Effects of microstructure on the sky-green color in imitating ancient Jun glazes
The sky-green glaze of ancient Jun ware was successfully imitated with the addition of 4 wt % calcium phosphate for introducing the phosphorus (P) to the composition. Effects of the calcium phosphate contents on the chromaticity, precipitated phase and microstructure of sky-green glaze were investig...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Jianfeng ZHU [verfasserIn] |
|---|
| Format: |
Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2016 |
|---|
| Übergeordnetes Werk: |
Enthalten in: Nihon Seramikkusu Kyōkai gakujutsu ronbunshi - Tōkyō : Kyōkai, 1988, 124(2016), 3, Seite 229 |
|---|---|
| Übergeordnetes Werk: |
volume:124 ; year:2016 ; number:3 ; pages:229 |
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| 520 | |a The sky-green glaze of ancient Jun ware was successfully imitated with the addition of 4 wt % calcium phosphate for introducing the phosphorus (P) to the composition. Effects of the calcium phosphate contents on the chromaticity, precipitated phase and microstructure of sky-green glaze were investigated. Based on the analysis of colorimeter, XRD, FT-IR, XPS and SEM, a possible coloring mechanism was proposed to explain the variation of glaze colors with the increasing of calcium phosphate content. The results indicated that the addition of calcium phosphate contributed to increasing the content of calcium iron phosphate [Ca19Fe2(PO4)14] and the size of phase separation droplets in glazes. The formation of Ca19Fe2(PO4)14 decreased the ratio of Fe2+ to Fe3+ and the increased size of phase separation droplets weakened the structural color, which increased the L* and b* value of glazes. Therefore, the color of sky-green glaze got more green and white gradually. | ||
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Effects of microstructure on the sky-green color in imitating ancient Jun glazes |
| abstract |
The sky-green glaze of ancient Jun ware was successfully imitated with the addition of 4 wt % calcium phosphate for introducing the phosphorus (P) to the composition. Effects of the calcium phosphate contents on the chromaticity, precipitated phase and microstructure of sky-green glaze were investigated. Based on the analysis of colorimeter, XRD, FT-IR, XPS and SEM, a possible coloring mechanism was proposed to explain the variation of glaze colors with the increasing of calcium phosphate content. The results indicated that the addition of calcium phosphate contributed to increasing the content of calcium iron phosphate [Ca19Fe2(PO4)14] and the size of phase separation droplets in glazes. The formation of Ca19Fe2(PO4)14 decreased the ratio of Fe2+ to Fe3+ and the increased size of phase separation droplets weakened the structural color, which increased the L* and b* value of glazes. Therefore, the color of sky-green glaze got more green and white gradually. |
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The sky-green glaze of ancient Jun ware was successfully imitated with the addition of 4 wt % calcium phosphate for introducing the phosphorus (P) to the composition. Effects of the calcium phosphate contents on the chromaticity, precipitated phase and microstructure of sky-green glaze were investigated. Based on the analysis of colorimeter, XRD, FT-IR, XPS and SEM, a possible coloring mechanism was proposed to explain the variation of glaze colors with the increasing of calcium phosphate content. The results indicated that the addition of calcium phosphate contributed to increasing the content of calcium iron phosphate [Ca19Fe2(PO4)14] and the size of phase separation droplets in glazes. The formation of Ca19Fe2(PO4)14 decreased the ratio of Fe2+ to Fe3+ and the increased size of phase separation droplets weakened the structural color, which increased the L* and b* value of glazes. Therefore, the color of sky-green glaze got more green and white gradually. |
| abstract_unstemmed |
The sky-green glaze of ancient Jun ware was successfully imitated with the addition of 4 wt % calcium phosphate for introducing the phosphorus (P) to the composition. Effects of the calcium phosphate contents on the chromaticity, precipitated phase and microstructure of sky-green glaze were investigated. Based on the analysis of colorimeter, XRD, FT-IR, XPS and SEM, a possible coloring mechanism was proposed to explain the variation of glaze colors with the increasing of calcium phosphate content. The results indicated that the addition of calcium phosphate contributed to increasing the content of calcium iron phosphate [Ca19Fe2(PO4)14] and the size of phase separation droplets in glazes. The formation of Ca19Fe2(PO4)14 decreased the ratio of Fe2+ to Fe3+ and the increased size of phase separation droplets weakened the structural color, which increased the L* and b* value of glazes. Therefore, the color of sky-green glaze got more green and white gradually. |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a2200265 4500</leader><controlfield tag="001">OLC1972666975</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230714183407.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">160427s2016 xx ||||| 00| ||eng c</controlfield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">PQ20160430</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC1972666975</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVOLC1972666975</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(PRQ)p889-46606555d1793fd0007be9bacd86764ab3376a49e7de510c7e338a7c905896603</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(KEY)0032314420160000124000300229effectsofmicrostructureontheskygreencolorinimitati</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">DNB</subfield></datafield><datafield tag="100" ind1="0" ind2=" "><subfield code="a">Jianfeng ZHU</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Effects of microstructure on the sky-green color in imitating ancient Jun glazes</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2016</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The sky-green glaze of ancient Jun ware was successfully imitated with the addition of 4 wt % calcium phosphate for introducing the phosphorus (P) to the composition. Effects of the calcium phosphate contents on the chromaticity, precipitated phase and microstructure of sky-green glaze were investigated. Based on the analysis of colorimeter, XRD, FT-IR, XPS and SEM, a possible coloring mechanism was proposed to explain the variation of glaze colors with the increasing of calcium phosphate content. The results indicated that the addition of calcium phosphate contributed to increasing the content of calcium iron phosphate [Ca19Fe2(PO4)14] and the size of phase separation droplets in glazes. The formation of Ca19Fe2(PO4)14 decreased the ratio of Fe2+ to Fe3+ and the increased size of phase separation droplets weakened the structural color, which increased the L* and b* value of glazes. 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