Binary eutectics formed between ammonium nitrate and amine salts of 5-nitrotetrazole I. preparation and initial characterization
We have found that both the ammonium salt of 5-nitrotetrazole (ANT) and the ethylenediamine salt of 5-nitrotetrazole (ENT) form eutectics with ammonium nitrate (AN). Initial characterization and small-scale sensitivity tests of CO2-balanced AN/ANT and AN/ENT formulations were performed; it was found...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Lee, K. -Y. [verfasserIn] Coburn, M. D. [verfasserIn] |
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| Format: |
E-Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2011 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of energetic materials - Philadelphia, Pa. [u.a.] : Taylor and Francis, 1983, 1(1983), 1, Seite 109-122 |
|---|---|
| Übergeordnetes Werk: |
number:1 ; volume:1 ; year:1983 ; pages:109-122 |
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| DOI / URN: |
10.1080/07370658308010822 |
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NLEJ253075394 |
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| 520 | |a We have found that both the ammonium salt of 5-nitrotetrazole (ANT) and the ethylenediamine salt of 5-nitrotetrazole (ENT) form eutectics with ammonium nitrate (AN). Initial characterization and small-scale sensitivity tests of CO2-balanced AN/ANT and AN/ENT formulations were performed; it was found that both eutectics were less sensitive in all tests than pure ANT or ENT, respectively. The phase diagrams of both mixtures were also determined. ANT forms a eutectic with AN that melts at 121°C; the eutectic composition of the AN/ANT system is 78.5 mol% AN. The eutectic temperature and composition of the AN/ENT system were found to be 110.5°C and 87.8 mol% AN, respectively. Thermal stability studies of the eutectics indicate that they are stable below 160°C and that thermal decomposition occurs slowly over a long period of time.The detonation velocities of both eutectics, measured unconfined at 2.54-cm diameter, were found to be within 95% of those predicted by the Kamlet-Jacobs method assuming ideal behavior. | ||
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10.1080/07370658308010822 doi (DE-627)NLEJ253075394 (TFO)752776546 DE-627 ger DE-627 rda eng Lee, K. -Y. verfasserin aut Binary eutectics formed between ammonium nitrate and amine salts of 5-nitrotetrazole I. preparation and initial characterization 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier We have found that both the ammonium salt of 5-nitrotetrazole (ANT) and the ethylenediamine salt of 5-nitrotetrazole (ENT) form eutectics with ammonium nitrate (AN). Initial characterization and small-scale sensitivity tests of CO2-balanced AN/ANT and AN/ENT formulations were performed; it was found that both eutectics were less sensitive in all tests than pure ANT or ENT, respectively. The phase diagrams of both mixtures were also determined. ANT forms a eutectic with AN that melts at 121°C; the eutectic composition of the AN/ANT system is 78.5 mol% AN. The eutectic temperature and composition of the AN/ENT system were found to be 110.5°C and 87.8 mol% AN, respectively. Thermal stability studies of the eutectics indicate that they are stable below 160°C and that thermal decomposition occurs slowly over a long period of time.The detonation velocities of both eutectics, measured unconfined at 2.54-cm diameter, were found to be within 95% of those predicted by the Kamlet-Jacobs method assuming ideal behavior. Coburn, M. D. verfasserin aut Enthalten in Journal of energetic materials Philadelphia, Pa. [u.a.] : Taylor and Francis, 1983 1(1983), 1, Seite 109-122 Online-Ressource (DE-627)NLEJ253073758 (DE-600)2112655-0 (DE-576)256275696 1545-8822 nnns number:1 volume:1 year:1983 pages:109-122 https://www.tib.eu/de/suchen/id/tandf%3A67b7e8da99e5a80f45992f5601546d8ea8485199 Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 1 1 1983 109-122 |
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10.1080/07370658308010822 doi (DE-627)NLEJ253075394 (TFO)752776546 DE-627 ger DE-627 rda eng Lee, K. -Y. verfasserin aut Binary eutectics formed between ammonium nitrate and amine salts of 5-nitrotetrazole I. preparation and initial characterization 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier We have found that both the ammonium salt of 5-nitrotetrazole (ANT) and the ethylenediamine salt of 5-nitrotetrazole (ENT) form eutectics with ammonium nitrate (AN). Initial characterization and small-scale sensitivity tests of CO2-balanced AN/ANT and AN/ENT formulations were performed; it was found that both eutectics were less sensitive in all tests than pure ANT or ENT, respectively. The phase diagrams of both mixtures were also determined. ANT forms a eutectic with AN that melts at 121°C; the eutectic composition of the AN/ANT system is 78.5 mol% AN. The eutectic temperature and composition of the AN/ENT system were found to be 110.5°C and 87.8 mol% AN, respectively. Thermal stability studies of the eutectics indicate that they are stable below 160°C and that thermal decomposition occurs slowly over a long period of time.The detonation velocities of both eutectics, measured unconfined at 2.54-cm diameter, were found to be within 95% of those predicted by the Kamlet-Jacobs method assuming ideal behavior. Coburn, M. D. verfasserin aut Enthalten in Journal of energetic materials Philadelphia, Pa. [u.a.] : Taylor and Francis, 1983 1(1983), 1, Seite 109-122 Online-Ressource (DE-627)NLEJ253073758 (DE-600)2112655-0 (DE-576)256275696 1545-8822 nnns number:1 volume:1 year:1983 pages:109-122 https://www.tib.eu/de/suchen/id/tandf%3A67b7e8da99e5a80f45992f5601546d8ea8485199 Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 1 1 1983 109-122 |
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10.1080/07370658308010822 doi (DE-627)NLEJ253075394 (TFO)752776546 DE-627 ger DE-627 rda eng Lee, K. -Y. verfasserin aut Binary eutectics formed between ammonium nitrate and amine salts of 5-nitrotetrazole I. preparation and initial characterization 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier We have found that both the ammonium salt of 5-nitrotetrazole (ANT) and the ethylenediamine salt of 5-nitrotetrazole (ENT) form eutectics with ammonium nitrate (AN). Initial characterization and small-scale sensitivity tests of CO2-balanced AN/ANT and AN/ENT formulations were performed; it was found that both eutectics were less sensitive in all tests than pure ANT or ENT, respectively. The phase diagrams of both mixtures were also determined. ANT forms a eutectic with AN that melts at 121°C; the eutectic composition of the AN/ANT system is 78.5 mol% AN. The eutectic temperature and composition of the AN/ENT system were found to be 110.5°C and 87.8 mol% AN, respectively. Thermal stability studies of the eutectics indicate that they are stable below 160°C and that thermal decomposition occurs slowly over a long period of time.The detonation velocities of both eutectics, measured unconfined at 2.54-cm diameter, were found to be within 95% of those predicted by the Kamlet-Jacobs method assuming ideal behavior. Coburn, M. D. verfasserin aut Enthalten in Journal of energetic materials Philadelphia, Pa. [u.a.] : Taylor and Francis, 1983 1(1983), 1, Seite 109-122 Online-Ressource (DE-627)NLEJ253073758 (DE-600)2112655-0 (DE-576)256275696 1545-8822 nnns number:1 volume:1 year:1983 pages:109-122 https://www.tib.eu/de/suchen/id/tandf%3A67b7e8da99e5a80f45992f5601546d8ea8485199 Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 1 1 1983 109-122 |
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10.1080/07370658308010822 doi (DE-627)NLEJ253075394 (TFO)752776546 DE-627 ger DE-627 rda eng Lee, K. -Y. verfasserin aut Binary eutectics formed between ammonium nitrate and amine salts of 5-nitrotetrazole I. preparation and initial characterization 2011 Text txt rdacontent Computermedien c rdamedia Online-Ressource cr rdacarrier We have found that both the ammonium salt of 5-nitrotetrazole (ANT) and the ethylenediamine salt of 5-nitrotetrazole (ENT) form eutectics with ammonium nitrate (AN). Initial characterization and small-scale sensitivity tests of CO2-balanced AN/ANT and AN/ENT formulations were performed; it was found that both eutectics were less sensitive in all tests than pure ANT or ENT, respectively. The phase diagrams of both mixtures were also determined. ANT forms a eutectic with AN that melts at 121°C; the eutectic composition of the AN/ANT system is 78.5 mol% AN. The eutectic temperature and composition of the AN/ENT system were found to be 110.5°C and 87.8 mol% AN, respectively. Thermal stability studies of the eutectics indicate that they are stable below 160°C and that thermal decomposition occurs slowly over a long period of time.The detonation velocities of both eutectics, measured unconfined at 2.54-cm diameter, were found to be within 95% of those predicted by the Kamlet-Jacobs method assuming ideal behavior. Coburn, M. D. verfasserin aut Enthalten in Journal of energetic materials Philadelphia, Pa. [u.a.] : Taylor and Francis, 1983 1(1983), 1, Seite 109-122 Online-Ressource (DE-627)NLEJ253073758 (DE-600)2112655-0 (DE-576)256275696 1545-8822 nnns number:1 volume:1 year:1983 pages:109-122 https://www.tib.eu/de/suchen/id/tandf%3A67b7e8da99e5a80f45992f5601546d8ea8485199 Digitalisierung Deutschlandweit zugänglich ZDB-1-TFO GBV_NL_ARTICLE AR 1 1 1983 109-122 |
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Binary eutectics formed between ammonium nitrate and amine salts of 5-nitrotetrazole I. preparation and initial characterization |
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We have found that both the ammonium salt of 5-nitrotetrazole (ANT) and the ethylenediamine salt of 5-nitrotetrazole (ENT) form eutectics with ammonium nitrate (AN). Initial characterization and small-scale sensitivity tests of CO2-balanced AN/ANT and AN/ENT formulations were performed; it was found that both eutectics were less sensitive in all tests than pure ANT or ENT, respectively. The phase diagrams of both mixtures were also determined. ANT forms a eutectic with AN that melts at 121°C; the eutectic composition of the AN/ANT system is 78.5 mol% AN. The eutectic temperature and composition of the AN/ENT system were found to be 110.5°C and 87.8 mol% AN, respectively. Thermal stability studies of the eutectics indicate that they are stable below 160°C and that thermal decomposition occurs slowly over a long period of time.The detonation velocities of both eutectics, measured unconfined at 2.54-cm diameter, were found to be within 95% of those predicted by the Kamlet-Jacobs method assuming ideal behavior. |
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We have found that both the ammonium salt of 5-nitrotetrazole (ANT) and the ethylenediamine salt of 5-nitrotetrazole (ENT) form eutectics with ammonium nitrate (AN). Initial characterization and small-scale sensitivity tests of CO2-balanced AN/ANT and AN/ENT formulations were performed; it was found that both eutectics were less sensitive in all tests than pure ANT or ENT, respectively. The phase diagrams of both mixtures were also determined. ANT forms a eutectic with AN that melts at 121°C; the eutectic composition of the AN/ANT system is 78.5 mol% AN. The eutectic temperature and composition of the AN/ENT system were found to be 110.5°C and 87.8 mol% AN, respectively. Thermal stability studies of the eutectics indicate that they are stable below 160°C and that thermal decomposition occurs slowly over a long period of time.The detonation velocities of both eutectics, measured unconfined at 2.54-cm diameter, were found to be within 95% of those predicted by the Kamlet-Jacobs method assuming ideal behavior. |
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We have found that both the ammonium salt of 5-nitrotetrazole (ANT) and the ethylenediamine salt of 5-nitrotetrazole (ENT) form eutectics with ammonium nitrate (AN). Initial characterization and small-scale sensitivity tests of CO2-balanced AN/ANT and AN/ENT formulations were performed; it was found that both eutectics were less sensitive in all tests than pure ANT or ENT, respectively. The phase diagrams of both mixtures were also determined. ANT forms a eutectic with AN that melts at 121°C; the eutectic composition of the AN/ANT system is 78.5 mol% AN. The eutectic temperature and composition of the AN/ENT system were found to be 110.5°C and 87.8 mol% AN, respectively. Thermal stability studies of the eutectics indicate that they are stable below 160°C and that thermal decomposition occurs slowly over a long period of time.The detonation velocities of both eutectics, measured unconfined at 2.54-cm diameter, were found to be within 95% of those predicted by the Kamlet-Jacobs method assuming ideal behavior. |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000naa a22002652 4500</leader><controlfield tag="001">NLEJ253075394</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20231206144118.0</controlfield><controlfield tag="007">cr uuu---uuuuu</controlfield><controlfield tag="008">231206s2011 xx |||||o 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1080/07370658308010822</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)NLEJ253075394</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(TFO)752776546</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rda</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Lee, K. -Y.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Binary eutectics formed between ammonium nitrate and amine salts of 5-nitrotetrazole I. preparation and initial characterization</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2011</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">Computermedien</subfield><subfield code="b">c</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Online-Ressource</subfield><subfield code="b">cr</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">We have found that both the ammonium salt of 5-nitrotetrazole (ANT) and the ethylenediamine salt of 5-nitrotetrazole (ENT) form eutectics with ammonium nitrate (AN). Initial characterization and small-scale sensitivity tests of CO2-balanced AN/ANT and AN/ENT formulations were performed; it was found that both eutectics were less sensitive in all tests than pure ANT or ENT, respectively. The phase diagrams of both mixtures were also determined. ANT forms a eutectic with AN that melts at 121°C; the eutectic composition of the AN/ANT system is 78.5 mol% AN. The eutectic temperature and composition of the AN/ENT system were found to be 110.5°C and 87.8 mol% AN, respectively. Thermal stability studies of the eutectics indicate that they are stable below 160°C and that thermal decomposition occurs slowly over a long period of time.The detonation velocities of both eutectics, measured unconfined at 2.54-cm diameter, were found to be within 95% of those predicted by the Kamlet-Jacobs method assuming ideal behavior.</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Coburn, M. D.</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of energetic materials</subfield><subfield code="d">Philadelphia, Pa. [u.a.] : Taylor and Francis, 1983</subfield><subfield code="g">1(1983), 1, Seite 109-122</subfield><subfield code="h">Online-Ressource</subfield><subfield code="w">(DE-627)NLEJ253073758</subfield><subfield code="w">(DE-600)2112655-0</subfield><subfield code="w">(DE-576)256275696</subfield><subfield code="x">1545-8822</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">number:1</subfield><subfield code="g">volume:1</subfield><subfield code="g">year:1983</subfield><subfield code="g">pages:109-122</subfield></datafield><datafield tag="856" ind1="4" ind2="0"><subfield code="u">https://www.tib.eu/de/suchen/id/tandf%3A67b7e8da99e5a80f45992f5601546d8ea8485199</subfield><subfield code="x">Digitalisierung</subfield><subfield code="z">Deutschlandweit zugänglich</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">ZDB-1-TFO</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_NL_ARTICLE</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="e">1</subfield><subfield code="d">1</subfield><subfield code="j">1983</subfield><subfield code="h">109-122</subfield></datafield></record></collection>
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