Contributions to the generalized oscillator strength for the inner-shell C 1s→3sσg transition in CO2 from the vibronic coupling mechanism
An approach is proposed to account for the general effect of the nuclei motion in the intensity of electronic transitions caused by fast electron collision with molecular targets, following a similar procedure that has recently been used by our group to determine the optical oscillator strength of s...
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E-Artikel |
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2002 |
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Online-Ressource 4 |
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APS Digital Backfile Archive 1893-2003 |
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| Übergeordnetes Werk: |
Enthalten in: Physical review / A - College Park, Md., 1970, 66(2002), 5 |
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volume:66 ; year:2002 ; number:5 ; extent:4 |
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| 245 | 1 | 0 | |a Contributions to the generalized oscillator strength for the inner-shell C 1s→3sσg transition in CO2 from the vibronic coupling mechanism |
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| 520 | |a An approach is proposed to account for the general effect of the nuclei motion in the intensity of electronic transitions caused by fast electron collision with molecular targets, following a similar procedure that has recently been used by our group to determine the optical oscillator strength of symmetry-forbidden transition, and which consists of expanding the (squared) transition moment along the normal coordinates of vibration. It is shown that the profile of total generalized oscillator strength as a function of the squared transferred moment can be significantly changed by the inclusion of terms that depend explicitly on the normal coordinates of vibration. The generalized oscillator strength for the inner-shell C 1s→3sσg transition in CO2 is calculated within this approach and compared with experimental results. | ||
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(DE-627)NLEJ248267248 (DE-601)aps:5ea06cfecc3d6ac1a32456b826400677f56fa4bf DE-627 ger DE-627 rakwb Contributions to the generalized oscillator strength for the inner-shell C 1s→3sσg transition in CO2 from the vibronic coupling mechanism 2002 Online-Ressource 4 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier An approach is proposed to account for the general effect of the nuclei motion in the intensity of electronic transitions caused by fast electron collision with molecular targets, following a similar procedure that has recently been used by our group to determine the optical oscillator strength of symmetry-forbidden transition, and which consists of expanding the (squared) transition moment along the normal coordinates of vibration. It is shown that the profile of total generalized oscillator strength as a function of the squared transferred moment can be significantly changed by the inclusion of terms that depend explicitly on the normal coordinates of vibration. The generalized oscillator strength for the inner-shell C 1s→3sσg transition in CO2 is calculated within this approach and compared with experimental results. APS Digital Backfile Archive 1893-2003 Rocha, Alexandre B. oth Enthalten in Physical review / A College Park, Md., 1970 66(2002), 5 Online-Ressource (DE-627)NLEJ248237853 (DE-600)1472694-4 1094-1622 nnns volume:66 year:2002 number:5 extent:4 https://www.tib.eu/de/suchen/id/aps%3A5ea06cfecc3d6ac1a32456b826400677f56fa4bf Verlag Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-APS GBV_NL_ARTICLE AR 66 2002 5 4 |
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(DE-627)NLEJ248267248 (DE-601)aps:5ea06cfecc3d6ac1a32456b826400677f56fa4bf DE-627 ger DE-627 rakwb Contributions to the generalized oscillator strength for the inner-shell C 1s→3sσg transition in CO2 from the vibronic coupling mechanism 2002 Online-Ressource 4 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier An approach is proposed to account for the general effect of the nuclei motion in the intensity of electronic transitions caused by fast electron collision with molecular targets, following a similar procedure that has recently been used by our group to determine the optical oscillator strength of symmetry-forbidden transition, and which consists of expanding the (squared) transition moment along the normal coordinates of vibration. It is shown that the profile of total generalized oscillator strength as a function of the squared transferred moment can be significantly changed by the inclusion of terms that depend explicitly on the normal coordinates of vibration. The generalized oscillator strength for the inner-shell C 1s→3sσg transition in CO2 is calculated within this approach and compared with experimental results. APS Digital Backfile Archive 1893-2003 Rocha, Alexandre B. oth Enthalten in Physical review / A College Park, Md., 1970 66(2002), 5 Online-Ressource (DE-627)NLEJ248237853 (DE-600)1472694-4 1094-1622 nnns volume:66 year:2002 number:5 extent:4 https://www.tib.eu/de/suchen/id/aps%3A5ea06cfecc3d6ac1a32456b826400677f56fa4bf Verlag Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-APS GBV_NL_ARTICLE AR 66 2002 5 4 |
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(DE-627)NLEJ248267248 (DE-601)aps:5ea06cfecc3d6ac1a32456b826400677f56fa4bf DE-627 ger DE-627 rakwb Contributions to the generalized oscillator strength for the inner-shell C 1s→3sσg transition in CO2 from the vibronic coupling mechanism 2002 Online-Ressource 4 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier An approach is proposed to account for the general effect of the nuclei motion in the intensity of electronic transitions caused by fast electron collision with molecular targets, following a similar procedure that has recently been used by our group to determine the optical oscillator strength of symmetry-forbidden transition, and which consists of expanding the (squared) transition moment along the normal coordinates of vibration. It is shown that the profile of total generalized oscillator strength as a function of the squared transferred moment can be significantly changed by the inclusion of terms that depend explicitly on the normal coordinates of vibration. The generalized oscillator strength for the inner-shell C 1s→3sσg transition in CO2 is calculated within this approach and compared with experimental results. APS Digital Backfile Archive 1893-2003 Rocha, Alexandre B. oth Enthalten in Physical review / A College Park, Md., 1970 66(2002), 5 Online-Ressource (DE-627)NLEJ248237853 (DE-600)1472694-4 1094-1622 nnns volume:66 year:2002 number:5 extent:4 https://www.tib.eu/de/suchen/id/aps%3A5ea06cfecc3d6ac1a32456b826400677f56fa4bf Verlag Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-APS GBV_NL_ARTICLE AR 66 2002 5 4 |
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(DE-627)NLEJ248267248 (DE-601)aps:5ea06cfecc3d6ac1a32456b826400677f56fa4bf DE-627 ger DE-627 rakwb Contributions to the generalized oscillator strength for the inner-shell C 1s→3sσg transition in CO2 from the vibronic coupling mechanism 2002 Online-Ressource 4 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier An approach is proposed to account for the general effect of the nuclei motion in the intensity of electronic transitions caused by fast electron collision with molecular targets, following a similar procedure that has recently been used by our group to determine the optical oscillator strength of symmetry-forbidden transition, and which consists of expanding the (squared) transition moment along the normal coordinates of vibration. It is shown that the profile of total generalized oscillator strength as a function of the squared transferred moment can be significantly changed by the inclusion of terms that depend explicitly on the normal coordinates of vibration. The generalized oscillator strength for the inner-shell C 1s→3sσg transition in CO2 is calculated within this approach and compared with experimental results. APS Digital Backfile Archive 1893-2003 Rocha, Alexandre B. oth Enthalten in Physical review / A College Park, Md., 1970 66(2002), 5 Online-Ressource (DE-627)NLEJ248237853 (DE-600)1472694-4 1094-1622 nnns volume:66 year:2002 number:5 extent:4 https://www.tib.eu/de/suchen/id/aps%3A5ea06cfecc3d6ac1a32456b826400677f56fa4bf Verlag Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-APS GBV_NL_ARTICLE AR 66 2002 5 4 |
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(DE-627)NLEJ248267248 (DE-601)aps:5ea06cfecc3d6ac1a32456b826400677f56fa4bf DE-627 ger DE-627 rakwb Contributions to the generalized oscillator strength for the inner-shell C 1s→3sσg transition in CO2 from the vibronic coupling mechanism 2002 Online-Ressource 4 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier An approach is proposed to account for the general effect of the nuclei motion in the intensity of electronic transitions caused by fast electron collision with molecular targets, following a similar procedure that has recently been used by our group to determine the optical oscillator strength of symmetry-forbidden transition, and which consists of expanding the (squared) transition moment along the normal coordinates of vibration. It is shown that the profile of total generalized oscillator strength as a function of the squared transferred moment can be significantly changed by the inclusion of terms that depend explicitly on the normal coordinates of vibration. The generalized oscillator strength for the inner-shell C 1s→3sσg transition in CO2 is calculated within this approach and compared with experimental results. APS Digital Backfile Archive 1893-2003 Rocha, Alexandre B. oth Enthalten in Physical review / A College Park, Md., 1970 66(2002), 5 Online-Ressource (DE-627)NLEJ248237853 (DE-600)1472694-4 1094-1622 nnns volume:66 year:2002 number:5 extent:4 https://www.tib.eu/de/suchen/id/aps%3A5ea06cfecc3d6ac1a32456b826400677f56fa4bf Verlag Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-APS GBV_NL_ARTICLE AR 66 2002 5 4 |
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Contributions to the generalized oscillator strength for the inner-shell C 1s→3sσg transition in CO2 from the vibronic coupling mechanism |
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An approach is proposed to account for the general effect of the nuclei motion in the intensity of electronic transitions caused by fast electron collision with molecular targets, following a similar procedure that has recently been used by our group to determine the optical oscillator strength of symmetry-forbidden transition, and which consists of expanding the (squared) transition moment along the normal coordinates of vibration. It is shown that the profile of total generalized oscillator strength as a function of the squared transferred moment can be significantly changed by the inclusion of terms that depend explicitly on the normal coordinates of vibration. The generalized oscillator strength for the inner-shell C 1s→3sσg transition in CO2 is calculated within this approach and compared with experimental results. |
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An approach is proposed to account for the general effect of the nuclei motion in the intensity of electronic transitions caused by fast electron collision with molecular targets, following a similar procedure that has recently been used by our group to determine the optical oscillator strength of symmetry-forbidden transition, and which consists of expanding the (squared) transition moment along the normal coordinates of vibration. It is shown that the profile of total generalized oscillator strength as a function of the squared transferred moment can be significantly changed by the inclusion of terms that depend explicitly on the normal coordinates of vibration. The generalized oscillator strength for the inner-shell C 1s→3sσg transition in CO2 is calculated within this approach and compared with experimental results. |
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An approach is proposed to account for the general effect of the nuclei motion in the intensity of electronic transitions caused by fast electron collision with molecular targets, following a similar procedure that has recently been used by our group to determine the optical oscillator strength of symmetry-forbidden transition, and which consists of expanding the (squared) transition moment along the normal coordinates of vibration. It is shown that the profile of total generalized oscillator strength as a function of the squared transferred moment can be significantly changed by the inclusion of terms that depend explicitly on the normal coordinates of vibration. The generalized oscillator strength for the inner-shell C 1s→3sσg transition in CO2 is calculated within this approach and compared with experimental results. |
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