Synthesis, Characterization, and Oxidative Cleavage Activities of Binaphthol-Modified Cyclotriphosphazene Bidentate Ligands
A series of novel cyclotriphosphazene derivatives were synthesized from hexachlorocyclotriphosphazene (HCCP) and (S)-BINOL. The target ligands were characterized by 1 H NMR, 13 C NMR, 31 P NMR, ESI-MS, and HR-MS. Preliminary studies on the oxidative cleavage of pUC19 DNA in the presence of their met...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Ding, Pei-Gang [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2015 |
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| Rechteinformationen: |
Nutzungsrecht: Copyright © Taylor & Francis Group, LLC 2015 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Phosphorus, sulfur and silicon and the related elements - Philadelphia, Pa [u.a.] : Taylor & Francis, 1989, 190(2015), 2, Seite 240 |
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| Übergeordnetes Werk: |
volume:190 ; year:2015 ; number:2 ; pages:240 |
| Links: |
|---|
| DOI / URN: |
10.1080/10426507.2014.914938 |
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OLC1963265289 |
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| 520 | |a A series of novel cyclotriphosphazene derivatives were synthesized from hexachlorocyclotriphosphazene (HCCP) and (S)-BINOL. The target ligands were characterized by 1 H NMR, 13 C NMR, 31 P NMR, ESI-MS, and HR-MS. Preliminary studies on the oxidative cleavage of pUC19 DNA in the presence of their metal complexes have also been performed. The results revealed that their Cu 2+ complexes could act as powerful catalysts for the cleavage of pUC19 DNA under physiological conditions. The oxidative cleavage conditions were optimized. | ||
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| 700 | 1 | |a Zhao, Yufen |4 oth | |
| 700 | 1 | |a Ye, Yong |4 oth | |
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10.1080/10426507.2014.914938 doi PQ20160617 (DE-627)OLC1963265289 (DE-599)GBVOLC1963265289 (PRQ)c2112-788e3d3ee882d89033383c1f39e7ecb24b52640fab7736b3e7ad5e865ac525410 (KEY)0015125420150000190000200240synthesischaracterizationandoxidativecleavageactiv DE-627 ger DE-627 rakwb eng 660 540 DNB Ding, Pei-Gang verfasserin aut Synthesis, Characterization, and Oxidative Cleavage Activities of Binaphthol-Modified Cyclotriphosphazene Bidentate Ligands 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier A series of novel cyclotriphosphazene derivatives were synthesized from hexachlorocyclotriphosphazene (HCCP) and (S)-BINOL. The target ligands were characterized by 1 H NMR, 13 C NMR, 31 P NMR, ESI-MS, and HR-MS. Preliminary studies on the oxidative cleavage of pUC19 DNA in the presence of their metal complexes have also been performed. The results revealed that their Cu 2+ complexes could act as powerful catalysts for the cleavage of pUC19 DNA under physiological conditions. The oxidative cleavage conditions were optimized. Nutzungsrecht: Copyright © Taylor & Francis Group, LLC 2015 bidentate ligands pUC19 DNA oxidative cleavage Cyclotriphosphazene derivatives Medical research Deoxyribonucleic acid--DNA Ligands Zou, Ruyi oth Yang, Xian oth Zhang, Di oth Zhao, Yufen oth Ye, Yong oth Enthalten in Phosphorus, sulfur and silicon and the related elements Philadelphia, Pa [u.a.] : Taylor & Francis, 1989 190(2015), 2, Seite 240 (DE-627)130784885 (DE-600)1004997-6 (DE-576)017720621 1042-6507 nnns volume:190 year:2015 number:2 pages:240 http://dx.doi.org/10.1080/10426507.2014.914938 Volltext http://www.tandfonline.com/doi/abs/10.1080/10426507.2014.914938 http://search.proquest.com/docview/1679903285 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_4305 AR 190 2015 2 240 |
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10.1080/10426507.2014.914938 doi PQ20160617 (DE-627)OLC1963265289 (DE-599)GBVOLC1963265289 (PRQ)c2112-788e3d3ee882d89033383c1f39e7ecb24b52640fab7736b3e7ad5e865ac525410 (KEY)0015125420150000190000200240synthesischaracterizationandoxidativecleavageactiv DE-627 ger DE-627 rakwb eng 660 540 DNB Ding, Pei-Gang verfasserin aut Synthesis, Characterization, and Oxidative Cleavage Activities of Binaphthol-Modified Cyclotriphosphazene Bidentate Ligands 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier A series of novel cyclotriphosphazene derivatives were synthesized from hexachlorocyclotriphosphazene (HCCP) and (S)-BINOL. The target ligands were characterized by 1 H NMR, 13 C NMR, 31 P NMR, ESI-MS, and HR-MS. Preliminary studies on the oxidative cleavage of pUC19 DNA in the presence of their metal complexes have also been performed. The results revealed that their Cu 2+ complexes could act as powerful catalysts for the cleavage of pUC19 DNA under physiological conditions. The oxidative cleavage conditions were optimized. Nutzungsrecht: Copyright © Taylor & Francis Group, LLC 2015 bidentate ligands pUC19 DNA oxidative cleavage Cyclotriphosphazene derivatives Medical research Deoxyribonucleic acid--DNA Ligands Zou, Ruyi oth Yang, Xian oth Zhang, Di oth Zhao, Yufen oth Ye, Yong oth Enthalten in Phosphorus, sulfur and silicon and the related elements Philadelphia, Pa [u.a.] : Taylor & Francis, 1989 190(2015), 2, Seite 240 (DE-627)130784885 (DE-600)1004997-6 (DE-576)017720621 1042-6507 nnns volume:190 year:2015 number:2 pages:240 http://dx.doi.org/10.1080/10426507.2014.914938 Volltext http://www.tandfonline.com/doi/abs/10.1080/10426507.2014.914938 http://search.proquest.com/docview/1679903285 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_4305 AR 190 2015 2 240 |
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Phosphorus, sulfur and silicon and the related elements |
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660 - Chemical engineering 540 - Chemistry |
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Phosphorus, sulfur and silicon and the related elements |
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Synthesis, Characterization, and Oxidative Cleavage Activities of Binaphthol-Modified Cyclotriphosphazene Bidentate Ligands |
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Synthesis, Characterization, and Oxidative Cleavage Activities of Binaphthol-Modified Cyclotriphosphazene Bidentate Ligands |
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Ding, Pei-Gang |
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Phosphorus, sulfur and silicon and the related elements |
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Phosphorus, sulfur and silicon and the related elements |
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10.1080/10426507.2014.914938 |
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660 540 |
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synthesis, characterization, and oxidative cleavage activities of binaphthol-modified cyclotriphosphazene bidentate ligands |
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Synthesis, Characterization, and Oxidative Cleavage Activities of Binaphthol-Modified Cyclotriphosphazene Bidentate Ligands |
| abstract |
A series of novel cyclotriphosphazene derivatives were synthesized from hexachlorocyclotriphosphazene (HCCP) and (S)-BINOL. The target ligands were characterized by 1 H NMR, 13 C NMR, 31 P NMR, ESI-MS, and HR-MS. Preliminary studies on the oxidative cleavage of pUC19 DNA in the presence of their metal complexes have also been performed. The results revealed that their Cu 2+ complexes could act as powerful catalysts for the cleavage of pUC19 DNA under physiological conditions. The oxidative cleavage conditions were optimized. |
| abstractGer |
A series of novel cyclotriphosphazene derivatives were synthesized from hexachlorocyclotriphosphazene (HCCP) and (S)-BINOL. The target ligands were characterized by 1 H NMR, 13 C NMR, 31 P NMR, ESI-MS, and HR-MS. Preliminary studies on the oxidative cleavage of pUC19 DNA in the presence of their metal complexes have also been performed. The results revealed that their Cu 2+ complexes could act as powerful catalysts for the cleavage of pUC19 DNA under physiological conditions. The oxidative cleavage conditions were optimized. |
| abstract_unstemmed |
A series of novel cyclotriphosphazene derivatives were synthesized from hexachlorocyclotriphosphazene (HCCP) and (S)-BINOL. The target ligands were characterized by 1 H NMR, 13 C NMR, 31 P NMR, ESI-MS, and HR-MS. Preliminary studies on the oxidative cleavage of pUC19 DNA in the presence of their metal complexes have also been performed. The results revealed that their Cu 2+ complexes could act as powerful catalysts for the cleavage of pUC19 DNA under physiological conditions. The oxidative cleavage conditions were optimized. |
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| title_short |
Synthesis, Characterization, and Oxidative Cleavage Activities of Binaphthol-Modified Cyclotriphosphazene Bidentate Ligands |
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Zou, Ruyi Yang, Xian Zhang, Di Zhao, Yufen Ye, Yong |
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