Ambient observations of hygroscopic growth factor and f(RH) below 1: Case studies from surface and airborne measurements
This study reports a detailed set of ambient observations of optical/physical shrinking of particles from exposure to water vapor with consistency across different instruments and regions. Data have been utilized from (i) a shipboard humidified tandem differential mobility analyzer during the Easter...
Ausführliche Beschreibung
Autor*in: |
Taylor Shingler [verfasserIn] |
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Format: |
Artikel |
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Sprache: |
Englisch |
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2016 |
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Übergeordnetes Werk: |
Enthalten in: Journal of geophysical research / D - Washington, DC : Union, 1984, 121(2016), 22 |
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Übergeordnetes Werk: |
volume:121 ; year:2016 ; number:22 |
Links: |
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DOI / URN: |
10.1002/2016JD025471 |
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Katalog-ID: |
OLC1988774624 |
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520 | |a This study reports a detailed set of ambient observations of optical/physical shrinking of particles from exposure to water vapor with consistency across different instruments and regions. Data have been utilized from (i) a shipboard humidified tandem differential mobility analyzer during the Eastern Pacific Emitted Aerosol Cloud Experiment in 2011, (ii) multiple instruments on the NASA DC-8 research aircraft during the Studies of Emissions, Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys in 2013, and (iii) the Differential Aerosol Sizing and Hygroscopicity Spectrometer Probe during ambient measurements in Tucson, Arizona, during summer 2014 and winter 2015. Hygroscopic growth factor (ratio of humidified-to-dry diameter, GF=Dp,wet/Dp,dry) and f(RH) (ratio of humidified-to-dry scattering coefficients) values below 1 were observed across the range of relative humidity (RH) investigated (75-95%). A commonality of observations of GF and f(RH) below 1 in these experiments was the presence of particles enriched with carbonaceous matter, especially from biomass burning. Evidence of externally mixed aerosol, and thus multiple GFs with at least one GF<1, was observed concurrently with f(RH)<1 during smoke periods. Possible mechanisms responsible for observed shrinkage are discussed and include particle restructuring, volatilization effects, and refractive index modifications due to aqueous processing resulting in optical size modification. To further investigate ambient observations of GFs and f(RH) values less than 1, it is recommended to add an optional prehumidification bypass module to hygroscopicity instruments, to preemptively collapse particles prior to controlled RH measurements. Key Points Observations are reported for growth factor (GF) and f(RH) values below 1 in multiple regions using three instruments GF and f(RH) values less than 1 are observed in biomass burning plumes, organic-rich particles, and wintertime in an urban area f(RH) increases as a function of effective particle density with the majority of values below 1 coincident with density <1.2gcm-3 | ||
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700 | 0 | |a Anne E Perring |4 oth | |
700 | 0 | |a Andreas Beyersdorf |4 oth | |
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700 | 0 | |a Pedro Campuzano-Jost |4 oth | |
700 | 0 | |a Tomas Mikoviny |4 oth | |
700 | 0 | |a Armin Wisthaler |4 oth | |
700 | 0 | |a Lynn M Russell |4 oth | |
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10.1002/2016JD025471 doi PQ20170206 (DE-627)OLC1988774624 (DE-599)GBVOLC1988774624 (PRQ)p1170-9a9d0d141a68778122b1dcb1a202ece2a987782129310c939814200507efd47f0 (KEY)0137985220160000121002200000ambientobservationsofhygroscopicgrowthfactorandfrh DE-627 ger DE-627 rakwb eng 550 DNB Taylor Shingler verfasserin aut Ambient observations of hygroscopic growth factor and f(RH) below 1: Case studies from surface and airborne measurements 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier This study reports a detailed set of ambient observations of optical/physical shrinking of particles from exposure to water vapor with consistency across different instruments and regions. Data have been utilized from (i) a shipboard humidified tandem differential mobility analyzer during the Eastern Pacific Emitted Aerosol Cloud Experiment in 2011, (ii) multiple instruments on the NASA DC-8 research aircraft during the Studies of Emissions, Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys in 2013, and (iii) the Differential Aerosol Sizing and Hygroscopicity Spectrometer Probe during ambient measurements in Tucson, Arizona, during summer 2014 and winter 2015. Hygroscopic growth factor (ratio of humidified-to-dry diameter, GF=Dp,wet/Dp,dry) and f(RH) (ratio of humidified-to-dry scattering coefficients) values below 1 were observed across the range of relative humidity (RH) investigated (75-95%). A commonality of observations of GF and f(RH) below 1 in these experiments was the presence of particles enriched with carbonaceous matter, especially from biomass burning. Evidence of externally mixed aerosol, and thus multiple GFs with at least one GF<1, was observed concurrently with f(RH)<1 during smoke periods. Possible mechanisms responsible for observed shrinkage are discussed and include particle restructuring, volatilization effects, and refractive index modifications due to aqueous processing resulting in optical size modification. To further investigate ambient observations of GFs and f(RH) values less than 1, it is recommended to add an optional prehumidification bypass module to hygroscopicity instruments, to preemptively collapse particles prior to controlled RH measurements. Key Points Observations are reported for growth factor (GF) and f(RH) values below 1 in multiple regions using three instruments GF and f(RH) values less than 1 are observed in biomass burning plumes, organic-rich particles, and wintertime in an urban area f(RH) increases as a function of effective particle density with the majority of values below 1 coincident with density <1.2gcm-3 Studies Growth factors Armin Sorooshian oth Amber Ortega oth Ewan Crosbie oth Anna Wonaschutz oth Anne E Perring oth Andreas Beyersdorf oth Luke Ziemba oth Jose L Jimenez oth Pedro Campuzano-Jost oth Tomas Mikoviny oth Armin Wisthaler oth Lynn M Russell oth Enthalten in Journal of geophysical research / D Washington, DC : Union, 1984 121(2016), 22 (DE-627)130444391 (DE-600)710256-2 (DE-576)015978818 2169-897X nnns volume:121 year:2016 number:22 http://dx.doi.org/10.1002/2016JD025471 Volltext http://search.proquest.com/docview/1847915132 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-GEO SSG-OPC-GGO SSG-OPC-GEO GBV_ILN_62 GBV_ILN_154 AR 121 2016 22 |
spelling |
10.1002/2016JD025471 doi PQ20170206 (DE-627)OLC1988774624 (DE-599)GBVOLC1988774624 (PRQ)p1170-9a9d0d141a68778122b1dcb1a202ece2a987782129310c939814200507efd47f0 (KEY)0137985220160000121002200000ambientobservationsofhygroscopicgrowthfactorandfrh DE-627 ger DE-627 rakwb eng 550 DNB Taylor Shingler verfasserin aut Ambient observations of hygroscopic growth factor and f(RH) below 1: Case studies from surface and airborne measurements 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier This study reports a detailed set of ambient observations of optical/physical shrinking of particles from exposure to water vapor with consistency across different instruments and regions. Data have been utilized from (i) a shipboard humidified tandem differential mobility analyzer during the Eastern Pacific Emitted Aerosol Cloud Experiment in 2011, (ii) multiple instruments on the NASA DC-8 research aircraft during the Studies of Emissions, Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys in 2013, and (iii) the Differential Aerosol Sizing and Hygroscopicity Spectrometer Probe during ambient measurements in Tucson, Arizona, during summer 2014 and winter 2015. Hygroscopic growth factor (ratio of humidified-to-dry diameter, GF=Dp,wet/Dp,dry) and f(RH) (ratio of humidified-to-dry scattering coefficients) values below 1 were observed across the range of relative humidity (RH) investigated (75-95%). A commonality of observations of GF and f(RH) below 1 in these experiments was the presence of particles enriched with carbonaceous matter, especially from biomass burning. Evidence of externally mixed aerosol, and thus multiple GFs with at least one GF<1, was observed concurrently with f(RH)<1 during smoke periods. Possible mechanisms responsible for observed shrinkage are discussed and include particle restructuring, volatilization effects, and refractive index modifications due to aqueous processing resulting in optical size modification. To further investigate ambient observations of GFs and f(RH) values less than 1, it is recommended to add an optional prehumidification bypass module to hygroscopicity instruments, to preemptively collapse particles prior to controlled RH measurements. Key Points Observations are reported for growth factor (GF) and f(RH) values below 1 in multiple regions using three instruments GF and f(RH) values less than 1 are observed in biomass burning plumes, organic-rich particles, and wintertime in an urban area f(RH) increases as a function of effective particle density with the majority of values below 1 coincident with density <1.2gcm-3 Studies Growth factors Armin Sorooshian oth Amber Ortega oth Ewan Crosbie oth Anna Wonaschutz oth Anne E Perring oth Andreas Beyersdorf oth Luke Ziemba oth Jose L Jimenez oth Pedro Campuzano-Jost oth Tomas Mikoviny oth Armin Wisthaler oth Lynn M Russell oth Enthalten in Journal of geophysical research / D Washington, DC : Union, 1984 121(2016), 22 (DE-627)130444391 (DE-600)710256-2 (DE-576)015978818 2169-897X nnns volume:121 year:2016 number:22 http://dx.doi.org/10.1002/2016JD025471 Volltext http://search.proquest.com/docview/1847915132 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-GEO SSG-OPC-GGO SSG-OPC-GEO GBV_ILN_62 GBV_ILN_154 AR 121 2016 22 |
allfields_unstemmed |
10.1002/2016JD025471 doi PQ20170206 (DE-627)OLC1988774624 (DE-599)GBVOLC1988774624 (PRQ)p1170-9a9d0d141a68778122b1dcb1a202ece2a987782129310c939814200507efd47f0 (KEY)0137985220160000121002200000ambientobservationsofhygroscopicgrowthfactorandfrh DE-627 ger DE-627 rakwb eng 550 DNB Taylor Shingler verfasserin aut Ambient observations of hygroscopic growth factor and f(RH) below 1: Case studies from surface and airborne measurements 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier This study reports a detailed set of ambient observations of optical/physical shrinking of particles from exposure to water vapor with consistency across different instruments and regions. Data have been utilized from (i) a shipboard humidified tandem differential mobility analyzer during the Eastern Pacific Emitted Aerosol Cloud Experiment in 2011, (ii) multiple instruments on the NASA DC-8 research aircraft during the Studies of Emissions, Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys in 2013, and (iii) the Differential Aerosol Sizing and Hygroscopicity Spectrometer Probe during ambient measurements in Tucson, Arizona, during summer 2014 and winter 2015. Hygroscopic growth factor (ratio of humidified-to-dry diameter, GF=Dp,wet/Dp,dry) and f(RH) (ratio of humidified-to-dry scattering coefficients) values below 1 were observed across the range of relative humidity (RH) investigated (75-95%). A commonality of observations of GF and f(RH) below 1 in these experiments was the presence of particles enriched with carbonaceous matter, especially from biomass burning. Evidence of externally mixed aerosol, and thus multiple GFs with at least one GF<1, was observed concurrently with f(RH)<1 during smoke periods. Possible mechanisms responsible for observed shrinkage are discussed and include particle restructuring, volatilization effects, and refractive index modifications due to aqueous processing resulting in optical size modification. To further investigate ambient observations of GFs and f(RH) values less than 1, it is recommended to add an optional prehumidification bypass module to hygroscopicity instruments, to preemptively collapse particles prior to controlled RH measurements. Key Points Observations are reported for growth factor (GF) and f(RH) values below 1 in multiple regions using three instruments GF and f(RH) values less than 1 are observed in biomass burning plumes, organic-rich particles, and wintertime in an urban area f(RH) increases as a function of effective particle density with the majority of values below 1 coincident with density <1.2gcm-3 Studies Growth factors Armin Sorooshian oth Amber Ortega oth Ewan Crosbie oth Anna Wonaschutz oth Anne E Perring oth Andreas Beyersdorf oth Luke Ziemba oth Jose L Jimenez oth Pedro Campuzano-Jost oth Tomas Mikoviny oth Armin Wisthaler oth Lynn M Russell oth Enthalten in Journal of geophysical research / D Washington, DC : Union, 1984 121(2016), 22 (DE-627)130444391 (DE-600)710256-2 (DE-576)015978818 2169-897X nnns volume:121 year:2016 number:22 http://dx.doi.org/10.1002/2016JD025471 Volltext http://search.proquest.com/docview/1847915132 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-GEO SSG-OPC-GGO SSG-OPC-GEO GBV_ILN_62 GBV_ILN_154 AR 121 2016 22 |
allfieldsGer |
10.1002/2016JD025471 doi PQ20170206 (DE-627)OLC1988774624 (DE-599)GBVOLC1988774624 (PRQ)p1170-9a9d0d141a68778122b1dcb1a202ece2a987782129310c939814200507efd47f0 (KEY)0137985220160000121002200000ambientobservationsofhygroscopicgrowthfactorandfrh DE-627 ger DE-627 rakwb eng 550 DNB Taylor Shingler verfasserin aut Ambient observations of hygroscopic growth factor and f(RH) below 1: Case studies from surface and airborne measurements 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier This study reports a detailed set of ambient observations of optical/physical shrinking of particles from exposure to water vapor with consistency across different instruments and regions. Data have been utilized from (i) a shipboard humidified tandem differential mobility analyzer during the Eastern Pacific Emitted Aerosol Cloud Experiment in 2011, (ii) multiple instruments on the NASA DC-8 research aircraft during the Studies of Emissions, Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys in 2013, and (iii) the Differential Aerosol Sizing and Hygroscopicity Spectrometer Probe during ambient measurements in Tucson, Arizona, during summer 2014 and winter 2015. Hygroscopic growth factor (ratio of humidified-to-dry diameter, GF=Dp,wet/Dp,dry) and f(RH) (ratio of humidified-to-dry scattering coefficients) values below 1 were observed across the range of relative humidity (RH) investigated (75-95%). A commonality of observations of GF and f(RH) below 1 in these experiments was the presence of particles enriched with carbonaceous matter, especially from biomass burning. Evidence of externally mixed aerosol, and thus multiple GFs with at least one GF<1, was observed concurrently with f(RH)<1 during smoke periods. Possible mechanisms responsible for observed shrinkage are discussed and include particle restructuring, volatilization effects, and refractive index modifications due to aqueous processing resulting in optical size modification. To further investigate ambient observations of GFs and f(RH) values less than 1, it is recommended to add an optional prehumidification bypass module to hygroscopicity instruments, to preemptively collapse particles prior to controlled RH measurements. Key Points Observations are reported for growth factor (GF) and f(RH) values below 1 in multiple regions using three instruments GF and f(RH) values less than 1 are observed in biomass burning plumes, organic-rich particles, and wintertime in an urban area f(RH) increases as a function of effective particle density with the majority of values below 1 coincident with density <1.2gcm-3 Studies Growth factors Armin Sorooshian oth Amber Ortega oth Ewan Crosbie oth Anna Wonaschutz oth Anne E Perring oth Andreas Beyersdorf oth Luke Ziemba oth Jose L Jimenez oth Pedro Campuzano-Jost oth Tomas Mikoviny oth Armin Wisthaler oth Lynn M Russell oth Enthalten in Journal of geophysical research / D Washington, DC : Union, 1984 121(2016), 22 (DE-627)130444391 (DE-600)710256-2 (DE-576)015978818 2169-897X nnns volume:121 year:2016 number:22 http://dx.doi.org/10.1002/2016JD025471 Volltext http://search.proquest.com/docview/1847915132 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-GEO SSG-OPC-GGO SSG-OPC-GEO GBV_ILN_62 GBV_ILN_154 AR 121 2016 22 |
allfieldsSound |
10.1002/2016JD025471 doi PQ20170206 (DE-627)OLC1988774624 (DE-599)GBVOLC1988774624 (PRQ)p1170-9a9d0d141a68778122b1dcb1a202ece2a987782129310c939814200507efd47f0 (KEY)0137985220160000121002200000ambientobservationsofhygroscopicgrowthfactorandfrh DE-627 ger DE-627 rakwb eng 550 DNB Taylor Shingler verfasserin aut Ambient observations of hygroscopic growth factor and f(RH) below 1: Case studies from surface and airborne measurements 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier This study reports a detailed set of ambient observations of optical/physical shrinking of particles from exposure to water vapor with consistency across different instruments and regions. Data have been utilized from (i) a shipboard humidified tandem differential mobility analyzer during the Eastern Pacific Emitted Aerosol Cloud Experiment in 2011, (ii) multiple instruments on the NASA DC-8 research aircraft during the Studies of Emissions, Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys in 2013, and (iii) the Differential Aerosol Sizing and Hygroscopicity Spectrometer Probe during ambient measurements in Tucson, Arizona, during summer 2014 and winter 2015. Hygroscopic growth factor (ratio of humidified-to-dry diameter, GF=Dp,wet/Dp,dry) and f(RH) (ratio of humidified-to-dry scattering coefficients) values below 1 were observed across the range of relative humidity (RH) investigated (75-95%). A commonality of observations of GF and f(RH) below 1 in these experiments was the presence of particles enriched with carbonaceous matter, especially from biomass burning. Evidence of externally mixed aerosol, and thus multiple GFs with at least one GF<1, was observed concurrently with f(RH)<1 during smoke periods. Possible mechanisms responsible for observed shrinkage are discussed and include particle restructuring, volatilization effects, and refractive index modifications due to aqueous processing resulting in optical size modification. To further investigate ambient observations of GFs and f(RH) values less than 1, it is recommended to add an optional prehumidification bypass module to hygroscopicity instruments, to preemptively collapse particles prior to controlled RH measurements. Key Points Observations are reported for growth factor (GF) and f(RH) values below 1 in multiple regions using three instruments GF and f(RH) values less than 1 are observed in biomass burning plumes, organic-rich particles, and wintertime in an urban area f(RH) increases as a function of effective particle density with the majority of values below 1 coincident with density <1.2gcm-3 Studies Growth factors Armin Sorooshian oth Amber Ortega oth Ewan Crosbie oth Anna Wonaschutz oth Anne E Perring oth Andreas Beyersdorf oth Luke Ziemba oth Jose L Jimenez oth Pedro Campuzano-Jost oth Tomas Mikoviny oth Armin Wisthaler oth Lynn M Russell oth Enthalten in Journal of geophysical research / D Washington, DC : Union, 1984 121(2016), 22 (DE-627)130444391 (DE-600)710256-2 (DE-576)015978818 2169-897X nnns volume:121 year:2016 number:22 http://dx.doi.org/10.1002/2016JD025471 Volltext http://search.proquest.com/docview/1847915132 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-GEO SSG-OPC-GGO SSG-OPC-GEO GBV_ILN_62 GBV_ILN_154 AR 121 2016 22 |
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Taylor Shingler @@aut@@ Armin Sorooshian @@oth@@ Amber Ortega @@oth@@ Ewan Crosbie @@oth@@ Anna Wonaschutz @@oth@@ Anne E Perring @@oth@@ Andreas Beyersdorf @@oth@@ Luke Ziemba @@oth@@ Jose L Jimenez @@oth@@ Pedro Campuzano-Jost @@oth@@ Tomas Mikoviny @@oth@@ Armin Wisthaler @@oth@@ Lynn M Russell @@oth@@ |
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Evidence of externally mixed aerosol, and thus multiple GFs with at least one GF<1, was observed concurrently with f(RH)<1 during smoke periods. Possible mechanisms responsible for observed shrinkage are discussed and include particle restructuring, volatilization effects, and refractive index modifications due to aqueous processing resulting in optical size modification. To further investigate ambient observations of GFs and f(RH) values less than 1, it is recommended to add an optional prehumidification bypass module to hygroscopicity instruments, to preemptively collapse particles prior to controlled RH measurements. 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ambient observations of hygroscopic growth factor and f(rh) below 1: case studies from surface and airborne measurements |
title_auth |
Ambient observations of hygroscopic growth factor and f(RH) below 1: Case studies from surface and airborne measurements |
abstract |
This study reports a detailed set of ambient observations of optical/physical shrinking of particles from exposure to water vapor with consistency across different instruments and regions. Data have been utilized from (i) a shipboard humidified tandem differential mobility analyzer during the Eastern Pacific Emitted Aerosol Cloud Experiment in 2011, (ii) multiple instruments on the NASA DC-8 research aircraft during the Studies of Emissions, Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys in 2013, and (iii) the Differential Aerosol Sizing and Hygroscopicity Spectrometer Probe during ambient measurements in Tucson, Arizona, during summer 2014 and winter 2015. Hygroscopic growth factor (ratio of humidified-to-dry diameter, GF=Dp,wet/Dp,dry) and f(RH) (ratio of humidified-to-dry scattering coefficients) values below 1 were observed across the range of relative humidity (RH) investigated (75-95%). A commonality of observations of GF and f(RH) below 1 in these experiments was the presence of particles enriched with carbonaceous matter, especially from biomass burning. Evidence of externally mixed aerosol, and thus multiple GFs with at least one GF<1, was observed concurrently with f(RH)<1 during smoke periods. Possible mechanisms responsible for observed shrinkage are discussed and include particle restructuring, volatilization effects, and refractive index modifications due to aqueous processing resulting in optical size modification. To further investigate ambient observations of GFs and f(RH) values less than 1, it is recommended to add an optional prehumidification bypass module to hygroscopicity instruments, to preemptively collapse particles prior to controlled RH measurements. Key Points Observations are reported for growth factor (GF) and f(RH) values below 1 in multiple regions using three instruments GF and f(RH) values less than 1 are observed in biomass burning plumes, organic-rich particles, and wintertime in an urban area f(RH) increases as a function of effective particle density with the majority of values below 1 coincident with density <1.2gcm-3 |
abstractGer |
This study reports a detailed set of ambient observations of optical/physical shrinking of particles from exposure to water vapor with consistency across different instruments and regions. Data have been utilized from (i) a shipboard humidified tandem differential mobility analyzer during the Eastern Pacific Emitted Aerosol Cloud Experiment in 2011, (ii) multiple instruments on the NASA DC-8 research aircraft during the Studies of Emissions, Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys in 2013, and (iii) the Differential Aerosol Sizing and Hygroscopicity Spectrometer Probe during ambient measurements in Tucson, Arizona, during summer 2014 and winter 2015. Hygroscopic growth factor (ratio of humidified-to-dry diameter, GF=Dp,wet/Dp,dry) and f(RH) (ratio of humidified-to-dry scattering coefficients) values below 1 were observed across the range of relative humidity (RH) investigated (75-95%). A commonality of observations of GF and f(RH) below 1 in these experiments was the presence of particles enriched with carbonaceous matter, especially from biomass burning. Evidence of externally mixed aerosol, and thus multiple GFs with at least one GF<1, was observed concurrently with f(RH)<1 during smoke periods. Possible mechanisms responsible for observed shrinkage are discussed and include particle restructuring, volatilization effects, and refractive index modifications due to aqueous processing resulting in optical size modification. To further investigate ambient observations of GFs and f(RH) values less than 1, it is recommended to add an optional prehumidification bypass module to hygroscopicity instruments, to preemptively collapse particles prior to controlled RH measurements. Key Points Observations are reported for growth factor (GF) and f(RH) values below 1 in multiple regions using three instruments GF and f(RH) values less than 1 are observed in biomass burning plumes, organic-rich particles, and wintertime in an urban area f(RH) increases as a function of effective particle density with the majority of values below 1 coincident with density <1.2gcm-3 |
abstract_unstemmed |
This study reports a detailed set of ambient observations of optical/physical shrinking of particles from exposure to water vapor with consistency across different instruments and regions. Data have been utilized from (i) a shipboard humidified tandem differential mobility analyzer during the Eastern Pacific Emitted Aerosol Cloud Experiment in 2011, (ii) multiple instruments on the NASA DC-8 research aircraft during the Studies of Emissions, Atmospheric Composition, Clouds and Climate Coupling by Regional Surveys in 2013, and (iii) the Differential Aerosol Sizing and Hygroscopicity Spectrometer Probe during ambient measurements in Tucson, Arizona, during summer 2014 and winter 2015. Hygroscopic growth factor (ratio of humidified-to-dry diameter, GF=Dp,wet/Dp,dry) and f(RH) (ratio of humidified-to-dry scattering coefficients) values below 1 were observed across the range of relative humidity (RH) investigated (75-95%). A commonality of observations of GF and f(RH) below 1 in these experiments was the presence of particles enriched with carbonaceous matter, especially from biomass burning. Evidence of externally mixed aerosol, and thus multiple GFs with at least one GF<1, was observed concurrently with f(RH)<1 during smoke periods. Possible mechanisms responsible for observed shrinkage are discussed and include particle restructuring, volatilization effects, and refractive index modifications due to aqueous processing resulting in optical size modification. To further investigate ambient observations of GFs and f(RH) values less than 1, it is recommended to add an optional prehumidification bypass module to hygroscopicity instruments, to preemptively collapse particles prior to controlled RH measurements. Key Points Observations are reported for growth factor (GF) and f(RH) values below 1 in multiple regions using three instruments GF and f(RH) values less than 1 are observed in biomass burning plumes, organic-rich particles, and wintertime in an urban area f(RH) increases as a function of effective particle density with the majority of values below 1 coincident with density <1.2gcm-3 |
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title_short |
Ambient observations of hygroscopic growth factor and f(RH) below 1: Case studies from surface and airborne measurements |
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Armin Sorooshian Amber Ortega Ewan Crosbie Anna Wonaschutz Anne E Perring Andreas Beyersdorf Luke Ziemba Jose L Jimenez Pedro Campuzano-Jost Tomas Mikoviny Armin Wisthaler Lynn M Russell |
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