Novel insights on the physicochemical properties of eumelanins and their DMSO derivatives
The biopigment eumelanin, ubiquitous in flora and fauna, is made up of chemically heterogeneous macromolecules based on the 5,6‐dihydroxyindole and 5,6‐dihydroxyindole‐2‐carboxylic acid building blocks. The exciting possibility of designing eumelanin‐based technologies for bioelectronics and sustain...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Albano, Luiz GS [verfasserIn] |
|---|
| Format: |
Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2016 |
|---|
| Rechteinformationen: |
Nutzungsrecht: © 2016 Society of Chemical Industry |
|---|
| Schlagwörter: |
|---|
| Übergeordnetes Werk: |
Enthalten in: Polymer international - Chichester, West Sussex : Wiley InterScience, 1990, 65(2016), 11, Seite 1315-1322 |
|---|---|
| Übergeordnetes Werk: |
volume:65 ; year:2016 ; number:11 ; pages:1315-1322 |
| Links: |
|---|
| DOI / URN: |
10.1002/pi.5167 |
|---|
| Katalog-ID: |
OLC1984955306 |
|---|
| LEADER | 01000caa a2200265 4500 | ||
|---|---|---|---|
| 001 | OLC1984955306 | ||
| 003 | DE-627 | ||
| 005 | 20230516165607.0 | ||
| 007 | tu | ||
| 008 | 161202s2016 xx ||||| 00| ||eng c | ||
| 024 | 7 | |a 10.1002/pi.5167 |2 doi | |
| 028 | 5 | 2 | |a PQ20161201 |
| 035 | |a (DE-627)OLC1984955306 | ||
| 035 | |a (DE-599)GBVOLC1984955306 | ||
| 035 | |a (PRQ)p1899-e34417bbbbb1754b88da3b46149d9f862cb2f363e3ad1d092a940f7beb0fa5f73 | ||
| 035 | |a (KEY)0074273220160000065001101315novelinsightsonthephysicochemicalpropertiesofeumel | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 082 | 0 | 4 | |a 660 |a 670 |q DNB |
| 084 | |a 35.80 |2 bkl | ||
| 084 | |a 58.22 |2 bkl | ||
| 084 | |a 51.70 |2 bkl | ||
| 100 | 1 | |a Albano, Luiz GS |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Novel insights on the physicochemical properties of eumelanins and their DMSO derivatives |
| 264 | 1 | |c 2016 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ohne Hilfsmittel zu benutzen |b n |2 rdamedia | ||
| 338 | |a Band |b nc |2 rdacarrier | ||
| 520 | |a The biopigment eumelanin, ubiquitous in flora and fauna, is made up of chemically heterogeneous macromolecules based on the 5,6‐dihydroxyindole and 5,6‐dihydroxyindole‐2‐carboxylic acid building blocks. The exciting possibility of designing eumelanin‐based technologies for bioelectronics and sustainable electronics has to be properly assessed by gaining insights on the charge transfer and charge carrier transport in the pigment, preferably in film form, easily amenable to devices. In this work, we report a study on the electrochemical behaviour of films of eumelanin and its derivatives synthesized in dimethyl sulfoxide (DMSO eumelanins) in different aqueous electrolytes, with different chemical compositions and pH. DMSO eumelanins feature an improved solubility in the solvent DMSO, of relevance for processing purposes. The voltammetric currents are higher at relatively low pH (5.5), as expected considering the well‐established proton transport properties of the biopigment. Raman spectroscopy and atomic force microscopy performed on eumelanin films were combined with thermogravimetry with the aim of advancing knowledge on the molecular and supramolecular features of synthetic commercially available eumelanin, DMSO eumelanins as well as natural eumelanin (Sepia melanin). The results collected permit unprecedented insights on the physicochemical properties of eumelanin. © 2016 Society of Chemical Industry We gain insight on the molecular and supramolecular properties as well as electrochemical behaviour of eumelanins and their DMSO derivatives, to promote their use in emerging technologies. | ||
| 540 | |a Nutzungsrecht: © 2016 Society of Chemical Industry | ||
| 650 | 4 | |a Sepia melanin | |
| 650 | 4 | |a Raman spectroscopy | |
| 650 | 4 | |a eumelanin | |
| 650 | 4 | |a thermogravimetry | |
| 650 | 4 | |a electrochemistry | |
| 650 | 4 | |a DMSO eumelanin | |
| 700 | 1 | |a Di Mauro, Eduardo |4 oth | |
| 700 | 1 | |a Kumar, Prajwal |4 oth | |
| 700 | 1 | |a Cicoira, Fabio |4 oth | |
| 700 | 1 | |a Graeff, Carlos FO |4 oth | |
| 700 | 1 | |a Santato, Clara |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |t Polymer international |d Chichester, West Sussex : Wiley InterScience, 1990 |g 65(2016), 11, Seite 1315-1322 |w (DE-627)130921866 |w (DE-600)1053542-1 |w (DE-576)025008994 |x 0959-8103 |7 nnns |
| 773 | 1 | 8 | |g volume:65 |g year:2016 |g number:11 |g pages:1315-1322 |
| 856 | 4 | 1 | |u http://dx.doi.org/10.1002/pi.5167 |3 Volltext |
| 856 | 4 | 2 | |u http://onlinelibrary.wiley.com/doi/10.1002/pi.5167/abstract |
| 856 | 4 | 2 | |u http://search.proquest.com/docview/1823366553 |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a SYSFLAG_A | ||
| 912 | |a GBV_OLC | ||
| 912 | |a SSG-OLC-TEC | ||
| 912 | |a SSG-OLC-CHE | ||
| 912 | |a SSG-OLC-PHA | ||
| 912 | |a SSG-OLC-DE-84 | ||
| 912 | |a GBV_ILN_70 | ||
| 936 | b | k | |a 35.80 |q AVZ |
| 936 | b | k | |a 58.22 |q AVZ |
| 936 | b | k | |a 51.70 |q AVZ |
| 951 | |a AR | ||
| 952 | |d 65 |j 2016 |e 11 |h 1315-1322 | ||
| author_variant |
l g a lg lga |
|---|---|
| matchkey_str |
article:09598103:2016----::oeisgtotehscceiapoeteoemlnna |
| hierarchy_sort_str |
2016 |
| bklnumber |
35.80 58.22 51.70 |
| publishDate |
2016 |
| allfields |
10.1002/pi.5167 doi PQ20161201 (DE-627)OLC1984955306 (DE-599)GBVOLC1984955306 (PRQ)p1899-e34417bbbbb1754b88da3b46149d9f862cb2f363e3ad1d092a940f7beb0fa5f73 (KEY)0074273220160000065001101315novelinsightsonthephysicochemicalpropertiesofeumel DE-627 ger DE-627 rakwb eng 660 670 DNB 35.80 bkl 58.22 bkl 51.70 bkl Albano, Luiz GS verfasserin aut Novel insights on the physicochemical properties of eumelanins and their DMSO derivatives 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier The biopigment eumelanin, ubiquitous in flora and fauna, is made up of chemically heterogeneous macromolecules based on the 5,6‐dihydroxyindole and 5,6‐dihydroxyindole‐2‐carboxylic acid building blocks. The exciting possibility of designing eumelanin‐based technologies for bioelectronics and sustainable electronics has to be properly assessed by gaining insights on the charge transfer and charge carrier transport in the pigment, preferably in film form, easily amenable to devices. In this work, we report a study on the electrochemical behaviour of films of eumelanin and its derivatives synthesized in dimethyl sulfoxide (DMSO eumelanins) in different aqueous electrolytes, with different chemical compositions and pH. DMSO eumelanins feature an improved solubility in the solvent DMSO, of relevance for processing purposes. The voltammetric currents are higher at relatively low pH (5.5), as expected considering the well‐established proton transport properties of the biopigment. Raman spectroscopy and atomic force microscopy performed on eumelanin films were combined with thermogravimetry with the aim of advancing knowledge on the molecular and supramolecular features of synthetic commercially available eumelanin, DMSO eumelanins as well as natural eumelanin (Sepia melanin). The results collected permit unprecedented insights on the physicochemical properties of eumelanin. © 2016 Society of Chemical Industry We gain insight on the molecular and supramolecular properties as well as electrochemical behaviour of eumelanins and their DMSO derivatives, to promote their use in emerging technologies. Nutzungsrecht: © 2016 Society of Chemical Industry Sepia melanin Raman spectroscopy eumelanin thermogravimetry electrochemistry DMSO eumelanin Di Mauro, Eduardo oth Kumar, Prajwal oth Cicoira, Fabio oth Graeff, Carlos FO oth Santato, Clara oth Enthalten in Polymer international Chichester, West Sussex : Wiley InterScience, 1990 65(2016), 11, Seite 1315-1322 (DE-627)130921866 (DE-600)1053542-1 (DE-576)025008994 0959-8103 nnns volume:65 year:2016 number:11 pages:1315-1322 http://dx.doi.org/10.1002/pi.5167 Volltext http://onlinelibrary.wiley.com/doi/10.1002/pi.5167/abstract http://search.proquest.com/docview/1823366553 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 35.80 AVZ 58.22 AVZ 51.70 AVZ AR 65 2016 11 1315-1322 |
| spelling |
10.1002/pi.5167 doi PQ20161201 (DE-627)OLC1984955306 (DE-599)GBVOLC1984955306 (PRQ)p1899-e34417bbbbb1754b88da3b46149d9f862cb2f363e3ad1d092a940f7beb0fa5f73 (KEY)0074273220160000065001101315novelinsightsonthephysicochemicalpropertiesofeumel DE-627 ger DE-627 rakwb eng 660 670 DNB 35.80 bkl 58.22 bkl 51.70 bkl Albano, Luiz GS verfasserin aut Novel insights on the physicochemical properties of eumelanins and their DMSO derivatives 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier The biopigment eumelanin, ubiquitous in flora and fauna, is made up of chemically heterogeneous macromolecules based on the 5,6‐dihydroxyindole and 5,6‐dihydroxyindole‐2‐carboxylic acid building blocks. The exciting possibility of designing eumelanin‐based technologies for bioelectronics and sustainable electronics has to be properly assessed by gaining insights on the charge transfer and charge carrier transport in the pigment, preferably in film form, easily amenable to devices. In this work, we report a study on the electrochemical behaviour of films of eumelanin and its derivatives synthesized in dimethyl sulfoxide (DMSO eumelanins) in different aqueous electrolytes, with different chemical compositions and pH. DMSO eumelanins feature an improved solubility in the solvent DMSO, of relevance for processing purposes. The voltammetric currents are higher at relatively low pH (5.5), as expected considering the well‐established proton transport properties of the biopigment. Raman spectroscopy and atomic force microscopy performed on eumelanin films were combined with thermogravimetry with the aim of advancing knowledge on the molecular and supramolecular features of synthetic commercially available eumelanin, DMSO eumelanins as well as natural eumelanin (Sepia melanin). The results collected permit unprecedented insights on the physicochemical properties of eumelanin. © 2016 Society of Chemical Industry We gain insight on the molecular and supramolecular properties as well as electrochemical behaviour of eumelanins and their DMSO derivatives, to promote their use in emerging technologies. Nutzungsrecht: © 2016 Society of Chemical Industry Sepia melanin Raman spectroscopy eumelanin thermogravimetry electrochemistry DMSO eumelanin Di Mauro, Eduardo oth Kumar, Prajwal oth Cicoira, Fabio oth Graeff, Carlos FO oth Santato, Clara oth Enthalten in Polymer international Chichester, West Sussex : Wiley InterScience, 1990 65(2016), 11, Seite 1315-1322 (DE-627)130921866 (DE-600)1053542-1 (DE-576)025008994 0959-8103 nnns volume:65 year:2016 number:11 pages:1315-1322 http://dx.doi.org/10.1002/pi.5167 Volltext http://onlinelibrary.wiley.com/doi/10.1002/pi.5167/abstract http://search.proquest.com/docview/1823366553 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 35.80 AVZ 58.22 AVZ 51.70 AVZ AR 65 2016 11 1315-1322 |
| allfields_unstemmed |
10.1002/pi.5167 doi PQ20161201 (DE-627)OLC1984955306 (DE-599)GBVOLC1984955306 (PRQ)p1899-e34417bbbbb1754b88da3b46149d9f862cb2f363e3ad1d092a940f7beb0fa5f73 (KEY)0074273220160000065001101315novelinsightsonthephysicochemicalpropertiesofeumel DE-627 ger DE-627 rakwb eng 660 670 DNB 35.80 bkl 58.22 bkl 51.70 bkl Albano, Luiz GS verfasserin aut Novel insights on the physicochemical properties of eumelanins and their DMSO derivatives 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier The biopigment eumelanin, ubiquitous in flora and fauna, is made up of chemically heterogeneous macromolecules based on the 5,6‐dihydroxyindole and 5,6‐dihydroxyindole‐2‐carboxylic acid building blocks. The exciting possibility of designing eumelanin‐based technologies for bioelectronics and sustainable electronics has to be properly assessed by gaining insights on the charge transfer and charge carrier transport in the pigment, preferably in film form, easily amenable to devices. In this work, we report a study on the electrochemical behaviour of films of eumelanin and its derivatives synthesized in dimethyl sulfoxide (DMSO eumelanins) in different aqueous electrolytes, with different chemical compositions and pH. DMSO eumelanins feature an improved solubility in the solvent DMSO, of relevance for processing purposes. The voltammetric currents are higher at relatively low pH (5.5), as expected considering the well‐established proton transport properties of the biopigment. Raman spectroscopy and atomic force microscopy performed on eumelanin films were combined with thermogravimetry with the aim of advancing knowledge on the molecular and supramolecular features of synthetic commercially available eumelanin, DMSO eumelanins as well as natural eumelanin (Sepia melanin). The results collected permit unprecedented insights on the physicochemical properties of eumelanin. © 2016 Society of Chemical Industry We gain insight on the molecular and supramolecular properties as well as electrochemical behaviour of eumelanins and their DMSO derivatives, to promote their use in emerging technologies. Nutzungsrecht: © 2016 Society of Chemical Industry Sepia melanin Raman spectroscopy eumelanin thermogravimetry electrochemistry DMSO eumelanin Di Mauro, Eduardo oth Kumar, Prajwal oth Cicoira, Fabio oth Graeff, Carlos FO oth Santato, Clara oth Enthalten in Polymer international Chichester, West Sussex : Wiley InterScience, 1990 65(2016), 11, Seite 1315-1322 (DE-627)130921866 (DE-600)1053542-1 (DE-576)025008994 0959-8103 nnns volume:65 year:2016 number:11 pages:1315-1322 http://dx.doi.org/10.1002/pi.5167 Volltext http://onlinelibrary.wiley.com/doi/10.1002/pi.5167/abstract http://search.proquest.com/docview/1823366553 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 35.80 AVZ 58.22 AVZ 51.70 AVZ AR 65 2016 11 1315-1322 |
| allfieldsGer |
10.1002/pi.5167 doi PQ20161201 (DE-627)OLC1984955306 (DE-599)GBVOLC1984955306 (PRQ)p1899-e34417bbbbb1754b88da3b46149d9f862cb2f363e3ad1d092a940f7beb0fa5f73 (KEY)0074273220160000065001101315novelinsightsonthephysicochemicalpropertiesofeumel DE-627 ger DE-627 rakwb eng 660 670 DNB 35.80 bkl 58.22 bkl 51.70 bkl Albano, Luiz GS verfasserin aut Novel insights on the physicochemical properties of eumelanins and their DMSO derivatives 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier The biopigment eumelanin, ubiquitous in flora and fauna, is made up of chemically heterogeneous macromolecules based on the 5,6‐dihydroxyindole and 5,6‐dihydroxyindole‐2‐carboxylic acid building blocks. The exciting possibility of designing eumelanin‐based technologies for bioelectronics and sustainable electronics has to be properly assessed by gaining insights on the charge transfer and charge carrier transport in the pigment, preferably in film form, easily amenable to devices. In this work, we report a study on the electrochemical behaviour of films of eumelanin and its derivatives synthesized in dimethyl sulfoxide (DMSO eumelanins) in different aqueous electrolytes, with different chemical compositions and pH. DMSO eumelanins feature an improved solubility in the solvent DMSO, of relevance for processing purposes. The voltammetric currents are higher at relatively low pH (5.5), as expected considering the well‐established proton transport properties of the biopigment. Raman spectroscopy and atomic force microscopy performed on eumelanin films were combined with thermogravimetry with the aim of advancing knowledge on the molecular and supramolecular features of synthetic commercially available eumelanin, DMSO eumelanins as well as natural eumelanin (Sepia melanin). The results collected permit unprecedented insights on the physicochemical properties of eumelanin. © 2016 Society of Chemical Industry We gain insight on the molecular and supramolecular properties as well as electrochemical behaviour of eumelanins and their DMSO derivatives, to promote their use in emerging technologies. Nutzungsrecht: © 2016 Society of Chemical Industry Sepia melanin Raman spectroscopy eumelanin thermogravimetry electrochemistry DMSO eumelanin Di Mauro, Eduardo oth Kumar, Prajwal oth Cicoira, Fabio oth Graeff, Carlos FO oth Santato, Clara oth Enthalten in Polymer international Chichester, West Sussex : Wiley InterScience, 1990 65(2016), 11, Seite 1315-1322 (DE-627)130921866 (DE-600)1053542-1 (DE-576)025008994 0959-8103 nnns volume:65 year:2016 number:11 pages:1315-1322 http://dx.doi.org/10.1002/pi.5167 Volltext http://onlinelibrary.wiley.com/doi/10.1002/pi.5167/abstract http://search.proquest.com/docview/1823366553 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 35.80 AVZ 58.22 AVZ 51.70 AVZ AR 65 2016 11 1315-1322 |
| allfieldsSound |
10.1002/pi.5167 doi PQ20161201 (DE-627)OLC1984955306 (DE-599)GBVOLC1984955306 (PRQ)p1899-e34417bbbbb1754b88da3b46149d9f862cb2f363e3ad1d092a940f7beb0fa5f73 (KEY)0074273220160000065001101315novelinsightsonthephysicochemicalpropertiesofeumel DE-627 ger DE-627 rakwb eng 660 670 DNB 35.80 bkl 58.22 bkl 51.70 bkl Albano, Luiz GS verfasserin aut Novel insights on the physicochemical properties of eumelanins and their DMSO derivatives 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier The biopigment eumelanin, ubiquitous in flora and fauna, is made up of chemically heterogeneous macromolecules based on the 5,6‐dihydroxyindole and 5,6‐dihydroxyindole‐2‐carboxylic acid building blocks. The exciting possibility of designing eumelanin‐based technologies for bioelectronics and sustainable electronics has to be properly assessed by gaining insights on the charge transfer and charge carrier transport in the pigment, preferably in film form, easily amenable to devices. In this work, we report a study on the electrochemical behaviour of films of eumelanin and its derivatives synthesized in dimethyl sulfoxide (DMSO eumelanins) in different aqueous electrolytes, with different chemical compositions and pH. DMSO eumelanins feature an improved solubility in the solvent DMSO, of relevance for processing purposes. The voltammetric currents are higher at relatively low pH (5.5), as expected considering the well‐established proton transport properties of the biopigment. Raman spectroscopy and atomic force microscopy performed on eumelanin films were combined with thermogravimetry with the aim of advancing knowledge on the molecular and supramolecular features of synthetic commercially available eumelanin, DMSO eumelanins as well as natural eumelanin (Sepia melanin). The results collected permit unprecedented insights on the physicochemical properties of eumelanin. © 2016 Society of Chemical Industry We gain insight on the molecular and supramolecular properties as well as electrochemical behaviour of eumelanins and their DMSO derivatives, to promote their use in emerging technologies. Nutzungsrecht: © 2016 Society of Chemical Industry Sepia melanin Raman spectroscopy eumelanin thermogravimetry electrochemistry DMSO eumelanin Di Mauro, Eduardo oth Kumar, Prajwal oth Cicoira, Fabio oth Graeff, Carlos FO oth Santato, Clara oth Enthalten in Polymer international Chichester, West Sussex : Wiley InterScience, 1990 65(2016), 11, Seite 1315-1322 (DE-627)130921866 (DE-600)1053542-1 (DE-576)025008994 0959-8103 nnns volume:65 year:2016 number:11 pages:1315-1322 http://dx.doi.org/10.1002/pi.5167 Volltext http://onlinelibrary.wiley.com/doi/10.1002/pi.5167/abstract http://search.proquest.com/docview/1823366553 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 35.80 AVZ 58.22 AVZ 51.70 AVZ AR 65 2016 11 1315-1322 |
| language |
English |
| source |
Enthalten in Polymer international 65(2016), 11, Seite 1315-1322 volume:65 year:2016 number:11 pages:1315-1322 |
| sourceStr |
Enthalten in Polymer international 65(2016), 11, Seite 1315-1322 volume:65 year:2016 number:11 pages:1315-1322 |
| format_phy_str_mv |
Article |
| institution |
findex.gbv.de |
| topic_facet |
Sepia melanin Raman spectroscopy eumelanin thermogravimetry electrochemistry DMSO eumelanin |
| dewey-raw |
660 |
| isfreeaccess_bool |
false |
| container_title |
Polymer international |
| authorswithroles_txt_mv |
Albano, Luiz GS @@aut@@ Di Mauro, Eduardo @@oth@@ Kumar, Prajwal @@oth@@ Cicoira, Fabio @@oth@@ Graeff, Carlos FO @@oth@@ Santato, Clara @@oth@@ |
| publishDateDaySort_date |
2016-01-01T00:00:00Z |
| hierarchy_top_id |
130921866 |
| dewey-sort |
3660 |
| id |
OLC1984955306 |
| language_de |
englisch |
| fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a2200265 4500</leader><controlfield tag="001">OLC1984955306</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230516165607.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">161202s2016 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1002/pi.5167</subfield><subfield code="2">doi</subfield></datafield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">PQ20161201</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC1984955306</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVOLC1984955306</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(PRQ)p1899-e34417bbbbb1754b88da3b46149d9f862cb2f363e3ad1d092a940f7beb0fa5f73</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(KEY)0074273220160000065001101315novelinsightsonthephysicochemicalpropertiesofeumel</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="a">670</subfield><subfield code="q">DNB</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.80</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">58.22</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">51.70</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Albano, Luiz GS</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Novel insights on the physicochemical properties of eumelanins and their DMSO derivatives</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2016</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The biopigment eumelanin, ubiquitous in flora and fauna, is made up of chemically heterogeneous macromolecules based on the 5,6‐dihydroxyindole and 5,6‐dihydroxyindole‐2‐carboxylic acid building blocks. The exciting possibility of designing eumelanin‐based technologies for bioelectronics and sustainable electronics has to be properly assessed by gaining insights on the charge transfer and charge carrier transport in the pigment, preferably in film form, easily amenable to devices. In this work, we report a study on the electrochemical behaviour of films of eumelanin and its derivatives synthesized in dimethyl sulfoxide (DMSO eumelanins) in different aqueous electrolytes, with different chemical compositions and pH. DMSO eumelanins feature an improved solubility in the solvent DMSO, of relevance for processing purposes. The voltammetric currents are higher at relatively low pH (5.5), as expected considering the well‐established proton transport properties of the biopigment. Raman spectroscopy and atomic force microscopy performed on eumelanin films were combined with thermogravimetry with the aim of advancing knowledge on the molecular and supramolecular features of synthetic commercially available eumelanin, DMSO eumelanins as well as natural eumelanin (Sepia melanin). The results collected permit unprecedented insights on the physicochemical properties of eumelanin. © 2016 Society of Chemical Industry We gain insight on the molecular and supramolecular properties as well as electrochemical behaviour of eumelanins and their DMSO derivatives, to promote their use in emerging technologies.</subfield></datafield><datafield tag="540" ind1=" " ind2=" "><subfield code="a">Nutzungsrecht: © 2016 Society of Chemical Industry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Sepia melanin</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Raman spectroscopy</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">eumelanin</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">thermogravimetry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">electrochemistry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">DMSO eumelanin</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Di Mauro, Eduardo</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kumar, Prajwal</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Cicoira, Fabio</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Graeff, Carlos FO</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Santato, Clara</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Polymer international</subfield><subfield code="d">Chichester, West Sussex : Wiley InterScience, 1990</subfield><subfield code="g">65(2016), 11, Seite 1315-1322</subfield><subfield code="w">(DE-627)130921866</subfield><subfield code="w">(DE-600)1053542-1</subfield><subfield code="w">(DE-576)025008994</subfield><subfield code="x">0959-8103</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:65</subfield><subfield code="g">year:2016</subfield><subfield code="g">number:11</subfield><subfield code="g">pages:1315-1322</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">http://dx.doi.org/10.1002/pi.5167</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">http://onlinelibrary.wiley.com/doi/10.1002/pi.5167/abstract</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">http://search.proquest.com/docview/1823366553</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-DE-84</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">35.80</subfield><subfield code="q">AVZ</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">58.22</subfield><subfield code="q">AVZ</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">51.70</subfield><subfield code="q">AVZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">65</subfield><subfield code="j">2016</subfield><subfield code="e">11</subfield><subfield code="h">1315-1322</subfield></datafield></record></collection>
|
| author |
Albano, Luiz GS |
| spellingShingle |
Albano, Luiz GS ddc 660 bkl 35.80 bkl 58.22 bkl 51.70 misc Sepia melanin misc Raman spectroscopy misc eumelanin misc thermogravimetry misc electrochemistry misc DMSO eumelanin Novel insights on the physicochemical properties of eumelanins and their DMSO derivatives |
| authorStr |
Albano, Luiz GS |
| ppnlink_with_tag_str_mv |
@@773@@(DE-627)130921866 |
| format |
Article |
| dewey-ones |
660 - Chemical engineering 670 - Manufacturing |
| delete_txt_mv |
keep |
| author_role |
aut |
| collection |
OLC |
| remote_str |
false |
| illustrated |
Not Illustrated |
| issn |
0959-8103 |
| topic_title |
660 670 DNB 35.80 bkl 58.22 bkl 51.70 bkl Novel insights on the physicochemical properties of eumelanins and their DMSO derivatives Sepia melanin Raman spectroscopy eumelanin thermogravimetry electrochemistry DMSO eumelanin |
| topic |
ddc 660 bkl 35.80 bkl 58.22 bkl 51.70 misc Sepia melanin misc Raman spectroscopy misc eumelanin misc thermogravimetry misc electrochemistry misc DMSO eumelanin |
| topic_unstemmed |
ddc 660 bkl 35.80 bkl 58.22 bkl 51.70 misc Sepia melanin misc Raman spectroscopy misc eumelanin misc thermogravimetry misc electrochemistry misc DMSO eumelanin |
| topic_browse |
ddc 660 bkl 35.80 bkl 58.22 bkl 51.70 misc Sepia melanin misc Raman spectroscopy misc eumelanin misc thermogravimetry misc electrochemistry misc DMSO eumelanin |
| format_facet |
Aufsätze Gedruckte Aufsätze |
| format_main_str_mv |
Text Zeitschrift/Artikel |
| carriertype_str_mv |
nc |
| author2_variant |
m e d me med p k pk f c fc c f g cf cfg c s cs |
| hierarchy_parent_title |
Polymer international |
| hierarchy_parent_id |
130921866 |
| dewey-tens |
660 - Chemical engineering 670 - Manufacturing |
| hierarchy_top_title |
Polymer international |
| isfreeaccess_txt |
false |
| familylinks_str_mv |
(DE-627)130921866 (DE-600)1053542-1 (DE-576)025008994 |
| title |
Novel insights on the physicochemical properties of eumelanins and their DMSO derivatives |
| ctrlnum |
(DE-627)OLC1984955306 (DE-599)GBVOLC1984955306 (PRQ)p1899-e34417bbbbb1754b88da3b46149d9f862cb2f363e3ad1d092a940f7beb0fa5f73 (KEY)0074273220160000065001101315novelinsightsonthephysicochemicalpropertiesofeumel |
| title_full |
Novel insights on the physicochemical properties of eumelanins and their DMSO derivatives |
| author_sort |
Albano, Luiz GS |
| journal |
Polymer international |
| journalStr |
Polymer international |
| lang_code |
eng |
| isOA_bool |
false |
| dewey-hundreds |
600 - Technology |
| recordtype |
marc |
| publishDateSort |
2016 |
| contenttype_str_mv |
txt |
| container_start_page |
1315 |
| author_browse |
Albano, Luiz GS |
| container_volume |
65 |
| class |
660 670 DNB 35.80 bkl 58.22 bkl 51.70 bkl |
| format_se |
Aufsätze |
| author-letter |
Albano, Luiz GS |
| doi_str_mv |
10.1002/pi.5167 |
| dewey-full |
660 670 |
| title_sort |
novel insights on the physicochemical properties of eumelanins and their dmso derivatives |
| title_auth |
Novel insights on the physicochemical properties of eumelanins and their DMSO derivatives |
| abstract |
The biopigment eumelanin, ubiquitous in flora and fauna, is made up of chemically heterogeneous macromolecules based on the 5,6‐dihydroxyindole and 5,6‐dihydroxyindole‐2‐carboxylic acid building blocks. The exciting possibility of designing eumelanin‐based technologies for bioelectronics and sustainable electronics has to be properly assessed by gaining insights on the charge transfer and charge carrier transport in the pigment, preferably in film form, easily amenable to devices. In this work, we report a study on the electrochemical behaviour of films of eumelanin and its derivatives synthesized in dimethyl sulfoxide (DMSO eumelanins) in different aqueous electrolytes, with different chemical compositions and pH. DMSO eumelanins feature an improved solubility in the solvent DMSO, of relevance for processing purposes. The voltammetric currents are higher at relatively low pH (5.5), as expected considering the well‐established proton transport properties of the biopigment. Raman spectroscopy and atomic force microscopy performed on eumelanin films were combined with thermogravimetry with the aim of advancing knowledge on the molecular and supramolecular features of synthetic commercially available eumelanin, DMSO eumelanins as well as natural eumelanin (Sepia melanin). The results collected permit unprecedented insights on the physicochemical properties of eumelanin. © 2016 Society of Chemical Industry We gain insight on the molecular and supramolecular properties as well as electrochemical behaviour of eumelanins and their DMSO derivatives, to promote their use in emerging technologies. |
| abstractGer |
The biopigment eumelanin, ubiquitous in flora and fauna, is made up of chemically heterogeneous macromolecules based on the 5,6‐dihydroxyindole and 5,6‐dihydroxyindole‐2‐carboxylic acid building blocks. The exciting possibility of designing eumelanin‐based technologies for bioelectronics and sustainable electronics has to be properly assessed by gaining insights on the charge transfer and charge carrier transport in the pigment, preferably in film form, easily amenable to devices. In this work, we report a study on the electrochemical behaviour of films of eumelanin and its derivatives synthesized in dimethyl sulfoxide (DMSO eumelanins) in different aqueous electrolytes, with different chemical compositions and pH. DMSO eumelanins feature an improved solubility in the solvent DMSO, of relevance for processing purposes. The voltammetric currents are higher at relatively low pH (5.5), as expected considering the well‐established proton transport properties of the biopigment. Raman spectroscopy and atomic force microscopy performed on eumelanin films were combined with thermogravimetry with the aim of advancing knowledge on the molecular and supramolecular features of synthetic commercially available eumelanin, DMSO eumelanins as well as natural eumelanin (Sepia melanin). The results collected permit unprecedented insights on the physicochemical properties of eumelanin. © 2016 Society of Chemical Industry We gain insight on the molecular and supramolecular properties as well as electrochemical behaviour of eumelanins and their DMSO derivatives, to promote their use in emerging technologies. |
| abstract_unstemmed |
The biopigment eumelanin, ubiquitous in flora and fauna, is made up of chemically heterogeneous macromolecules based on the 5,6‐dihydroxyindole and 5,6‐dihydroxyindole‐2‐carboxylic acid building blocks. The exciting possibility of designing eumelanin‐based technologies for bioelectronics and sustainable electronics has to be properly assessed by gaining insights on the charge transfer and charge carrier transport in the pigment, preferably in film form, easily amenable to devices. In this work, we report a study on the electrochemical behaviour of films of eumelanin and its derivatives synthesized in dimethyl sulfoxide (DMSO eumelanins) in different aqueous electrolytes, with different chemical compositions and pH. DMSO eumelanins feature an improved solubility in the solvent DMSO, of relevance for processing purposes. The voltammetric currents are higher at relatively low pH (5.5), as expected considering the well‐established proton transport properties of the biopigment. Raman spectroscopy and atomic force microscopy performed on eumelanin films were combined with thermogravimetry with the aim of advancing knowledge on the molecular and supramolecular features of synthetic commercially available eumelanin, DMSO eumelanins as well as natural eumelanin (Sepia melanin). The results collected permit unprecedented insights on the physicochemical properties of eumelanin. © 2016 Society of Chemical Industry We gain insight on the molecular and supramolecular properties as well as electrochemical behaviour of eumelanins and their DMSO derivatives, to promote their use in emerging technologies. |
| collection_details |
GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 |
| container_issue |
11 |
| title_short |
Novel insights on the physicochemical properties of eumelanins and their DMSO derivatives |
| url |
http://dx.doi.org/10.1002/pi.5167 http://onlinelibrary.wiley.com/doi/10.1002/pi.5167/abstract http://search.proquest.com/docview/1823366553 |
| remote_bool |
false |
| author2 |
Di Mauro, Eduardo Kumar, Prajwal Cicoira, Fabio Graeff, Carlos FO Santato, Clara |
| author2Str |
Di Mauro, Eduardo Kumar, Prajwal Cicoira, Fabio Graeff, Carlos FO Santato, Clara |
| ppnlink |
130921866 |
| mediatype_str_mv |
n |
| isOA_txt |
false |
| hochschulschrift_bool |
false |
| author2_role |
oth oth oth oth oth |
| doi_str |
10.1002/pi.5167 |
| up_date |
2024-07-04T01:56:34.466Z |
| _version_ |
1803611741321428992 |
| fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a2200265 4500</leader><controlfield tag="001">OLC1984955306</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230516165607.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">161202s2016 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1002/pi.5167</subfield><subfield code="2">doi</subfield></datafield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">PQ20161201</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC1984955306</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVOLC1984955306</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(PRQ)p1899-e34417bbbbb1754b88da3b46149d9f862cb2f363e3ad1d092a940f7beb0fa5f73</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(KEY)0074273220160000065001101315novelinsightsonthephysicochemicalpropertiesofeumel</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="a">670</subfield><subfield code="q">DNB</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">35.80</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">58.22</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">51.70</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Albano, Luiz GS</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Novel insights on the physicochemical properties of eumelanins and their DMSO derivatives</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2016</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The biopigment eumelanin, ubiquitous in flora and fauna, is made up of chemically heterogeneous macromolecules based on the 5,6‐dihydroxyindole and 5,6‐dihydroxyindole‐2‐carboxylic acid building blocks. The exciting possibility of designing eumelanin‐based technologies for bioelectronics and sustainable electronics has to be properly assessed by gaining insights on the charge transfer and charge carrier transport in the pigment, preferably in film form, easily amenable to devices. In this work, we report a study on the electrochemical behaviour of films of eumelanin and its derivatives synthesized in dimethyl sulfoxide (DMSO eumelanins) in different aqueous electrolytes, with different chemical compositions and pH. DMSO eumelanins feature an improved solubility in the solvent DMSO, of relevance for processing purposes. The voltammetric currents are higher at relatively low pH (5.5), as expected considering the well‐established proton transport properties of the biopigment. Raman spectroscopy and atomic force microscopy performed on eumelanin films were combined with thermogravimetry with the aim of advancing knowledge on the molecular and supramolecular features of synthetic commercially available eumelanin, DMSO eumelanins as well as natural eumelanin (Sepia melanin). The results collected permit unprecedented insights on the physicochemical properties of eumelanin. © 2016 Society of Chemical Industry We gain insight on the molecular and supramolecular properties as well as electrochemical behaviour of eumelanins and their DMSO derivatives, to promote their use in emerging technologies.</subfield></datafield><datafield tag="540" ind1=" " ind2=" "><subfield code="a">Nutzungsrecht: © 2016 Society of Chemical Industry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Sepia melanin</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Raman spectroscopy</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">eumelanin</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">thermogravimetry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">electrochemistry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">DMSO eumelanin</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Di Mauro, Eduardo</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kumar, Prajwal</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Cicoira, Fabio</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Graeff, Carlos FO</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Santato, Clara</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Polymer international</subfield><subfield code="d">Chichester, West Sussex : Wiley InterScience, 1990</subfield><subfield code="g">65(2016), 11, Seite 1315-1322</subfield><subfield code="w">(DE-627)130921866</subfield><subfield code="w">(DE-600)1053542-1</subfield><subfield code="w">(DE-576)025008994</subfield><subfield code="x">0959-8103</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:65</subfield><subfield code="g">year:2016</subfield><subfield code="g">number:11</subfield><subfield code="g">pages:1315-1322</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">http://dx.doi.org/10.1002/pi.5167</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">http://onlinelibrary.wiley.com/doi/10.1002/pi.5167/abstract</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">http://search.proquest.com/docview/1823366553</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-DE-84</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">35.80</subfield><subfield code="q">AVZ</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">58.22</subfield><subfield code="q">AVZ</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">51.70</subfield><subfield code="q">AVZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">65</subfield><subfield code="j">2016</subfield><subfield code="e">11</subfield><subfield code="h">1315-1322</subfield></datafield></record></collection>
|
| score |
7.4002047 |