KINETICS OF THE CHROMIUM(II) REDUCTIONS OF CHELATED AMINO ACIDO-BIS(ETHYLENE-DIAMINE)COBALT(III) COMPLEXES

The kinetics of Cr2+(aq) reductions of glycinato-, D,L-alanato, D,L-phenylalanato-, and D,L-leucinatobis-(ethylenediamine)cobalt(III) ions have been investigated. The rate law is of the form d(ln[Co(III)]/dt = k[Cr2+], where the rate constant k(M-1sec-1) and associated activation parameters δHδ(kcal...
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Autor*in:	Williams, Robert [verfasserIn] Pennington, David [verfasserIn]

Format:	E-Artikel
Sprache:	Englisch

Erschienen:	2011

Übergeordnetes Werk:	Enthalten in: Journal of coordination chemistry - London [u.a.] : Taylor & Francis, 1971, 7(1978), 3 vom: 01. Jan., Seite 187-191
Übergeordnetes Werk:	number:3 ; volume:7 ; year:1978 ; month:01 ; day:01 ; pages:187-191

Links:	Link aufrufen

DOI / URN:	10.1080/00958977808073060

Katalog-ID:	NLEJ252476956

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520			\|a The kinetics of Cr2+(aq) reductions of glycinato-, D,L-alanato, D,L-phenylalanato-, and D,L-leucinatobis-(ethylenediamine)cobalt(III) ions have been investigated. The rate law is of the form d(ln[Co(III)]/dt = k[Cr2+], where the rate constant k(M-1sec-1) and associated activation parameters δHδ(kcal mol-1 and δSδ (cal deg -1mol-1) in parentheses, are respectively 1.65 · 0.06 (9.7 · 0.1, -25 · 1), 0.367 · 0.008 (10.9 · 04,-24 ·1), 0.529 · 0.021 (11.2 · 0.4, -22 · 1); and 0.358 · 0.019 (11.5 · 0.3, -22 · 1) at 298·K and ·[CIO·] = 1.0 M. The reactions are all inner-sphere.
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allfields	10.1080/00958977808073060 doi (DE-627)NLEJ252476956 (TFO)767939678 DE-627 ger DE-627 rda eng Williams, Robert verfasserin aut KINETICS OF THE CHROMIUM(II) REDUCTIONS OF CHELATED AMINO ACIDO-BIS(ETHYLENE-DIAMINE)COBALT(III) COMPLEXES 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The kinetics of Cr2+(aq) reductions of glycinato-, D,L-alanato, D,L-phenylalanato-, and D,L-leucinatobis-(ethylenediamine)cobalt(III) ions have been investigated. The rate law is of the form d(ln[Co(III)]/dt = k[Cr2+], where the rate constant k(M-1sec-1) and associated activation parameters δHδ(kcal mol-1 and δSδ (cal deg -1mol-1) in parentheses, are respectively 1.65 · 0.06 (9.7 · 0.1, -25 · 1), 0.367 · 0.008 (10.9 · 04,-24 ·1), 0.529 · 0.021 (11.2 · 0.4, -22 · 1); and 0.358 · 0.019 (11.5 · 0.3, -22 · 1) at 298·K and ·[CIO·] = 1.0 M. The reactions are all inner-sphere. Pennington, David verfasserin aut Enthalten in Journal of coordination chemistry London [u.a.] : Taylor & Francis, 1971 7(1978), 3 vom: 01. Jan., Seite 187-191 Online-Ressource (DE-627)NLEJ252458060 (DE-600)2041175-3 (DE-576)099426706 1029-0389 nnns number:3 volume:7 year:1978 month:01 day:01 pages:187-191 https://www.tib.eu/de/suchen/id/tandf%3A3798518b4b00504834c65356c983a15ca2ea806e Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 3 7 1978 1 01 187-191
spelling	10.1080/00958977808073060 doi (DE-627)NLEJ252476956 (TFO)767939678 DE-627 ger DE-627 rda eng Williams, Robert verfasserin aut KINETICS OF THE CHROMIUM(II) REDUCTIONS OF CHELATED AMINO ACIDO-BIS(ETHYLENE-DIAMINE)COBALT(III) COMPLEXES 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The kinetics of Cr2+(aq) reductions of glycinato-, D,L-alanato, D,L-phenylalanato-, and D,L-leucinatobis-(ethylenediamine)cobalt(III) ions have been investigated. The rate law is of the form d(ln[Co(III)]/dt = k[Cr2+], where the rate constant k(M-1sec-1) and associated activation parameters δHδ(kcal mol-1 and δSδ (cal deg -1mol-1) in parentheses, are respectively 1.65 · 0.06 (9.7 · 0.1, -25 · 1), 0.367 · 0.008 (10.9 · 04,-24 ·1), 0.529 · 0.021 (11.2 · 0.4, -22 · 1); and 0.358 · 0.019 (11.5 · 0.3, -22 · 1) at 298·K and ·[CIO·] = 1.0 M. The reactions are all inner-sphere. Pennington, David verfasserin aut Enthalten in Journal of coordination chemistry London [u.a.] : Taylor & Francis, 1971 7(1978), 3 vom: 01. Jan., Seite 187-191 Online-Ressource (DE-627)NLEJ252458060 (DE-600)2041175-3 (DE-576)099426706 1029-0389 nnns number:3 volume:7 year:1978 month:01 day:01 pages:187-191 https://www.tib.eu/de/suchen/id/tandf%3A3798518b4b00504834c65356c983a15ca2ea806e Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 3 7 1978 1 01 187-191
allfields_unstemmed	10.1080/00958977808073060 doi (DE-627)NLEJ252476956 (TFO)767939678 DE-627 ger DE-627 rda eng Williams, Robert verfasserin aut KINETICS OF THE CHROMIUM(II) REDUCTIONS OF CHELATED AMINO ACIDO-BIS(ETHYLENE-DIAMINE)COBALT(III) COMPLEXES 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The kinetics of Cr2+(aq) reductions of glycinato-, D,L-alanato, D,L-phenylalanato-, and D,L-leucinatobis-(ethylenediamine)cobalt(III) ions have been investigated. The rate law is of the form d(ln[Co(III)]/dt = k[Cr2+], where the rate constant k(M-1sec-1) and associated activation parameters δHδ(kcal mol-1 and δSδ (cal deg -1mol-1) in parentheses, are respectively 1.65 · 0.06 (9.7 · 0.1, -25 · 1), 0.367 · 0.008 (10.9 · 04,-24 ·1), 0.529 · 0.021 (11.2 · 0.4, -22 · 1); and 0.358 · 0.019 (11.5 · 0.3, -22 · 1) at 298·K and ·[CIO·] = 1.0 M. The reactions are all inner-sphere. Pennington, David verfasserin aut Enthalten in Journal of coordination chemistry London [u.a.] : Taylor & Francis, 1971 7(1978), 3 vom: 01. Jan., Seite 187-191 Online-Ressource (DE-627)NLEJ252458060 (DE-600)2041175-3 (DE-576)099426706 1029-0389 nnns number:3 volume:7 year:1978 month:01 day:01 pages:187-191 https://www.tib.eu/de/suchen/id/tandf%3A3798518b4b00504834c65356c983a15ca2ea806e Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 3 7 1978 1 01 187-191
allfieldsGer	10.1080/00958977808073060 doi (DE-627)NLEJ252476956 (TFO)767939678 DE-627 ger DE-627 rda eng Williams, Robert verfasserin aut KINETICS OF THE CHROMIUM(II) REDUCTIONS OF CHELATED AMINO ACIDO-BIS(ETHYLENE-DIAMINE)COBALT(III) COMPLEXES 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The kinetics of Cr2+(aq) reductions of glycinato-, D,L-alanato, D,L-phenylalanato-, and D,L-leucinatobis-(ethylenediamine)cobalt(III) ions have been investigated. The rate law is of the form d(ln[Co(III)]/dt = k[Cr2+], where the rate constant k(M-1sec-1) and associated activation parameters δHδ(kcal mol-1 and δSδ (cal deg -1mol-1) in parentheses, are respectively 1.65 · 0.06 (9.7 · 0.1, -25 · 1), 0.367 · 0.008 (10.9 · 04,-24 ·1), 0.529 · 0.021 (11.2 · 0.4, -22 · 1); and 0.358 · 0.019 (11.5 · 0.3, -22 · 1) at 298·K and ·[CIO·] = 1.0 M. The reactions are all inner-sphere. Pennington, David verfasserin aut Enthalten in Journal of coordination chemistry London [u.a.] : Taylor & Francis, 1971 7(1978), 3 vom: 01. Jan., Seite 187-191 Online-Ressource (DE-627)NLEJ252458060 (DE-600)2041175-3 (DE-576)099426706 1029-0389 nnns number:3 volume:7 year:1978 month:01 day:01 pages:187-191 https://www.tib.eu/de/suchen/id/tandf%3A3798518b4b00504834c65356c983a15ca2ea806e Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 3 7 1978 1 01 187-191
allfieldsSound	10.1080/00958977808073060 doi (DE-627)NLEJ252476956 (TFO)767939678 DE-627 ger DE-627 rda eng Williams, Robert verfasserin aut KINETICS OF THE CHROMIUM(II) REDUCTIONS OF CHELATED AMINO ACIDO-BIS(ETHYLENE-DIAMINE)COBALT(III) COMPLEXES 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier The kinetics of Cr2+(aq) reductions of glycinato-, D,L-alanato, D,L-phenylalanato-, and D,L-leucinatobis-(ethylenediamine)cobalt(III) ions have been investigated. The rate law is of the form d(ln[Co(III)]/dt = k[Cr2+], where the rate constant k(M-1sec-1) and associated activation parameters δHδ(kcal mol-1 and δSδ (cal deg -1mol-1) in parentheses, are respectively 1.65 · 0.06 (9.7 · 0.1, -25 · 1), 0.367 · 0.008 (10.9 · 04,-24 ·1), 0.529 · 0.021 (11.2 · 0.4, -22 · 1); and 0.358 · 0.019 (11.5 · 0.3, -22 · 1) at 298·K and ·[CIO·] = 1.0 M. The reactions are all inner-sphere. Pennington, David verfasserin aut Enthalten in Journal of coordination chemistry London [u.a.] : Taylor & Francis, 1971 7(1978), 3 vom: 01. Jan., Seite 187-191 Online-Ressource (DE-627)NLEJ252458060 (DE-600)2041175-3 (DE-576)099426706 1029-0389 nnns number:3 volume:7 year:1978 month:01 day:01 pages:187-191 https://www.tib.eu/de/suchen/id/tandf%3A3798518b4b00504834c65356c983a15ca2ea806e Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 3 7 1978 1 01 187-191
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author	Williams, Robert
spellingShingle	Williams, Robert KINETICS OF THE CHROMIUM(II) REDUCTIONS OF CHELATED AMINO ACIDO-BIS(ETHYLENE-DIAMINE)COBALT(III) COMPLEXES
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title_full	KINETICS OF THE CHROMIUM(II) REDUCTIONS OF CHELATED AMINO ACIDO-BIS(ETHYLENE-DIAMINE)COBALT(III) COMPLEXES
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title_sort	kinetics of the chromium(ii) reductions of chelated amino acido-bis(ethylene-diamine)cobalt(iii) complexes
title_auth	KINETICS OF THE CHROMIUM(II) REDUCTIONS OF CHELATED AMINO ACIDO-BIS(ETHYLENE-DIAMINE)COBALT(III) COMPLEXES
abstract	The kinetics of Cr2+(aq) reductions of glycinato-, D,L-alanato, D,L-phenylalanato-, and D,L-leucinatobis-(ethylenediamine)cobalt(III) ions have been investigated. The rate law is of the form d(ln[Co(III)]/dt = k[Cr2+], where the rate constant k(M-1sec-1) and associated activation parameters δHδ(kcal mol-1 and δSδ (cal deg -1mol-1) in parentheses, are respectively 1.65 · 0.06 (9.7 · 0.1, -25 · 1), 0.367 · 0.008 (10.9 · 04,-24 ·1), 0.529 · 0.021 (11.2 · 0.4, -22 · 1); and 0.358 · 0.019 (11.5 · 0.3, -22 · 1) at 298·K and ·[CIO·] = 1.0 M. The reactions are all inner-sphere.
abstractGer	The kinetics of Cr2+(aq) reductions of glycinato-, D,L-alanato, D,L-phenylalanato-, and D,L-leucinatobis-(ethylenediamine)cobalt(III) ions have been investigated. The rate law is of the form d(ln[Co(III)]/dt = k[Cr2+], where the rate constant k(M-1sec-1) and associated activation parameters δHδ(kcal mol-1 and δSδ (cal deg -1mol-1) in parentheses, are respectively 1.65 · 0.06 (9.7 · 0.1, -25 · 1), 0.367 · 0.008 (10.9 · 04,-24 ·1), 0.529 · 0.021 (11.2 · 0.4, -22 · 1); and 0.358 · 0.019 (11.5 · 0.3, -22 · 1) at 298·K and ·[CIO·] = 1.0 M. The reactions are all inner-sphere.
abstract_unstemmed	The kinetics of Cr2+(aq) reductions of glycinato-, D,L-alanato, D,L-phenylalanato-, and D,L-leucinatobis-(ethylenediamine)cobalt(III) ions have been investigated. The rate law is of the form d(ln[Co(III)]/dt = k[Cr2+], where the rate constant k(M-1sec-1) and associated activation parameters δHδ(kcal mol-1 and δSδ (cal deg -1mol-1) in parentheses, are respectively 1.65 · 0.06 (9.7 · 0.1, -25 · 1), 0.367 · 0.008 (10.9 · 04,-24 ·1), 0.529 · 0.021 (11.2 · 0.4, -22 · 1); and 0.358 · 0.019 (11.5 · 0.3, -22 · 1) at 298·K and ·[CIO·] = 1.0 M. The reactions are all inner-sphere.
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up_date	2024-07-06T12:52:56.251Z
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fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">NLEJ252476956</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20231206142327.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">231206s2011 xx \|\|\|\|\|o 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1080/00958977808073060</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)NLEJ252476956</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(TFO)767939678</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Williams, Robert</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">KINETICS OF THE CHROMIUM(II) REDUCTIONS OF CHELATED AMINO ACIDO-BIS(ETHYLENE-DIAMINE)COBALT(III) COMPLEXES</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2011</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The kinetics of Cr2+(aq) reductions of glycinato-, D,L-alanato, D,L-phenylalanato-, and D,L-leucinatobis-(ethylenediamine)cobalt(III) ions have been investigated. The rate law is of the form d(ln[Co(III)]/dt = k[Cr2+], where the rate constant k(M-1sec-1) and associated activation parameters δHδ(kcal mol-1 and δSδ (cal deg -1mol-1) in parentheses, are respectively 1.65 · 0.06 (9.7 · 0.1, -25 · 1), 0.367 · 0.008 (10.9 · 04,-24 ·1), 0.529 · 0.021 (11.2 · 0.4, -22 · 1); and 0.358 · 0.019 (11.5 · 0.3, -22 · 1) at 298·K and ·[CIO·] = 1.0 M. The reactions are all inner-sphere.</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Pennington, David</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of coordination chemistry</subfield><subfield code="d">London [u.a.] : Taylor & Francis, 1971</subfield><subfield code="g">7(1978), 3 vom: 01. Jan., Seite 187-191</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)NLEJ252458060</subfield><subfield code="w">(DE-600)2041175-3</subfield><subfield code="w">(DE-576)099426706</subfield><subfield code="x">1029-0389</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">number:3</subfield><subfield code="g">volume:7</subfield><subfield code="g">year:1978</subfield><subfield code="g">month:01</subfield><subfield code="g">day:01</subfield><subfield code="g">pages:187-191</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://www.tib.eu/de/suchen/id/tandf%3A3798518b4b00504834c65356c983a15ca2ea806e</subfield><subfield code="x">Digitalisierung</subfield><subfield code="z">Deutschlandweit zugänglich</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">ZDB-1-TFO</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_NL_ARTICLE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="e">3</subfield><subfield code="d">7</subfield><subfield code="j">1978</subfield><subfield code="c">1</subfield><subfield code="b">01</subfield><subfield code="h">187-191</subfield></datafield></record></collection>
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KINETICS OF THE CHROMIUM(II) REDUCTIONS OF CHELATED AMINO ACIDO-BIS(ETHYLENE-DIAMINE)COBALT(III) COMPLEXES

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