Lattice-Stiffening Transition in Copolymer Films of Vinylidene Fluoride (70%) with Trifluoroethylene (30%)
We report the discovery of a compressibility phase transition at 160 K in crystalline copolymer films of vinylidene fluoride ( 70%) with trifluoroethylene ( 30%). This phase transition is distinct from the known bulk ferroelectric-paraelectric phase transition at 353 K and surface ferroelectric phas...
Ausführliche Beschreibung
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1999 |
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Online-Ressource 4 |
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APS Digital Backfile Archive 1893-2003 |
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Enthalten in: Physical review letters - College Park, Md. : APS, 1958, 83(1999), 22, Seite 4562-4565 |
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volume:83 ; year:1999 ; number:22 ; pages:4562-4565 ; extent:4 |
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| 520 | |a We report the discovery of a compressibility phase transition at 160 K in crystalline copolymer films of vinylidene fluoride ( 70%) with trifluoroethylene ( 30%). This phase transition is distinct from the known bulk ferroelectric-paraelectric phase transition at 353 K and surface ferroelectric phase transition at 295 K. The new phase transition is characterized by an increase in the effective Debye temperature from 48 to 245 K along the 〈010〉 direction as the temperature falls below 160 K. This phase transition is evident in neutron scattering, x-ray diffraction, angle-resolved photoemission, and in the dipole active phonon modes in electron energy-loss spectroscopy. | ||
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(DE-627)NLEJ250686600 (DE-601)aps:55f36ff890ef41fcd1fef52a6aee94285b961512 DE-627 ger DE-627 rakwb Lattice-Stiffening Transition in Copolymer Films of Vinylidene Fluoride (70%) with Trifluoroethylene (30%) 1999 Online-Ressource 4 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier We report the discovery of a compressibility phase transition at 160 K in crystalline copolymer films of vinylidene fluoride ( 70%) with trifluoroethylene ( 30%). This phase transition is distinct from the known bulk ferroelectric-paraelectric phase transition at 353 K and surface ferroelectric phase transition at 295 K. The new phase transition is characterized by an increase in the effective Debye temperature from 48 to 245 K along the 〈010〉 direction as the temperature falls below 160 K. This phase transition is evident in neutron scattering, x-ray diffraction, angle-resolved photoemission, and in the dipole active phonon modes in electron energy-loss spectroscopy. APS Digital Backfile Archive 1893-2003 Borca, C. N. oth Adenwalla, S. oth Choi, Jaewu oth Sprunger, P. T. oth Ducharme, Stephen oth Robertson, Lee oth Palto, S. P. oth Liu, Jianglai oth Poulsen, Matt oth Fridkin, V. M. oth You, H. oth Dowben, P. A. oth Enthalten in Physical review letters College Park, Md. : APS, 1958 83(1999), 22, Seite 4562-4565 Online-Ressource (DE-627)NLEJ248237888 (DE-600)1472655-5 1079-7114 nnns volume:83 year:1999 number:22 pages:4562-4565 extent:4 https://www.tib.eu/de/suchen/id/aps%3A55f36ff890ef41fcd1fef52a6aee94285b961512 Verlag Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-APS GBV_NL_ARTICLE AR 83 1999 22 4562-4565 4 |
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(DE-627)NLEJ250686600 (DE-601)aps:55f36ff890ef41fcd1fef52a6aee94285b961512 DE-627 ger DE-627 rakwb Lattice-Stiffening Transition in Copolymer Films of Vinylidene Fluoride (70%) with Trifluoroethylene (30%) 1999 Online-Ressource 4 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier We report the discovery of a compressibility phase transition at 160 K in crystalline copolymer films of vinylidene fluoride ( 70%) with trifluoroethylene ( 30%). This phase transition is distinct from the known bulk ferroelectric-paraelectric phase transition at 353 K and surface ferroelectric phase transition at 295 K. The new phase transition is characterized by an increase in the effective Debye temperature from 48 to 245 K along the 〈010〉 direction as the temperature falls below 160 K. This phase transition is evident in neutron scattering, x-ray diffraction, angle-resolved photoemission, and in the dipole active phonon modes in electron energy-loss spectroscopy. APS Digital Backfile Archive 1893-2003 Borca, C. N. oth Adenwalla, S. oth Choi, Jaewu oth Sprunger, P. T. oth Ducharme, Stephen oth Robertson, Lee oth Palto, S. P. oth Liu, Jianglai oth Poulsen, Matt oth Fridkin, V. M. oth You, H. oth Dowben, P. A. oth Enthalten in Physical review letters College Park, Md. : APS, 1958 83(1999), 22, Seite 4562-4565 Online-Ressource (DE-627)NLEJ248237888 (DE-600)1472655-5 1079-7114 nnns volume:83 year:1999 number:22 pages:4562-4565 extent:4 https://www.tib.eu/de/suchen/id/aps%3A55f36ff890ef41fcd1fef52a6aee94285b961512 Verlag Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-APS GBV_NL_ARTICLE AR 83 1999 22 4562-4565 4 |
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(DE-627)NLEJ250686600 (DE-601)aps:55f36ff890ef41fcd1fef52a6aee94285b961512 DE-627 ger DE-627 rakwb Lattice-Stiffening Transition in Copolymer Films of Vinylidene Fluoride (70%) with Trifluoroethylene (30%) 1999 Online-Ressource 4 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier We report the discovery of a compressibility phase transition at 160 K in crystalline copolymer films of vinylidene fluoride ( 70%) with trifluoroethylene ( 30%). This phase transition is distinct from the known bulk ferroelectric-paraelectric phase transition at 353 K and surface ferroelectric phase transition at 295 K. The new phase transition is characterized by an increase in the effective Debye temperature from 48 to 245 K along the 〈010〉 direction as the temperature falls below 160 K. This phase transition is evident in neutron scattering, x-ray diffraction, angle-resolved photoemission, and in the dipole active phonon modes in electron energy-loss spectroscopy. APS Digital Backfile Archive 1893-2003 Borca, C. N. oth Adenwalla, S. oth Choi, Jaewu oth Sprunger, P. T. oth Ducharme, Stephen oth Robertson, Lee oth Palto, S. P. oth Liu, Jianglai oth Poulsen, Matt oth Fridkin, V. M. oth You, H. oth Dowben, P. A. oth Enthalten in Physical review letters College Park, Md. : APS, 1958 83(1999), 22, Seite 4562-4565 Online-Ressource (DE-627)NLEJ248237888 (DE-600)1472655-5 1079-7114 nnns volume:83 year:1999 number:22 pages:4562-4565 extent:4 https://www.tib.eu/de/suchen/id/aps%3A55f36ff890ef41fcd1fef52a6aee94285b961512 Verlag Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-APS GBV_NL_ARTICLE AR 83 1999 22 4562-4565 4 |
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(DE-627)NLEJ250686600 (DE-601)aps:55f36ff890ef41fcd1fef52a6aee94285b961512 DE-627 ger DE-627 rakwb Lattice-Stiffening Transition in Copolymer Films of Vinylidene Fluoride (70%) with Trifluoroethylene (30%) 1999 Online-Ressource 4 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier We report the discovery of a compressibility phase transition at 160 K in crystalline copolymer films of vinylidene fluoride ( 70%) with trifluoroethylene ( 30%). This phase transition is distinct from the known bulk ferroelectric-paraelectric phase transition at 353 K and surface ferroelectric phase transition at 295 K. The new phase transition is characterized by an increase in the effective Debye temperature from 48 to 245 K along the 〈010〉 direction as the temperature falls below 160 K. This phase transition is evident in neutron scattering, x-ray diffraction, angle-resolved photoemission, and in the dipole active phonon modes in electron energy-loss spectroscopy. APS Digital Backfile Archive 1893-2003 Borca, C. N. oth Adenwalla, S. oth Choi, Jaewu oth Sprunger, P. T. oth Ducharme, Stephen oth Robertson, Lee oth Palto, S. P. oth Liu, Jianglai oth Poulsen, Matt oth Fridkin, V. M. oth You, H. oth Dowben, P. A. oth Enthalten in Physical review letters College Park, Md. : APS, 1958 83(1999), 22, Seite 4562-4565 Online-Ressource (DE-627)NLEJ248237888 (DE-600)1472655-5 1079-7114 nnns volume:83 year:1999 number:22 pages:4562-4565 extent:4 https://www.tib.eu/de/suchen/id/aps%3A55f36ff890ef41fcd1fef52a6aee94285b961512 Verlag Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-APS GBV_NL_ARTICLE AR 83 1999 22 4562-4565 4 |
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(DE-627)NLEJ250686600 (DE-601)aps:55f36ff890ef41fcd1fef52a6aee94285b961512 DE-627 ger DE-627 rakwb Lattice-Stiffening Transition in Copolymer Films of Vinylidene Fluoride (70%) with Trifluoroethylene (30%) 1999 Online-Ressource 4 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier We report the discovery of a compressibility phase transition at 160 K in crystalline copolymer films of vinylidene fluoride ( 70%) with trifluoroethylene ( 30%). This phase transition is distinct from the known bulk ferroelectric-paraelectric phase transition at 353 K and surface ferroelectric phase transition at 295 K. The new phase transition is characterized by an increase in the effective Debye temperature from 48 to 245 K along the 〈010〉 direction as the temperature falls below 160 K. This phase transition is evident in neutron scattering, x-ray diffraction, angle-resolved photoemission, and in the dipole active phonon modes in electron energy-loss spectroscopy. APS Digital Backfile Archive 1893-2003 Borca, C. N. oth Adenwalla, S. oth Choi, Jaewu oth Sprunger, P. T. oth Ducharme, Stephen oth Robertson, Lee oth Palto, S. P. oth Liu, Jianglai oth Poulsen, Matt oth Fridkin, V. M. oth You, H. oth Dowben, P. A. oth Enthalten in Physical review letters College Park, Md. : APS, 1958 83(1999), 22, Seite 4562-4565 Online-Ressource (DE-627)NLEJ248237888 (DE-600)1472655-5 1079-7114 nnns volume:83 year:1999 number:22 pages:4562-4565 extent:4 https://www.tib.eu/de/suchen/id/aps%3A55f36ff890ef41fcd1fef52a6aee94285b961512 Verlag Deutschlandweit zugänglich GBV_USEFLAG_U ZDB-1-APS GBV_NL_ARTICLE AR 83 1999 22 4562-4565 4 |
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Lattice-Stiffening Transition in Copolymer Films of Vinylidene Fluoride (70%) with Trifluoroethylene (30%) |
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We report the discovery of a compressibility phase transition at 160 K in crystalline copolymer films of vinylidene fluoride ( 70%) with trifluoroethylene ( 30%). This phase transition is distinct from the known bulk ferroelectric-paraelectric phase transition at 353 K and surface ferroelectric phase transition at 295 K. The new phase transition is characterized by an increase in the effective Debye temperature from 48 to 245 K along the 〈010〉 direction as the temperature falls below 160 K. This phase transition is evident in neutron scattering, x-ray diffraction, angle-resolved photoemission, and in the dipole active phonon modes in electron energy-loss spectroscopy. |
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We report the discovery of a compressibility phase transition at 160 K in crystalline copolymer films of vinylidene fluoride ( 70%) with trifluoroethylene ( 30%). This phase transition is distinct from the known bulk ferroelectric-paraelectric phase transition at 353 K and surface ferroelectric phase transition at 295 K. The new phase transition is characterized by an increase in the effective Debye temperature from 48 to 245 K along the 〈010〉 direction as the temperature falls below 160 K. This phase transition is evident in neutron scattering, x-ray diffraction, angle-resolved photoemission, and in the dipole active phonon modes in electron energy-loss spectroscopy. |
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We report the discovery of a compressibility phase transition at 160 K in crystalline copolymer films of vinylidene fluoride ( 70%) with trifluoroethylene ( 30%). This phase transition is distinct from the known bulk ferroelectric-paraelectric phase transition at 353 K and surface ferroelectric phase transition at 295 K. The new phase transition is characterized by an increase in the effective Debye temperature from 48 to 245 K along the 〈010〉 direction as the temperature falls below 160 K. This phase transition is evident in neutron scattering, x-ray diffraction, angle-resolved photoemission, and in the dipole active phonon modes in electron energy-loss spectroscopy. |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">NLEJ250686600</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20231114105422.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">231114s1999 xx |||||o 00| ||und c</controlfield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)NLEJ250686600</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-601)aps:55f36ff890ef41fcd1fef52a6aee94285b961512</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Lattice-Stiffening Transition in Copolymer Films of Vinylidene Fluoride (70%) with Trifluoroethylene (30%)</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">1999</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield></datafield><datafield tag="300" ind1=" " ind2=" "><subfield code="a">4</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">We report the discovery of a compressibility phase transition at 160 K in crystalline copolymer films of vinylidene fluoride ( 70%) with trifluoroethylene ( 30%). This phase transition is distinct from the known bulk ferroelectric-paraelectric phase transition at 353 K and surface ferroelectric phase transition at 295 K. The new phase transition is characterized by an increase in the effective Debye temperature from 48 to 245 K along the 〈010〉 direction as the temperature falls below 160 K. This phase transition is evident in neutron scattering, x-ray diffraction, angle-resolved photoemission, and in the dipole active phonon modes in electron energy-loss spectroscopy.</subfield></datafield><datafield tag="533" ind1=" " ind2=" "><subfield code="f">APS Digital Backfile Archive 1893-2003</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Borca, C. N.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Adenwalla, S.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Choi, Jaewu</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Sprunger, P. T.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Ducharme, Stephen</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Robertson, Lee</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Palto, S. 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A.</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Physical review letters</subfield><subfield code="d">College Park, Md. : APS, 1958</subfield><subfield code="g">83(1999), 22, Seite 4562-4565</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)NLEJ248237888</subfield><subfield code="w">(DE-600)1472655-5</subfield><subfield code="x">1079-7114</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:83</subfield><subfield code="g">year:1999</subfield><subfield code="g">number:22</subfield><subfield code="g">pages:4562-4565</subfield><subfield code="g">extent:4</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://www.tib.eu/de/suchen/id/aps%3A55f36ff890ef41fcd1fef52a6aee94285b961512</subfield><subfield code="x">Verlag</subfield><subfield code="z">Deutschlandweit zugänglich</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_U</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">ZDB-1-APS</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_NL_ARTICLE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">83</subfield><subfield code="j">1999</subfield><subfield code="e">22</subfield><subfield code="h">4562-4565</subfield><subfield code="g">4</subfield></datafield></record></collection>
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