Synthesis of β-Keto Acids and Methyl Ketones Using Bis(trimethylsilyl) Malonate and Triethylamine in the Presence of Lithium or Magnesium Halides
Bis(trimethylsilyl) malonate is acylated in good yields with acid chlorides and acyl carbonates using triethylamine and magnesium or lithium salts to give β-keto acids or methyl ketones. Compared to other procedures, which use strong bases, this method is inexpensive, safe and convenient; especially...
Ausführliche Beschreibung
Autor*in: |
Rathke, Michael [verfasserIn] Nowak, Michael [verfasserIn] |
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Format: |
E-Artikel |
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Sprache: |
Englisch |
Erschienen: |
2011 |
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Übergeordnetes Werk: |
Enthalten in: Synthetic communications - Philadelphia, Pa. : Taylor & Francis, 1971, 15(1985), 12 vom: 01. Okt., Seite 1039-1049 |
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Übergeordnetes Werk: |
number:12 ; volume:15 ; year:1985 ; month:10 ; day:01 ; pages:1039-1049 |
Links: |
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DOI / URN: |
10.1080/00397918508076840 |
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Katalog-ID: |
NLEJ252320530 |
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10.1080/00397918508076840 doi (DE-627)NLEJ252320530 (TFO)768324381 DE-627 ger DE-627 rda eng Rathke, Michael verfasserin aut Synthesis of β-Keto Acids and Methyl Ketones Using Bis(trimethylsilyl) Malonate and Triethylamine in the Presence of Lithium or Magnesium Halides 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Bis(trimethylsilyl) malonate is acylated in good yields with acid chlorides and acyl carbonates using triethylamine and magnesium or lithium salts to give β-keto acids or methyl ketones. Compared to other procedures, which use strong bases, this method is inexpensive, safe and convenient; especially for large scale reactions. Nowak, Michael verfasserin aut Enthalten in Synthetic communications Philadelphia, Pa. : Taylor & Francis, 1971 15(1985), 12 vom: 01. Okt., Seite 1039-1049 Online-Ressource (DE-627)NLEJ252311264 (DE-600)2043259-8 (DE-576)117544086 1532-2432 nnns number:12 volume:15 year:1985 month:10 day:01 pages:1039-1049 https://www.tib.eu/de/suchen/id/tandf%3A35873fef717a5bfe992a934415385c981863b9af Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 12 15 1985 10 01 1039-1049 |
spelling |
10.1080/00397918508076840 doi (DE-627)NLEJ252320530 (TFO)768324381 DE-627 ger DE-627 rda eng Rathke, Michael verfasserin aut Synthesis of β-Keto Acids and Methyl Ketones Using Bis(trimethylsilyl) Malonate and Triethylamine in the Presence of Lithium or Magnesium Halides 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Bis(trimethylsilyl) malonate is acylated in good yields with acid chlorides and acyl carbonates using triethylamine and magnesium or lithium salts to give β-keto acids or methyl ketones. Compared to other procedures, which use strong bases, this method is inexpensive, safe and convenient; especially for large scale reactions. Nowak, Michael verfasserin aut Enthalten in Synthetic communications Philadelphia, Pa. : Taylor & Francis, 1971 15(1985), 12 vom: 01. Okt., Seite 1039-1049 Online-Ressource (DE-627)NLEJ252311264 (DE-600)2043259-8 (DE-576)117544086 1532-2432 nnns number:12 volume:15 year:1985 month:10 day:01 pages:1039-1049 https://www.tib.eu/de/suchen/id/tandf%3A35873fef717a5bfe992a934415385c981863b9af Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 12 15 1985 10 01 1039-1049 |
allfields_unstemmed |
10.1080/00397918508076840 doi (DE-627)NLEJ252320530 (TFO)768324381 DE-627 ger DE-627 rda eng Rathke, Michael verfasserin aut Synthesis of β-Keto Acids and Methyl Ketones Using Bis(trimethylsilyl) Malonate and Triethylamine in the Presence of Lithium or Magnesium Halides 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Bis(trimethylsilyl) malonate is acylated in good yields with acid chlorides and acyl carbonates using triethylamine and magnesium or lithium salts to give β-keto acids or methyl ketones. Compared to other procedures, which use strong bases, this method is inexpensive, safe and convenient; especially for large scale reactions. Nowak, Michael verfasserin aut Enthalten in Synthetic communications Philadelphia, Pa. : Taylor & Francis, 1971 15(1985), 12 vom: 01. Okt., Seite 1039-1049 Online-Ressource (DE-627)NLEJ252311264 (DE-600)2043259-8 (DE-576)117544086 1532-2432 nnns number:12 volume:15 year:1985 month:10 day:01 pages:1039-1049 https://www.tib.eu/de/suchen/id/tandf%3A35873fef717a5bfe992a934415385c981863b9af Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 12 15 1985 10 01 1039-1049 |
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10.1080/00397918508076840 doi (DE-627)NLEJ252320530 (TFO)768324381 DE-627 ger DE-627 rda eng Rathke, Michael verfasserin aut Synthesis of β-Keto Acids and Methyl Ketones Using Bis(trimethylsilyl) Malonate and Triethylamine in the Presence of Lithium or Magnesium Halides 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Bis(trimethylsilyl) malonate is acylated in good yields with acid chlorides and acyl carbonates using triethylamine and magnesium or lithium salts to give β-keto acids or methyl ketones. Compared to other procedures, which use strong bases, this method is inexpensive, safe and convenient; especially for large scale reactions. Nowak, Michael verfasserin aut Enthalten in Synthetic communications Philadelphia, Pa. : Taylor & Francis, 1971 15(1985), 12 vom: 01. Okt., Seite 1039-1049 Online-Ressource (DE-627)NLEJ252311264 (DE-600)2043259-8 (DE-576)117544086 1532-2432 nnns number:12 volume:15 year:1985 month:10 day:01 pages:1039-1049 https://www.tib.eu/de/suchen/id/tandf%3A35873fef717a5bfe992a934415385c981863b9af Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 12 15 1985 10 01 1039-1049 |
allfieldsSound |
10.1080/00397918508076840 doi (DE-627)NLEJ252320530 (TFO)768324381 DE-627 ger DE-627 rda eng Rathke, Michael verfasserin aut Synthesis of β-Keto Acids and Methyl Ketones Using Bis(trimethylsilyl) Malonate and Triethylamine in the Presence of Lithium or Magnesium Halides 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Bis(trimethylsilyl) malonate is acylated in good yields with acid chlorides and acyl carbonates using triethylamine and magnesium or lithium salts to give β-keto acids or methyl ketones. Compared to other procedures, which use strong bases, this method is inexpensive, safe and convenient; especially for large scale reactions. Nowak, Michael verfasserin aut Enthalten in Synthetic communications Philadelphia, Pa. : Taylor & Francis, 1971 15(1985), 12 vom: 01. Okt., Seite 1039-1049 Online-Ressource (DE-627)NLEJ252311264 (DE-600)2043259-8 (DE-576)117544086 1532-2432 nnns number:12 volume:15 year:1985 month:10 day:01 pages:1039-1049 https://www.tib.eu/de/suchen/id/tandf%3A35873fef717a5bfe992a934415385c981863b9af Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 12 15 1985 10 01 1039-1049 |
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Rathke, Michael Synthesis of β-Keto Acids and Methyl Ketones Using Bis(trimethylsilyl) Malonate and Triethylamine in the Presence of Lithium or Magnesium Halides |
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Synthesis of β-Keto Acids and Methyl Ketones Using Bis(trimethylsilyl) Malonate and Triethylamine in the Presence of Lithium or Magnesium Halides |
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Synthesis of β-Keto Acids and Methyl Ketones Using Bis(trimethylsilyl) Malonate and Triethylamine in the Presence of Lithium or Magnesium Halides |
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synthesis of β-keto acids and methyl ketones using bis(trimethylsilyl) malonate and triethylamine in the presence of lithium or magnesium halides |
title_auth |
Synthesis of β-Keto Acids and Methyl Ketones Using Bis(trimethylsilyl) Malonate and Triethylamine in the Presence of Lithium or Magnesium Halides |
abstract |
Bis(trimethylsilyl) malonate is acylated in good yields with acid chlorides and acyl carbonates using triethylamine and magnesium or lithium salts to give β-keto acids or methyl ketones. Compared to other procedures, which use strong bases, this method is inexpensive, safe and convenient; especially for large scale reactions. |
abstractGer |
Bis(trimethylsilyl) malonate is acylated in good yields with acid chlorides and acyl carbonates using triethylamine and magnesium or lithium salts to give β-keto acids or methyl ketones. Compared to other procedures, which use strong bases, this method is inexpensive, safe and convenient; especially for large scale reactions. |
abstract_unstemmed |
Bis(trimethylsilyl) malonate is acylated in good yields with acid chlorides and acyl carbonates using triethylamine and magnesium or lithium salts to give β-keto acids or methyl ketones. Compared to other procedures, which use strong bases, this method is inexpensive, safe and convenient; especially for large scale reactions. |
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Synthesis of β-Keto Acids and Methyl Ketones Using Bis(trimethylsilyl) Malonate and Triethylamine in the Presence of Lithium or Magnesium Halides |
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