Biopolymer based ion imprinting cryogel traps for the removal of Tl(I)

The aim of this study is to prepare supermacroporous cryogel with embedded ion imprinted polymer (IIP) particles which can be used for the selective removal of Tl(I) from aqueous solution. In the first step, Tl(I) has complexed with chitosan and crosslinked with ephychlorohydrin. In the second step,...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Cankara, Semra [verfasserIn] Özkütük, Ebru Birlik Öztürk, Ömer Ersöz, Arzu Say, Rıdvan

Format:	Artikel
Sprache:	Englisch

Erschienen:	2016

Rechteinformationen:	Nutzungsrecht: © 2016 Taylor & Francis 2016

Schlagwörter:	IIP cryogel Tl(I)

Übergeordnetes Werk:	Enthalten in: Separation science and technology - Philadelphia, Pa. : Taylor & Francis, 1978, 51(2016), 6, Seite 901-8
Übergeordnetes Werk:	volume:51 ; year:2016 ; number:6 ; pages:901-8

Links:	Volltext Link aufrufen

DOI / URN:	10.1080/01496395.2015.1105265

Katalog-ID:	OLC1973572737

Internformat


LEADER	01000caa a2200265 4500
001	OLC1973572737
003	DE-627
005	20230714184804.0
007	tu
008	160430s2016 xx \|\|\|\|\| 00\| \|\|eng c
024	7		\|a 10.1080/01496395.2015.1105265 \|2 doi
028	5	2	\|a PQ20160610
035			\|a (DE-627)OLC1973572737
035			\|a (DE-599)GBVOLC1973572737
035			\|a (PRQ)c1265-e82f90517a17fb8dbf8a9ecf9b7e638e222ed2673706c96102b51268da79f4750
035			\|a (KEY)0017461020160000051000600901biopolymerbasedionimprintingcryogeltrapsfortheremo
040			\|a DE-627 \|b ger \|c DE-627 \|e rakwb
041			\|a eng
082	0	4	\|a 540 \|q DNB
100	1		\|a Cankara, Semra \|e verfasserin \|4 aut
245	1	0	\|a Biopolymer based ion imprinting cryogel traps for the removal of Tl(I)
264		1	\|c 2016
336			\|a Text \|b txt \|2 rdacontent
337			\|a ohne Hilfsmittel zu benutzen \|b n \|2 rdamedia
338			\|a Band \|b nc \|2 rdacarrier
520			\|a The aim of this study is to prepare supermacroporous cryogel with embedded ion imprinted polymer (IIP) particles which can be used for the selective removal of Tl(I) from aqueous solution. In the first step, Tl(I) has complexed with chitosan and crosslinked with ephychlorohydrin. In the second step, the supermacroporous poly(hydroxyethyl methacrylate) (PHEMA) cryogel with embedded IIP particles [PHEMA/MIP composite cryogel] which have been produced by free radical polymerization initiated by N,N,N',N'-tetramethylene diamine (TEMED) and ammonium persulfate (APS) pair in ice bath. The template, Tl(I), has been removed from the polymer using 0.1 M EDTA solution. The cryogel is characterized by swelling test, scanning electron microscopy, and Fourier transform infrared spectroscopy. The effective parameters on Tl(I) adsorption process have evaluated by investigating the dependency of the adsorption capacity on flow-rate, Tl(I) concentration and contact time. The maximum adsorption capacity of Tl(I) ions has been found to be 1.55 µgg −1 . The selectivity of the IIP biopolymer cryogel has investigated by competitive adsorption of Cd(II), Cu(II), K(I), and Fe(II). The relative selectivity coefficients of IIP biopolymer cryogel are 3.98 and 62.5 for Cd(II) and Cu(II), respectively. The IIP biopolymer cryogel could be used many times without any significant decrease in the adsorption capacity. As a conclusion it can be said that the IIP biopolymer cryogel could be used for specific separation of Tl(I) ions from nuclear, industrial, and environmental waste.
540			\|a Nutzungsrecht: © 2016 Taylor & Francis 2016
650		4	\|a IIP
650		4	\|a cryogel
650		4	\|a Tl(I)
700	1		\|a Özkütük, Ebru Birlik \|4 oth
700	1		\|a Öztürk, Ömer \|4 oth
700	1		\|a Ersöz, Arzu \|4 oth
700	1		\|a Say, Rıdvan \|4 oth
773	0	8	\|i Enthalten in \|t Separation science and technology \|d Philadelphia, Pa. : Taylor & Francis, 1978 \|g 51(2016), 6, Seite 901-8 \|w (DE-627)12994100X \|w (DE-600)391905-5 \|w (DE-576)015504247 \|x 0149-6395 \|7 nnns
773	1	8	\|g volume:51 \|g year:2016 \|g number:6 \|g pages:901-8
856	4	1	\|u http://dx.doi.org/10.1080/01496395.2015.1105265 \|3 Volltext
856	4	2	\|u http://www.tandfonline.com/doi/abs/10.1080/01496395.2015.1105265
912			\|a GBV_USEFLAG_A
912			\|a SYSFLAG_A
912			\|a GBV_OLC
912			\|a SSG-OLC-TEC
912			\|a SSG-OLC-CHE
912			\|a SSG-OLC-PHA
912			\|a SSG-OLC-DE-84
912			\|a GBV_ILN_70
951			\|a AR
952			\|d 51 \|j 2016 \|e 6 \|h 901-8

Indexfelder

author_variant	s c sc
matchkey_str	article:01496395:2016----::iplmraeinmrnigroetaso
hierarchy_sort_str	2016
publishDate	2016
allfields	10.1080/01496395.2015.1105265 doi PQ20160610 (DE-627)OLC1973572737 (DE-599)GBVOLC1973572737 (PRQ)c1265-e82f90517a17fb8dbf8a9ecf9b7e638e222ed2673706c96102b51268da79f4750 (KEY)0017461020160000051000600901biopolymerbasedionimprintingcryogeltrapsfortheremo DE-627 ger DE-627 rakwb eng 540 DNB Cankara, Semra verfasserin aut Biopolymer based ion imprinting cryogel traps for the removal of Tl(I) 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier The aim of this study is to prepare supermacroporous cryogel with embedded ion imprinted polymer (IIP) particles which can be used for the selective removal of Tl(I) from aqueous solution. In the first step, Tl(I) has complexed with chitosan and crosslinked with ephychlorohydrin. In the second step, the supermacroporous poly(hydroxyethyl methacrylate) (PHEMA) cryogel with embedded IIP particles [PHEMA/MIP composite cryogel] which have been produced by free radical polymerization initiated by N,N,N',N'-tetramethylene diamine (TEMED) and ammonium persulfate (APS) pair in ice bath. The template, Tl(I), has been removed from the polymer using 0.1 M EDTA solution. The cryogel is characterized by swelling test, scanning electron microscopy, and Fourier transform infrared spectroscopy. The effective parameters on Tl(I) adsorption process have evaluated by investigating the dependency of the adsorption capacity on flow-rate, Tl(I) concentration and contact time. The maximum adsorption capacity of Tl(I) ions has been found to be 1.55 µgg −1 . The selectivity of the IIP biopolymer cryogel has investigated by competitive adsorption of Cd(II), Cu(II), K(I), and Fe(II). The relative selectivity coefficients of IIP biopolymer cryogel are 3.98 and 62.5 for Cd(II) and Cu(II), respectively. The IIP biopolymer cryogel could be used many times without any significant decrease in the adsorption capacity. As a conclusion it can be said that the IIP biopolymer cryogel could be used for specific separation of Tl(I) ions from nuclear, industrial, and environmental waste. Nutzungsrecht: © 2016 Taylor & Francis 2016 IIP cryogel Tl(I) Özkütük, Ebru Birlik oth Öztürk, Ömer oth Ersöz, Arzu oth Say, Rıdvan oth Enthalten in Separation science and technology Philadelphia, Pa. : Taylor & Francis, 1978 51(2016), 6, Seite 901-8 (DE-627)12994100X (DE-600)391905-5 (DE-576)015504247 0149-6395 nnns volume:51 year:2016 number:6 pages:901-8 http://dx.doi.org/10.1080/01496395.2015.1105265 Volltext http://www.tandfonline.com/doi/abs/10.1080/01496395.2015.1105265 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 51 2016 6 901-8
spelling	10.1080/01496395.2015.1105265 doi PQ20160610 (DE-627)OLC1973572737 (DE-599)GBVOLC1973572737 (PRQ)c1265-e82f90517a17fb8dbf8a9ecf9b7e638e222ed2673706c96102b51268da79f4750 (KEY)0017461020160000051000600901biopolymerbasedionimprintingcryogeltrapsfortheremo DE-627 ger DE-627 rakwb eng 540 DNB Cankara, Semra verfasserin aut Biopolymer based ion imprinting cryogel traps for the removal of Tl(I) 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier The aim of this study is to prepare supermacroporous cryogel with embedded ion imprinted polymer (IIP) particles which can be used for the selective removal of Tl(I) from aqueous solution. In the first step, Tl(I) has complexed with chitosan and crosslinked with ephychlorohydrin. In the second step, the supermacroporous poly(hydroxyethyl methacrylate) (PHEMA) cryogel with embedded IIP particles [PHEMA/MIP composite cryogel] which have been produced by free radical polymerization initiated by N,N,N',N'-tetramethylene diamine (TEMED) and ammonium persulfate (APS) pair in ice bath. The template, Tl(I), has been removed from the polymer using 0.1 M EDTA solution. The cryogel is characterized by swelling test, scanning electron microscopy, and Fourier transform infrared spectroscopy. The effective parameters on Tl(I) adsorption process have evaluated by investigating the dependency of the adsorption capacity on flow-rate, Tl(I) concentration and contact time. The maximum adsorption capacity of Tl(I) ions has been found to be 1.55 µgg −1 . The selectivity of the IIP biopolymer cryogel has investigated by competitive adsorption of Cd(II), Cu(II), K(I), and Fe(II). The relative selectivity coefficients of IIP biopolymer cryogel are 3.98 and 62.5 for Cd(II) and Cu(II), respectively. The IIP biopolymer cryogel could be used many times without any significant decrease in the adsorption capacity. As a conclusion it can be said that the IIP biopolymer cryogel could be used for specific separation of Tl(I) ions from nuclear, industrial, and environmental waste. Nutzungsrecht: © 2016 Taylor & Francis 2016 IIP cryogel Tl(I) Özkütük, Ebru Birlik oth Öztürk, Ömer oth Ersöz, Arzu oth Say, Rıdvan oth Enthalten in Separation science and technology Philadelphia, Pa. : Taylor & Francis, 1978 51(2016), 6, Seite 901-8 (DE-627)12994100X (DE-600)391905-5 (DE-576)015504247 0149-6395 nnns volume:51 year:2016 number:6 pages:901-8 http://dx.doi.org/10.1080/01496395.2015.1105265 Volltext http://www.tandfonline.com/doi/abs/10.1080/01496395.2015.1105265 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 51 2016 6 901-8
allfields_unstemmed	10.1080/01496395.2015.1105265 doi PQ20160610 (DE-627)OLC1973572737 (DE-599)GBVOLC1973572737 (PRQ)c1265-e82f90517a17fb8dbf8a9ecf9b7e638e222ed2673706c96102b51268da79f4750 (KEY)0017461020160000051000600901biopolymerbasedionimprintingcryogeltrapsfortheremo DE-627 ger DE-627 rakwb eng 540 DNB Cankara, Semra verfasserin aut Biopolymer based ion imprinting cryogel traps for the removal of Tl(I) 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier The aim of this study is to prepare supermacroporous cryogel with embedded ion imprinted polymer (IIP) particles which can be used for the selective removal of Tl(I) from aqueous solution. In the first step, Tl(I) has complexed with chitosan and crosslinked with ephychlorohydrin. In the second step, the supermacroporous poly(hydroxyethyl methacrylate) (PHEMA) cryogel with embedded IIP particles [PHEMA/MIP composite cryogel] which have been produced by free radical polymerization initiated by N,N,N',N'-tetramethylene diamine (TEMED) and ammonium persulfate (APS) pair in ice bath. The template, Tl(I), has been removed from the polymer using 0.1 M EDTA solution. The cryogel is characterized by swelling test, scanning electron microscopy, and Fourier transform infrared spectroscopy. The effective parameters on Tl(I) adsorption process have evaluated by investigating the dependency of the adsorption capacity on flow-rate, Tl(I) concentration and contact time. The maximum adsorption capacity of Tl(I) ions has been found to be 1.55 µgg −1 . The selectivity of the IIP biopolymer cryogel has investigated by competitive adsorption of Cd(II), Cu(II), K(I), and Fe(II). The relative selectivity coefficients of IIP biopolymer cryogel are 3.98 and 62.5 for Cd(II) and Cu(II), respectively. The IIP biopolymer cryogel could be used many times without any significant decrease in the adsorption capacity. As a conclusion it can be said that the IIP biopolymer cryogel could be used for specific separation of Tl(I) ions from nuclear, industrial, and environmental waste. Nutzungsrecht: © 2016 Taylor & Francis 2016 IIP cryogel Tl(I) Özkütük, Ebru Birlik oth Öztürk, Ömer oth Ersöz, Arzu oth Say, Rıdvan oth Enthalten in Separation science and technology Philadelphia, Pa. : Taylor & Francis, 1978 51(2016), 6, Seite 901-8 (DE-627)12994100X (DE-600)391905-5 (DE-576)015504247 0149-6395 nnns volume:51 year:2016 number:6 pages:901-8 http://dx.doi.org/10.1080/01496395.2015.1105265 Volltext http://www.tandfonline.com/doi/abs/10.1080/01496395.2015.1105265 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 51 2016 6 901-8
allfieldsGer	10.1080/01496395.2015.1105265 doi PQ20160610 (DE-627)OLC1973572737 (DE-599)GBVOLC1973572737 (PRQ)c1265-e82f90517a17fb8dbf8a9ecf9b7e638e222ed2673706c96102b51268da79f4750 (KEY)0017461020160000051000600901biopolymerbasedionimprintingcryogeltrapsfortheremo DE-627 ger DE-627 rakwb eng 540 DNB Cankara, Semra verfasserin aut Biopolymer based ion imprinting cryogel traps for the removal of Tl(I) 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier The aim of this study is to prepare supermacroporous cryogel with embedded ion imprinted polymer (IIP) particles which can be used for the selective removal of Tl(I) from aqueous solution. In the first step, Tl(I) has complexed with chitosan and crosslinked with ephychlorohydrin. In the second step, the supermacroporous poly(hydroxyethyl methacrylate) (PHEMA) cryogel with embedded IIP particles [PHEMA/MIP composite cryogel] which have been produced by free radical polymerization initiated by N,N,N',N'-tetramethylene diamine (TEMED) and ammonium persulfate (APS) pair in ice bath. The template, Tl(I), has been removed from the polymer using 0.1 M EDTA solution. The cryogel is characterized by swelling test, scanning electron microscopy, and Fourier transform infrared spectroscopy. The effective parameters on Tl(I) adsorption process have evaluated by investigating the dependency of the adsorption capacity on flow-rate, Tl(I) concentration and contact time. The maximum adsorption capacity of Tl(I) ions has been found to be 1.55 µgg −1 . The selectivity of the IIP biopolymer cryogel has investigated by competitive adsorption of Cd(II), Cu(II), K(I), and Fe(II). The relative selectivity coefficients of IIP biopolymer cryogel are 3.98 and 62.5 for Cd(II) and Cu(II), respectively. The IIP biopolymer cryogel could be used many times without any significant decrease in the adsorption capacity. As a conclusion it can be said that the IIP biopolymer cryogel could be used for specific separation of Tl(I) ions from nuclear, industrial, and environmental waste. Nutzungsrecht: © 2016 Taylor & Francis 2016 IIP cryogel Tl(I) Özkütük, Ebru Birlik oth Öztürk, Ömer oth Ersöz, Arzu oth Say, Rıdvan oth Enthalten in Separation science and technology Philadelphia, Pa. : Taylor & Francis, 1978 51(2016), 6, Seite 901-8 (DE-627)12994100X (DE-600)391905-5 (DE-576)015504247 0149-6395 nnns volume:51 year:2016 number:6 pages:901-8 http://dx.doi.org/10.1080/01496395.2015.1105265 Volltext http://www.tandfonline.com/doi/abs/10.1080/01496395.2015.1105265 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 51 2016 6 901-8
allfieldsSound	10.1080/01496395.2015.1105265 doi PQ20160610 (DE-627)OLC1973572737 (DE-599)GBVOLC1973572737 (PRQ)c1265-e82f90517a17fb8dbf8a9ecf9b7e638e222ed2673706c96102b51268da79f4750 (KEY)0017461020160000051000600901biopolymerbasedionimprintingcryogeltrapsfortheremo DE-627 ger DE-627 rakwb eng 540 DNB Cankara, Semra verfasserin aut Biopolymer based ion imprinting cryogel traps for the removal of Tl(I) 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier The aim of this study is to prepare supermacroporous cryogel with embedded ion imprinted polymer (IIP) particles which can be used for the selective removal of Tl(I) from aqueous solution. In the first step, Tl(I) has complexed with chitosan and crosslinked with ephychlorohydrin. In the second step, the supermacroporous poly(hydroxyethyl methacrylate) (PHEMA) cryogel with embedded IIP particles [PHEMA/MIP composite cryogel] which have been produced by free radical polymerization initiated by N,N,N',N'-tetramethylene diamine (TEMED) and ammonium persulfate (APS) pair in ice bath. The template, Tl(I), has been removed from the polymer using 0.1 M EDTA solution. The cryogel is characterized by swelling test, scanning electron microscopy, and Fourier transform infrared spectroscopy. The effective parameters on Tl(I) adsorption process have evaluated by investigating the dependency of the adsorption capacity on flow-rate, Tl(I) concentration and contact time. The maximum adsorption capacity of Tl(I) ions has been found to be 1.55 µgg −1 . The selectivity of the IIP biopolymer cryogel has investigated by competitive adsorption of Cd(II), Cu(II), K(I), and Fe(II). The relative selectivity coefficients of IIP biopolymer cryogel are 3.98 and 62.5 for Cd(II) and Cu(II), respectively. The IIP biopolymer cryogel could be used many times without any significant decrease in the adsorption capacity. As a conclusion it can be said that the IIP biopolymer cryogel could be used for specific separation of Tl(I) ions from nuclear, industrial, and environmental waste. Nutzungsrecht: © 2016 Taylor & Francis 2016 IIP cryogel Tl(I) Özkütük, Ebru Birlik oth Öztürk, Ömer oth Ersöz, Arzu oth Say, Rıdvan oth Enthalten in Separation science and technology Philadelphia, Pa. : Taylor & Francis, 1978 51(2016), 6, Seite 901-8 (DE-627)12994100X (DE-600)391905-5 (DE-576)015504247 0149-6395 nnns volume:51 year:2016 number:6 pages:901-8 http://dx.doi.org/10.1080/01496395.2015.1105265 Volltext http://www.tandfonline.com/doi/abs/10.1080/01496395.2015.1105265 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 51 2016 6 901-8
language	English
source	Enthalten in Separation science and technology 51(2016), 6, Seite 901-8 volume:51 year:2016 number:6 pages:901-8
sourceStr	Enthalten in Separation science and technology 51(2016), 6, Seite 901-8 volume:51 year:2016 number:6 pages:901-8
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	IIP cryogel Tl(I)
dewey-raw	540
isfreeaccess_bool	false
container_title	Separation science and technology
authorswithroles_txt_mv	Cankara, Semra @@aut@@ Özkütük, Ebru Birlik @@oth@@ Öztürk, Ömer @@oth@@ Ersöz, Arzu @@oth@@ Say, Rıdvan @@oth@@
publishDateDaySort_date	2016-01-01T00:00:00Z
hierarchy_top_id	12994100X
dewey-sort	3540
id	OLC1973572737
language_de	englisch
fullrecord	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a2200265 4500</leader><controlfield tag="001">OLC1973572737</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230714184804.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">160430s2016 xx \|\|\|\|\| 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1080/01496395.2015.1105265</subfield><subfield code="2">doi</subfield></datafield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">PQ20160610</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC1973572737</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVOLC1973572737</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(PRQ)c1265-e82f90517a17fb8dbf8a9ecf9b7e638e222ed2673706c96102b51268da79f4750</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(KEY)0017461020160000051000600901biopolymerbasedionimprintingcryogeltrapsfortheremo</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">DNB</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Cankara, Semra</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Biopolymer based ion imprinting cryogel traps for the removal of Tl(I)</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2016</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The aim of this study is to prepare supermacroporous cryogel with embedded ion imprinted polymer (IIP) particles which can be used for the selective removal of Tl(I) from aqueous solution. In the first step, Tl(I) has complexed with chitosan and crosslinked with ephychlorohydrin. In the second step, the supermacroporous poly(hydroxyethyl methacrylate) (PHEMA) cryogel with embedded IIP particles [PHEMA/MIP composite cryogel] which have been produced by free radical polymerization initiated by N,N,N',N'-tetramethylene diamine (TEMED) and ammonium persulfate (APS) pair in ice bath. The template, Tl(I), has been removed from the polymer using 0.1 M EDTA solution. The cryogel is characterized by swelling test, scanning electron microscopy, and Fourier transform infrared spectroscopy. The effective parameters on Tl(I) adsorption process have evaluated by investigating the dependency of the adsorption capacity on flow-rate, Tl(I) concentration and contact time. The maximum adsorption capacity of Tl(I) ions has been found to be 1.55 µgg −1 . The selectivity of the IIP biopolymer cryogel has investigated by competitive adsorption of Cd(II), Cu(II), K(I), and Fe(II). The relative selectivity coefficients of IIP biopolymer cryogel are 3.98 and 62.5 for Cd(II) and Cu(II), respectively. The IIP biopolymer cryogel could be used many times without any significant decrease in the adsorption capacity. As a conclusion it can be said that the IIP biopolymer cryogel could be used for specific separation of Tl(I) ions from nuclear, industrial, and environmental waste.</subfield></datafield><datafield tag="540" ind1=" " ind2=" "><subfield code="a">Nutzungsrecht: © 2016 Taylor & Francis 2016</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">IIP</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">cryogel</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Tl(I)</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Özkütük, Ebru Birlik</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Öztürk, Ömer</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Ersöz, Arzu</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Say, Rıdvan</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Separation science and technology</subfield><subfield code="d">Philadelphia, Pa. : Taylor & Francis, 1978</subfield><subfield code="g">51(2016), 6, Seite 901-8</subfield><subfield code="w">(DE-627)12994100X</subfield><subfield code="w">(DE-600)391905-5</subfield><subfield code="w">(DE-576)015504247</subfield><subfield code="x">0149-6395</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:51</subfield><subfield code="g">year:2016</subfield><subfield code="g">number:6</subfield><subfield code="g">pages:901-8</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">http://dx.doi.org/10.1080/01496395.2015.1105265</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">http://www.tandfonline.com/doi/abs/10.1080/01496395.2015.1105265</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-DE-84</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">51</subfield><subfield code="j">2016</subfield><subfield code="e">6</subfield><subfield code="h">901-8</subfield></datafield></record></collection>
author	Cankara, Semra
spellingShingle	Cankara, Semra ddc 540 misc IIP misc cryogel misc Tl(I) Biopolymer based ion imprinting cryogel traps for the removal of Tl(I)
authorStr	Cankara, Semra
ppnlink_with_tag_str_mv	@@773@@(DE-627)12994100X
format	Article
dewey-ones	540 - Chemistry & allied sciences
delete_txt_mv	keep
author_role	aut
collection	OLC
remote_str	false
illustrated	Not Illustrated
issn	0149-6395
topic_title	540 DNB Biopolymer based ion imprinting cryogel traps for the removal of Tl(I) IIP cryogel Tl(I)
topic	ddc 540 misc IIP misc cryogel misc Tl(I)
topic_unstemmed	ddc 540 misc IIP misc cryogel misc Tl(I)
topic_browse	ddc 540 misc IIP misc cryogel misc Tl(I)
format_facet	Aufsätze Gedruckte Aufsätze
format_main_str_mv	Text Zeitschrift/Artikel
carriertype_str_mv	nc
author2_variant	e b ö eb ebö ö ö öö a e ae r s rs
hierarchy_parent_title	Separation science and technology
hierarchy_parent_id	12994100X
dewey-tens	540 - Chemistry
hierarchy_top_title	Separation science and technology
isfreeaccess_txt	false
familylinks_str_mv	(DE-627)12994100X (DE-600)391905-5 (DE-576)015504247
title	Biopolymer based ion imprinting cryogel traps for the removal of Tl(I)
ctrlnum	(DE-627)OLC1973572737 (DE-599)GBVOLC1973572737 (PRQ)c1265-e82f90517a17fb8dbf8a9ecf9b7e638e222ed2673706c96102b51268da79f4750 (KEY)0017461020160000051000600901biopolymerbasedionimprintingcryogeltrapsfortheremo
title_full	Biopolymer based ion imprinting cryogel traps for the removal of Tl(I)
author_sort	Cankara, Semra
journal	Separation science and technology
journalStr	Separation science and technology
lang_code	eng
isOA_bool	false
dewey-hundreds	500 - Science
recordtype	marc
publishDateSort	2016
contenttype_str_mv	txt
container_start_page	901
author_browse	Cankara, Semra
container_volume	51
class	540 DNB
format_se	Aufsätze
author-letter	Cankara, Semra
doi_str_mv	10.1080/01496395.2015.1105265
dewey-full	540
title_sort	biopolymer based ion imprinting cryogel traps for the removal of tl(i)
title_auth	Biopolymer based ion imprinting cryogel traps for the removal of Tl(I)
abstract	The aim of this study is to prepare supermacroporous cryogel with embedded ion imprinted polymer (IIP) particles which can be used for the selective removal of Tl(I) from aqueous solution. In the first step, Tl(I) has complexed with chitosan and crosslinked with ephychlorohydrin. In the second step, the supermacroporous poly(hydroxyethyl methacrylate) (PHEMA) cryogel with embedded IIP particles [PHEMA/MIP composite cryogel] which have been produced by free radical polymerization initiated by N,N,N',N'-tetramethylene diamine (TEMED) and ammonium persulfate (APS) pair in ice bath. The template, Tl(I), has been removed from the polymer using 0.1 M EDTA solution. The cryogel is characterized by swelling test, scanning electron microscopy, and Fourier transform infrared spectroscopy. The effective parameters on Tl(I) adsorption process have evaluated by investigating the dependency of the adsorption capacity on flow-rate, Tl(I) concentration and contact time. The maximum adsorption capacity of Tl(I) ions has been found to be 1.55 µgg −1 . The selectivity of the IIP biopolymer cryogel has investigated by competitive adsorption of Cd(II), Cu(II), K(I), and Fe(II). The relative selectivity coefficients of IIP biopolymer cryogel are 3.98 and 62.5 for Cd(II) and Cu(II), respectively. The IIP biopolymer cryogel could be used many times without any significant decrease in the adsorption capacity. As a conclusion it can be said that the IIP biopolymer cryogel could be used for specific separation of Tl(I) ions from nuclear, industrial, and environmental waste.
abstractGer	The aim of this study is to prepare supermacroporous cryogel with embedded ion imprinted polymer (IIP) particles which can be used for the selective removal of Tl(I) from aqueous solution. In the first step, Tl(I) has complexed with chitosan and crosslinked with ephychlorohydrin. In the second step, the supermacroporous poly(hydroxyethyl methacrylate) (PHEMA) cryogel with embedded IIP particles [PHEMA/MIP composite cryogel] which have been produced by free radical polymerization initiated by N,N,N',N'-tetramethylene diamine (TEMED) and ammonium persulfate (APS) pair in ice bath. The template, Tl(I), has been removed from the polymer using 0.1 M EDTA solution. The cryogel is characterized by swelling test, scanning electron microscopy, and Fourier transform infrared spectroscopy. The effective parameters on Tl(I) adsorption process have evaluated by investigating the dependency of the adsorption capacity on flow-rate, Tl(I) concentration and contact time. The maximum adsorption capacity of Tl(I) ions has been found to be 1.55 µgg −1 . The selectivity of the IIP biopolymer cryogel has investigated by competitive adsorption of Cd(II), Cu(II), K(I), and Fe(II). The relative selectivity coefficients of IIP biopolymer cryogel are 3.98 and 62.5 for Cd(II) and Cu(II), respectively. The IIP biopolymer cryogel could be used many times without any significant decrease in the adsorption capacity. As a conclusion it can be said that the IIP biopolymer cryogel could be used for specific separation of Tl(I) ions from nuclear, industrial, and environmental waste.
abstract_unstemmed	The aim of this study is to prepare supermacroporous cryogel with embedded ion imprinted polymer (IIP) particles which can be used for the selective removal of Tl(I) from aqueous solution. In the first step, Tl(I) has complexed with chitosan and crosslinked with ephychlorohydrin. In the second step, the supermacroporous poly(hydroxyethyl methacrylate) (PHEMA) cryogel with embedded IIP particles [PHEMA/MIP composite cryogel] which have been produced by free radical polymerization initiated by N,N,N',N'-tetramethylene diamine (TEMED) and ammonium persulfate (APS) pair in ice bath. The template, Tl(I), has been removed from the polymer using 0.1 M EDTA solution. The cryogel is characterized by swelling test, scanning electron microscopy, and Fourier transform infrared spectroscopy. The effective parameters on Tl(I) adsorption process have evaluated by investigating the dependency of the adsorption capacity on flow-rate, Tl(I) concentration and contact time. The maximum adsorption capacity of Tl(I) ions has been found to be 1.55 µgg −1 . The selectivity of the IIP biopolymer cryogel has investigated by competitive adsorption of Cd(II), Cu(II), K(I), and Fe(II). The relative selectivity coefficients of IIP biopolymer cryogel are 3.98 and 62.5 for Cd(II) and Cu(II), respectively. The IIP biopolymer cryogel could be used many times without any significant decrease in the adsorption capacity. As a conclusion it can be said that the IIP biopolymer cryogel could be used for specific separation of Tl(I) ions from nuclear, industrial, and environmental waste.
collection_details	GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70
container_issue	6
title_short	Biopolymer based ion imprinting cryogel traps for the removal of Tl(I)
url	http://dx.doi.org/10.1080/01496395.2015.1105265 http://www.tandfonline.com/doi/abs/10.1080/01496395.2015.1105265
remote_bool	false
author2	Özkütük, Ebru Birlik Öztürk, Ömer Ersöz, Arzu Say, Rıdvan
author2Str	Özkütük, Ebru Birlik Öztürk, Ömer Ersöz, Arzu Say, Rıdvan
ppnlink	12994100X
mediatype_str_mv	n
isOA_txt	false
hochschulschrift_bool	false
author2_role	oth oth oth oth
doi_str	10.1080/01496395.2015.1105265
up_date	2024-07-04T02:43:45.010Z
_version_	1803614709367177216
fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a2200265 4500</leader><controlfield tag="001">OLC1973572737</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230714184804.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">160430s2016 xx \|\|\|\|\| 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1080/01496395.2015.1105265</subfield><subfield code="2">doi</subfield></datafield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">PQ20160610</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC1973572737</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVOLC1973572737</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(PRQ)c1265-e82f90517a17fb8dbf8a9ecf9b7e638e222ed2673706c96102b51268da79f4750</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(KEY)0017461020160000051000600901biopolymerbasedionimprintingcryogeltrapsfortheremo</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">DNB</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Cankara, Semra</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Biopolymer based ion imprinting cryogel traps for the removal of Tl(I)</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2016</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The aim of this study is to prepare supermacroporous cryogel with embedded ion imprinted polymer (IIP) particles which can be used for the selective removal of Tl(I) from aqueous solution. In the first step, Tl(I) has complexed with chitosan and crosslinked with ephychlorohydrin. In the second step, the supermacroporous poly(hydroxyethyl methacrylate) (PHEMA) cryogel with embedded IIP particles [PHEMA/MIP composite cryogel] which have been produced by free radical polymerization initiated by N,N,N',N'-tetramethylene diamine (TEMED) and ammonium persulfate (APS) pair in ice bath. The template, Tl(I), has been removed from the polymer using 0.1 M EDTA solution. The cryogel is characterized by swelling test, scanning electron microscopy, and Fourier transform infrared spectroscopy. The effective parameters on Tl(I) adsorption process have evaluated by investigating the dependency of the adsorption capacity on flow-rate, Tl(I) concentration and contact time. The maximum adsorption capacity of Tl(I) ions has been found to be 1.55 µgg −1 . The selectivity of the IIP biopolymer cryogel has investigated by competitive adsorption of Cd(II), Cu(II), K(I), and Fe(II). The relative selectivity coefficients of IIP biopolymer cryogel are 3.98 and 62.5 for Cd(II) and Cu(II), respectively. The IIP biopolymer cryogel could be used many times without any significant decrease in the adsorption capacity. As a conclusion it can be said that the IIP biopolymer cryogel could be used for specific separation of Tl(I) ions from nuclear, industrial, and environmental waste.</subfield></datafield><datafield tag="540" ind1=" " ind2=" "><subfield code="a">Nutzungsrecht: © 2016 Taylor & Francis 2016</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">IIP</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">cryogel</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Tl(I)</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Özkütük, Ebru Birlik</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Öztürk, Ömer</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Ersöz, Arzu</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Say, Rıdvan</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Separation science and technology</subfield><subfield code="d">Philadelphia, Pa. : Taylor & Francis, 1978</subfield><subfield code="g">51(2016), 6, Seite 901-8</subfield><subfield code="w">(DE-627)12994100X</subfield><subfield code="w">(DE-600)391905-5</subfield><subfield code="w">(DE-576)015504247</subfield><subfield code="x">0149-6395</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:51</subfield><subfield code="g">year:2016</subfield><subfield code="g">number:6</subfield><subfield code="g">pages:901-8</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">http://dx.doi.org/10.1080/01496395.2015.1105265</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">http://www.tandfonline.com/doi/abs/10.1080/01496395.2015.1105265</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-DE-84</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">51</subfield><subfield code="j">2016</subfield><subfield code="e">6</subfield><subfield code="h">901-8</subfield></datafield></record></collection>
score	7.3993473

Nicht das Richtige dabei?

Schreiben Sie uns!

Biopolymer based ion imprinting cryogel traps for the removal of Tl(I)

Nicht das Richtige dabei?

Zugang & Verfügbarkeit

Vorhandene Bände

Nicht das Richtige dabei?