Induced cholesteric solutions of highly soluble bis-salicylaldiminate Cu(II) metallomesogens and their rheological behaviour
Copper(II) complexes containing chiral centres and functionalised with citronellyl end groups were synthesised. Isomerisation of citronellyl double bond was exploited to decrease the melting temperature of the complexes and improve their solubility in organic media. The chiral metallomesogens were s...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Borbone, Fabio [verfasserIn] |
|---|
| Format: |
Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2015 |
|---|
| Rechteinformationen: |
Nutzungsrecht: © 2015 Taylor & Francis 2015 |
|---|
| Schlagwörter: |
|---|
| Übergeordnetes Werk: |
Enthalten in: Liquid crystals - London : Taylor & Francis, 1986, 42(2015), 7, Seite 1003-1012 |
|---|---|
| Übergeordnetes Werk: |
volume:42 ; year:2015 ; number:7 ; pages:1003-1012 |
| Links: |
|---|
| DOI / URN: |
10.1080/02678292.2015.1013069 |
|---|
| Katalog-ID: |
OLC1957440007 |
|---|
| LEADER | 01000caa a2200265 4500 | ||
|---|---|---|---|
| 001 | OLC1957440007 | ||
| 003 | DE-627 | ||
| 005 | 20230515121726.0 | ||
| 007 | tu | ||
| 008 | 160206s2015 xx ||||| 00| ||eng c | ||
| 024 | 7 | |a 10.1080/02678292.2015.1013069 |2 doi | |
| 028 | 5 | 2 | |a PQ20160617 |
| 035 | |a (DE-627)OLC1957440007 | ||
| 035 | |a (DE-599)GBVOLC1957440007 | ||
| 035 | |a (PRQ)c2420-5dddd8171977b85f1efa7845f1318bd6e7f5a17e8a301cab2f759a94e2437dcb0 | ||
| 035 | |a (KEY)0153239120150000042000701003inducedcholestericsolutionsofhighlysolublebissalic | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 082 | 0 | 4 | |a 530 |a 550 |q DNB |
| 084 | |a 33.70 |2 bkl | ||
| 100 | 1 | |a Borbone, Fabio |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Induced cholesteric solutions of highly soluble bis-salicylaldiminate Cu(II) metallomesogens and their rheological behaviour |
| 264 | 1 | |c 2015 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ohne Hilfsmittel zu benutzen |b n |2 rdamedia | ||
| 338 | |a Band |b nc |2 rdacarrier | ||
| 520 | |a Copper(II) complexes containing chiral centres and functionalised with citronellyl end groups were synthesised. Isomerisation of citronellyl double bond was exploited to decrease the melting temperature of the complexes and improve their solubility in organic media. The chiral metallomesogens were successfully used to produce induced cholesteric solutions in commercial nematic liquid crystals also in high concentrations. Transparent and coloured thin films were easily obtained showing good reflective properties across the visible spectrum. The rheological behaviour of the nematic and the cholesteric phases was investigated. The nematic system showed the characteristics of a tumbling phase with a very peculiar transient behaviour. The cholesteric samples also showed a very unusual, flow-history-dependent transient behaviour. The viscosity trend presumably indicates a flow-induced orientation of the cholesteric superstructure, thus opening the way to the possibility of tuning the yield stress level of the material. The results support the potentiality of these compounds for applications in light reflecting technology. | ||
| 540 | |a Nutzungsrecht: © 2015 Taylor & Francis 2015 | ||
| 650 | 4 | |a citronellyl | |
| 650 | 4 | |a cholesteric | |
| 650 | 4 | |a copper | |
| 650 | 4 | |a rheology | |
| 650 | 4 | |a metallomesogen | |
| 650 | 4 | |a Yield stress | |
| 650 | 4 | |a Rheology | |
| 650 | 4 | |a Chemical synthesis | |
| 650 | 4 | |a Viscosity | |
| 650 | 4 | |a Temperature | |
| 650 | 4 | |a Crystals | |
| 650 | 4 | |a Thin films | |
| 700 | 1 | |a Grizzuti, Nino |4 oth | |
| 700 | 1 | |a Pasquino, Rossana |4 oth | |
| 700 | 1 | |a Ricciotti, Laura |4 oth | |
| 700 | 1 | |a Roviello, Antonio |4 oth | |
| 700 | 1 | |a Roviello, Giuseppina |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |t Liquid crystals |d London : Taylor & Francis, 1986 |g 42(2015), 7, Seite 1003-1012 |w (DE-627)129209058 |w (DE-600)55170-3 |w (DE-576)014457628 |x 0267-8292 |7 nnns |
| 773 | 1 | 8 | |g volume:42 |g year:2015 |g number:7 |g pages:1003-1012 |
| 856 | 4 | 1 | |u http://dx.doi.org/10.1080/02678292.2015.1013069 |3 Volltext |
| 856 | 4 | 2 | |u http://www.tandfonline.com/doi/abs/10.1080/02678292.2015.1013069 |
| 856 | 4 | 2 | |u http://search.proquest.com/docview/1702683401 |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a SYSFLAG_A | ||
| 912 | |a GBV_OLC | ||
| 912 | |a SSG-OLC-PHY | ||
| 912 | |a SSG-OLC-PHA | ||
| 912 | |a SSG-OLC-DE-84 | ||
| 912 | |a GBV_ILN_70 | ||
| 936 | b | k | |a 33.70 |q AVZ |
| 951 | |a AR | ||
| 952 | |d 42 |j 2015 |e 7 |h 1003-1012 | ||
| author_variant |
f b fb |
|---|---|
| matchkey_str |
article:02678292:2015----::nuecoetrcouinohglslbeislclliiaeuiealmsgn |
| hierarchy_sort_str |
2015 |
| bklnumber |
33.70 |
| publishDate |
2015 |
| allfields |
10.1080/02678292.2015.1013069 doi PQ20160617 (DE-627)OLC1957440007 (DE-599)GBVOLC1957440007 (PRQ)c2420-5dddd8171977b85f1efa7845f1318bd6e7f5a17e8a301cab2f759a94e2437dcb0 (KEY)0153239120150000042000701003inducedcholestericsolutionsofhighlysolublebissalic DE-627 ger DE-627 rakwb eng 530 550 DNB 33.70 bkl Borbone, Fabio verfasserin aut Induced cholesteric solutions of highly soluble bis-salicylaldiminate Cu(II) metallomesogens and their rheological behaviour 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Copper(II) complexes containing chiral centres and functionalised with citronellyl end groups were synthesised. Isomerisation of citronellyl double bond was exploited to decrease the melting temperature of the complexes and improve their solubility in organic media. The chiral metallomesogens were successfully used to produce induced cholesteric solutions in commercial nematic liquid crystals also in high concentrations. Transparent and coloured thin films were easily obtained showing good reflective properties across the visible spectrum. The rheological behaviour of the nematic and the cholesteric phases was investigated. The nematic system showed the characteristics of a tumbling phase with a very peculiar transient behaviour. The cholesteric samples also showed a very unusual, flow-history-dependent transient behaviour. The viscosity trend presumably indicates a flow-induced orientation of the cholesteric superstructure, thus opening the way to the possibility of tuning the yield stress level of the material. The results support the potentiality of these compounds for applications in light reflecting technology. Nutzungsrecht: © 2015 Taylor & Francis 2015 citronellyl cholesteric copper rheology metallomesogen Yield stress Rheology Chemical synthesis Viscosity Temperature Crystals Thin films Grizzuti, Nino oth Pasquino, Rossana oth Ricciotti, Laura oth Roviello, Antonio oth Roviello, Giuseppina oth Enthalten in Liquid crystals London : Taylor & Francis, 1986 42(2015), 7, Seite 1003-1012 (DE-627)129209058 (DE-600)55170-3 (DE-576)014457628 0267-8292 nnns volume:42 year:2015 number:7 pages:1003-1012 http://dx.doi.org/10.1080/02678292.2015.1013069 Volltext http://www.tandfonline.com/doi/abs/10.1080/02678292.2015.1013069 http://search.proquest.com/docview/1702683401 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 33.70 AVZ AR 42 2015 7 1003-1012 |
| spelling |
10.1080/02678292.2015.1013069 doi PQ20160617 (DE-627)OLC1957440007 (DE-599)GBVOLC1957440007 (PRQ)c2420-5dddd8171977b85f1efa7845f1318bd6e7f5a17e8a301cab2f759a94e2437dcb0 (KEY)0153239120150000042000701003inducedcholestericsolutionsofhighlysolublebissalic DE-627 ger DE-627 rakwb eng 530 550 DNB 33.70 bkl Borbone, Fabio verfasserin aut Induced cholesteric solutions of highly soluble bis-salicylaldiminate Cu(II) metallomesogens and their rheological behaviour 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Copper(II) complexes containing chiral centres and functionalised with citronellyl end groups were synthesised. Isomerisation of citronellyl double bond was exploited to decrease the melting temperature of the complexes and improve their solubility in organic media. The chiral metallomesogens were successfully used to produce induced cholesteric solutions in commercial nematic liquid crystals also in high concentrations. Transparent and coloured thin films were easily obtained showing good reflective properties across the visible spectrum. The rheological behaviour of the nematic and the cholesteric phases was investigated. The nematic system showed the characteristics of a tumbling phase with a very peculiar transient behaviour. The cholesteric samples also showed a very unusual, flow-history-dependent transient behaviour. The viscosity trend presumably indicates a flow-induced orientation of the cholesteric superstructure, thus opening the way to the possibility of tuning the yield stress level of the material. The results support the potentiality of these compounds for applications in light reflecting technology. Nutzungsrecht: © 2015 Taylor & Francis 2015 citronellyl cholesteric copper rheology metallomesogen Yield stress Rheology Chemical synthesis Viscosity Temperature Crystals Thin films Grizzuti, Nino oth Pasquino, Rossana oth Ricciotti, Laura oth Roviello, Antonio oth Roviello, Giuseppina oth Enthalten in Liquid crystals London : Taylor & Francis, 1986 42(2015), 7, Seite 1003-1012 (DE-627)129209058 (DE-600)55170-3 (DE-576)014457628 0267-8292 nnns volume:42 year:2015 number:7 pages:1003-1012 http://dx.doi.org/10.1080/02678292.2015.1013069 Volltext http://www.tandfonline.com/doi/abs/10.1080/02678292.2015.1013069 http://search.proquest.com/docview/1702683401 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 33.70 AVZ AR 42 2015 7 1003-1012 |
| allfields_unstemmed |
10.1080/02678292.2015.1013069 doi PQ20160617 (DE-627)OLC1957440007 (DE-599)GBVOLC1957440007 (PRQ)c2420-5dddd8171977b85f1efa7845f1318bd6e7f5a17e8a301cab2f759a94e2437dcb0 (KEY)0153239120150000042000701003inducedcholestericsolutionsofhighlysolublebissalic DE-627 ger DE-627 rakwb eng 530 550 DNB 33.70 bkl Borbone, Fabio verfasserin aut Induced cholesteric solutions of highly soluble bis-salicylaldiminate Cu(II) metallomesogens and their rheological behaviour 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Copper(II) complexes containing chiral centres and functionalised with citronellyl end groups were synthesised. Isomerisation of citronellyl double bond was exploited to decrease the melting temperature of the complexes and improve their solubility in organic media. The chiral metallomesogens were successfully used to produce induced cholesteric solutions in commercial nematic liquid crystals also in high concentrations. Transparent and coloured thin films were easily obtained showing good reflective properties across the visible spectrum. The rheological behaviour of the nematic and the cholesteric phases was investigated. The nematic system showed the characteristics of a tumbling phase with a very peculiar transient behaviour. The cholesteric samples also showed a very unusual, flow-history-dependent transient behaviour. The viscosity trend presumably indicates a flow-induced orientation of the cholesteric superstructure, thus opening the way to the possibility of tuning the yield stress level of the material. The results support the potentiality of these compounds for applications in light reflecting technology. Nutzungsrecht: © 2015 Taylor & Francis 2015 citronellyl cholesteric copper rheology metallomesogen Yield stress Rheology Chemical synthesis Viscosity Temperature Crystals Thin films Grizzuti, Nino oth Pasquino, Rossana oth Ricciotti, Laura oth Roviello, Antonio oth Roviello, Giuseppina oth Enthalten in Liquid crystals London : Taylor & Francis, 1986 42(2015), 7, Seite 1003-1012 (DE-627)129209058 (DE-600)55170-3 (DE-576)014457628 0267-8292 nnns volume:42 year:2015 number:7 pages:1003-1012 http://dx.doi.org/10.1080/02678292.2015.1013069 Volltext http://www.tandfonline.com/doi/abs/10.1080/02678292.2015.1013069 http://search.proquest.com/docview/1702683401 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 33.70 AVZ AR 42 2015 7 1003-1012 |
| allfieldsGer |
10.1080/02678292.2015.1013069 doi PQ20160617 (DE-627)OLC1957440007 (DE-599)GBVOLC1957440007 (PRQ)c2420-5dddd8171977b85f1efa7845f1318bd6e7f5a17e8a301cab2f759a94e2437dcb0 (KEY)0153239120150000042000701003inducedcholestericsolutionsofhighlysolublebissalic DE-627 ger DE-627 rakwb eng 530 550 DNB 33.70 bkl Borbone, Fabio verfasserin aut Induced cholesteric solutions of highly soluble bis-salicylaldiminate Cu(II) metallomesogens and their rheological behaviour 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Copper(II) complexes containing chiral centres and functionalised with citronellyl end groups were synthesised. Isomerisation of citronellyl double bond was exploited to decrease the melting temperature of the complexes and improve their solubility in organic media. The chiral metallomesogens were successfully used to produce induced cholesteric solutions in commercial nematic liquid crystals also in high concentrations. Transparent and coloured thin films were easily obtained showing good reflective properties across the visible spectrum. The rheological behaviour of the nematic and the cholesteric phases was investigated. The nematic system showed the characteristics of a tumbling phase with a very peculiar transient behaviour. The cholesteric samples also showed a very unusual, flow-history-dependent transient behaviour. The viscosity trend presumably indicates a flow-induced orientation of the cholesteric superstructure, thus opening the way to the possibility of tuning the yield stress level of the material. The results support the potentiality of these compounds for applications in light reflecting technology. Nutzungsrecht: © 2015 Taylor & Francis 2015 citronellyl cholesteric copper rheology metallomesogen Yield stress Rheology Chemical synthesis Viscosity Temperature Crystals Thin films Grizzuti, Nino oth Pasquino, Rossana oth Ricciotti, Laura oth Roviello, Antonio oth Roviello, Giuseppina oth Enthalten in Liquid crystals London : Taylor & Francis, 1986 42(2015), 7, Seite 1003-1012 (DE-627)129209058 (DE-600)55170-3 (DE-576)014457628 0267-8292 nnns volume:42 year:2015 number:7 pages:1003-1012 http://dx.doi.org/10.1080/02678292.2015.1013069 Volltext http://www.tandfonline.com/doi/abs/10.1080/02678292.2015.1013069 http://search.proquest.com/docview/1702683401 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 33.70 AVZ AR 42 2015 7 1003-1012 |
| allfieldsSound |
10.1080/02678292.2015.1013069 doi PQ20160617 (DE-627)OLC1957440007 (DE-599)GBVOLC1957440007 (PRQ)c2420-5dddd8171977b85f1efa7845f1318bd6e7f5a17e8a301cab2f759a94e2437dcb0 (KEY)0153239120150000042000701003inducedcholestericsolutionsofhighlysolublebissalic DE-627 ger DE-627 rakwb eng 530 550 DNB 33.70 bkl Borbone, Fabio verfasserin aut Induced cholesteric solutions of highly soluble bis-salicylaldiminate Cu(II) metallomesogens and their rheological behaviour 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Copper(II) complexes containing chiral centres and functionalised with citronellyl end groups were synthesised. Isomerisation of citronellyl double bond was exploited to decrease the melting temperature of the complexes and improve their solubility in organic media. The chiral metallomesogens were successfully used to produce induced cholesteric solutions in commercial nematic liquid crystals also in high concentrations. Transparent and coloured thin films were easily obtained showing good reflective properties across the visible spectrum. The rheological behaviour of the nematic and the cholesteric phases was investigated. The nematic system showed the characteristics of a tumbling phase with a very peculiar transient behaviour. The cholesteric samples also showed a very unusual, flow-history-dependent transient behaviour. The viscosity trend presumably indicates a flow-induced orientation of the cholesteric superstructure, thus opening the way to the possibility of tuning the yield stress level of the material. The results support the potentiality of these compounds for applications in light reflecting technology. Nutzungsrecht: © 2015 Taylor & Francis 2015 citronellyl cholesteric copper rheology metallomesogen Yield stress Rheology Chemical synthesis Viscosity Temperature Crystals Thin films Grizzuti, Nino oth Pasquino, Rossana oth Ricciotti, Laura oth Roviello, Antonio oth Roviello, Giuseppina oth Enthalten in Liquid crystals London : Taylor & Francis, 1986 42(2015), 7, Seite 1003-1012 (DE-627)129209058 (DE-600)55170-3 (DE-576)014457628 0267-8292 nnns volume:42 year:2015 number:7 pages:1003-1012 http://dx.doi.org/10.1080/02678292.2015.1013069 Volltext http://www.tandfonline.com/doi/abs/10.1080/02678292.2015.1013069 http://search.proquest.com/docview/1702683401 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 33.70 AVZ AR 42 2015 7 1003-1012 |
| language |
English |
| source |
Enthalten in Liquid crystals 42(2015), 7, Seite 1003-1012 volume:42 year:2015 number:7 pages:1003-1012 |
| sourceStr |
Enthalten in Liquid crystals 42(2015), 7, Seite 1003-1012 volume:42 year:2015 number:7 pages:1003-1012 |
| format_phy_str_mv |
Article |
| institution |
findex.gbv.de |
| topic_facet |
citronellyl cholesteric copper rheology metallomesogen Yield stress Rheology Chemical synthesis Viscosity Temperature Crystals Thin films |
| dewey-raw |
530 |
| isfreeaccess_bool |
false |
| container_title |
Liquid crystals |
| authorswithroles_txt_mv |
Borbone, Fabio @@aut@@ Grizzuti, Nino @@oth@@ Pasquino, Rossana @@oth@@ Ricciotti, Laura @@oth@@ Roviello, Antonio @@oth@@ Roviello, Giuseppina @@oth@@ |
| publishDateDaySort_date |
2015-01-01T00:00:00Z |
| hierarchy_top_id |
129209058 |
| dewey-sort |
3530 |
| id |
OLC1957440007 |
| language_de |
englisch |
| fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a2200265 4500</leader><controlfield tag="001">OLC1957440007</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230515121726.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">160206s2015 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1080/02678292.2015.1013069</subfield><subfield code="2">doi</subfield></datafield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">PQ20160617</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC1957440007</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVOLC1957440007</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(PRQ)c2420-5dddd8171977b85f1efa7845f1318bd6e7f5a17e8a301cab2f759a94e2437dcb0</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(KEY)0153239120150000042000701003inducedcholestericsolutionsofhighlysolublebissalic</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">530</subfield><subfield code="a">550</subfield><subfield code="q">DNB</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">33.70</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Borbone, Fabio</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Induced cholesteric solutions of highly soluble bis-salicylaldiminate Cu(II) metallomesogens and their rheological behaviour</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2015</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Copper(II) complexes containing chiral centres and functionalised with citronellyl end groups were synthesised. Isomerisation of citronellyl double bond was exploited to decrease the melting temperature of the complexes and improve their solubility in organic media. The chiral metallomesogens were successfully used to produce induced cholesteric solutions in commercial nematic liquid crystals also in high concentrations. Transparent and coloured thin films were easily obtained showing good reflective properties across the visible spectrum. The rheological behaviour of the nematic and the cholesteric phases was investigated. The nematic system showed the characteristics of a tumbling phase with a very peculiar transient behaviour. The cholesteric samples also showed a very unusual, flow-history-dependent transient behaviour. The viscosity trend presumably indicates a flow-induced orientation of the cholesteric superstructure, thus opening the way to the possibility of tuning the yield stress level of the material. The results support the potentiality of these compounds for applications in light reflecting technology.</subfield></datafield><datafield tag="540" ind1=" " ind2=" "><subfield code="a">Nutzungsrecht: © 2015 Taylor & Francis 2015</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">citronellyl</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">cholesteric</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">copper</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">rheology</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">metallomesogen</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Yield stress</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Rheology</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Chemical synthesis</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Viscosity</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Temperature</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Crystals</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Thin films</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Grizzuti, Nino</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Pasquino, Rossana</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Ricciotti, Laura</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Roviello, Antonio</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Roviello, Giuseppina</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Liquid crystals</subfield><subfield code="d">London : Taylor & Francis, 1986</subfield><subfield code="g">42(2015), 7, Seite 1003-1012</subfield><subfield code="w">(DE-627)129209058</subfield><subfield code="w">(DE-600)55170-3</subfield><subfield code="w">(DE-576)014457628</subfield><subfield code="x">0267-8292</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:42</subfield><subfield code="g">year:2015</subfield><subfield code="g">number:7</subfield><subfield code="g">pages:1003-1012</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">http://dx.doi.org/10.1080/02678292.2015.1013069</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">http://www.tandfonline.com/doi/abs/10.1080/02678292.2015.1013069</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">http://search.proquest.com/docview/1702683401</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHY</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-DE-84</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">33.70</subfield><subfield code="q">AVZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">42</subfield><subfield code="j">2015</subfield><subfield code="e">7</subfield><subfield code="h">1003-1012</subfield></datafield></record></collection>
|
| author |
Borbone, Fabio |
| spellingShingle |
Borbone, Fabio ddc 530 bkl 33.70 misc citronellyl misc cholesteric misc copper misc rheology misc metallomesogen misc Yield stress misc Rheology misc Chemical synthesis misc Viscosity misc Temperature misc Crystals misc Thin films Induced cholesteric solutions of highly soluble bis-salicylaldiminate Cu(II) metallomesogens and their rheological behaviour |
| authorStr |
Borbone, Fabio |
| ppnlink_with_tag_str_mv |
@@773@@(DE-627)129209058 |
| format |
Article |
| dewey-ones |
530 - Physics 550 - Earth sciences |
| delete_txt_mv |
keep |
| author_role |
aut |
| collection |
OLC |
| remote_str |
false |
| illustrated |
Not Illustrated |
| issn |
0267-8292 |
| topic_title |
530 550 DNB 33.70 bkl Induced cholesteric solutions of highly soluble bis-salicylaldiminate Cu(II) metallomesogens and their rheological behaviour citronellyl cholesteric copper rheology metallomesogen Yield stress Rheology Chemical synthesis Viscosity Temperature Crystals Thin films |
| topic |
ddc 530 bkl 33.70 misc citronellyl misc cholesteric misc copper misc rheology misc metallomesogen misc Yield stress misc Rheology misc Chemical synthesis misc Viscosity misc Temperature misc Crystals misc Thin films |
| topic_unstemmed |
ddc 530 bkl 33.70 misc citronellyl misc cholesteric misc copper misc rheology misc metallomesogen misc Yield stress misc Rheology misc Chemical synthesis misc Viscosity misc Temperature misc Crystals misc Thin films |
| topic_browse |
ddc 530 bkl 33.70 misc citronellyl misc cholesteric misc copper misc rheology misc metallomesogen misc Yield stress misc Rheology misc Chemical synthesis misc Viscosity misc Temperature misc Crystals misc Thin films |
| format_facet |
Aufsätze Gedruckte Aufsätze |
| format_main_str_mv |
Text Zeitschrift/Artikel |
| carriertype_str_mv |
nc |
| author2_variant |
n g ng r p rp l r lr a r ar g r gr |
| hierarchy_parent_title |
Liquid crystals |
| hierarchy_parent_id |
129209058 |
| dewey-tens |
530 - Physics 550 - Earth sciences & geology |
| hierarchy_top_title |
Liquid crystals |
| isfreeaccess_txt |
false |
| familylinks_str_mv |
(DE-627)129209058 (DE-600)55170-3 (DE-576)014457628 |
| title |
Induced cholesteric solutions of highly soluble bis-salicylaldiminate Cu(II) metallomesogens and their rheological behaviour |
| ctrlnum |
(DE-627)OLC1957440007 (DE-599)GBVOLC1957440007 (PRQ)c2420-5dddd8171977b85f1efa7845f1318bd6e7f5a17e8a301cab2f759a94e2437dcb0 (KEY)0153239120150000042000701003inducedcholestericsolutionsofhighlysolublebissalic |
| title_full |
Induced cholesteric solutions of highly soluble bis-salicylaldiminate Cu(II) metallomesogens and their rheological behaviour |
| author_sort |
Borbone, Fabio |
| journal |
Liquid crystals |
| journalStr |
Liquid crystals |
| lang_code |
eng |
| isOA_bool |
false |
| dewey-hundreds |
500 - Science |
| recordtype |
marc |
| publishDateSort |
2015 |
| contenttype_str_mv |
txt |
| container_start_page |
1003 |
| author_browse |
Borbone, Fabio |
| container_volume |
42 |
| class |
530 550 DNB 33.70 bkl |
| format_se |
Aufsätze |
| author-letter |
Borbone, Fabio |
| doi_str_mv |
10.1080/02678292.2015.1013069 |
| dewey-full |
530 550 |
| title_sort |
induced cholesteric solutions of highly soluble bis-salicylaldiminate cu(ii) metallomesogens and their rheological behaviour |
| title_auth |
Induced cholesteric solutions of highly soluble bis-salicylaldiminate Cu(II) metallomesogens and their rheological behaviour |
| abstract |
Copper(II) complexes containing chiral centres and functionalised with citronellyl end groups were synthesised. Isomerisation of citronellyl double bond was exploited to decrease the melting temperature of the complexes and improve their solubility in organic media. The chiral metallomesogens were successfully used to produce induced cholesteric solutions in commercial nematic liquid crystals also in high concentrations. Transparent and coloured thin films were easily obtained showing good reflective properties across the visible spectrum. The rheological behaviour of the nematic and the cholesteric phases was investigated. The nematic system showed the characteristics of a tumbling phase with a very peculiar transient behaviour. The cholesteric samples also showed a very unusual, flow-history-dependent transient behaviour. The viscosity trend presumably indicates a flow-induced orientation of the cholesteric superstructure, thus opening the way to the possibility of tuning the yield stress level of the material. The results support the potentiality of these compounds for applications in light reflecting technology. |
| abstractGer |
Copper(II) complexes containing chiral centres and functionalised with citronellyl end groups were synthesised. Isomerisation of citronellyl double bond was exploited to decrease the melting temperature of the complexes and improve their solubility in organic media. The chiral metallomesogens were successfully used to produce induced cholesteric solutions in commercial nematic liquid crystals also in high concentrations. Transparent and coloured thin films were easily obtained showing good reflective properties across the visible spectrum. The rheological behaviour of the nematic and the cholesteric phases was investigated. The nematic system showed the characteristics of a tumbling phase with a very peculiar transient behaviour. The cholesteric samples also showed a very unusual, flow-history-dependent transient behaviour. The viscosity trend presumably indicates a flow-induced orientation of the cholesteric superstructure, thus opening the way to the possibility of tuning the yield stress level of the material. The results support the potentiality of these compounds for applications in light reflecting technology. |
| abstract_unstemmed |
Copper(II) complexes containing chiral centres and functionalised with citronellyl end groups were synthesised. Isomerisation of citronellyl double bond was exploited to decrease the melting temperature of the complexes and improve their solubility in organic media. The chiral metallomesogens were successfully used to produce induced cholesteric solutions in commercial nematic liquid crystals also in high concentrations. Transparent and coloured thin films were easily obtained showing good reflective properties across the visible spectrum. The rheological behaviour of the nematic and the cholesteric phases was investigated. The nematic system showed the characteristics of a tumbling phase with a very peculiar transient behaviour. The cholesteric samples also showed a very unusual, flow-history-dependent transient behaviour. The viscosity trend presumably indicates a flow-induced orientation of the cholesteric superstructure, thus opening the way to the possibility of tuning the yield stress level of the material. The results support the potentiality of these compounds for applications in light reflecting technology. |
| collection_details |
GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 |
| container_issue |
7 |
| title_short |
Induced cholesteric solutions of highly soluble bis-salicylaldiminate Cu(II) metallomesogens and their rheological behaviour |
| url |
http://dx.doi.org/10.1080/02678292.2015.1013069 http://www.tandfonline.com/doi/abs/10.1080/02678292.2015.1013069 http://search.proquest.com/docview/1702683401 |
| remote_bool |
false |
| author2 |
Grizzuti, Nino Pasquino, Rossana Ricciotti, Laura Roviello, Antonio Roviello, Giuseppina |
| author2Str |
Grizzuti, Nino Pasquino, Rossana Ricciotti, Laura Roviello, Antonio Roviello, Giuseppina |
| ppnlink |
129209058 |
| mediatype_str_mv |
n |
| isOA_txt |
false |
| hochschulschrift_bool |
false |
| author2_role |
oth oth oth oth oth |
| doi_str |
10.1080/02678292.2015.1013069 |
| up_date |
2024-07-04T00:15:51.692Z |
| _version_ |
1803605405013639169 |
| fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a2200265 4500</leader><controlfield tag="001">OLC1957440007</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230515121726.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">160206s2015 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1080/02678292.2015.1013069</subfield><subfield code="2">doi</subfield></datafield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">PQ20160617</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC1957440007</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVOLC1957440007</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(PRQ)c2420-5dddd8171977b85f1efa7845f1318bd6e7f5a17e8a301cab2f759a94e2437dcb0</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(KEY)0153239120150000042000701003inducedcholestericsolutionsofhighlysolublebissalic</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">530</subfield><subfield code="a">550</subfield><subfield code="q">DNB</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">33.70</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Borbone, Fabio</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Induced cholesteric solutions of highly soluble bis-salicylaldiminate Cu(II) metallomesogens and their rheological behaviour</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2015</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Copper(II) complexes containing chiral centres and functionalised with citronellyl end groups were synthesised. Isomerisation of citronellyl double bond was exploited to decrease the melting temperature of the complexes and improve their solubility in organic media. The chiral metallomesogens were successfully used to produce induced cholesteric solutions in commercial nematic liquid crystals also in high concentrations. Transparent and coloured thin films were easily obtained showing good reflective properties across the visible spectrum. The rheological behaviour of the nematic and the cholesteric phases was investigated. The nematic system showed the characteristics of a tumbling phase with a very peculiar transient behaviour. The cholesteric samples also showed a very unusual, flow-history-dependent transient behaviour. The viscosity trend presumably indicates a flow-induced orientation of the cholesteric superstructure, thus opening the way to the possibility of tuning the yield stress level of the material. The results support the potentiality of these compounds for applications in light reflecting technology.</subfield></datafield><datafield tag="540" ind1=" " ind2=" "><subfield code="a">Nutzungsrecht: © 2015 Taylor & Francis 2015</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">citronellyl</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">cholesteric</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">copper</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">rheology</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">metallomesogen</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Yield stress</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Rheology</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Chemical synthesis</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Viscosity</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Temperature</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Crystals</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Thin films</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Grizzuti, Nino</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Pasquino, Rossana</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Ricciotti, Laura</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Roviello, Antonio</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Roviello, Giuseppina</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Liquid crystals</subfield><subfield code="d">London : Taylor & Francis, 1986</subfield><subfield code="g">42(2015), 7, Seite 1003-1012</subfield><subfield code="w">(DE-627)129209058</subfield><subfield code="w">(DE-600)55170-3</subfield><subfield code="w">(DE-576)014457628</subfield><subfield code="x">0267-8292</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:42</subfield><subfield code="g">year:2015</subfield><subfield code="g">number:7</subfield><subfield code="g">pages:1003-1012</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">http://dx.doi.org/10.1080/02678292.2015.1013069</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">http://www.tandfonline.com/doi/abs/10.1080/02678292.2015.1013069</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">http://search.proquest.com/docview/1702683401</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHY</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-DE-84</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">33.70</subfield><subfield code="q">AVZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">42</subfield><subfield code="j">2015</subfield><subfield code="e">7</subfield><subfield code="h">1003-1012</subfield></datafield></record></collection>
|
| score |
7.401374 |