[2+2] Photo-cycloadditions for polymer modification and surface decoration
Photo-induced reactions play an important role in precision polymer design. Photoreactions are often cost-effective reactions that proceed under relatively mild reaction conditions. Additionally, photo reactions add spatial and temporal control over reactions, which gives rise to a large number of a...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
JUNKERS, Thomas [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2015 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: European polymer journal - Oxford : Elsevier, 1965, (2015) |
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| Übergeordnetes Werk: |
year:2015 |
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| DOI / URN: |
10.1016/j.eurpolymj.2014.08.005 |
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| 520 | |a Photo-induced reactions play an important role in precision polymer design. Photoreactions are often cost-effective reactions that proceed under relatively mild reaction conditions. Additionally, photo reactions add spatial and temporal control over reactions, which gives rise to a large number of applications that would otherwise be inaccessible. Among the various photochemistries available, [2+2] cycloadditions are a prominent example for effective conversions. In the field of polymer chemistry, such reactions are often used for crosslinking. If reaction conditions are chosen carefully, they can, however, also be employed for advanced polymer transformations, such as polymer endgroup modification or specific ligation to substrates. Especially when applying flow chemistry approaches, very high reaction efficiencies are gained, bringing [2+2] cycloadditions close in use to other well known click-like techniques such as thiol-ene chemistry. (C) 2014 Elsevier Ltd. Support from the European Science Foundation - "Precision Polymer Materials (P2M)" program as well as the Belgian Science Policy (Belspo) in the framework of the Interuniversity Attraction Poles Program TAP-PAI P7/05 "Functional Supramolecular Systems" is gratefully acknowledged. photocycloaddition; [2+2]; polymer modification; surface modification; surface patterning | ||
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Photo-induced reactions play an important role in precision polymer design. Photoreactions are often cost-effective reactions that proceed under relatively mild reaction conditions. Additionally, photo reactions add spatial and temporal control over reactions, which gives rise to a large number of applications that would otherwise be inaccessible. Among the various photochemistries available, [2+2] cycloadditions are a prominent example for effective conversions. In the field of polymer chemistry, such reactions are often used for crosslinking. If reaction conditions are chosen carefully, they can, however, also be employed for advanced polymer transformations, such as polymer endgroup modification or specific ligation to substrates. Especially when applying flow chemistry approaches, very high reaction efficiencies are gained, bringing [2+2] cycloadditions close in use to other well known click-like techniques such as thiol-ene chemistry. (C) 2014 Elsevier Ltd. Support from the European Science Foundation - "Precision Polymer Materials (P2M)" program as well as the Belgian Science Policy (Belspo) in the framework of the Interuniversity Attraction Poles Program TAP-PAI P7/05 "Functional Supramolecular Systems" is gratefully acknowledged. photocycloaddition; [2+2]; polymer modification; surface modification; surface patterning |
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Photo-induced reactions play an important role in precision polymer design. Photoreactions are often cost-effective reactions that proceed under relatively mild reaction conditions. Additionally, photo reactions add spatial and temporal control over reactions, which gives rise to a large number of applications that would otherwise be inaccessible. Among the various photochemistries available, [2+2] cycloadditions are a prominent example for effective conversions. In the field of polymer chemistry, such reactions are often used for crosslinking. If reaction conditions are chosen carefully, they can, however, also be employed for advanced polymer transformations, such as polymer endgroup modification or specific ligation to substrates. Especially when applying flow chemistry approaches, very high reaction efficiencies are gained, bringing [2+2] cycloadditions close in use to other well known click-like techniques such as thiol-ene chemistry. (C) 2014 Elsevier Ltd. Support from the European Science Foundation - "Precision Polymer Materials (P2M)" program as well as the Belgian Science Policy (Belspo) in the framework of the Interuniversity Attraction Poles Program TAP-PAI P7/05 "Functional Supramolecular Systems" is gratefully acknowledged. photocycloaddition; [2+2]; polymer modification; surface modification; surface patterning |
| abstract_unstemmed |
Photo-induced reactions play an important role in precision polymer design. Photoreactions are often cost-effective reactions that proceed under relatively mild reaction conditions. Additionally, photo reactions add spatial and temporal control over reactions, which gives rise to a large number of applications that would otherwise be inaccessible. Among the various photochemistries available, [2+2] cycloadditions are a prominent example for effective conversions. In the field of polymer chemistry, such reactions are often used for crosslinking. If reaction conditions are chosen carefully, they can, however, also be employed for advanced polymer transformations, such as polymer endgroup modification or specific ligation to substrates. Especially when applying flow chemistry approaches, very high reaction efficiencies are gained, bringing [2+2] cycloadditions close in use to other well known click-like techniques such as thiol-ene chemistry. (C) 2014 Elsevier Ltd. Support from the European Science Foundation - "Precision Polymer Materials (P2M)" program as well as the Belgian Science Policy (Belspo) in the framework of the Interuniversity Attraction Poles Program TAP-PAI P7/05 "Functional Supramolecular Systems" is gratefully acknowledged. photocycloaddition; [2+2]; polymer modification; surface modification; surface patterning |
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[2+2] Photo-cycloadditions for polymer modification and surface decoration |
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http://dx.doi.org/10.1016/j.eurpolymj.2014.08.005 http://hdl.handle.net/1942/18692 |
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7.399541 |