Bio-based epoxy/chitin nanofiber composites cured with amine-type hardeners containing chitosan
Sorbitol polyglycidyl ether (SPE) which is a bio-based water-soluble epoxy resin was cured with chitosan (CS) and/or a commercial water-soluble polyamidoamine- or polyetheramine-type epoxy hardener (PAA or PEA). Furthermore, biocomposites of the CS-cured SPE (CS-SPE) and CS/PAA- or CS/PEA-cured SPE...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Shibata, Mitsuhiro [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2016 |
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| Rechteinformationen: |
Nutzungsrecht: Copyright © 2016 Elsevier Ltd. All rights reserved. |
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| Übergeordnetes Werk: |
Enthalten in: Carbohydrate polymers - Barking, Essex : Applied Science Publ., 1981, 144(2016), Seite 89-97 |
|---|---|
| Übergeordnetes Werk: |
volume:144 ; year:2016 ; pages:89-97 |
| Links: |
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| DOI / URN: |
10.1016/j.carbpol.2016.02.033 |
|---|
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| 520 | |a Sorbitol polyglycidyl ether (SPE) which is a bio-based water-soluble epoxy resin was cured with chitosan (CS) and/or a commercial water-soluble polyamidoamine- or polyetheramine-type epoxy hardener (PAA or PEA). Furthermore, biocomposites of the CS-cured SPE (CS-SPE) and CS/PAA- or CS/PEA-cured SPE (SPE-CA or SPE-CE) biocomposites with chitin nanofiber (CNF) were prepared by casting and compression molding methods, respectively. The curing reaction of epoxy and amino groups of the reactants was confirmed by the FT-IR spectral analysis. SPE-CS and SPE-CA were almost transparent films, while SPE-CE was opaque. Transparency of SPE-CS/CNF and SPE-CA/CNF became a little worse with increasing CNF content. The tanδ peak temperature of SPE-CS was higher than those of SPE-PAA and SPE-PEA. SPE-CA or SPE-CE exhibited two tanδ peak temperatures related to glass transitions of the CS-rich and PAA-rich or PEA-rich moieties. The tanδ peak temperatures related to the CS-rich and PAA-rich moieties increased with increasing CNF content. A higher order of tensile strengths and moduli of the cured resins was SPE-CS≫SPE-CA>SPE-CE. The tensile strength and modulus of each sample were much improved by the addition of 3wt% CNF, while further addition of CNF caused a lowering of the strength and modulus. | ||
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| 700 | 1 | |a Sakazume, Katsumi |4 oth | |
| 700 | 1 | |a Ifuku, Shinsuke |4 oth | |
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10.1016/j.carbpol.2016.02.033 doi PQ20160719 (DE-627)OLC197790582X (DE-599)GBVOLC197790582X (PRQ)c1650-cfd0c54d564fbefce2cf17417a9b8b082c1ca589655fc78695bfab4d7d142ae0 (KEY)0110347420160000144000000089biobasedepoxychitinnanofibercompositescuredwithami DE-627 ger DE-627 rakwb eng 540 660 DNB 58.34 bkl 49.25 bkl Shibata, Mitsuhiro verfasserin aut Bio-based epoxy/chitin nanofiber composites cured with amine-type hardeners containing chitosan 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Sorbitol polyglycidyl ether (SPE) which is a bio-based water-soluble epoxy resin was cured with chitosan (CS) and/or a commercial water-soluble polyamidoamine- or polyetheramine-type epoxy hardener (PAA or PEA). Furthermore, biocomposites of the CS-cured SPE (CS-SPE) and CS/PAA- or CS/PEA-cured SPE (SPE-CA or SPE-CE) biocomposites with chitin nanofiber (CNF) were prepared by casting and compression molding methods, respectively. The curing reaction of epoxy and amino groups of the reactants was confirmed by the FT-IR spectral analysis. SPE-CS and SPE-CA were almost transparent films, while SPE-CE was opaque. Transparency of SPE-CS/CNF and SPE-CA/CNF became a little worse with increasing CNF content. The tanδ peak temperature of SPE-CS was higher than those of SPE-PAA and SPE-PEA. SPE-CA or SPE-CE exhibited two tanδ peak temperatures related to glass transitions of the CS-rich and PAA-rich or PEA-rich moieties. The tanδ peak temperatures related to the CS-rich and PAA-rich moieties increased with increasing CNF content. A higher order of tensile strengths and moduli of the cured resins was SPE-CS≫SPE-CA>SPE-CE. The tensile strength and modulus of each sample were much improved by the addition of 3wt% CNF, while further addition of CNF caused a lowering of the strength and modulus. Nutzungsrecht: Copyright © 2016 Elsevier Ltd. All rights reserved. Enjoji, Motohiro oth Sakazume, Katsumi oth Ifuku, Shinsuke oth Enthalten in Carbohydrate polymers Barking, Essex : Applied Science Publ., 1981 144(2016), Seite 89-97 (DE-627)130549746 (DE-600)782631-X (DE-576)481341323 0144-8617 nnns volume:144 year:2016 pages:89-97 http://dx.doi.org/10.1016/j.carbpol.2016.02.033 Volltext http://www.ncbi.nlm.nih.gov/pubmed/27083797 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 58.34 AVZ 49.25 AVZ AR 144 2016 89-97 |
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10.1016/j.carbpol.2016.02.033 doi PQ20160719 (DE-627)OLC197790582X (DE-599)GBVOLC197790582X (PRQ)c1650-cfd0c54d564fbefce2cf17417a9b8b082c1ca589655fc78695bfab4d7d142ae0 (KEY)0110347420160000144000000089biobasedepoxychitinnanofibercompositescuredwithami DE-627 ger DE-627 rakwb eng 540 660 DNB 58.34 bkl 49.25 bkl Shibata, Mitsuhiro verfasserin aut Bio-based epoxy/chitin nanofiber composites cured with amine-type hardeners containing chitosan 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Sorbitol polyglycidyl ether (SPE) which is a bio-based water-soluble epoxy resin was cured with chitosan (CS) and/or a commercial water-soluble polyamidoamine- or polyetheramine-type epoxy hardener (PAA or PEA). Furthermore, biocomposites of the CS-cured SPE (CS-SPE) and CS/PAA- or CS/PEA-cured SPE (SPE-CA or SPE-CE) biocomposites with chitin nanofiber (CNF) were prepared by casting and compression molding methods, respectively. The curing reaction of epoxy and amino groups of the reactants was confirmed by the FT-IR spectral analysis. SPE-CS and SPE-CA were almost transparent films, while SPE-CE was opaque. Transparency of SPE-CS/CNF and SPE-CA/CNF became a little worse with increasing CNF content. The tanδ peak temperature of SPE-CS was higher than those of SPE-PAA and SPE-PEA. SPE-CA or SPE-CE exhibited two tanδ peak temperatures related to glass transitions of the CS-rich and PAA-rich or PEA-rich moieties. The tanδ peak temperatures related to the CS-rich and PAA-rich moieties increased with increasing CNF content. A higher order of tensile strengths and moduli of the cured resins was SPE-CS≫SPE-CA>SPE-CE. The tensile strength and modulus of each sample were much improved by the addition of 3wt% CNF, while further addition of CNF caused a lowering of the strength and modulus. Nutzungsrecht: Copyright © 2016 Elsevier Ltd. All rights reserved. Enjoji, Motohiro oth Sakazume, Katsumi oth Ifuku, Shinsuke oth Enthalten in Carbohydrate polymers Barking, Essex : Applied Science Publ., 1981 144(2016), Seite 89-97 (DE-627)130549746 (DE-600)782631-X (DE-576)481341323 0144-8617 nnns volume:144 year:2016 pages:89-97 http://dx.doi.org/10.1016/j.carbpol.2016.02.033 Volltext http://www.ncbi.nlm.nih.gov/pubmed/27083797 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 58.34 AVZ 49.25 AVZ AR 144 2016 89-97 |
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10.1016/j.carbpol.2016.02.033 doi PQ20160719 (DE-627)OLC197790582X (DE-599)GBVOLC197790582X (PRQ)c1650-cfd0c54d564fbefce2cf17417a9b8b082c1ca589655fc78695bfab4d7d142ae0 (KEY)0110347420160000144000000089biobasedepoxychitinnanofibercompositescuredwithami DE-627 ger DE-627 rakwb eng 540 660 DNB 58.34 bkl 49.25 bkl Shibata, Mitsuhiro verfasserin aut Bio-based epoxy/chitin nanofiber composites cured with amine-type hardeners containing chitosan 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Sorbitol polyglycidyl ether (SPE) which is a bio-based water-soluble epoxy resin was cured with chitosan (CS) and/or a commercial water-soluble polyamidoamine- or polyetheramine-type epoxy hardener (PAA or PEA). Furthermore, biocomposites of the CS-cured SPE (CS-SPE) and CS/PAA- or CS/PEA-cured SPE (SPE-CA or SPE-CE) biocomposites with chitin nanofiber (CNF) were prepared by casting and compression molding methods, respectively. The curing reaction of epoxy and amino groups of the reactants was confirmed by the FT-IR spectral analysis. SPE-CS and SPE-CA were almost transparent films, while SPE-CE was opaque. Transparency of SPE-CS/CNF and SPE-CA/CNF became a little worse with increasing CNF content. The tanδ peak temperature of SPE-CS was higher than those of SPE-PAA and SPE-PEA. SPE-CA or SPE-CE exhibited two tanδ peak temperatures related to glass transitions of the CS-rich and PAA-rich or PEA-rich moieties. The tanδ peak temperatures related to the CS-rich and PAA-rich moieties increased with increasing CNF content. A higher order of tensile strengths and moduli of the cured resins was SPE-CS≫SPE-CA>SPE-CE. The tensile strength and modulus of each sample were much improved by the addition of 3wt% CNF, while further addition of CNF caused a lowering of the strength and modulus. Nutzungsrecht: Copyright © 2016 Elsevier Ltd. All rights reserved. Enjoji, Motohiro oth Sakazume, Katsumi oth Ifuku, Shinsuke oth Enthalten in Carbohydrate polymers Barking, Essex : Applied Science Publ., 1981 144(2016), Seite 89-97 (DE-627)130549746 (DE-600)782631-X (DE-576)481341323 0144-8617 nnns volume:144 year:2016 pages:89-97 http://dx.doi.org/10.1016/j.carbpol.2016.02.033 Volltext http://www.ncbi.nlm.nih.gov/pubmed/27083797 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 58.34 AVZ 49.25 AVZ AR 144 2016 89-97 |
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10.1016/j.carbpol.2016.02.033 doi PQ20160719 (DE-627)OLC197790582X (DE-599)GBVOLC197790582X (PRQ)c1650-cfd0c54d564fbefce2cf17417a9b8b082c1ca589655fc78695bfab4d7d142ae0 (KEY)0110347420160000144000000089biobasedepoxychitinnanofibercompositescuredwithami DE-627 ger DE-627 rakwb eng 540 660 DNB 58.34 bkl 49.25 bkl Shibata, Mitsuhiro verfasserin aut Bio-based epoxy/chitin nanofiber composites cured with amine-type hardeners containing chitosan 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Sorbitol polyglycidyl ether (SPE) which is a bio-based water-soluble epoxy resin was cured with chitosan (CS) and/or a commercial water-soluble polyamidoamine- or polyetheramine-type epoxy hardener (PAA or PEA). Furthermore, biocomposites of the CS-cured SPE (CS-SPE) and CS/PAA- or CS/PEA-cured SPE (SPE-CA or SPE-CE) biocomposites with chitin nanofiber (CNF) were prepared by casting and compression molding methods, respectively. The curing reaction of epoxy and amino groups of the reactants was confirmed by the FT-IR spectral analysis. SPE-CS and SPE-CA were almost transparent films, while SPE-CE was opaque. Transparency of SPE-CS/CNF and SPE-CA/CNF became a little worse with increasing CNF content. The tanδ peak temperature of SPE-CS was higher than those of SPE-PAA and SPE-PEA. SPE-CA or SPE-CE exhibited two tanδ peak temperatures related to glass transitions of the CS-rich and PAA-rich or PEA-rich moieties. The tanδ peak temperatures related to the CS-rich and PAA-rich moieties increased with increasing CNF content. A higher order of tensile strengths and moduli of the cured resins was SPE-CS≫SPE-CA>SPE-CE. The tensile strength and modulus of each sample were much improved by the addition of 3wt% CNF, while further addition of CNF caused a lowering of the strength and modulus. Nutzungsrecht: Copyright © 2016 Elsevier Ltd. All rights reserved. Enjoji, Motohiro oth Sakazume, Katsumi oth Ifuku, Shinsuke oth Enthalten in Carbohydrate polymers Barking, Essex : Applied Science Publ., 1981 144(2016), Seite 89-97 (DE-627)130549746 (DE-600)782631-X (DE-576)481341323 0144-8617 nnns volume:144 year:2016 pages:89-97 http://dx.doi.org/10.1016/j.carbpol.2016.02.033 Volltext http://www.ncbi.nlm.nih.gov/pubmed/27083797 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 58.34 AVZ 49.25 AVZ AR 144 2016 89-97 |
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10.1016/j.carbpol.2016.02.033 doi PQ20160719 (DE-627)OLC197790582X (DE-599)GBVOLC197790582X (PRQ)c1650-cfd0c54d564fbefce2cf17417a9b8b082c1ca589655fc78695bfab4d7d142ae0 (KEY)0110347420160000144000000089biobasedepoxychitinnanofibercompositescuredwithami DE-627 ger DE-627 rakwb eng 540 660 DNB 58.34 bkl 49.25 bkl Shibata, Mitsuhiro verfasserin aut Bio-based epoxy/chitin nanofiber composites cured with amine-type hardeners containing chitosan 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Sorbitol polyglycidyl ether (SPE) which is a bio-based water-soluble epoxy resin was cured with chitosan (CS) and/or a commercial water-soluble polyamidoamine- or polyetheramine-type epoxy hardener (PAA or PEA). Furthermore, biocomposites of the CS-cured SPE (CS-SPE) and CS/PAA- or CS/PEA-cured SPE (SPE-CA or SPE-CE) biocomposites with chitin nanofiber (CNF) were prepared by casting and compression molding methods, respectively. The curing reaction of epoxy and amino groups of the reactants was confirmed by the FT-IR spectral analysis. SPE-CS and SPE-CA were almost transparent films, while SPE-CE was opaque. Transparency of SPE-CS/CNF and SPE-CA/CNF became a little worse with increasing CNF content. The tanδ peak temperature of SPE-CS was higher than those of SPE-PAA and SPE-PEA. SPE-CA or SPE-CE exhibited two tanδ peak temperatures related to glass transitions of the CS-rich and PAA-rich or PEA-rich moieties. The tanδ peak temperatures related to the CS-rich and PAA-rich moieties increased with increasing CNF content. A higher order of tensile strengths and moduli of the cured resins was SPE-CS≫SPE-CA>SPE-CE. The tensile strength and modulus of each sample were much improved by the addition of 3wt% CNF, while further addition of CNF caused a lowering of the strength and modulus. Nutzungsrecht: Copyright © 2016 Elsevier Ltd. All rights reserved. Enjoji, Motohiro oth Sakazume, Katsumi oth Ifuku, Shinsuke oth Enthalten in Carbohydrate polymers Barking, Essex : Applied Science Publ., 1981 144(2016), Seite 89-97 (DE-627)130549746 (DE-600)782631-X (DE-576)481341323 0144-8617 nnns volume:144 year:2016 pages:89-97 http://dx.doi.org/10.1016/j.carbpol.2016.02.033 Volltext http://www.ncbi.nlm.nih.gov/pubmed/27083797 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 58.34 AVZ 49.25 AVZ AR 144 2016 89-97 |
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Shibata, Mitsuhiro ddc 540 bkl 58.34 bkl 49.25 Bio-based epoxy/chitin nanofiber composites cured with amine-type hardeners containing chitosan |
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Bio-based epoxy/chitin nanofiber composites cured with amine-type hardeners containing chitosan |
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bio-based epoxy/chitin nanofiber composites cured with amine-type hardeners containing chitosan |
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Bio-based epoxy/chitin nanofiber composites cured with amine-type hardeners containing chitosan |
| abstract |
Sorbitol polyglycidyl ether (SPE) which is a bio-based water-soluble epoxy resin was cured with chitosan (CS) and/or a commercial water-soluble polyamidoamine- or polyetheramine-type epoxy hardener (PAA or PEA). Furthermore, biocomposites of the CS-cured SPE (CS-SPE) and CS/PAA- or CS/PEA-cured SPE (SPE-CA or SPE-CE) biocomposites with chitin nanofiber (CNF) were prepared by casting and compression molding methods, respectively. The curing reaction of epoxy and amino groups of the reactants was confirmed by the FT-IR spectral analysis. SPE-CS and SPE-CA were almost transparent films, while SPE-CE was opaque. Transparency of SPE-CS/CNF and SPE-CA/CNF became a little worse with increasing CNF content. The tanδ peak temperature of SPE-CS was higher than those of SPE-PAA and SPE-PEA. SPE-CA or SPE-CE exhibited two tanδ peak temperatures related to glass transitions of the CS-rich and PAA-rich or PEA-rich moieties. The tanδ peak temperatures related to the CS-rich and PAA-rich moieties increased with increasing CNF content. A higher order of tensile strengths and moduli of the cured resins was SPE-CS≫SPE-CA>SPE-CE. The tensile strength and modulus of each sample were much improved by the addition of 3wt% CNF, while further addition of CNF caused a lowering of the strength and modulus. |
| abstractGer |
Sorbitol polyglycidyl ether (SPE) which is a bio-based water-soluble epoxy resin was cured with chitosan (CS) and/or a commercial water-soluble polyamidoamine- or polyetheramine-type epoxy hardener (PAA or PEA). Furthermore, biocomposites of the CS-cured SPE (CS-SPE) and CS/PAA- or CS/PEA-cured SPE (SPE-CA or SPE-CE) biocomposites with chitin nanofiber (CNF) were prepared by casting and compression molding methods, respectively. The curing reaction of epoxy and amino groups of the reactants was confirmed by the FT-IR spectral analysis. SPE-CS and SPE-CA were almost transparent films, while SPE-CE was opaque. Transparency of SPE-CS/CNF and SPE-CA/CNF became a little worse with increasing CNF content. The tanδ peak temperature of SPE-CS was higher than those of SPE-PAA and SPE-PEA. SPE-CA or SPE-CE exhibited two tanδ peak temperatures related to glass transitions of the CS-rich and PAA-rich or PEA-rich moieties. The tanδ peak temperatures related to the CS-rich and PAA-rich moieties increased with increasing CNF content. A higher order of tensile strengths and moduli of the cured resins was SPE-CS≫SPE-CA>SPE-CE. The tensile strength and modulus of each sample were much improved by the addition of 3wt% CNF, while further addition of CNF caused a lowering of the strength and modulus. |
| abstract_unstemmed |
Sorbitol polyglycidyl ether (SPE) which is a bio-based water-soluble epoxy resin was cured with chitosan (CS) and/or a commercial water-soluble polyamidoamine- or polyetheramine-type epoxy hardener (PAA or PEA). Furthermore, biocomposites of the CS-cured SPE (CS-SPE) and CS/PAA- or CS/PEA-cured SPE (SPE-CA or SPE-CE) biocomposites with chitin nanofiber (CNF) were prepared by casting and compression molding methods, respectively. The curing reaction of epoxy and amino groups of the reactants was confirmed by the FT-IR spectral analysis. SPE-CS and SPE-CA were almost transparent films, while SPE-CE was opaque. Transparency of SPE-CS/CNF and SPE-CA/CNF became a little worse with increasing CNF content. The tanδ peak temperature of SPE-CS was higher than those of SPE-PAA and SPE-PEA. SPE-CA or SPE-CE exhibited two tanδ peak temperatures related to glass transitions of the CS-rich and PAA-rich or PEA-rich moieties. The tanδ peak temperatures related to the CS-rich and PAA-rich moieties increased with increasing CNF content. A higher order of tensile strengths and moduli of the cured resins was SPE-CS≫SPE-CA>SPE-CE. The tensile strength and modulus of each sample were much improved by the addition of 3wt% CNF, while further addition of CNF caused a lowering of the strength and modulus. |
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Bio-based epoxy/chitin nanofiber composites cured with amine-type hardeners containing chitosan |
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http://dx.doi.org/10.1016/j.carbpol.2016.02.033 http://www.ncbi.nlm.nih.gov/pubmed/27083797 |
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Enjoji, Motohiro Sakazume, Katsumi Ifuku, Shinsuke |
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