Crosslinking-Dependent Relaxation Dynamics in Ethylene-Propylene-Diene (EPDM) Terpolymer above the Glass Transition Temperature
Dynamic mechanical experiments performed on ethylene-propylene-diene (EPDM) terpolymer, cross linked to different extents, evidenced three relaxation processes. Besides the glass transition (T g ) and the melting of the ethylene crystals formed in the ethylene-based EPDM, a new transition appeared a...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Gu, Zhen [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2015 |
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| Rechteinformationen: |
Nutzungsrecht: Copyright © Taylor & Francis Group, LLC 2015 |
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| Schlagwörter: |
|---|
| Übergeordnetes Werk: |
Enthalten in: Journal of macromolecular science / B - New York, NY : Dekker Chemistry, 1967, 54(2015), 5, Seite 618-627 |
|---|---|
| Übergeordnetes Werk: |
volume:54 ; year:2015 ; number:5 ; pages:618-627 |
| Links: |
|---|
| DOI / URN: |
10.1080/00222348.2015.1018438 |
|---|
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OLC1962606422 |
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| 520 | |a Dynamic mechanical experiments performed on ethylene-propylene-diene (EPDM) terpolymer, cross linked to different extents, evidenced three relaxation processes. Besides the glass transition (T g ) and the melting of the ethylene crystals formed in the ethylene-based EPDM, a new transition appeared at a temperature higher than the glass transition temperature (so-called tan δ gh ) and decreased dramatically in amplitude with increase in the degree of cure. The new transition (tan δ gh ) was also above the melting point. The viscoelastic properties of the rubber with various crosslinking degrees are described. Based on the behavior of tan δ gh and the curing properties of EPDM, the tan δ gh peak is primarily attributed to the motion of non-elastic network chains loosely attached to the three-dimensional network, including free chains. | ||
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| 700 | 1 | |a Tian, Xingyou |4 oth | |
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10.1080/00222348.2015.1018438 doi PQ20160617 (DE-627)OLC1962606422 (DE-599)GBVOLC1962606422 (PRQ)c1989-4f035d871b24461c94fc17985050cfed7a99a9890c62c67b2af5abcf511a194e0 (KEY)0005784320150000054000500618crosslinkingdependentrelaxationdynamicsinethylenep DE-627 ger DE-627 rakwb eng 530 DNB 33.00 bkl Gu, Zhen verfasserin aut Crosslinking-Dependent Relaxation Dynamics in Ethylene-Propylene-Diene (EPDM) Terpolymer above the Glass Transition Temperature 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Dynamic mechanical experiments performed on ethylene-propylene-diene (EPDM) terpolymer, cross linked to different extents, evidenced three relaxation processes. Besides the glass transition (T g ) and the melting of the ethylene crystals formed in the ethylene-based EPDM, a new transition appeared at a temperature higher than the glass transition temperature (so-called tan δ gh ) and decreased dramatically in amplitude with increase in the degree of cure. The new transition (tan δ gh ) was also above the melting point. The viscoelastic properties of the rubber with various crosslinking degrees are described. Based on the behavior of tan δ gh and the curing properties of EPDM, the tan δ gh peak is primarily attributed to the motion of non-elastic network chains loosely attached to the three-dimensional network, including free chains. Nutzungsrecht: Copyright © Taylor & Francis Group, LLC 2015 EPDM relaxation dynamics non-elastic network chains cross-link Zhang, Xian oth Bao, Chao oth Xue, Meng oth Wang, Huan oth Tian, Xingyou oth Enthalten in Journal of macromolecular science / B New York, NY : Dekker Chemistry, 1967 54(2015), 5, Seite 618-627 (DE-627)12955670X (DE-600)220815-5 (DE-576)015014274 0022-2348 nnns volume:54 year:2015 number:5 pages:618-627 http://dx.doi.org/10.1080/00222348.2015.1018438 Volltext http://www.tandfonline.com/doi/abs/10.1080/00222348.2015.1018438 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_2411 33.00 AVZ AR 54 2015 5 618-627 |
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10.1080/00222348.2015.1018438 doi PQ20160617 (DE-627)OLC1962606422 (DE-599)GBVOLC1962606422 (PRQ)c1989-4f035d871b24461c94fc17985050cfed7a99a9890c62c67b2af5abcf511a194e0 (KEY)0005784320150000054000500618crosslinkingdependentrelaxationdynamicsinethylenep DE-627 ger DE-627 rakwb eng 530 DNB 33.00 bkl Gu, Zhen verfasserin aut Crosslinking-Dependent Relaxation Dynamics in Ethylene-Propylene-Diene (EPDM) Terpolymer above the Glass Transition Temperature 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Dynamic mechanical experiments performed on ethylene-propylene-diene (EPDM) terpolymer, cross linked to different extents, evidenced three relaxation processes. Besides the glass transition (T g ) and the melting of the ethylene crystals formed in the ethylene-based EPDM, a new transition appeared at a temperature higher than the glass transition temperature (so-called tan δ gh ) and decreased dramatically in amplitude with increase in the degree of cure. The new transition (tan δ gh ) was also above the melting point. The viscoelastic properties of the rubber with various crosslinking degrees are described. Based on the behavior of tan δ gh and the curing properties of EPDM, the tan δ gh peak is primarily attributed to the motion of non-elastic network chains loosely attached to the three-dimensional network, including free chains. Nutzungsrecht: Copyright © Taylor & Francis Group, LLC 2015 EPDM relaxation dynamics non-elastic network chains cross-link Zhang, Xian oth Bao, Chao oth Xue, Meng oth Wang, Huan oth Tian, Xingyou oth Enthalten in Journal of macromolecular science / B New York, NY : Dekker Chemistry, 1967 54(2015), 5, Seite 618-627 (DE-627)12955670X (DE-600)220815-5 (DE-576)015014274 0022-2348 nnns volume:54 year:2015 number:5 pages:618-627 http://dx.doi.org/10.1080/00222348.2015.1018438 Volltext http://www.tandfonline.com/doi/abs/10.1080/00222348.2015.1018438 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_2411 33.00 AVZ AR 54 2015 5 618-627 |
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10.1080/00222348.2015.1018438 doi PQ20160617 (DE-627)OLC1962606422 (DE-599)GBVOLC1962606422 (PRQ)c1989-4f035d871b24461c94fc17985050cfed7a99a9890c62c67b2af5abcf511a194e0 (KEY)0005784320150000054000500618crosslinkingdependentrelaxationdynamicsinethylenep DE-627 ger DE-627 rakwb eng 530 DNB 33.00 bkl Gu, Zhen verfasserin aut Crosslinking-Dependent Relaxation Dynamics in Ethylene-Propylene-Diene (EPDM) Terpolymer above the Glass Transition Temperature 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Dynamic mechanical experiments performed on ethylene-propylene-diene (EPDM) terpolymer, cross linked to different extents, evidenced three relaxation processes. Besides the glass transition (T g ) and the melting of the ethylene crystals formed in the ethylene-based EPDM, a new transition appeared at a temperature higher than the glass transition temperature (so-called tan δ gh ) and decreased dramatically in amplitude with increase in the degree of cure. The new transition (tan δ gh ) was also above the melting point. The viscoelastic properties of the rubber with various crosslinking degrees are described. Based on the behavior of tan δ gh and the curing properties of EPDM, the tan δ gh peak is primarily attributed to the motion of non-elastic network chains loosely attached to the three-dimensional network, including free chains. Nutzungsrecht: Copyright © Taylor & Francis Group, LLC 2015 EPDM relaxation dynamics non-elastic network chains cross-link Zhang, Xian oth Bao, Chao oth Xue, Meng oth Wang, Huan oth Tian, Xingyou oth Enthalten in Journal of macromolecular science / B New York, NY : Dekker Chemistry, 1967 54(2015), 5, Seite 618-627 (DE-627)12955670X (DE-600)220815-5 (DE-576)015014274 0022-2348 nnns volume:54 year:2015 number:5 pages:618-627 http://dx.doi.org/10.1080/00222348.2015.1018438 Volltext http://www.tandfonline.com/doi/abs/10.1080/00222348.2015.1018438 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_2411 33.00 AVZ AR 54 2015 5 618-627 |
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10.1080/00222348.2015.1018438 doi PQ20160617 (DE-627)OLC1962606422 (DE-599)GBVOLC1962606422 (PRQ)c1989-4f035d871b24461c94fc17985050cfed7a99a9890c62c67b2af5abcf511a194e0 (KEY)0005784320150000054000500618crosslinkingdependentrelaxationdynamicsinethylenep DE-627 ger DE-627 rakwb eng 530 DNB 33.00 bkl Gu, Zhen verfasserin aut Crosslinking-Dependent Relaxation Dynamics in Ethylene-Propylene-Diene (EPDM) Terpolymer above the Glass Transition Temperature 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Dynamic mechanical experiments performed on ethylene-propylene-diene (EPDM) terpolymer, cross linked to different extents, evidenced three relaxation processes. Besides the glass transition (T g ) and the melting of the ethylene crystals formed in the ethylene-based EPDM, a new transition appeared at a temperature higher than the glass transition temperature (so-called tan δ gh ) and decreased dramatically in amplitude with increase in the degree of cure. The new transition (tan δ gh ) was also above the melting point. The viscoelastic properties of the rubber with various crosslinking degrees are described. Based on the behavior of tan δ gh and the curing properties of EPDM, the tan δ gh peak is primarily attributed to the motion of non-elastic network chains loosely attached to the three-dimensional network, including free chains. Nutzungsrecht: Copyright © Taylor & Francis Group, LLC 2015 EPDM relaxation dynamics non-elastic network chains cross-link Zhang, Xian oth Bao, Chao oth Xue, Meng oth Wang, Huan oth Tian, Xingyou oth Enthalten in Journal of macromolecular science / B New York, NY : Dekker Chemistry, 1967 54(2015), 5, Seite 618-627 (DE-627)12955670X (DE-600)220815-5 (DE-576)015014274 0022-2348 nnns volume:54 year:2015 number:5 pages:618-627 http://dx.doi.org/10.1080/00222348.2015.1018438 Volltext http://www.tandfonline.com/doi/abs/10.1080/00222348.2015.1018438 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_2411 33.00 AVZ AR 54 2015 5 618-627 |
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Crosslinking-Dependent Relaxation Dynamics in Ethylene-Propylene-Diene (EPDM) Terpolymer above the Glass Transition Temperature |
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Crosslinking-Dependent Relaxation Dynamics in Ethylene-Propylene-Diene (EPDM) Terpolymer above the Glass Transition Temperature |
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Gu, Zhen |
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Journal of macromolecular science / B |
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10.1080/00222348.2015.1018438 |
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crosslinking-dependent relaxation dynamics in ethylene-propylene-diene (epdm) terpolymer above the glass transition temperature |
| title_auth |
Crosslinking-Dependent Relaxation Dynamics in Ethylene-Propylene-Diene (EPDM) Terpolymer above the Glass Transition Temperature |
| abstract |
Dynamic mechanical experiments performed on ethylene-propylene-diene (EPDM) terpolymer, cross linked to different extents, evidenced three relaxation processes. Besides the glass transition (T g ) and the melting of the ethylene crystals formed in the ethylene-based EPDM, a new transition appeared at a temperature higher than the glass transition temperature (so-called tan δ gh ) and decreased dramatically in amplitude with increase in the degree of cure. The new transition (tan δ gh ) was also above the melting point. The viscoelastic properties of the rubber with various crosslinking degrees are described. Based on the behavior of tan δ gh and the curing properties of EPDM, the tan δ gh peak is primarily attributed to the motion of non-elastic network chains loosely attached to the three-dimensional network, including free chains. |
| abstractGer |
Dynamic mechanical experiments performed on ethylene-propylene-diene (EPDM) terpolymer, cross linked to different extents, evidenced three relaxation processes. Besides the glass transition (T g ) and the melting of the ethylene crystals formed in the ethylene-based EPDM, a new transition appeared at a temperature higher than the glass transition temperature (so-called tan δ gh ) and decreased dramatically in amplitude with increase in the degree of cure. The new transition (tan δ gh ) was also above the melting point. The viscoelastic properties of the rubber with various crosslinking degrees are described. Based on the behavior of tan δ gh and the curing properties of EPDM, the tan δ gh peak is primarily attributed to the motion of non-elastic network chains loosely attached to the three-dimensional network, including free chains. |
| abstract_unstemmed |
Dynamic mechanical experiments performed on ethylene-propylene-diene (EPDM) terpolymer, cross linked to different extents, evidenced three relaxation processes. Besides the glass transition (T g ) and the melting of the ethylene crystals formed in the ethylene-based EPDM, a new transition appeared at a temperature higher than the glass transition temperature (so-called tan δ gh ) and decreased dramatically in amplitude with increase in the degree of cure. The new transition (tan δ gh ) was also above the melting point. The viscoelastic properties of the rubber with various crosslinking degrees are described. Based on the behavior of tan δ gh and the curing properties of EPDM, the tan δ gh peak is primarily attributed to the motion of non-elastic network chains loosely attached to the three-dimensional network, including free chains. |
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5 |
| title_short |
Crosslinking-Dependent Relaxation Dynamics in Ethylene-Propylene-Diene (EPDM) Terpolymer above the Glass Transition Temperature |
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http://dx.doi.org/10.1080/00222348.2015.1018438 http://www.tandfonline.com/doi/abs/10.1080/00222348.2015.1018438 |
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Zhang, Xian Bao, Chao Xue, Meng Wang, Huan Tian, Xingyou |
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