In situ fibrillation of polypropylene/polyamide 6 blends: Effect of organoclay addition
In situ fibrillation of PP/PA6 blends (85/15 wt %) is investigated in presence of two kinds of organically modified montmorillonite, differing by the polarity of their surfactant. The organoclay is primary dispersed either in the PP (for the low‐polarity Cloisite® 15A) or in the PA6 (for the high‐po...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Chomat, Dimitri [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2015 |
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| Rechteinformationen: |
Nutzungsrecht: © 2014 Wiley Periodicals, Inc. |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Journal of applied polymer science - Hoboken, NJ [u.a.] : Wiley InterScience, 1959, 132(2015), 12 |
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| Übergeordnetes Werk: |
volume:132 ; year:2015 ; number:12 |
| Links: |
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| DOI / URN: |
10.1002/app.41680 |
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| 520 | |a In situ fibrillation of PP/PA6 blends (85/15 wt %) is investigated in presence of two kinds of organically modified montmorillonite, differing by the polarity of their surfactant. The organoclay is primary dispersed either in the PP (for the low‐polarity Cloisite® 15A) or in the PA6 (for the high‐polarity Cloisite® 30B), according to its assumed affinity. In absence of organoclay, a fibrillar morphology is achieved after the melt‐blending and hot‐stretching step, as evidenced by SEM analysis. Upon clay addition, different morphological trends are evidenced. The C15A leads to a refinement of the fibrils whether the C30B induces a transition from fibrillar to nodular structure. These trends are ascribed to drastic changes in viscosity and elasticity ratios, due to the filler initial localization. Several techniques (DSC, STEM) point out a C15A migration from the PP to the PP/PA6 interface. Rheological measurements highlight the possibility of a double‐percolation phenomenon, linked to the fibrillar microstructure of the PP/PA6/C15A blend. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132 , 41680. | ||
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10.1002/app.41680 doi PQ20160617 (DE-627)OLC1956406964 (DE-599)GBVOLC1956406964 (PRQ)p3214-c43ba94d7cc08664c55e26e5df6877a1b6e32898d480d66975761cd6906b0ef83 (KEY)0117731120150000132001200000insitufibrillationofpolypropylenepolyamide6blendse DE-627 ger DE-627 rakwb eng 540 DE-600 35.80 bkl 51.70 bkl Chomat, Dimitri verfasserin aut In situ fibrillation of polypropylene/polyamide 6 blends: Effect of organoclay addition 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier In situ fibrillation of PP/PA6 blends (85/15 wt %) is investigated in presence of two kinds of organically modified montmorillonite, differing by the polarity of their surfactant. The organoclay is primary dispersed either in the PP (for the low‐polarity Cloisite® 15A) or in the PA6 (for the high‐polarity Cloisite® 30B), according to its assumed affinity. In absence of organoclay, a fibrillar morphology is achieved after the melt‐blending and hot‐stretching step, as evidenced by SEM analysis. Upon clay addition, different morphological trends are evidenced. The C15A leads to a refinement of the fibrils whether the C30B induces a transition from fibrillar to nodular structure. These trends are ascribed to drastic changes in viscosity and elasticity ratios, due to the filler initial localization. Several techniques (DSC, STEM) point out a C15A migration from the PP to the PP/PA6 interface. Rheological measurements highlight the possibility of a double‐percolation phenomenon, linked to the fibrillar microstructure of the PP/PA6/C15A blend. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132 , 41680. Nutzungsrecht: © 2014 Wiley Periodicals, Inc. polyolefins polyamides viscosity and viscoelasticity blends composites Soulestin, Jérémie oth Lacrampe, Marie‐France oth Sclavons, Michel oth Krawczak, Patricia oth Enthalten in Journal of applied polymer science Hoboken, NJ [u.a.] : Wiley InterScience, 1959 132(2015), 12 (DE-627)129595799 (DE-600)240694-9 (DE-576)015088812 0021-8995 nnns volume:132 year:2015 number:12 http://dx.doi.org/10.1002/app.41680 Volltext http://onlinelibrary.wiley.com/doi/10.1002/app.41680/abstract http://search.proquest.com/docview/1637368758 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 35.80 AVZ 51.70 AVZ AR 132 2015 12 |
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10.1002/app.41680 doi PQ20160617 (DE-627)OLC1956406964 (DE-599)GBVOLC1956406964 (PRQ)p3214-c43ba94d7cc08664c55e26e5df6877a1b6e32898d480d66975761cd6906b0ef83 (KEY)0117731120150000132001200000insitufibrillationofpolypropylenepolyamide6blendse DE-627 ger DE-627 rakwb eng 540 DE-600 35.80 bkl 51.70 bkl Chomat, Dimitri verfasserin aut In situ fibrillation of polypropylene/polyamide 6 blends: Effect of organoclay addition 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier In situ fibrillation of PP/PA6 blends (85/15 wt %) is investigated in presence of two kinds of organically modified montmorillonite, differing by the polarity of their surfactant. The organoclay is primary dispersed either in the PP (for the low‐polarity Cloisite® 15A) or in the PA6 (for the high‐polarity Cloisite® 30B), according to its assumed affinity. In absence of organoclay, a fibrillar morphology is achieved after the melt‐blending and hot‐stretching step, as evidenced by SEM analysis. Upon clay addition, different morphological trends are evidenced. The C15A leads to a refinement of the fibrils whether the C30B induces a transition from fibrillar to nodular structure. These trends are ascribed to drastic changes in viscosity and elasticity ratios, due to the filler initial localization. Several techniques (DSC, STEM) point out a C15A migration from the PP to the PP/PA6 interface. Rheological measurements highlight the possibility of a double‐percolation phenomenon, linked to the fibrillar microstructure of the PP/PA6/C15A blend. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132 , 41680. Nutzungsrecht: © 2014 Wiley Periodicals, Inc. polyolefins polyamides viscosity and viscoelasticity blends composites Soulestin, Jérémie oth Lacrampe, Marie‐France oth Sclavons, Michel oth Krawczak, Patricia oth Enthalten in Journal of applied polymer science Hoboken, NJ [u.a.] : Wiley InterScience, 1959 132(2015), 12 (DE-627)129595799 (DE-600)240694-9 (DE-576)015088812 0021-8995 nnns volume:132 year:2015 number:12 http://dx.doi.org/10.1002/app.41680 Volltext http://onlinelibrary.wiley.com/doi/10.1002/app.41680/abstract http://search.proquest.com/docview/1637368758 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 35.80 AVZ 51.70 AVZ AR 132 2015 12 |
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10.1002/app.41680 doi PQ20160617 (DE-627)OLC1956406964 (DE-599)GBVOLC1956406964 (PRQ)p3214-c43ba94d7cc08664c55e26e5df6877a1b6e32898d480d66975761cd6906b0ef83 (KEY)0117731120150000132001200000insitufibrillationofpolypropylenepolyamide6blendse DE-627 ger DE-627 rakwb eng 540 DE-600 35.80 bkl 51.70 bkl Chomat, Dimitri verfasserin aut In situ fibrillation of polypropylene/polyamide 6 blends: Effect of organoclay addition 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier In situ fibrillation of PP/PA6 blends (85/15 wt %) is investigated in presence of two kinds of organically modified montmorillonite, differing by the polarity of their surfactant. The organoclay is primary dispersed either in the PP (for the low‐polarity Cloisite® 15A) or in the PA6 (for the high‐polarity Cloisite® 30B), according to its assumed affinity. In absence of organoclay, a fibrillar morphology is achieved after the melt‐blending and hot‐stretching step, as evidenced by SEM analysis. Upon clay addition, different morphological trends are evidenced. The C15A leads to a refinement of the fibrils whether the C30B induces a transition from fibrillar to nodular structure. These trends are ascribed to drastic changes in viscosity and elasticity ratios, due to the filler initial localization. Several techniques (DSC, STEM) point out a C15A migration from the PP to the PP/PA6 interface. Rheological measurements highlight the possibility of a double‐percolation phenomenon, linked to the fibrillar microstructure of the PP/PA6/C15A blend. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132 , 41680. Nutzungsrecht: © 2014 Wiley Periodicals, Inc. polyolefins polyamides viscosity and viscoelasticity blends composites Soulestin, Jérémie oth Lacrampe, Marie‐France oth Sclavons, Michel oth Krawczak, Patricia oth Enthalten in Journal of applied polymer science Hoboken, NJ [u.a.] : Wiley InterScience, 1959 132(2015), 12 (DE-627)129595799 (DE-600)240694-9 (DE-576)015088812 0021-8995 nnns volume:132 year:2015 number:12 http://dx.doi.org/10.1002/app.41680 Volltext http://onlinelibrary.wiley.com/doi/10.1002/app.41680/abstract http://search.proquest.com/docview/1637368758 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 35.80 AVZ 51.70 AVZ AR 132 2015 12 |
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10.1002/app.41680 doi PQ20160617 (DE-627)OLC1956406964 (DE-599)GBVOLC1956406964 (PRQ)p3214-c43ba94d7cc08664c55e26e5df6877a1b6e32898d480d66975761cd6906b0ef83 (KEY)0117731120150000132001200000insitufibrillationofpolypropylenepolyamide6blendse DE-627 ger DE-627 rakwb eng 540 DE-600 35.80 bkl 51.70 bkl Chomat, Dimitri verfasserin aut In situ fibrillation of polypropylene/polyamide 6 blends: Effect of organoclay addition 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier In situ fibrillation of PP/PA6 blends (85/15 wt %) is investigated in presence of two kinds of organically modified montmorillonite, differing by the polarity of their surfactant. The organoclay is primary dispersed either in the PP (for the low‐polarity Cloisite® 15A) or in the PA6 (for the high‐polarity Cloisite® 30B), according to its assumed affinity. In absence of organoclay, a fibrillar morphology is achieved after the melt‐blending and hot‐stretching step, as evidenced by SEM analysis. Upon clay addition, different morphological trends are evidenced. The C15A leads to a refinement of the fibrils whether the C30B induces a transition from fibrillar to nodular structure. These trends are ascribed to drastic changes in viscosity and elasticity ratios, due to the filler initial localization. Several techniques (DSC, STEM) point out a C15A migration from the PP to the PP/PA6 interface. Rheological measurements highlight the possibility of a double‐percolation phenomenon, linked to the fibrillar microstructure of the PP/PA6/C15A blend. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132 , 41680. Nutzungsrecht: © 2014 Wiley Periodicals, Inc. polyolefins polyamides viscosity and viscoelasticity blends composites Soulestin, Jérémie oth Lacrampe, Marie‐France oth Sclavons, Michel oth Krawczak, Patricia oth Enthalten in Journal of applied polymer science Hoboken, NJ [u.a.] : Wiley InterScience, 1959 132(2015), 12 (DE-627)129595799 (DE-600)240694-9 (DE-576)015088812 0021-8995 nnns volume:132 year:2015 number:12 http://dx.doi.org/10.1002/app.41680 Volltext http://onlinelibrary.wiley.com/doi/10.1002/app.41680/abstract http://search.proquest.com/docview/1637368758 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 35.80 AVZ 51.70 AVZ AR 132 2015 12 |
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10.1002/app.41680 doi PQ20160617 (DE-627)OLC1956406964 (DE-599)GBVOLC1956406964 (PRQ)p3214-c43ba94d7cc08664c55e26e5df6877a1b6e32898d480d66975761cd6906b0ef83 (KEY)0117731120150000132001200000insitufibrillationofpolypropylenepolyamide6blendse DE-627 ger DE-627 rakwb eng 540 DE-600 35.80 bkl 51.70 bkl Chomat, Dimitri verfasserin aut In situ fibrillation of polypropylene/polyamide 6 blends: Effect of organoclay addition 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier In situ fibrillation of PP/PA6 blends (85/15 wt %) is investigated in presence of two kinds of organically modified montmorillonite, differing by the polarity of their surfactant. The organoclay is primary dispersed either in the PP (for the low‐polarity Cloisite® 15A) or in the PA6 (for the high‐polarity Cloisite® 30B), according to its assumed affinity. In absence of organoclay, a fibrillar morphology is achieved after the melt‐blending and hot‐stretching step, as evidenced by SEM analysis. Upon clay addition, different morphological trends are evidenced. The C15A leads to a refinement of the fibrils whether the C30B induces a transition from fibrillar to nodular structure. These trends are ascribed to drastic changes in viscosity and elasticity ratios, due to the filler initial localization. Several techniques (DSC, STEM) point out a C15A migration from the PP to the PP/PA6 interface. Rheological measurements highlight the possibility of a double‐percolation phenomenon, linked to the fibrillar microstructure of the PP/PA6/C15A blend. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132 , 41680. Nutzungsrecht: © 2014 Wiley Periodicals, Inc. polyolefins polyamides viscosity and viscoelasticity blends composites Soulestin, Jérémie oth Lacrampe, Marie‐France oth Sclavons, Michel oth Krawczak, Patricia oth Enthalten in Journal of applied polymer science Hoboken, NJ [u.a.] : Wiley InterScience, 1959 132(2015), 12 (DE-627)129595799 (DE-600)240694-9 (DE-576)015088812 0021-8995 nnns volume:132 year:2015 number:12 http://dx.doi.org/10.1002/app.41680 Volltext http://onlinelibrary.wiley.com/doi/10.1002/app.41680/abstract http://search.proquest.com/docview/1637368758 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 35.80 AVZ 51.70 AVZ AR 132 2015 12 |
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in situ fibrillation of polypropylene/polyamide 6 blends: effect of organoclay addition |
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In situ fibrillation of polypropylene/polyamide 6 blends: Effect of organoclay addition |
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In situ fibrillation of PP/PA6 blends (85/15 wt %) is investigated in presence of two kinds of organically modified montmorillonite, differing by the polarity of their surfactant. The organoclay is primary dispersed either in the PP (for the low‐polarity Cloisite® 15A) or in the PA6 (for the high‐polarity Cloisite® 30B), according to its assumed affinity. In absence of organoclay, a fibrillar morphology is achieved after the melt‐blending and hot‐stretching step, as evidenced by SEM analysis. Upon clay addition, different morphological trends are evidenced. The C15A leads to a refinement of the fibrils whether the C30B induces a transition from fibrillar to nodular structure. These trends are ascribed to drastic changes in viscosity and elasticity ratios, due to the filler initial localization. Several techniques (DSC, STEM) point out a C15A migration from the PP to the PP/PA6 interface. Rheological measurements highlight the possibility of a double‐percolation phenomenon, linked to the fibrillar microstructure of the PP/PA6/C15A blend. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132 , 41680. |
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In situ fibrillation of PP/PA6 blends (85/15 wt %) is investigated in presence of two kinds of organically modified montmorillonite, differing by the polarity of their surfactant. The organoclay is primary dispersed either in the PP (for the low‐polarity Cloisite® 15A) or in the PA6 (for the high‐polarity Cloisite® 30B), according to its assumed affinity. In absence of organoclay, a fibrillar morphology is achieved after the melt‐blending and hot‐stretching step, as evidenced by SEM analysis. Upon clay addition, different morphological trends are evidenced. The C15A leads to a refinement of the fibrils whether the C30B induces a transition from fibrillar to nodular structure. These trends are ascribed to drastic changes in viscosity and elasticity ratios, due to the filler initial localization. Several techniques (DSC, STEM) point out a C15A migration from the PP to the PP/PA6 interface. Rheological measurements highlight the possibility of a double‐percolation phenomenon, linked to the fibrillar microstructure of the PP/PA6/C15A blend. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132 , 41680. |
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In situ fibrillation of PP/PA6 blends (85/15 wt %) is investigated in presence of two kinds of organically modified montmorillonite, differing by the polarity of their surfactant. The organoclay is primary dispersed either in the PP (for the low‐polarity Cloisite® 15A) or in the PA6 (for the high‐polarity Cloisite® 30B), according to its assumed affinity. In absence of organoclay, a fibrillar morphology is achieved after the melt‐blending and hot‐stretching step, as evidenced by SEM analysis. Upon clay addition, different morphological trends are evidenced. The C15A leads to a refinement of the fibrils whether the C30B induces a transition from fibrillar to nodular structure. These trends are ascribed to drastic changes in viscosity and elasticity ratios, due to the filler initial localization. Several techniques (DSC, STEM) point out a C15A migration from the PP to the PP/PA6 interface. Rheological measurements highlight the possibility of a double‐percolation phenomenon, linked to the fibrillar microstructure of the PP/PA6/C15A blend. © 2014 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2015 , 132 , 41680. |
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In situ fibrillation of polypropylene/polyamide 6 blends: Effect of organoclay addition |
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