THE STRUCTURE OF A LOW-TEMPERATURE FORM OF TRANS-[Ir(PYRIDINE)4Cl2]Cl. 6H2O
Trans-[Ir(pyridine)4Cl2]Cl. 6H2O exists in at least two forms. A high temperature form, crystallized from water at room temperature, is disordered in the solid state. A low temperature form, crystallized from aqueous solution at 2°. has been structurally characterized using x-ray crystallographic me...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Gillard, R. D. [verfasserIn] Mitchell, Simon [verfasserIn] Williams, Peter [verfasserIn] Vagg, Robert [verfasserIn] |
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Englisch |
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2011 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of coordination chemistry - London [u.a.] : Taylor & Francis, 1971, 13(1984), 4 vom: 01. Sept., Seite 325-330 |
|---|---|
| Übergeordnetes Werk: |
number:4 ; volume:13 ; year:1984 ; month:09 ; day:01 ; pages:325-330 |
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10.1080/00958978408073886 |
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| 520 | |a Trans-[Ir(pyridine)4Cl2]Cl. 6H2O exists in at least two forms. A high temperature form, crystallized from water at room temperature, is disordered in the solid state. A low temperature form, crystallized from aqueous solution at 2°. has been structurally characterized using x-ray crystallographic methods. It is monoclinic, space group P21/c, a=12.595(2), b=10.498(3), c=21.243(5)Å, β=98.26(2)°, Z=4. The structure was refined to R=0.034, for 3998 reflexions for which I > 3σ(I). The cation has regular octahedral geometry with the Ir-Cl bond lengths equal to 2.35 and the Ir-N bond lengths equal to 2.06 Å. The water molecules, together with the chloride anion lie in hydrogen-bonded sheets at 0.5a. | ||
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10.1080/00958978408073886 doi (DE-627)NLEJ252459873 (TFO)767910861 DE-627 ger DE-627 rda eng Gillard, R. D. verfasserin aut THE STRUCTURE OF A LOW-TEMPERATURE FORM OF TRANS-[Ir(PYRIDINE)4Cl2]Cl. 6H2O 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Trans-[Ir(pyridine)4Cl2]Cl. 6H2O exists in at least two forms. A high temperature form, crystallized from water at room temperature, is disordered in the solid state. A low temperature form, crystallized from aqueous solution at 2°. has been structurally characterized using x-ray crystallographic methods. It is monoclinic, space group P21/c, a=12.595(2), b=10.498(3), c=21.243(5)Å, β=98.26(2)°, Z=4. The structure was refined to R=0.034, for 3998 reflexions for which I > 3σ(I). The cation has regular octahedral geometry with the Ir-Cl bond lengths equal to 2.35 and the Ir-N bond lengths equal to 2.06 Å. The water molecules, together with the chloride anion lie in hydrogen-bonded sheets at 0.5a. Mitchell, Simon verfasserin aut Williams, Peter verfasserin aut Vagg, Robert verfasserin aut Enthalten in Journal of coordination chemistry London [u.a.] : Taylor & Francis, 1971 13(1984), 4 vom: 01. Sept., Seite 325-330 Online-Ressource (DE-627)NLEJ252458060 (DE-600)2041175-3 (DE-576)099426706 1029-0389 nnns number:4 volume:13 year:1984 month:09 day:01 pages:325-330 https://www.tib.eu/de/suchen/id/tandf%3A94fe6620c41ce40c73a7452d7ae45403b2a9edbe Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 4 13 1984 9 01 325-330 |
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10.1080/00958978408073886 doi (DE-627)NLEJ252459873 (TFO)767910861 DE-627 ger DE-627 rda eng Gillard, R. D. verfasserin aut THE STRUCTURE OF A LOW-TEMPERATURE FORM OF TRANS-[Ir(PYRIDINE)4Cl2]Cl. 6H2O 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Trans-[Ir(pyridine)4Cl2]Cl. 6H2O exists in at least two forms. A high temperature form, crystallized from water at room temperature, is disordered in the solid state. A low temperature form, crystallized from aqueous solution at 2°. has been structurally characterized using x-ray crystallographic methods. It is monoclinic, space group P21/c, a=12.595(2), b=10.498(3), c=21.243(5)Å, β=98.26(2)°, Z=4. The structure was refined to R=0.034, for 3998 reflexions for which I > 3σ(I). The cation has regular octahedral geometry with the Ir-Cl bond lengths equal to 2.35 and the Ir-N bond lengths equal to 2.06 Å. The water molecules, together with the chloride anion lie in hydrogen-bonded sheets at 0.5a. Mitchell, Simon verfasserin aut Williams, Peter verfasserin aut Vagg, Robert verfasserin aut Enthalten in Journal of coordination chemistry London [u.a.] : Taylor & Francis, 1971 13(1984), 4 vom: 01. Sept., Seite 325-330 Online-Ressource (DE-627)NLEJ252458060 (DE-600)2041175-3 (DE-576)099426706 1029-0389 nnns number:4 volume:13 year:1984 month:09 day:01 pages:325-330 https://www.tib.eu/de/suchen/id/tandf%3A94fe6620c41ce40c73a7452d7ae45403b2a9edbe Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 4 13 1984 9 01 325-330 |
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10.1080/00958978408073886 doi (DE-627)NLEJ252459873 (TFO)767910861 DE-627 ger DE-627 rda eng Gillard, R. D. verfasserin aut THE STRUCTURE OF A LOW-TEMPERATURE FORM OF TRANS-[Ir(PYRIDINE)4Cl2]Cl. 6H2O 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Trans-[Ir(pyridine)4Cl2]Cl. 6H2O exists in at least two forms. A high temperature form, crystallized from water at room temperature, is disordered in the solid state. A low temperature form, crystallized from aqueous solution at 2°. has been structurally characterized using x-ray crystallographic methods. It is monoclinic, space group P21/c, a=12.595(2), b=10.498(3), c=21.243(5)Å, β=98.26(2)°, Z=4. The structure was refined to R=0.034, for 3998 reflexions for which I > 3σ(I). The cation has regular octahedral geometry with the Ir-Cl bond lengths equal to 2.35 and the Ir-N bond lengths equal to 2.06 Å. The water molecules, together with the chloride anion lie in hydrogen-bonded sheets at 0.5a. Mitchell, Simon verfasserin aut Williams, Peter verfasserin aut Vagg, Robert verfasserin aut Enthalten in Journal of coordination chemistry London [u.a.] : Taylor & Francis, 1971 13(1984), 4 vom: 01. Sept., Seite 325-330 Online-Ressource (DE-627)NLEJ252458060 (DE-600)2041175-3 (DE-576)099426706 1029-0389 nnns number:4 volume:13 year:1984 month:09 day:01 pages:325-330 https://www.tib.eu/de/suchen/id/tandf%3A94fe6620c41ce40c73a7452d7ae45403b2a9edbe Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 4 13 1984 9 01 325-330 |
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10.1080/00958978408073886 doi (DE-627)NLEJ252459873 (TFO)767910861 DE-627 ger DE-627 rda eng Gillard, R. D. verfasserin aut THE STRUCTURE OF A LOW-TEMPERATURE FORM OF TRANS-[Ir(PYRIDINE)4Cl2]Cl. 6H2O 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Trans-[Ir(pyridine)4Cl2]Cl. 6H2O exists in at least two forms. A high temperature form, crystallized from water at room temperature, is disordered in the solid state. A low temperature form, crystallized from aqueous solution at 2°. has been structurally characterized using x-ray crystallographic methods. It is monoclinic, space group P21/c, a=12.595(2), b=10.498(3), c=21.243(5)Å, β=98.26(2)°, Z=4. The structure was refined to R=0.034, for 3998 reflexions for which I > 3σ(I). The cation has regular octahedral geometry with the Ir-Cl bond lengths equal to 2.35 and the Ir-N bond lengths equal to 2.06 Å. The water molecules, together with the chloride anion lie in hydrogen-bonded sheets at 0.5a. Mitchell, Simon verfasserin aut Williams, Peter verfasserin aut Vagg, Robert verfasserin aut Enthalten in Journal of coordination chemistry London [u.a.] : Taylor & Francis, 1971 13(1984), 4 vom: 01. Sept., Seite 325-330 Online-Ressource (DE-627)NLEJ252458060 (DE-600)2041175-3 (DE-576)099426706 1029-0389 nnns number:4 volume:13 year:1984 month:09 day:01 pages:325-330 https://www.tib.eu/de/suchen/id/tandf%3A94fe6620c41ce40c73a7452d7ae45403b2a9edbe Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 4 13 1984 9 01 325-330 |
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10.1080/00958978408073886 doi (DE-627)NLEJ252459873 (TFO)767910861 DE-627 ger DE-627 rda eng Gillard, R. D. verfasserin aut THE STRUCTURE OF A LOW-TEMPERATURE FORM OF TRANS-[Ir(PYRIDINE)4Cl2]Cl. 6H2O 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier Trans-[Ir(pyridine)4Cl2]Cl. 6H2O exists in at least two forms. A high temperature form, crystallized from water at room temperature, is disordered in the solid state. A low temperature form, crystallized from aqueous solution at 2°. has been structurally characterized using x-ray crystallographic methods. It is monoclinic, space group P21/c, a=12.595(2), b=10.498(3), c=21.243(5)Å, β=98.26(2)°, Z=4. The structure was refined to R=0.034, for 3998 reflexions for which I > 3σ(I). The cation has regular octahedral geometry with the Ir-Cl bond lengths equal to 2.35 and the Ir-N bond lengths equal to 2.06 Å. The water molecules, together with the chloride anion lie in hydrogen-bonded sheets at 0.5a. Mitchell, Simon verfasserin aut Williams, Peter verfasserin aut Vagg, Robert verfasserin aut Enthalten in Journal of coordination chemistry London [u.a.] : Taylor & Francis, 1971 13(1984), 4 vom: 01. Sept., Seite 325-330 Online-Ressource (DE-627)NLEJ252458060 (DE-600)2041175-3 (DE-576)099426706 1029-0389 nnns number:4 volume:13 year:1984 month:09 day:01 pages:325-330 https://www.tib.eu/de/suchen/id/tandf%3A94fe6620c41ce40c73a7452d7ae45403b2a9edbe Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 4 13 1984 9 01 325-330 |
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THE STRUCTURE OF A LOW-TEMPERATURE FORM OF TRANS-[Ir(PYRIDINE)4Cl2]Cl. 6H2O |
| abstract |
Trans-[Ir(pyridine)4Cl2]Cl. 6H2O exists in at least two forms. A high temperature form, crystallized from water at room temperature, is disordered in the solid state. A low temperature form, crystallized from aqueous solution at 2°. has been structurally characterized using x-ray crystallographic methods. It is monoclinic, space group P21/c, a=12.595(2), b=10.498(3), c=21.243(5)Å, β=98.26(2)°, Z=4. The structure was refined to R=0.034, for 3998 reflexions for which I > 3σ(I). The cation has regular octahedral geometry with the Ir-Cl bond lengths equal to 2.35 and the Ir-N bond lengths equal to 2.06 Å. The water molecules, together with the chloride anion lie in hydrogen-bonded sheets at 0.5a. |
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Trans-[Ir(pyridine)4Cl2]Cl. 6H2O exists in at least two forms. A high temperature form, crystallized from water at room temperature, is disordered in the solid state. A low temperature form, crystallized from aqueous solution at 2°. has been structurally characterized using x-ray crystallographic methods. It is monoclinic, space group P21/c, a=12.595(2), b=10.498(3), c=21.243(5)Å, β=98.26(2)°, Z=4. The structure was refined to R=0.034, for 3998 reflexions for which I > 3σ(I). The cation has regular octahedral geometry with the Ir-Cl bond lengths equal to 2.35 and the Ir-N bond lengths equal to 2.06 Å. The water molecules, together with the chloride anion lie in hydrogen-bonded sheets at 0.5a. |
| abstract_unstemmed |
Trans-[Ir(pyridine)4Cl2]Cl. 6H2O exists in at least two forms. A high temperature form, crystallized from water at room temperature, is disordered in the solid state. A low temperature form, crystallized from aqueous solution at 2°. has been structurally characterized using x-ray crystallographic methods. It is monoclinic, space group P21/c, a=12.595(2), b=10.498(3), c=21.243(5)Å, β=98.26(2)°, Z=4. The structure was refined to R=0.034, for 3998 reflexions for which I > 3σ(I). The cation has regular octahedral geometry with the Ir-Cl bond lengths equal to 2.35 and the Ir-N bond lengths equal to 2.06 Å. The water molecules, together with the chloride anion lie in hydrogen-bonded sheets at 0.5a. |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">NLEJ252459873</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20231206142257.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">231206s2011 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1080/00958978408073886</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)NLEJ252459873</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(TFO)767910861</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Gillard, R. D.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">THE STRUCTURE OF A LOW-TEMPERATURE FORM OF TRANS-[Ir(PYRIDINE)4Cl2]Cl. 6H2O</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2011</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Trans-[Ir(pyridine)4Cl2]Cl. 6H2O exists in at least two forms. A high temperature form, crystallized from water at room temperature, is disordered in the solid state. A low temperature form, crystallized from aqueous solution at 2°. has been structurally characterized using x-ray crystallographic methods. It is monoclinic, space group P21/c, a=12.595(2), b=10.498(3), c=21.243(5)Å, β=98.26(2)°, Z=4. The structure was refined to R=0.034, for 3998 reflexions for which I > 3σ(I). The cation has regular octahedral geometry with the Ir-Cl bond lengths equal to 2.35 and the Ir-N bond lengths equal to 2.06 Å. The water molecules, together with the chloride anion lie in hydrogen-bonded sheets at 0.5a.</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Mitchell, Simon</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Williams, Peter</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Vagg, Robert</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of coordination chemistry</subfield><subfield code="d">London [u.a.] : Taylor & Francis, 1971</subfield><subfield code="g">13(1984), 4 vom: 01. Sept., Seite 325-330</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)NLEJ252458060</subfield><subfield code="w">(DE-600)2041175-3</subfield><subfield code="w">(DE-576)099426706</subfield><subfield code="x">1029-0389</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">number:4</subfield><subfield code="g">volume:13</subfield><subfield code="g">year:1984</subfield><subfield code="g">month:09</subfield><subfield code="g">day:01</subfield><subfield code="g">pages:325-330</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://www.tib.eu/de/suchen/id/tandf%3A94fe6620c41ce40c73a7452d7ae45403b2a9edbe</subfield><subfield code="x">Digitalisierung</subfield><subfield code="z">Deutschlandweit zugänglich</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">ZDB-1-TFO</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_NL_ARTICLE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="e">4</subfield><subfield code="d">13</subfield><subfield code="j">1984</subfield><subfield code="c">9</subfield><subfield code="b">01</subfield><subfield code="h">325-330</subfield></datafield></record></collection>
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