Does Particle Size of Clinoptilolite Zeolite Have a Role in Textural Properties? Insight through Differential Pore-Volume Distribution of Barret, Joyner, and Halenda Model
Analysis of differential pore-volume distribution (PVD) patterns of commercial clinoptilolite fractions [(<125 µ (Z8; fine), 125-250 µ (Z9; medium), and >250 µ (Z10; coarse)] has been conducted experimentally using an analyzer to measure the nitrogen (N 2 ) adsorption isotherms. The differenti...
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| Autor*in: |
Ramesh, K [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2015 |
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| Rechteinformationen: |
Nutzungsrecht: Copyright © Taylor & Francis Group, LLC |
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Enthalten in: Communications in soil science and plant analysis - Philadelphia, Pa. : Taylor & Francis, 1970, 46(2015), 16, Seite 2070-9 |
|---|---|
| Übergeordnetes Werk: |
volume:46 ; year:2015 ; number:16 ; pages:2070-9 |
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| DOI / URN: |
10.1080/00103624.2015.1069312 |
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| 520 | |a Analysis of differential pore-volume distribution (PVD) patterns of commercial clinoptilolite fractions [(<125 µ (Z8; fine), 125-250 µ (Z9; medium), and >250 µ (Z10; coarse)] has been conducted experimentally using an analyzer to measure the nitrogen (N 2 ) adsorption isotherms. The differential PVDs of the clinoptilolite fractions were calculated from the hysteresis loop according to the adsorption and desorption curves of the Barret, Joyner, and Halenda (BJH) model. The adsorption and desorption cycles of BJH produced heterogeneous as well as dissimilar differential PVD patterns with assorted peaks. While the adsorption curve has prolonged up to 300 nm, the desorption cycle was confined up to 190-nm pore diameter only. In the adsorption cycle, all the clinoptilolite fractions displayed U-shaped curves and had a differential pore volume in the range of 3 × 10 -3 to 8 × 10 -3 cm 3 /g A° in the micropore region with a sole peak at 1.75 nm for the fine fraction (Z8). In contrast, the curves were linear in the mesoporous region for all the fractions, with the fine fraction (Z8) having the greatest differential pore volume, whereas the other two fractions were almost parallel to each other. The desorption cycle has revealed an inverted V-shape curve with no definite patterns for the microporous region. Although the adsorption cycle could ascertain the micropore region, the desorption cycle was unable to do so. It was apparent from the differential PVD of the BJH model that fraction size has a major role in determining the textural properties of clinoptilolite fractions. | ||
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10.1080/00103624.2015.1069312 doi PQ20160617 (DE-627)OLC1964744857 (DE-599)GBVOLC1964744857 (PRQ)c2426-e8a9c94637f817217ce96461ac5a8e3f4c5afecaf7fd9a5ac1639a26450f1c680 (KEY)0035479120150000046001602070doesparticlesizeofclinoptilolitezeolitehavearolein DE-627 ger DE-627 rakwb eng 580 630 640 DNB BIODIV fid 38.60 bkl 48.32 bkl Ramesh, K verfasserin aut Does Particle Size of Clinoptilolite Zeolite Have a Role in Textural Properties? Insight through Differential Pore-Volume Distribution of Barret, Joyner, and Halenda Model 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Analysis of differential pore-volume distribution (PVD) patterns of commercial clinoptilolite fractions [(<125 µ (Z8; fine), 125-250 µ (Z9; medium), and >250 µ (Z10; coarse)] has been conducted experimentally using an analyzer to measure the nitrogen (N 2 ) adsorption isotherms. The differential PVDs of the clinoptilolite fractions were calculated from the hysteresis loop according to the adsorption and desorption curves of the Barret, Joyner, and Halenda (BJH) model. The adsorption and desorption cycles of BJH produced heterogeneous as well as dissimilar differential PVD patterns with assorted peaks. While the adsorption curve has prolonged up to 300 nm, the desorption cycle was confined up to 190-nm pore diameter only. In the adsorption cycle, all the clinoptilolite fractions displayed U-shaped curves and had a differential pore volume in the range of 3 × 10 -3 to 8 × 10 -3 cm 3 /g A° in the micropore region with a sole peak at 1.75 nm for the fine fraction (Z8). In contrast, the curves were linear in the mesoporous region for all the fractions, with the fine fraction (Z8) having the greatest differential pore volume, whereas the other two fractions were almost parallel to each other. The desorption cycle has revealed an inverted V-shape curve with no definite patterns for the microporous region. Although the adsorption cycle could ascertain the micropore region, the desorption cycle was unable to do so. It was apparent from the differential PVD of the BJH model that fraction size has a major role in determining the textural properties of clinoptilolite fractions. Nutzungsrecht: Copyright © Taylor & Francis Group, LLC Adsorption micropores desorption texture mesopores Reddy, K. Sammi oth Rashmi, I oth Biswas, A. K oth Islam, K. R oth Enthalten in Communications in soil science and plant analysis Philadelphia, Pa. : Taylor & Francis, 1970 46(2015), 16, Seite 2070-9 (DE-627)130015334 (DE-600)419718-5 (DE-576)015559149 0010-3624 nnns volume:46 year:2015 number:16 pages:2070-9 http://dx.doi.org/10.1080/00103624.2015.1069312 Volltext http://www.tandfonline.com/doi/abs/10.1080/00103624.2015.1069312 http://search.proquest.com/docview/1707097870 GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-GEO SSG-OLC-FOR SSG-OPC-GGO SSG-OPC-FOR GBV_ILN_70 GBV_ILN_4082 GBV_ILN_4219 38.60 AVZ 48.32 AVZ AR 46 2015 16 2070-9 |
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10.1080/00103624.2015.1069312 doi PQ20160617 (DE-627)OLC1964744857 (DE-599)GBVOLC1964744857 (PRQ)c2426-e8a9c94637f817217ce96461ac5a8e3f4c5afecaf7fd9a5ac1639a26450f1c680 (KEY)0035479120150000046001602070doesparticlesizeofclinoptilolitezeolitehavearolein DE-627 ger DE-627 rakwb eng 580 630 640 DNB BIODIV fid 38.60 bkl 48.32 bkl Ramesh, K verfasserin aut Does Particle Size of Clinoptilolite Zeolite Have a Role in Textural Properties? Insight through Differential Pore-Volume Distribution of Barret, Joyner, and Halenda Model 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Analysis of differential pore-volume distribution (PVD) patterns of commercial clinoptilolite fractions [(<125 µ (Z8; fine), 125-250 µ (Z9; medium), and >250 µ (Z10; coarse)] has been conducted experimentally using an analyzer to measure the nitrogen (N 2 ) adsorption isotherms. The differential PVDs of the clinoptilolite fractions were calculated from the hysteresis loop according to the adsorption and desorption curves of the Barret, Joyner, and Halenda (BJH) model. The adsorption and desorption cycles of BJH produced heterogeneous as well as dissimilar differential PVD patterns with assorted peaks. While the adsorption curve has prolonged up to 300 nm, the desorption cycle was confined up to 190-nm pore diameter only. In the adsorption cycle, all the clinoptilolite fractions displayed U-shaped curves and had a differential pore volume in the range of 3 × 10 -3 to 8 × 10 -3 cm 3 /g A° in the micropore region with a sole peak at 1.75 nm for the fine fraction (Z8). In contrast, the curves were linear in the mesoporous region for all the fractions, with the fine fraction (Z8) having the greatest differential pore volume, whereas the other two fractions were almost parallel to each other. The desorption cycle has revealed an inverted V-shape curve with no definite patterns for the microporous region. Although the adsorption cycle could ascertain the micropore region, the desorption cycle was unable to do so. It was apparent from the differential PVD of the BJH model that fraction size has a major role in determining the textural properties of clinoptilolite fractions. Nutzungsrecht: Copyright © Taylor & Francis Group, LLC Adsorption micropores desorption texture mesopores Reddy, K. Sammi oth Rashmi, I oth Biswas, A. K oth Islam, K. R oth Enthalten in Communications in soil science and plant analysis Philadelphia, Pa. : Taylor & Francis, 1970 46(2015), 16, Seite 2070-9 (DE-627)130015334 (DE-600)419718-5 (DE-576)015559149 0010-3624 nnns volume:46 year:2015 number:16 pages:2070-9 http://dx.doi.org/10.1080/00103624.2015.1069312 Volltext http://www.tandfonline.com/doi/abs/10.1080/00103624.2015.1069312 http://search.proquest.com/docview/1707097870 GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-GEO SSG-OLC-FOR SSG-OPC-GGO SSG-OPC-FOR GBV_ILN_70 GBV_ILN_4082 GBV_ILN_4219 38.60 AVZ 48.32 AVZ AR 46 2015 16 2070-9 |
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10.1080/00103624.2015.1069312 doi PQ20160617 (DE-627)OLC1964744857 (DE-599)GBVOLC1964744857 (PRQ)c2426-e8a9c94637f817217ce96461ac5a8e3f4c5afecaf7fd9a5ac1639a26450f1c680 (KEY)0035479120150000046001602070doesparticlesizeofclinoptilolitezeolitehavearolein DE-627 ger DE-627 rakwb eng 580 630 640 DNB BIODIV fid 38.60 bkl 48.32 bkl Ramesh, K verfasserin aut Does Particle Size of Clinoptilolite Zeolite Have a Role in Textural Properties? Insight through Differential Pore-Volume Distribution of Barret, Joyner, and Halenda Model 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Analysis of differential pore-volume distribution (PVD) patterns of commercial clinoptilolite fractions [(<125 µ (Z8; fine), 125-250 µ (Z9; medium), and >250 µ (Z10; coarse)] has been conducted experimentally using an analyzer to measure the nitrogen (N 2 ) adsorption isotherms. The differential PVDs of the clinoptilolite fractions were calculated from the hysteresis loop according to the adsorption and desorption curves of the Barret, Joyner, and Halenda (BJH) model. The adsorption and desorption cycles of BJH produced heterogeneous as well as dissimilar differential PVD patterns with assorted peaks. While the adsorption curve has prolonged up to 300 nm, the desorption cycle was confined up to 190-nm pore diameter only. In the adsorption cycle, all the clinoptilolite fractions displayed U-shaped curves and had a differential pore volume in the range of 3 × 10 -3 to 8 × 10 -3 cm 3 /g A° in the micropore region with a sole peak at 1.75 nm for the fine fraction (Z8). In contrast, the curves were linear in the mesoporous region for all the fractions, with the fine fraction (Z8) having the greatest differential pore volume, whereas the other two fractions were almost parallel to each other. The desorption cycle has revealed an inverted V-shape curve with no definite patterns for the microporous region. Although the adsorption cycle could ascertain the micropore region, the desorption cycle was unable to do so. It was apparent from the differential PVD of the BJH model that fraction size has a major role in determining the textural properties of clinoptilolite fractions. Nutzungsrecht: Copyright © Taylor & Francis Group, LLC Adsorption micropores desorption texture mesopores Reddy, K. Sammi oth Rashmi, I oth Biswas, A. K oth Islam, K. R oth Enthalten in Communications in soil science and plant analysis Philadelphia, Pa. : Taylor & Francis, 1970 46(2015), 16, Seite 2070-9 (DE-627)130015334 (DE-600)419718-5 (DE-576)015559149 0010-3624 nnns volume:46 year:2015 number:16 pages:2070-9 http://dx.doi.org/10.1080/00103624.2015.1069312 Volltext http://www.tandfonline.com/doi/abs/10.1080/00103624.2015.1069312 http://search.proquest.com/docview/1707097870 GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-GEO SSG-OLC-FOR SSG-OPC-GGO SSG-OPC-FOR GBV_ILN_70 GBV_ILN_4082 GBV_ILN_4219 38.60 AVZ 48.32 AVZ AR 46 2015 16 2070-9 |
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10.1080/00103624.2015.1069312 doi PQ20160617 (DE-627)OLC1964744857 (DE-599)GBVOLC1964744857 (PRQ)c2426-e8a9c94637f817217ce96461ac5a8e3f4c5afecaf7fd9a5ac1639a26450f1c680 (KEY)0035479120150000046001602070doesparticlesizeofclinoptilolitezeolitehavearolein DE-627 ger DE-627 rakwb eng 580 630 640 DNB BIODIV fid 38.60 bkl 48.32 bkl Ramesh, K verfasserin aut Does Particle Size of Clinoptilolite Zeolite Have a Role in Textural Properties? Insight through Differential Pore-Volume Distribution of Barret, Joyner, and Halenda Model 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Analysis of differential pore-volume distribution (PVD) patterns of commercial clinoptilolite fractions [(<125 µ (Z8; fine), 125-250 µ (Z9; medium), and >250 µ (Z10; coarse)] has been conducted experimentally using an analyzer to measure the nitrogen (N 2 ) adsorption isotherms. The differential PVDs of the clinoptilolite fractions were calculated from the hysteresis loop according to the adsorption and desorption curves of the Barret, Joyner, and Halenda (BJH) model. The adsorption and desorption cycles of BJH produced heterogeneous as well as dissimilar differential PVD patterns with assorted peaks. While the adsorption curve has prolonged up to 300 nm, the desorption cycle was confined up to 190-nm pore diameter only. In the adsorption cycle, all the clinoptilolite fractions displayed U-shaped curves and had a differential pore volume in the range of 3 × 10 -3 to 8 × 10 -3 cm 3 /g A° in the micropore region with a sole peak at 1.75 nm for the fine fraction (Z8). In contrast, the curves were linear in the mesoporous region for all the fractions, with the fine fraction (Z8) having the greatest differential pore volume, whereas the other two fractions were almost parallel to each other. The desorption cycle has revealed an inverted V-shape curve with no definite patterns for the microporous region. Although the adsorption cycle could ascertain the micropore region, the desorption cycle was unable to do so. It was apparent from the differential PVD of the BJH model that fraction size has a major role in determining the textural properties of clinoptilolite fractions. Nutzungsrecht: Copyright © Taylor & Francis Group, LLC Adsorption micropores desorption texture mesopores Reddy, K. Sammi oth Rashmi, I oth Biswas, A. K oth Islam, K. R oth Enthalten in Communications in soil science and plant analysis Philadelphia, Pa. : Taylor & Francis, 1970 46(2015), 16, Seite 2070-9 (DE-627)130015334 (DE-600)419718-5 (DE-576)015559149 0010-3624 nnns volume:46 year:2015 number:16 pages:2070-9 http://dx.doi.org/10.1080/00103624.2015.1069312 Volltext http://www.tandfonline.com/doi/abs/10.1080/00103624.2015.1069312 http://search.proquest.com/docview/1707097870 GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-GEO SSG-OLC-FOR SSG-OPC-GGO SSG-OPC-FOR GBV_ILN_70 GBV_ILN_4082 GBV_ILN_4219 38.60 AVZ 48.32 AVZ AR 46 2015 16 2070-9 |
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does particle size of clinoptilolite zeolite have a role in textural properties? insight through differential pore-volume distribution of barret, joyner, and halenda model |
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Does Particle Size of Clinoptilolite Zeolite Have a Role in Textural Properties? Insight through Differential Pore-Volume Distribution of Barret, Joyner, and Halenda Model |
| abstract |
Analysis of differential pore-volume distribution (PVD) patterns of commercial clinoptilolite fractions [(<125 µ (Z8; fine), 125-250 µ (Z9; medium), and >250 µ (Z10; coarse)] has been conducted experimentally using an analyzer to measure the nitrogen (N 2 ) adsorption isotherms. The differential PVDs of the clinoptilolite fractions were calculated from the hysteresis loop according to the adsorption and desorption curves of the Barret, Joyner, and Halenda (BJH) model. The adsorption and desorption cycles of BJH produced heterogeneous as well as dissimilar differential PVD patterns with assorted peaks. While the adsorption curve has prolonged up to 300 nm, the desorption cycle was confined up to 190-nm pore diameter only. In the adsorption cycle, all the clinoptilolite fractions displayed U-shaped curves and had a differential pore volume in the range of 3 × 10 -3 to 8 × 10 -3 cm 3 /g A° in the micropore region with a sole peak at 1.75 nm for the fine fraction (Z8). In contrast, the curves were linear in the mesoporous region for all the fractions, with the fine fraction (Z8) having the greatest differential pore volume, whereas the other two fractions were almost parallel to each other. The desorption cycle has revealed an inverted V-shape curve with no definite patterns for the microporous region. Although the adsorption cycle could ascertain the micropore region, the desorption cycle was unable to do so. It was apparent from the differential PVD of the BJH model that fraction size has a major role in determining the textural properties of clinoptilolite fractions. |
| abstractGer |
Analysis of differential pore-volume distribution (PVD) patterns of commercial clinoptilolite fractions [(<125 µ (Z8; fine), 125-250 µ (Z9; medium), and >250 µ (Z10; coarse)] has been conducted experimentally using an analyzer to measure the nitrogen (N 2 ) adsorption isotherms. The differential PVDs of the clinoptilolite fractions were calculated from the hysteresis loop according to the adsorption and desorption curves of the Barret, Joyner, and Halenda (BJH) model. The adsorption and desorption cycles of BJH produced heterogeneous as well as dissimilar differential PVD patterns with assorted peaks. While the adsorption curve has prolonged up to 300 nm, the desorption cycle was confined up to 190-nm pore diameter only. In the adsorption cycle, all the clinoptilolite fractions displayed U-shaped curves and had a differential pore volume in the range of 3 × 10 -3 to 8 × 10 -3 cm 3 /g A° in the micropore region with a sole peak at 1.75 nm for the fine fraction (Z8). In contrast, the curves were linear in the mesoporous region for all the fractions, with the fine fraction (Z8) having the greatest differential pore volume, whereas the other two fractions were almost parallel to each other. The desorption cycle has revealed an inverted V-shape curve with no definite patterns for the microporous region. Although the adsorption cycle could ascertain the micropore region, the desorption cycle was unable to do so. It was apparent from the differential PVD of the BJH model that fraction size has a major role in determining the textural properties of clinoptilolite fractions. |
| abstract_unstemmed |
Analysis of differential pore-volume distribution (PVD) patterns of commercial clinoptilolite fractions [(<125 µ (Z8; fine), 125-250 µ (Z9; medium), and >250 µ (Z10; coarse)] has been conducted experimentally using an analyzer to measure the nitrogen (N 2 ) adsorption isotherms. The differential PVDs of the clinoptilolite fractions were calculated from the hysteresis loop according to the adsorption and desorption curves of the Barret, Joyner, and Halenda (BJH) model. The adsorption and desorption cycles of BJH produced heterogeneous as well as dissimilar differential PVD patterns with assorted peaks. While the adsorption curve has prolonged up to 300 nm, the desorption cycle was confined up to 190-nm pore diameter only. In the adsorption cycle, all the clinoptilolite fractions displayed U-shaped curves and had a differential pore volume in the range of 3 × 10 -3 to 8 × 10 -3 cm 3 /g A° in the micropore region with a sole peak at 1.75 nm for the fine fraction (Z8). In contrast, the curves were linear in the mesoporous region for all the fractions, with the fine fraction (Z8) having the greatest differential pore volume, whereas the other two fractions were almost parallel to each other. The desorption cycle has revealed an inverted V-shape curve with no definite patterns for the microporous region. Although the adsorption cycle could ascertain the micropore region, the desorption cycle was unable to do so. It was apparent from the differential PVD of the BJH model that fraction size has a major role in determining the textural properties of clinoptilolite fractions. |
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Does Particle Size of Clinoptilolite Zeolite Have a Role in Textural Properties? Insight through Differential Pore-Volume Distribution of Barret, Joyner, and Halenda Model |
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