A novel grafting‐modified waste rubber powder as filler in natural rubber vulcanizates

Polycardanol was synthesized from cardanol, paraformaldehyde, p‐toluenesulfonic acid, phosphoric acid (H 3 PO 4 ), and phosphorus pentoxide (P 2 O 5 ) via a two‐step process. Results indicated that polycardanol is an acid with high molecular weight and can be self‐crosslinked at high temperature. A...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Guo, Weihong [verfasserIn] Liu, Chunling Zhang, Haibin Gong, Zhaohong Yu, Ruobing

Format:	Artikel
Sprache:	Englisch

Erschienen:	2016

Rechteinformationen:	Nutzungsrecht: © 2015 Wiley Periodicals, Inc.

Schlagwörter:	grafting rubber mechanical properties composites

Übergeordnetes Werk:	Enthalten in: Journal of applied polymer science - Hoboken, NJ [u.a.] : Wiley InterScience, 1959, 133(2016), 6
Übergeordnetes Werk:	volume:133 ; year:2016 ; number:6

Links:	Volltext Link aufrufen Link aufrufen

DOI / URN:	10.1002/app.42993

Katalog-ID:	OLC1970993553

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520			\|a Polycardanol was synthesized from cardanol, paraformaldehyde, p‐toluenesulfonic acid, phosphoric acid (H 3 PO 4 ), and phosphorus pentoxide (P 2 O 5 ) via a two‐step process. Results indicated that polycardanol is an acid with high molecular weight and can be self‐crosslinked at high temperature. A modified WRP (MWRP) grafted by long chain can be obtained from the reaction between WRP and polycardanol. The sulfur content of MWRP is 0.27%, which is lower than that of WRP by 0.47%. The oxygen content of MWRP is higher by 13% than that of WRP. The phosphorus content of MWRP reaches 5.25%. The water contact angle of MWRP is 91.5°, whereas that of WRP is 123.7°. The properties of the WRP/NR and MWRP/NR composites were also investigated. MWRP/NR possesses higher tensile strength than WRP/NR because of the enhanced interfacial interaction between MWRP and the NR matrix. Post‐treatment is also conducive for MWRP/NR to improve its tensile strength at high MWRP content. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133 , 42993.
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spelling	10.1002/app.42993 doi PQ20160212 (DE-627)OLC1970993553 (DE-599)GBVOLC1970993553 (PRQ)c2909-2c968db519bb5aa335bf8905908fd30eead92a24e3b79af1fa0628bb373993bb3 (KEY)0117731120160000133000600000novelgraftingmodifiedwasterubberpowderasfillerinna DE-627 ger DE-627 rakwb eng 540 DNB 35.80 bkl 51.70 bkl Guo, Weihong verfasserin aut A novel grafting‐modified waste rubber powder as filler in natural rubber vulcanizates 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Polycardanol was synthesized from cardanol, paraformaldehyde, p‐toluenesulfonic acid, phosphoric acid (H 3 PO 4 ), and phosphorus pentoxide (P 2 O 5 ) via a two‐step process. Results indicated that polycardanol is an acid with high molecular weight and can be self‐crosslinked at high temperature. A modified WRP (MWRP) grafted by long chain can be obtained from the reaction between WRP and polycardanol. The sulfur content of MWRP is 0.27%, which is lower than that of WRP by 0.47%. The oxygen content of MWRP is higher by 13% than that of WRP. The phosphorus content of MWRP reaches 5.25%. The water contact angle of MWRP is 91.5°, whereas that of WRP is 123.7°. The properties of the WRP/NR and MWRP/NR composites were also investigated. MWRP/NR possesses higher tensile strength than WRP/NR because of the enhanced interfacial interaction between MWRP and the NR matrix. Post‐treatment is also conducive for MWRP/NR to improve its tensile strength at high MWRP content. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133 , 42993. Nutzungsrecht: © 2015 Wiley Periodicals, Inc. grafting rubber mechanical properties composites Liu, Chunling oth Zhang, Haibin oth Gong, Zhaohong oth Yu, Ruobing oth Enthalten in Journal of applied polymer science Hoboken, NJ [u.a.] : Wiley InterScience, 1959 133(2016), 6 (DE-627)129595799 (DE-600)240694-9 (DE-576)015088812 0021-8995 nnns volume:133 year:2016 number:6 http://dx.doi.org/10.1002/app.42993 Volltext http://onlinelibrary.wiley.com/doi/10.1002/app.42993/abstract http://search.proquest.com/docview/1734542175 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 35.80 AVZ 51.70 AVZ AR 133 2016 6
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topic	ddc 540 bkl 35.80 bkl 51.70 misc grafting misc rubber misc mechanical properties misc composites
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topic_browse	ddc 540 bkl 35.80 bkl 51.70 misc grafting misc rubber misc mechanical properties misc composites
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title	A novel grafting‐modified waste rubber powder as filler in natural rubber vulcanizates
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title_full	A novel grafting‐modified waste rubber powder as filler in natural rubber vulcanizates
author_sort	Guo, Weihong
journal	Journal of applied polymer science
journalStr	Journal of applied polymer science
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author_browse	Guo, Weihong
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author-letter	Guo, Weihong
doi_str_mv	10.1002/app.42993
dewey-full	540
title_sort	novel grafting‐modified waste rubber powder as filler in natural rubber vulcanizates
title_auth	A novel grafting‐modified waste rubber powder as filler in natural rubber vulcanizates
abstract	Polycardanol was synthesized from cardanol, paraformaldehyde, p‐toluenesulfonic acid, phosphoric acid (H 3 PO 4 ), and phosphorus pentoxide (P 2 O 5 ) via a two‐step process. Results indicated that polycardanol is an acid with high molecular weight and can be self‐crosslinked at high temperature. A modified WRP (MWRP) grafted by long chain can be obtained from the reaction between WRP and polycardanol. The sulfur content of MWRP is 0.27%, which is lower than that of WRP by 0.47%. The oxygen content of MWRP is higher by 13% than that of WRP. The phosphorus content of MWRP reaches 5.25%. The water contact angle of MWRP is 91.5°, whereas that of WRP is 123.7°. The properties of the WRP/NR and MWRP/NR composites were also investigated. MWRP/NR possesses higher tensile strength than WRP/NR because of the enhanced interfacial interaction between MWRP and the NR matrix. Post‐treatment is also conducive for MWRP/NR to improve its tensile strength at high MWRP content. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133 , 42993.
abstractGer	Polycardanol was synthesized from cardanol, paraformaldehyde, p‐toluenesulfonic acid, phosphoric acid (H 3 PO 4 ), and phosphorus pentoxide (P 2 O 5 ) via a two‐step process. Results indicated that polycardanol is an acid with high molecular weight and can be self‐crosslinked at high temperature. A modified WRP (MWRP) grafted by long chain can be obtained from the reaction between WRP and polycardanol. The sulfur content of MWRP is 0.27%, which is lower than that of WRP by 0.47%. The oxygen content of MWRP is higher by 13% than that of WRP. The phosphorus content of MWRP reaches 5.25%. The water contact angle of MWRP is 91.5°, whereas that of WRP is 123.7°. The properties of the WRP/NR and MWRP/NR composites were also investigated. MWRP/NR possesses higher tensile strength than WRP/NR because of the enhanced interfacial interaction between MWRP and the NR matrix. Post‐treatment is also conducive for MWRP/NR to improve its tensile strength at high MWRP content. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133 , 42993.
abstract_unstemmed	Polycardanol was synthesized from cardanol, paraformaldehyde, p‐toluenesulfonic acid, phosphoric acid (H 3 PO 4 ), and phosphorus pentoxide (P 2 O 5 ) via a two‐step process. Results indicated that polycardanol is an acid with high molecular weight and can be self‐crosslinked at high temperature. A modified WRP (MWRP) grafted by long chain can be obtained from the reaction between WRP and polycardanol. The sulfur content of MWRP is 0.27%, which is lower than that of WRP by 0.47%. The oxygen content of MWRP is higher by 13% than that of WRP. The phosphorus content of MWRP reaches 5.25%. The water contact angle of MWRP is 91.5°, whereas that of WRP is 123.7°. The properties of the WRP/NR and MWRP/NR composites were also investigated. MWRP/NR possesses higher tensile strength than WRP/NR because of the enhanced interfacial interaction between MWRP and the NR matrix. Post‐treatment is also conducive for MWRP/NR to improve its tensile strength at high MWRP content. © 2015 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2016 , 133 , 42993.
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container_issue	6
title_short	A novel grafting‐modified waste rubber powder as filler in natural rubber vulcanizates
url	http://dx.doi.org/10.1002/app.42993 http://onlinelibrary.wiley.com/doi/10.1002/app.42993/abstract http://search.proquest.com/docview/1734542175
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author2	Liu, Chunling Zhang, Haibin Gong, Zhaohong Yu, Ruobing
author2Str	Liu, Chunling Zhang, Haibin Gong, Zhaohong Yu, Ruobing
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doi_str	10.1002/app.42993
up_date	2024-07-03T17:43:37.893Z
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