The Reaction Mechanism of 2,6-di-Tert. Butyl Phenol Alkylation by Methyl Acrylate in the Presence of 2,6-di-Tert. Butyl Phenolate of Potassium and Alkali
The reaction of 2,6-di-tert. butyl phenol alkylation in the conditions of alkali catalysis is used in the synthesis of antioxidants, inhibitors of radical reactions in the processes of polymer stabilizers production technology. The catalytic system consisting in 2,6-di-tert. butylphenolate of alkali...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Volod'kin, A. A. [verfasserIn] Zaitsev, A. S. [verfasserIn] Rubyailo, V. L. [verfasserIn] Belyakov, V. A. [verfasserIn] Zalkov, G. E. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2011 |
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| Übergeordnetes Werk: |
Enthalten in: International journal of polymeric materials - London [u.a.] : Taylor & Francis, 1971, 14(1990), 1-2 vom: 01. Sept., Seite 67-77 |
|---|---|
| Übergeordnetes Werk: |
number:1-2 ; volume:14 ; year:1990 ; month:09 ; day:01 ; pages:67-77 |
| Links: |
|---|
| DOI / URN: |
10.1080/00914039008041072 |
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NLEJ252417658 |
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| 520 | |a The reaction of 2,6-di-tert. butyl phenol alkylation in the conditions of alkali catalysis is used in the synthesis of antioxidants, inhibitors of radical reactions in the processes of polymer stabilizers production technology. The catalytic system consisting in 2,6-di-tert. butylphenolate of alkali metal and alkali metal hydroxide, is most efficient in the alkylation reaction of 2,6-di-tert. butyl phenol by methyl acrylate. For the investigation of the reaction mechanism of 2,6-di-tert. butyl phenol alkylation by methyl acrylate in the presence of 2,6-di-tert. butylphenolate of potassium (ArOK) and alkali (KOH) on the basis of consumption kinetics of 2,6-di-tert. butyl phenol (ArOH), the computer calculation procedure was used for the kinetic system containing 14 components with life times differing by a few magnitudes of order. The program was adapted for the operation in the operational system RT-60 of MINICOMPUTER (Model MERA-660). The kinetic scheme consists of 28 elementary stages which describe the formation mechanism of methylox compound, (4-hydroxy-3,5-di-tert. butyl phenol) potassium propionate as well as water, methyl alcohol, alkali monohydrate and ion pairs. | ||
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| 700 | 1 | |a Zalkov, G. E. |e verfasserin |4 aut | |
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10.1080/00914039008041072 doi (DE-627)NLEJ252417658 (TFO)758004148 DE-627 ger DE-627 rda eng Volod'kin, A. A. verfasserin aut The Reaction Mechanism of 2,6-di-Tert. Butyl Phenol Alkylation by Methyl Acrylate in the Presence of 2,6-di-Tert. Butyl Phenolate of Potassium and Alkali 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The reaction of 2,6-di-tert. butyl phenol alkylation in the conditions of alkali catalysis is used in the synthesis of antioxidants, inhibitors of radical reactions in the processes of polymer stabilizers production technology. The catalytic system consisting in 2,6-di-tert. butylphenolate of alkali metal and alkali metal hydroxide, is most efficient in the alkylation reaction of 2,6-di-tert. butyl phenol by methyl acrylate. For the investigation of the reaction mechanism of 2,6-di-tert. butyl phenol alkylation by methyl acrylate in the presence of 2,6-di-tert. butylphenolate of potassium (ArOK) and alkali (KOH) on the basis of consumption kinetics of 2,6-di-tert. butyl phenol (ArOH), the computer calculation procedure was used for the kinetic system containing 14 components with life times differing by a few magnitudes of order. The program was adapted for the operation in the operational system RT-60 of MINICOMPUTER (Model MERA-660). The kinetic scheme consists of 28 elementary stages which describe the formation mechanism of methylox compound, (4-hydroxy-3,5-di-tert. butyl phenol) potassium propionate as well as water, methyl alcohol, alkali monohydrate and ion pairs. Zaitsev, A. S. verfasserin aut Rubyailo, V. L. verfasserin aut Belyakov, V. A. verfasserin aut Zalkov, G. E. verfasserin aut Enthalten in International journal of polymeric materials London [u.a.] : Taylor & Francis, 1971 14(1990), 1-2 vom: 01. Sept., Seite 67-77 Online-Ressource (DE-627)NLEJ252416457 (DE-600)2045637-2 (DE-576)263254062 1563-535X nnns number:1-2 volume:14 year:1990 month:09 day:01 pages:67-77 https://www.tib.eu/de/suchen/id/tandf%3A14aaaf50129184bc36fc6348be6c0f1779f3088a Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 1-2 14 1990 9 01 67-77 |
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10.1080/00914039008041072 doi (DE-627)NLEJ252417658 (TFO)758004148 DE-627 ger DE-627 rda eng Volod'kin, A. A. verfasserin aut The Reaction Mechanism of 2,6-di-Tert. Butyl Phenol Alkylation by Methyl Acrylate in the Presence of 2,6-di-Tert. Butyl Phenolate of Potassium and Alkali 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The reaction of 2,6-di-tert. butyl phenol alkylation in the conditions of alkali catalysis is used in the synthesis of antioxidants, inhibitors of radical reactions in the processes of polymer stabilizers production technology. The catalytic system consisting in 2,6-di-tert. butylphenolate of alkali metal and alkali metal hydroxide, is most efficient in the alkylation reaction of 2,6-di-tert. butyl phenol by methyl acrylate. For the investigation of the reaction mechanism of 2,6-di-tert. butyl phenol alkylation by methyl acrylate in the presence of 2,6-di-tert. butylphenolate of potassium (ArOK) and alkali (KOH) on the basis of consumption kinetics of 2,6-di-tert. butyl phenol (ArOH), the computer calculation procedure was used for the kinetic system containing 14 components with life times differing by a few magnitudes of order. The program was adapted for the operation in the operational system RT-60 of MINICOMPUTER (Model MERA-660). The kinetic scheme consists of 28 elementary stages which describe the formation mechanism of methylox compound, (4-hydroxy-3,5-di-tert. butyl phenol) potassium propionate as well as water, methyl alcohol, alkali monohydrate and ion pairs. Zaitsev, A. S. verfasserin aut Rubyailo, V. L. verfasserin aut Belyakov, V. A. verfasserin aut Zalkov, G. E. verfasserin aut Enthalten in International journal of polymeric materials London [u.a.] : Taylor & Francis, 1971 14(1990), 1-2 vom: 01. Sept., Seite 67-77 Online-Ressource (DE-627)NLEJ252416457 (DE-600)2045637-2 (DE-576)263254062 1563-535X nnns number:1-2 volume:14 year:1990 month:09 day:01 pages:67-77 https://www.tib.eu/de/suchen/id/tandf%3A14aaaf50129184bc36fc6348be6c0f1779f3088a Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 1-2 14 1990 9 01 67-77 |
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10.1080/00914039008041072 doi (DE-627)NLEJ252417658 (TFO)758004148 DE-627 ger DE-627 rda eng Volod'kin, A. A. verfasserin aut The Reaction Mechanism of 2,6-di-Tert. Butyl Phenol Alkylation by Methyl Acrylate in the Presence of 2,6-di-Tert. Butyl Phenolate of Potassium and Alkali 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The reaction of 2,6-di-tert. butyl phenol alkylation in the conditions of alkali catalysis is used in the synthesis of antioxidants, inhibitors of radical reactions in the processes of polymer stabilizers production technology. The catalytic system consisting in 2,6-di-tert. butylphenolate of alkali metal and alkali metal hydroxide, is most efficient in the alkylation reaction of 2,6-di-tert. butyl phenol by methyl acrylate. For the investigation of the reaction mechanism of 2,6-di-tert. butyl phenol alkylation by methyl acrylate in the presence of 2,6-di-tert. butylphenolate of potassium (ArOK) and alkali (KOH) on the basis of consumption kinetics of 2,6-di-tert. butyl phenol (ArOH), the computer calculation procedure was used for the kinetic system containing 14 components with life times differing by a few magnitudes of order. The program was adapted for the operation in the operational system RT-60 of MINICOMPUTER (Model MERA-660). The kinetic scheme consists of 28 elementary stages which describe the formation mechanism of methylox compound, (4-hydroxy-3,5-di-tert. butyl phenol) potassium propionate as well as water, methyl alcohol, alkali monohydrate and ion pairs. Zaitsev, A. S. verfasserin aut Rubyailo, V. L. verfasserin aut Belyakov, V. A. verfasserin aut Zalkov, G. E. verfasserin aut Enthalten in International journal of polymeric materials London [u.a.] : Taylor & Francis, 1971 14(1990), 1-2 vom: 01. Sept., Seite 67-77 Online-Ressource (DE-627)NLEJ252416457 (DE-600)2045637-2 (DE-576)263254062 1563-535X nnns number:1-2 volume:14 year:1990 month:09 day:01 pages:67-77 https://www.tib.eu/de/suchen/id/tandf%3A14aaaf50129184bc36fc6348be6c0f1779f3088a Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 1-2 14 1990 9 01 67-77 |
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10.1080/00914039008041072 doi (DE-627)NLEJ252417658 (TFO)758004148 DE-627 ger DE-627 rda eng Volod'kin, A. A. verfasserin aut The Reaction Mechanism of 2,6-di-Tert. Butyl Phenol Alkylation by Methyl Acrylate in the Presence of 2,6-di-Tert. Butyl Phenolate of Potassium and Alkali 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The reaction of 2,6-di-tert. butyl phenol alkylation in the conditions of alkali catalysis is used in the synthesis of antioxidants, inhibitors of radical reactions in the processes of polymer stabilizers production technology. The catalytic system consisting in 2,6-di-tert. butylphenolate of alkali metal and alkali metal hydroxide, is most efficient in the alkylation reaction of 2,6-di-tert. butyl phenol by methyl acrylate. For the investigation of the reaction mechanism of 2,6-di-tert. butyl phenol alkylation by methyl acrylate in the presence of 2,6-di-tert. butylphenolate of potassium (ArOK) and alkali (KOH) on the basis of consumption kinetics of 2,6-di-tert. butyl phenol (ArOH), the computer calculation procedure was used for the kinetic system containing 14 components with life times differing by a few magnitudes of order. The program was adapted for the operation in the operational system RT-60 of MINICOMPUTER (Model MERA-660). The kinetic scheme consists of 28 elementary stages which describe the formation mechanism of methylox compound, (4-hydroxy-3,5-di-tert. butyl phenol) potassium propionate as well as water, methyl alcohol, alkali monohydrate and ion pairs. Zaitsev, A. S. verfasserin aut Rubyailo, V. L. verfasserin aut Belyakov, V. A. verfasserin aut Zalkov, G. E. verfasserin aut Enthalten in International journal of polymeric materials London [u.a.] : Taylor & Francis, 1971 14(1990), 1-2 vom: 01. Sept., Seite 67-77 Online-Ressource (DE-627)NLEJ252416457 (DE-600)2045637-2 (DE-576)263254062 1563-535X nnns number:1-2 volume:14 year:1990 month:09 day:01 pages:67-77 https://www.tib.eu/de/suchen/id/tandf%3A14aaaf50129184bc36fc6348be6c0f1779f3088a Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 1-2 14 1990 9 01 67-77 |
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10.1080/00914039008041072 doi (DE-627)NLEJ252417658 (TFO)758004148 DE-627 ger DE-627 rda eng Volod'kin, A. A. verfasserin aut The Reaction Mechanism of 2,6-di-Tert. Butyl Phenol Alkylation by Methyl Acrylate in the Presence of 2,6-di-Tert. Butyl Phenolate of Potassium and Alkali 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The reaction of 2,6-di-tert. butyl phenol alkylation in the conditions of alkali catalysis is used in the synthesis of antioxidants, inhibitors of radical reactions in the processes of polymer stabilizers production technology. The catalytic system consisting in 2,6-di-tert. butylphenolate of alkali metal and alkali metal hydroxide, is most efficient in the alkylation reaction of 2,6-di-tert. butyl phenol by methyl acrylate. For the investigation of the reaction mechanism of 2,6-di-tert. butyl phenol alkylation by methyl acrylate in the presence of 2,6-di-tert. butylphenolate of potassium (ArOK) and alkali (KOH) on the basis of consumption kinetics of 2,6-di-tert. butyl phenol (ArOH), the computer calculation procedure was used for the kinetic system containing 14 components with life times differing by a few magnitudes of order. The program was adapted for the operation in the operational system RT-60 of MINICOMPUTER (Model MERA-660). The kinetic scheme consists of 28 elementary stages which describe the formation mechanism of methylox compound, (4-hydroxy-3,5-di-tert. butyl phenol) potassium propionate as well as water, methyl alcohol, alkali monohydrate and ion pairs. Zaitsev, A. S. verfasserin aut Rubyailo, V. L. verfasserin aut Belyakov, V. A. verfasserin aut Zalkov, G. E. verfasserin aut Enthalten in International journal of polymeric materials London [u.a.] : Taylor & Francis, 1971 14(1990), 1-2 vom: 01. Sept., Seite 67-77 Online-Ressource (DE-627)NLEJ252416457 (DE-600)2045637-2 (DE-576)263254062 1563-535X nnns number:1-2 volume:14 year:1990 month:09 day:01 pages:67-77 https://www.tib.eu/de/suchen/id/tandf%3A14aaaf50129184bc36fc6348be6c0f1779f3088a Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 1-2 14 1990 9 01 67-77 |
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Volod'kin, A. A. The Reaction Mechanism of 2,6-di-Tert. Butyl Phenol Alkylation by Methyl Acrylate in the Presence of 2,6-di-Tert. Butyl Phenolate of Potassium and Alkali |
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the reaction mechanism of 2,6-di-tert. butyl phenol alkylation by methyl acrylate in the presence of 2,6-di-tert. butyl phenolate of potassium and alkali |
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The Reaction Mechanism of 2,6-di-Tert. Butyl Phenol Alkylation by Methyl Acrylate in the Presence of 2,6-di-Tert. Butyl Phenolate of Potassium and Alkali |
| abstract |
The reaction of 2,6-di-tert. butyl phenol alkylation in the conditions of alkali catalysis is used in the synthesis of antioxidants, inhibitors of radical reactions in the processes of polymer stabilizers production technology. The catalytic system consisting in 2,6-di-tert. butylphenolate of alkali metal and alkali metal hydroxide, is most efficient in the alkylation reaction of 2,6-di-tert. butyl phenol by methyl acrylate. For the investigation of the reaction mechanism of 2,6-di-tert. butyl phenol alkylation by methyl acrylate in the presence of 2,6-di-tert. butylphenolate of potassium (ArOK) and alkali (KOH) on the basis of consumption kinetics of 2,6-di-tert. butyl phenol (ArOH), the computer calculation procedure was used for the kinetic system containing 14 components with life times differing by a few magnitudes of order. The program was adapted for the operation in the operational system RT-60 of MINICOMPUTER (Model MERA-660). The kinetic scheme consists of 28 elementary stages which describe the formation mechanism of methylox compound, (4-hydroxy-3,5-di-tert. butyl phenol) potassium propionate as well as water, methyl alcohol, alkali monohydrate and ion pairs. |
| abstractGer |
The reaction of 2,6-di-tert. butyl phenol alkylation in the conditions of alkali catalysis is used in the synthesis of antioxidants, inhibitors of radical reactions in the processes of polymer stabilizers production technology. The catalytic system consisting in 2,6-di-tert. butylphenolate of alkali metal and alkali metal hydroxide, is most efficient in the alkylation reaction of 2,6-di-tert. butyl phenol by methyl acrylate. For the investigation of the reaction mechanism of 2,6-di-tert. butyl phenol alkylation by methyl acrylate in the presence of 2,6-di-tert. butylphenolate of potassium (ArOK) and alkali (KOH) on the basis of consumption kinetics of 2,6-di-tert. butyl phenol (ArOH), the computer calculation procedure was used for the kinetic system containing 14 components with life times differing by a few magnitudes of order. The program was adapted for the operation in the operational system RT-60 of MINICOMPUTER (Model MERA-660). The kinetic scheme consists of 28 elementary stages which describe the formation mechanism of methylox compound, (4-hydroxy-3,5-di-tert. butyl phenol) potassium propionate as well as water, methyl alcohol, alkali monohydrate and ion pairs. |
| abstract_unstemmed |
The reaction of 2,6-di-tert. butyl phenol alkylation in the conditions of alkali catalysis is used in the synthesis of antioxidants, inhibitors of radical reactions in the processes of polymer stabilizers production technology. The catalytic system consisting in 2,6-di-tert. butylphenolate of alkali metal and alkali metal hydroxide, is most efficient in the alkylation reaction of 2,6-di-tert. butyl phenol by methyl acrylate. For the investigation of the reaction mechanism of 2,6-di-tert. butyl phenol alkylation by methyl acrylate in the presence of 2,6-di-tert. butylphenolate of potassium (ArOK) and alkali (KOH) on the basis of consumption kinetics of 2,6-di-tert. butyl phenol (ArOH), the computer calculation procedure was used for the kinetic system containing 14 components with life times differing by a few magnitudes of order. The program was adapted for the operation in the operational system RT-60 of MINICOMPUTER (Model MERA-660). The kinetic scheme consists of 28 elementary stages which describe the formation mechanism of methylox compound, (4-hydroxy-3,5-di-tert. butyl phenol) potassium propionate as well as water, methyl alcohol, alkali monohydrate and ion pairs. |
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| title_short |
The Reaction Mechanism of 2,6-di-Tert. Butyl Phenol Alkylation by Methyl Acrylate in the Presence of 2,6-di-Tert. Butyl Phenolate of Potassium and Alkali |
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https://www.tib.eu/de/suchen/id/tandf%3A14aaaf50129184bc36fc6348be6c0f1779f3088a |
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Zaitsev, A. S. Rubyailo, V. L. Belyakov, V. A. Zalkov, G. E. |
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Zaitsev, A. S. Rubyailo, V. L. Belyakov, V. A. Zalkov, G. E. |
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| doi_str |
10.1080/00914039008041072 |
| up_date |
2024-07-06T12:46:22.787Z |
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