Physiochemical Characterization of Iodine(V) Oxide, Part 1: Hydration Rates

In the first of a series of papers on the iodine(V) oxide system, the chemical and physical properties associated with iodine(V) oxide in its anhydride (I 2 O 5 ) and hydrated states (HI 3 O 8 and HIO 3 ) are examined. The three forms of the oxide have been investigated utilizing differential scanni...
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Autor*in:	Little, Brian K [verfasserIn] Emery, Samuel B Nittinger, Joshua C Fantasia, Ryan C Lindsay, C. Michael

Format:	Artikel
Sprache:	Englisch

Erschienen:	2015

Rechteinformationen:	Nutzungsrecht: © 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim

Schlagwörter:	Iodine(V) oxide Iodine pentoxide Energetic material Hydration rate HIO Triperiodic acid Iodic acid Oxidizer Hydrogen iodate X rays Hydration Iodine

Übergeordnetes Werk:	Enthalten in: Propellants, explosives, pyrotechnics - Weinheim : Wiley-VCH, 1982, 40(2015), 4, Seite 595-603
Übergeordnetes Werk:	volume:40 ; year:2015 ; number:4 ; pages:595-603

Links:	Volltext Link aufrufen Link aufrufen

DOI / URN:	10.1002/prep.201400225

Katalog-ID:	OLC1965351719

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520			\|a In the first of a series of papers on the iodine(V) oxide system, the chemical and physical properties associated with iodine(V) oxide in its anhydride (I 2 O 5 ) and hydrated states (HI 3 O 8 and HIO 3 ) are examined. The three forms of the oxide have been investigated utilizing differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and powder X‐ray diffraction (PXRD). Furthermore, the hydration rates governing the conversion of the anhydride (I 2 O 5 ) to the initial hydrate (HI 3 O 8 ) and later to the final hydrated state (HIO 3 ) are reported and discussed. Results from this study suggest that the hydration mechanism for I 2 O 5 →HI 3 O 8 begins with an accelerating period described as a nucleation and growth phase followed by a decelerating period that is diffusion limited. The initial rate of hydration was observed to be governed by a nucleation and growth mechanism, which was inhibited by covering the surface of the particle with an inert metal. Based on this investigation the initial rate of hydration appears to be strongly dependent on the anhydride’s available surface area which facilitates nucleation and growth of HI 3 O 8 . The final step, HI 3 O 8 →HIO 3 , proceeds through an initial induction period followed by a continuous acceleratory period unlike the first hydration step.
540			\|a Nutzungsrecht: © 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim
650		4	\|a Iodine(V) oxide
650		4	\|a Iodine pentoxide
650		4	\|a Energetic material
650		4	\|a Hydration rate
650		4	\|a HIO
650		4	\|a Triperiodic acid
650		4	\|a Iodic acid
650		4	\|a Oxidizer
650		4	\|a Hydrogen iodate
650		4	\|a X rays
650		4	\|a Hydration
650		4	\|a Iodine
700	1		\|a Emery, Samuel B \|4 oth
700	1		\|a Nittinger, Joshua C \|4 oth
700	1		\|a Fantasia, Ryan C \|4 oth
700	1		\|a Lindsay, C. Michael \|4 oth
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allfields	10.1002/prep.201400225 doi PQ20160617 (DE-627)OLC1965351719 (DE-599)GBVOLC1965351719 (PRQ)c2295-a25875887d96061ea83464a77b3a3a66759c1e701c0b5ef1fdf4dc5054464e7d3 (KEY)0043344620150000040000400595physiochemicalcharacterizationofiodinevoxidepart1h DE-627 ger DE-627 rakwb eng 42 660 670 760 770 DNB 660 AVZ Little, Brian K verfasserin aut Physiochemical Characterization of Iodine(V) Oxide, Part 1: Hydration Rates 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier In the first of a series of papers on the iodine(V) oxide system, the chemical and physical properties associated with iodine(V) oxide in its anhydride (I 2 O 5 ) and hydrated states (HI 3 O 8 and HIO 3 ) are examined. The three forms of the oxide have been investigated utilizing differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and powder X‐ray diffraction (PXRD). Furthermore, the hydration rates governing the conversion of the anhydride (I 2 O 5 ) to the initial hydrate (HI 3 O 8 ) and later to the final hydrated state (HIO 3 ) are reported and discussed. Results from this study suggest that the hydration mechanism for I 2 O 5 →HI 3 O 8 begins with an accelerating period described as a nucleation and growth phase followed by a decelerating period that is diffusion limited. The initial rate of hydration was observed to be governed by a nucleation and growth mechanism, which was inhibited by covering the surface of the particle with an inert metal. Based on this investigation the initial rate of hydration appears to be strongly dependent on the anhydride’s available surface area which facilitates nucleation and growth of HI 3 O 8 . The final step, HI 3 O 8 →HIO 3 , proceeds through an initial induction period followed by a continuous acceleratory period unlike the first hydration step. Nutzungsrecht: © 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim Iodine(V) oxide Iodine pentoxide Energetic material Hydration rate HIO Triperiodic acid Iodic acid Oxidizer Hydrogen iodate X rays Hydration Iodine Emery, Samuel B oth Nittinger, Joshua C oth Fantasia, Ryan C oth Lindsay, C. Michael oth Enthalten in Propellants, explosives, pyrotechnics Weinheim : Wiley-VCH, 1982 40(2015), 4, Seite 595-603 (DE-627)129619957 (DE-600)245919-X (DE-576)015125769 0721-3115 nnns volume:40 year:2015 number:4 pages:595-603 http://dx.doi.org/10.1002/prep.201400225 Volltext http://onlinelibrary.wiley.com/doi/10.1002/prep.201400225/abstract http://search.proquest.com/docview/1702048493 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 AR 40 2015 4 595-603
spelling	10.1002/prep.201400225 doi PQ20160617 (DE-627)OLC1965351719 (DE-599)GBVOLC1965351719 (PRQ)c2295-a25875887d96061ea83464a77b3a3a66759c1e701c0b5ef1fdf4dc5054464e7d3 (KEY)0043344620150000040000400595physiochemicalcharacterizationofiodinevoxidepart1h DE-627 ger DE-627 rakwb eng 42 660 670 760 770 DNB 660 AVZ Little, Brian K verfasserin aut Physiochemical Characterization of Iodine(V) Oxide, Part 1: Hydration Rates 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier In the first of a series of papers on the iodine(V) oxide system, the chemical and physical properties associated with iodine(V) oxide in its anhydride (I 2 O 5 ) and hydrated states (HI 3 O 8 and HIO 3 ) are examined. The three forms of the oxide have been investigated utilizing differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and powder X‐ray diffraction (PXRD). Furthermore, the hydration rates governing the conversion of the anhydride (I 2 O 5 ) to the initial hydrate (HI 3 O 8 ) and later to the final hydrated state (HIO 3 ) are reported and discussed. Results from this study suggest that the hydration mechanism for I 2 O 5 →HI 3 O 8 begins with an accelerating period described as a nucleation and growth phase followed by a decelerating period that is diffusion limited. The initial rate of hydration was observed to be governed by a nucleation and growth mechanism, which was inhibited by covering the surface of the particle with an inert metal. Based on this investigation the initial rate of hydration appears to be strongly dependent on the anhydride’s available surface area which facilitates nucleation and growth of HI 3 O 8 . The final step, HI 3 O 8 →HIO 3 , proceeds through an initial induction period followed by a continuous acceleratory period unlike the first hydration step. Nutzungsrecht: © 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim Iodine(V) oxide Iodine pentoxide Energetic material Hydration rate HIO Triperiodic acid Iodic acid Oxidizer Hydrogen iodate X rays Hydration Iodine Emery, Samuel B oth Nittinger, Joshua C oth Fantasia, Ryan C oth Lindsay, C. Michael oth Enthalten in Propellants, explosives, pyrotechnics Weinheim : Wiley-VCH, 1982 40(2015), 4, Seite 595-603 (DE-627)129619957 (DE-600)245919-X (DE-576)015125769 0721-3115 nnns volume:40 year:2015 number:4 pages:595-603 http://dx.doi.org/10.1002/prep.201400225 Volltext http://onlinelibrary.wiley.com/doi/10.1002/prep.201400225/abstract http://search.proquest.com/docview/1702048493 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 AR 40 2015 4 595-603
allfields_unstemmed	10.1002/prep.201400225 doi PQ20160617 (DE-627)OLC1965351719 (DE-599)GBVOLC1965351719 (PRQ)c2295-a25875887d96061ea83464a77b3a3a66759c1e701c0b5ef1fdf4dc5054464e7d3 (KEY)0043344620150000040000400595physiochemicalcharacterizationofiodinevoxidepart1h DE-627 ger DE-627 rakwb eng 42 660 670 760 770 DNB 660 AVZ Little, Brian K verfasserin aut Physiochemical Characterization of Iodine(V) Oxide, Part 1: Hydration Rates 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier In the first of a series of papers on the iodine(V) oxide system, the chemical and physical properties associated with iodine(V) oxide in its anhydride (I 2 O 5 ) and hydrated states (HI 3 O 8 and HIO 3 ) are examined. The three forms of the oxide have been investigated utilizing differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and powder X‐ray diffraction (PXRD). Furthermore, the hydration rates governing the conversion of the anhydride (I 2 O 5 ) to the initial hydrate (HI 3 O 8 ) and later to the final hydrated state (HIO 3 ) are reported and discussed. Results from this study suggest that the hydration mechanism for I 2 O 5 →HI 3 O 8 begins with an accelerating period described as a nucleation and growth phase followed by a decelerating period that is diffusion limited. The initial rate of hydration was observed to be governed by a nucleation and growth mechanism, which was inhibited by covering the surface of the particle with an inert metal. Based on this investigation the initial rate of hydration appears to be strongly dependent on the anhydride’s available surface area which facilitates nucleation and growth of HI 3 O 8 . The final step, HI 3 O 8 →HIO 3 , proceeds through an initial induction period followed by a continuous acceleratory period unlike the first hydration step. Nutzungsrecht: © 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim Iodine(V) oxide Iodine pentoxide Energetic material Hydration rate HIO Triperiodic acid Iodic acid Oxidizer Hydrogen iodate X rays Hydration Iodine Emery, Samuel B oth Nittinger, Joshua C oth Fantasia, Ryan C oth Lindsay, C. Michael oth Enthalten in Propellants, explosives, pyrotechnics Weinheim : Wiley-VCH, 1982 40(2015), 4, Seite 595-603 (DE-627)129619957 (DE-600)245919-X (DE-576)015125769 0721-3115 nnns volume:40 year:2015 number:4 pages:595-603 http://dx.doi.org/10.1002/prep.201400225 Volltext http://onlinelibrary.wiley.com/doi/10.1002/prep.201400225/abstract http://search.proquest.com/docview/1702048493 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 AR 40 2015 4 595-603
allfieldsGer	10.1002/prep.201400225 doi PQ20160617 (DE-627)OLC1965351719 (DE-599)GBVOLC1965351719 (PRQ)c2295-a25875887d96061ea83464a77b3a3a66759c1e701c0b5ef1fdf4dc5054464e7d3 (KEY)0043344620150000040000400595physiochemicalcharacterizationofiodinevoxidepart1h DE-627 ger DE-627 rakwb eng 42 660 670 760 770 DNB 660 AVZ Little, Brian K verfasserin aut Physiochemical Characterization of Iodine(V) Oxide, Part 1: Hydration Rates 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier In the first of a series of papers on the iodine(V) oxide system, the chemical and physical properties associated with iodine(V) oxide in its anhydride (I 2 O 5 ) and hydrated states (HI 3 O 8 and HIO 3 ) are examined. The three forms of the oxide have been investigated utilizing differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and powder X‐ray diffraction (PXRD). Furthermore, the hydration rates governing the conversion of the anhydride (I 2 O 5 ) to the initial hydrate (HI 3 O 8 ) and later to the final hydrated state (HIO 3 ) are reported and discussed. Results from this study suggest that the hydration mechanism for I 2 O 5 →HI 3 O 8 begins with an accelerating period described as a nucleation and growth phase followed by a decelerating period that is diffusion limited. The initial rate of hydration was observed to be governed by a nucleation and growth mechanism, which was inhibited by covering the surface of the particle with an inert metal. Based on this investigation the initial rate of hydration appears to be strongly dependent on the anhydride’s available surface area which facilitates nucleation and growth of HI 3 O 8 . The final step, HI 3 O 8 →HIO 3 , proceeds through an initial induction period followed by a continuous acceleratory period unlike the first hydration step. Nutzungsrecht: © 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim Iodine(V) oxide Iodine pentoxide Energetic material Hydration rate HIO Triperiodic acid Iodic acid Oxidizer Hydrogen iodate X rays Hydration Iodine Emery, Samuel B oth Nittinger, Joshua C oth Fantasia, Ryan C oth Lindsay, C. Michael oth Enthalten in Propellants, explosives, pyrotechnics Weinheim : Wiley-VCH, 1982 40(2015), 4, Seite 595-603 (DE-627)129619957 (DE-600)245919-X (DE-576)015125769 0721-3115 nnns volume:40 year:2015 number:4 pages:595-603 http://dx.doi.org/10.1002/prep.201400225 Volltext http://onlinelibrary.wiley.com/doi/10.1002/prep.201400225/abstract http://search.proquest.com/docview/1702048493 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 AR 40 2015 4 595-603
allfieldsSound	10.1002/prep.201400225 doi PQ20160617 (DE-627)OLC1965351719 (DE-599)GBVOLC1965351719 (PRQ)c2295-a25875887d96061ea83464a77b3a3a66759c1e701c0b5ef1fdf4dc5054464e7d3 (KEY)0043344620150000040000400595physiochemicalcharacterizationofiodinevoxidepart1h DE-627 ger DE-627 rakwb eng 42 660 670 760 770 DNB 660 AVZ Little, Brian K verfasserin aut Physiochemical Characterization of Iodine(V) Oxide, Part 1: Hydration Rates 2015 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier In the first of a series of papers on the iodine(V) oxide system, the chemical and physical properties associated with iodine(V) oxide in its anhydride (I 2 O 5 ) and hydrated states (HI 3 O 8 and HIO 3 ) are examined. The three forms of the oxide have been investigated utilizing differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and powder X‐ray diffraction (PXRD). Furthermore, the hydration rates governing the conversion of the anhydride (I 2 O 5 ) to the initial hydrate (HI 3 O 8 ) and later to the final hydrated state (HIO 3 ) are reported and discussed. Results from this study suggest that the hydration mechanism for I 2 O 5 →HI 3 O 8 begins with an accelerating period described as a nucleation and growth phase followed by a decelerating period that is diffusion limited. The initial rate of hydration was observed to be governed by a nucleation and growth mechanism, which was inhibited by covering the surface of the particle with an inert metal. Based on this investigation the initial rate of hydration appears to be strongly dependent on the anhydride’s available surface area which facilitates nucleation and growth of HI 3 O 8 . The final step, HI 3 O 8 →HIO 3 , proceeds through an initial induction period followed by a continuous acceleratory period unlike the first hydration step. Nutzungsrecht: © 2015 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim Iodine(V) oxide Iodine pentoxide Energetic material Hydration rate HIO Triperiodic acid Iodic acid Oxidizer Hydrogen iodate X rays Hydration Iodine Emery, Samuel B oth Nittinger, Joshua C oth Fantasia, Ryan C oth Lindsay, C. Michael oth Enthalten in Propellants, explosives, pyrotechnics Weinheim : Wiley-VCH, 1982 40(2015), 4, Seite 595-603 (DE-627)129619957 (DE-600)245919-X (DE-576)015125769 0721-3115 nnns volume:40 year:2015 number:4 pages:595-603 http://dx.doi.org/10.1002/prep.201400225 Volltext http://onlinelibrary.wiley.com/doi/10.1002/prep.201400225/abstract http://search.proquest.com/docview/1702048493 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 AR 40 2015 4 595-603
language	English
source	Enthalten in Propellants, explosives, pyrotechnics 40(2015), 4, Seite 595-603 volume:40 year:2015 number:4 pages:595-603
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topic_facet	Iodine(V) oxide Iodine pentoxide Energetic material Hydration rate HIO Triperiodic acid Iodic acid Oxidizer Hydrogen iodate X rays Hydration Iodine
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author	Little, Brian K
spellingShingle	Little, Brian K ddc 42 ddc 660 misc Iodine(V) oxide misc Iodine pentoxide misc Energetic material misc Hydration rate misc HIO misc Triperiodic acid misc Iodic acid misc Oxidizer misc Hydrogen iodate misc X rays misc Hydration misc Iodine Physiochemical Characterization of Iodine(V) Oxide, Part 1: Hydration Rates
authorStr	Little, Brian K
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topic_title	42 660 670 760 770 DNB 660 AVZ Physiochemical Characterization of Iodine(V) Oxide, Part 1: Hydration Rates Iodine(V) oxide Iodine pentoxide Energetic material Hydration rate HIO Triperiodic acid Iodic acid Oxidizer Hydrogen iodate X rays Hydration Iodine
topic	ddc 42 ddc 660 misc Iodine(V) oxide misc Iodine pentoxide misc Energetic material misc Hydration rate misc HIO misc Triperiodic acid misc Iodic acid misc Oxidizer misc Hydrogen iodate misc X rays misc Hydration misc Iodine
topic_unstemmed	ddc 42 ddc 660 misc Iodine(V) oxide misc Iodine pentoxide misc Energetic material misc Hydration rate misc HIO misc Triperiodic acid misc Iodic acid misc Oxidizer misc Hydrogen iodate misc X rays misc Hydration misc Iodine
topic_browse	ddc 42 ddc 660 misc Iodine(V) oxide misc Iodine pentoxide misc Energetic material misc Hydration rate misc HIO misc Triperiodic acid misc Iodic acid misc Oxidizer misc Hydrogen iodate misc X rays misc Hydration misc Iodine
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title	Physiochemical Characterization of Iodine(V) Oxide, Part 1: Hydration Rates
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title_full	Physiochemical Characterization of Iodine(V) Oxide, Part 1: Hydration Rates
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title_sort	physiochemical characterization of iodine(v) oxide, part 1: hydration rates
title_auth	Physiochemical Characterization of Iodine(V) Oxide, Part 1: Hydration Rates
abstract	In the first of a series of papers on the iodine(V) oxide system, the chemical and physical properties associated with iodine(V) oxide in its anhydride (I 2 O 5 ) and hydrated states (HI 3 O 8 and HIO 3 ) are examined. The three forms of the oxide have been investigated utilizing differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and powder X‐ray diffraction (PXRD). Furthermore, the hydration rates governing the conversion of the anhydride (I 2 O 5 ) to the initial hydrate (HI 3 O 8 ) and later to the final hydrated state (HIO 3 ) are reported and discussed. Results from this study suggest that the hydration mechanism for I 2 O 5 →HI 3 O 8 begins with an accelerating period described as a nucleation and growth phase followed by a decelerating period that is diffusion limited. The initial rate of hydration was observed to be governed by a nucleation and growth mechanism, which was inhibited by covering the surface of the particle with an inert metal. Based on this investigation the initial rate of hydration appears to be strongly dependent on the anhydride’s available surface area which facilitates nucleation and growth of HI 3 O 8 . The final step, HI 3 O 8 →HIO 3 , proceeds through an initial induction period followed by a continuous acceleratory period unlike the first hydration step.
abstractGer	In the first of a series of papers on the iodine(V) oxide system, the chemical and physical properties associated with iodine(V) oxide in its anhydride (I 2 O 5 ) and hydrated states (HI 3 O 8 and HIO 3 ) are examined. The three forms of the oxide have been investigated utilizing differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and powder X‐ray diffraction (PXRD). Furthermore, the hydration rates governing the conversion of the anhydride (I 2 O 5 ) to the initial hydrate (HI 3 O 8 ) and later to the final hydrated state (HIO 3 ) are reported and discussed. Results from this study suggest that the hydration mechanism for I 2 O 5 →HI 3 O 8 begins with an accelerating period described as a nucleation and growth phase followed by a decelerating period that is diffusion limited. The initial rate of hydration was observed to be governed by a nucleation and growth mechanism, which was inhibited by covering the surface of the particle with an inert metal. Based on this investigation the initial rate of hydration appears to be strongly dependent on the anhydride’s available surface area which facilitates nucleation and growth of HI 3 O 8 . The final step, HI 3 O 8 →HIO 3 , proceeds through an initial induction period followed by a continuous acceleratory period unlike the first hydration step.
abstract_unstemmed	In the first of a series of papers on the iodine(V) oxide system, the chemical and physical properties associated with iodine(V) oxide in its anhydride (I 2 O 5 ) and hydrated states (HI 3 O 8 and HIO 3 ) are examined. The three forms of the oxide have been investigated utilizing differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), and powder X‐ray diffraction (PXRD). Furthermore, the hydration rates governing the conversion of the anhydride (I 2 O 5 ) to the initial hydrate (HI 3 O 8 ) and later to the final hydrated state (HIO 3 ) are reported and discussed. Results from this study suggest that the hydration mechanism for I 2 O 5 →HI 3 O 8 begins with an accelerating period described as a nucleation and growth phase followed by a decelerating period that is diffusion limited. The initial rate of hydration was observed to be governed by a nucleation and growth mechanism, which was inhibited by covering the surface of the particle with an inert metal. Based on this investigation the initial rate of hydration appears to be strongly dependent on the anhydride’s available surface area which facilitates nucleation and growth of HI 3 O 8 . The final step, HI 3 O 8 →HIO 3 , proceeds through an initial induction period followed by a continuous acceleratory period unlike the first hydration step.
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title_short	Physiochemical Characterization of Iodine(V) Oxide, Part 1: Hydration Rates
url	http://dx.doi.org/10.1002/prep.201400225 http://onlinelibrary.wiley.com/doi/10.1002/prep.201400225/abstract http://search.proquest.com/docview/1702048493
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author2	Emery, Samuel B Nittinger, Joshua C Fantasia, Ryan C Lindsay, C. Michael
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up_date	2024-07-03T17:26:41.869Z
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