a modified crucible assembly and the addition of excess SiO2 to the reaction system. A mullite melt of stable composition was thus obtained, setting the groundwork for inviscid melt spinning mullite fiber making process development. 2004 Blackwell Publishing Journal Backfiles 1879-2005 |2004|||||||||| mullite Mitchell, Brian S. verfasserin aut In American Ceramic Society ; GKD-ID: 6113X Journal of the American Ceramic Society Oxford [u.a.] : Wiley-Blackwell, 1918 83(2000), 4, Seite 0 Online-Ressource (DE-627)NLEJ243927835 (DE-600)2008170-4 1551-2916 nnns volume:83 year:2000 number:4 pages:0 http://dx.doi.org/10.1111/j.1151-2916.2000.tb01271.x text/html Verlag Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-DJB GBV_NL_ARTICLE AR 83 2000 4 0 |
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10.1111/j.1151-2916.2000.tb01271.x doi (DE-627)NLEJ243472293 DE-627 ger DE-627 rakwb Xiao, Zhijun verfasserin aut Mullite Decomposition Kinetics and Melt Stabilization in the Temperature Range 1900—2000°C Westerville, Ohio American Ceramics Society 2000 Online-Ressource nicht spezifiziert zzz rdacontent nicht spezifiziert z rdamedia nicht spezifiziert zu rdacarrier An investigation of the mullite decomposition mechanism and kinetics in the temperature range 1900—2000°C was conducted. SEM-EDS and XRD analysis showed that the decomposition of mullite in this temperature range was primarily caused by the presence of carbon from furnace components. A reaction mechanism, in which gas-phase SiO2 reacts with carbon to form SiO and CO, is proposed; both IR analysis and kinetic studies support the proposed mechanism. The decomposition was completely suppressed by the introduction of a modified crucible assembly and the addition of excess SiO2 to the reaction system. A mullite melt of stable composition was thus obtained, setting the groundwork for inviscid melt spinning mullite fiber making process development. 2004 Blackwell Publishing Journal Backfiles 1879-2005 |2004|||||||||| mullite Mitchell, Brian S. verfasserin aut In American Ceramic Society ; GKD-ID: 6113X Journal of the American Ceramic Society Oxford [u.a.] : Wiley-Blackwell, 1918 83(2000), 4, Seite 0 Online-Ressource (DE-627)NLEJ243927835 (DE-600)2008170-4 1551-2916 nnns volume:83 year:2000 number:4 pages:0 http://dx.doi.org/10.1111/j.1151-2916.2000.tb01271.x text/html Verlag Deutschlandweit zugänglich Volltext GBV_USEFLAG_U ZDB-1-DJB GBV_NL_ARTICLE AR 83 2000 4 0 |
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Mullite Decomposition Kinetics and Melt Stabilization in the Temperature Range 1900—2000°C |
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An investigation of the mullite decomposition mechanism and kinetics in the temperature range 1900—2000°C was conducted. SEM-EDS and XRD analysis showed that the decomposition of mullite in this temperature range was primarily caused by the presence of carbon from furnace components. A reaction mechanism, in which gas-phase SiO2 reacts with carbon to form SiO and CO, is proposed; both IR analysis and kinetic studies support the proposed mechanism. The decomposition was completely suppressed by the introduction of a modified crucible assembly and the addition of excess SiO2 to the reaction system. A mullite melt of stable composition was thus obtained, setting the groundwork for inviscid melt spinning mullite fiber making process development. |
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An investigation of the mullite decomposition mechanism and kinetics in the temperature range 1900—2000°C was conducted. SEM-EDS and XRD analysis showed that the decomposition of mullite in this temperature range was primarily caused by the presence of carbon from furnace components. A reaction mechanism, in which gas-phase SiO2 reacts with carbon to form SiO and CO, is proposed; both IR analysis and kinetic studies support the proposed mechanism. The decomposition was completely suppressed by the introduction of a modified crucible assembly and the addition of excess SiO2 to the reaction system. A mullite melt of stable composition was thus obtained, setting the groundwork for inviscid melt spinning mullite fiber making process development. |
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An investigation of the mullite decomposition mechanism and kinetics in the temperature range 1900—2000°C was conducted. SEM-EDS and XRD analysis showed that the decomposition of mullite in this temperature range was primarily caused by the presence of carbon from furnace components. A reaction mechanism, in which gas-phase SiO2 reacts with carbon to form SiO and CO, is proposed; both IR analysis and kinetic studies support the proposed mechanism. The decomposition was completely suppressed by the introduction of a modified crucible assembly and the addition of excess SiO2 to the reaction system. A mullite melt of stable composition was thus obtained, setting the groundwork for inviscid melt spinning mullite fiber making process development. |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">NLEJ243472293</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20210707181542.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">120427s2000 xx |||||o 00| ||und c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1111/j.1151-2916.2000.tb01271.x</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)NLEJ243472293</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Xiao, Zhijun</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Mullite Decomposition Kinetics and Melt Stabilization in the Temperature Range 1900—2000°C</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="a">Westerville, Ohio</subfield><subfield code="b">American Ceramics Society</subfield><subfield code="c">2000</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zzz</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">z</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">nicht spezifiziert</subfield><subfield code="b">zu</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">An investigation of the mullite decomposition mechanism and kinetics in the temperature range 1900—2000°C was conducted. SEM-EDS and XRD analysis showed that the decomposition of mullite in this temperature range was primarily caused by the presence of carbon from furnace components. A reaction mechanism, in which gas-phase SiO2 reacts with carbon to form SiO and CO, is proposed; both IR analysis and kinetic studies support the proposed mechanism. The decomposition was completely suppressed by the introduction of a modified crucible assembly and the addition of excess SiO2 to the reaction system. A mullite melt of stable composition was thus obtained, setting the groundwork for inviscid melt spinning mullite fiber making process development.</subfield></datafield><datafield tag="533" ind1=" " ind2=" "><subfield code="d">2004</subfield><subfield code="f">Blackwell Publishing Journal Backfiles 1879-2005</subfield><subfield code="7">|2004||||||||||</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">mullite</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Mitchell, Brian S.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">In</subfield><subfield code="a">American Ceramic Society ; GKD-ID: 6113X</subfield><subfield code="t">Journal of the American Ceramic Society</subfield><subfield code="d">Oxford [u.a.] : Wiley-Blackwell, 1918</subfield><subfield code="g">83(2000), 4, Seite 0</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)NLEJ243927835</subfield><subfield code="w">(DE-600)2008170-4</subfield><subfield code="x">1551-2916</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:83</subfield><subfield code="g">year:2000</subfield><subfield code="g">number:4</subfield><subfield code="g">pages:0</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">http://dx.doi.org/10.1111/j.1151-2916.2000.tb01271.x</subfield><subfield code="q">text/html</subfield><subfield code="x">Verlag</subfield><subfield code="z">Deutschlandweit zugänglich</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">ZDB-1-DJB</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_NL_ARTICLE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">83</subfield><subfield code="j">2000</subfield><subfield code="e">4</subfield><subfield code="h">0</subfield></datafield></record></collection>
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