Tuning the Solid Electrolyte Interphase for Selective Li‐ and Na‐Ion Storage in Hard Carbon
Solid‐electrolyte interphase (SEI) films with controllable properties are highly desirable for improving battery performance. In this paper, a combined experimental and theoretical approach is used to study SEI films formed on hard carbon in Li‐ and Na‐ion batteries. It is shown that a stable SEI la...
Ausführliche Beschreibung
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| Autor*in: |
Soto, Fernando A [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2017 |
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| Rechteinformationen: |
Nutzungsrecht: © 2017 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim |
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| Schlagwörter: |
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| Systematik: |
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| Übergeordnetes Werk: |
Enthalten in: Advanced materials - Weinheim : Wiley-VCH Verl., 1988, 29(2017), 18 |
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| Übergeordnetes Werk: |
volume:29 ; year:2017 ; number:18 |
| Links: |
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| DOI / URN: |
10.1002/adma.201606860 |
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OLC1993178120 |
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| 520 | |a Solid‐electrolyte interphase (SEI) films with controllable properties are highly desirable for improving battery performance. In this paper, a combined experimental and theoretical approach is used to study SEI films formed on hard carbon in Li‐ and Na‐ion batteries. It is shown that a stable SEI layer can be designed by precycling an electrode in a desired Li‐ or Na‐based electrolyte, and that ionic transport can be kinetically controlled. Selective Li‐ and Na‐based SEI membranes are produced using Li‐ or Na‐based electrolytes, respectively. The Na‐based SEI allows easy transport of Li ions, while the Li‐based SEI shuts off Na‐ion transport. Na‐ion storage can be manipulated by tuning the SEI layer with film‐forming electrolyte additives, or by preforming an SEI layer on the electrode surface. The Na specific capacity can be controlled to < 25 mAh g −1 ; ≈ 1/10 of the normal capacity (250 mAh g −1 ). Unusual selective/preferential transport of Li ions is demonstrated by preforming an SEI layer on the electrode surface and corroborated with a mixed electrolyte. This work may provide new guidance for preparing good ion‐selective conductors using electrochemical approaches. Selective Li‐ and Na‐based solid‐electrolyte interphase (SEI) membranes can be designed by precycling an electrode in a desired Li‐ or Na‐based electrolyte. Na‐based SEI membranes allow easy transport of Li ions, while Li‐based SEI membranes shut off Na‐ion transport. Therefore, Na‐ion storage in hard carbon can be controlled by tuning the SEI layer, while Li‐ion intercalation is not affected. | ||
| 540 | |a Nutzungsrecht: © 2017 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim | ||
| 650 | 4 | |a Na‐ion batteries | |
| 650 | 4 | |a Li‐ion batteries | |
| 650 | 4 | |a solid‐electrolyte interphase | |
| 650 | 4 | |a selective ion transfer | |
| 700 | 1 | |a Yan, Pengfei |4 oth | |
| 700 | 1 | |a Engelhard, Mark H |4 oth | |
| 700 | 1 | |a Marzouk, Asma |4 oth | |
| 700 | 1 | |a Wang, Chongmin |4 oth | |
| 700 | 1 | |a Xu, Guiliang |4 oth | |
| 700 | 1 | |a Chen, Zonghai |4 oth | |
| 700 | 1 | |a Amine, Khalil |4 oth | |
| 700 | 1 | |a Liu, Jun |4 oth | |
| 700 | 1 | |a Sprenkle, Vincent L |4 oth | |
| 700 | 1 | |a El‐Mellouhi, Fedwa |4 oth | |
| 700 | 1 | |a Balbuena, Perla B |4 oth | |
| 700 | 1 | |a Li, Xiaolin |4 oth | |
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10.1002/adma.201606860 doi PQ20170501 (DE-627)OLC1993178120 (DE-599)GBVOLC1993178120 (PRQ)s740-64fd0936ae1603a6bf1cb55688dd6b06d90494446809a673147355479fefd1c43 (KEY)0178503620170000029001800000tuningthesolidelectrolyteinterphaseforselectivelia DE-627 ger DE-627 rakwb eng 620 540 DE-101 540 AVZ UA 1538 AVZ rvk Soto, Fernando A verfasserin aut Tuning the Solid Electrolyte Interphase for Selective Li‐ and Na‐Ion Storage in Hard Carbon 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Solid‐electrolyte interphase (SEI) films with controllable properties are highly desirable for improving battery performance. In this paper, a combined experimental and theoretical approach is used to study SEI films formed on hard carbon in Li‐ and Na‐ion batteries. It is shown that a stable SEI layer can be designed by precycling an electrode in a desired Li‐ or Na‐based electrolyte, and that ionic transport can be kinetically controlled. Selective Li‐ and Na‐based SEI membranes are produced using Li‐ or Na‐based electrolytes, respectively. The Na‐based SEI allows easy transport of Li ions, while the Li‐based SEI shuts off Na‐ion transport. Na‐ion storage can be manipulated by tuning the SEI layer with film‐forming electrolyte additives, or by preforming an SEI layer on the electrode surface. The Na specific capacity can be controlled to < 25 mAh g −1 ; ≈ 1/10 of the normal capacity (250 mAh g −1 ). Unusual selective/preferential transport of Li ions is demonstrated by preforming an SEI layer on the electrode surface and corroborated with a mixed electrolyte. This work may provide new guidance for preparing good ion‐selective conductors using electrochemical approaches. Selective Li‐ and Na‐based solid‐electrolyte interphase (SEI) membranes can be designed by precycling an electrode in a desired Li‐ or Na‐based electrolyte. Na‐based SEI membranes allow easy transport of Li ions, while Li‐based SEI membranes shut off Na‐ion transport. Therefore, Na‐ion storage in hard carbon can be controlled by tuning the SEI layer, while Li‐ion intercalation is not affected. Nutzungsrecht: © 2017 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim Na‐ion batteries Li‐ion batteries solid‐electrolyte interphase selective ion transfer Yan, Pengfei oth Engelhard, Mark H oth Marzouk, Asma oth Wang, Chongmin oth Xu, Guiliang oth Chen, Zonghai oth Amine, Khalil oth Liu, Jun oth Sprenkle, Vincent L oth El‐Mellouhi, Fedwa oth Balbuena, Perla B oth Li, Xiaolin oth Enthalten in Advanced materials Weinheim : Wiley-VCH Verl., 1988 29(2017), 18 (DE-627)130815152 (DE-600)1012489-5 (DE-576)023057149 0935-9648 nnns volume:29 year:2017 number:18 http://dx.doi.org/10.1002/adma.201606860 Volltext http://onlinelibrary.wiley.com/doi/10.1002/adma.201606860/abstract GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_95 GBV_ILN_267 GBV_ILN_2004 GBV_ILN_2016 GBV_ILN_2018 GBV_ILN_2095 GBV_ILN_4306 UA 1538 AR 29 2017 18 |
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10.1002/adma.201606860 doi PQ20170501 (DE-627)OLC1993178120 (DE-599)GBVOLC1993178120 (PRQ)s740-64fd0936ae1603a6bf1cb55688dd6b06d90494446809a673147355479fefd1c43 (KEY)0178503620170000029001800000tuningthesolidelectrolyteinterphaseforselectivelia DE-627 ger DE-627 rakwb eng 620 540 DE-101 540 AVZ UA 1538 AVZ rvk Soto, Fernando A verfasserin aut Tuning the Solid Electrolyte Interphase for Selective Li‐ and Na‐Ion Storage in Hard Carbon 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Solid‐electrolyte interphase (SEI) films with controllable properties are highly desirable for improving battery performance. In this paper, a combined experimental and theoretical approach is used to study SEI films formed on hard carbon in Li‐ and Na‐ion batteries. It is shown that a stable SEI layer can be designed by precycling an electrode in a desired Li‐ or Na‐based electrolyte, and that ionic transport can be kinetically controlled. Selective Li‐ and Na‐based SEI membranes are produced using Li‐ or Na‐based electrolytes, respectively. The Na‐based SEI allows easy transport of Li ions, while the Li‐based SEI shuts off Na‐ion transport. Na‐ion storage can be manipulated by tuning the SEI layer with film‐forming electrolyte additives, or by preforming an SEI layer on the electrode surface. The Na specific capacity can be controlled to < 25 mAh g −1 ; ≈ 1/10 of the normal capacity (250 mAh g −1 ). Unusual selective/preferential transport of Li ions is demonstrated by preforming an SEI layer on the electrode surface and corroborated with a mixed electrolyte. This work may provide new guidance for preparing good ion‐selective conductors using electrochemical approaches. Selective Li‐ and Na‐based solid‐electrolyte interphase (SEI) membranes can be designed by precycling an electrode in a desired Li‐ or Na‐based electrolyte. Na‐based SEI membranes allow easy transport of Li ions, while Li‐based SEI membranes shut off Na‐ion transport. Therefore, Na‐ion storage in hard carbon can be controlled by tuning the SEI layer, while Li‐ion intercalation is not affected. Nutzungsrecht: © 2017 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim Na‐ion batteries Li‐ion batteries solid‐electrolyte interphase selective ion transfer Yan, Pengfei oth Engelhard, Mark H oth Marzouk, Asma oth Wang, Chongmin oth Xu, Guiliang oth Chen, Zonghai oth Amine, Khalil oth Liu, Jun oth Sprenkle, Vincent L oth El‐Mellouhi, Fedwa oth Balbuena, Perla B oth Li, Xiaolin oth Enthalten in Advanced materials Weinheim : Wiley-VCH Verl., 1988 29(2017), 18 (DE-627)130815152 (DE-600)1012489-5 (DE-576)023057149 0935-9648 nnns volume:29 year:2017 number:18 http://dx.doi.org/10.1002/adma.201606860 Volltext http://onlinelibrary.wiley.com/doi/10.1002/adma.201606860/abstract GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_95 GBV_ILN_267 GBV_ILN_2004 GBV_ILN_2016 GBV_ILN_2018 GBV_ILN_2095 GBV_ILN_4306 UA 1538 AR 29 2017 18 |
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10.1002/adma.201606860 doi PQ20170501 (DE-627)OLC1993178120 (DE-599)GBVOLC1993178120 (PRQ)s740-64fd0936ae1603a6bf1cb55688dd6b06d90494446809a673147355479fefd1c43 (KEY)0178503620170000029001800000tuningthesolidelectrolyteinterphaseforselectivelia DE-627 ger DE-627 rakwb eng 620 540 DE-101 540 AVZ UA 1538 AVZ rvk Soto, Fernando A verfasserin aut Tuning the Solid Electrolyte Interphase for Selective Li‐ and Na‐Ion Storage in Hard Carbon 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Solid‐electrolyte interphase (SEI) films with controllable properties are highly desirable for improving battery performance. In this paper, a combined experimental and theoretical approach is used to study SEI films formed on hard carbon in Li‐ and Na‐ion batteries. It is shown that a stable SEI layer can be designed by precycling an electrode in a desired Li‐ or Na‐based electrolyte, and that ionic transport can be kinetically controlled. Selective Li‐ and Na‐based SEI membranes are produced using Li‐ or Na‐based electrolytes, respectively. The Na‐based SEI allows easy transport of Li ions, while the Li‐based SEI shuts off Na‐ion transport. Na‐ion storage can be manipulated by tuning the SEI layer with film‐forming electrolyte additives, or by preforming an SEI layer on the electrode surface. The Na specific capacity can be controlled to < 25 mAh g −1 ; ≈ 1/10 of the normal capacity (250 mAh g −1 ). Unusual selective/preferential transport of Li ions is demonstrated by preforming an SEI layer on the electrode surface and corroborated with a mixed electrolyte. This work may provide new guidance for preparing good ion‐selective conductors using electrochemical approaches. Selective Li‐ and Na‐based solid‐electrolyte interphase (SEI) membranes can be designed by precycling an electrode in a desired Li‐ or Na‐based electrolyte. Na‐based SEI membranes allow easy transport of Li ions, while Li‐based SEI membranes shut off Na‐ion transport. Therefore, Na‐ion storage in hard carbon can be controlled by tuning the SEI layer, while Li‐ion intercalation is not affected. Nutzungsrecht: © 2017 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim Na‐ion batteries Li‐ion batteries solid‐electrolyte interphase selective ion transfer Yan, Pengfei oth Engelhard, Mark H oth Marzouk, Asma oth Wang, Chongmin oth Xu, Guiliang oth Chen, Zonghai oth Amine, Khalil oth Liu, Jun oth Sprenkle, Vincent L oth El‐Mellouhi, Fedwa oth Balbuena, Perla B oth Li, Xiaolin oth Enthalten in Advanced materials Weinheim : Wiley-VCH Verl., 1988 29(2017), 18 (DE-627)130815152 (DE-600)1012489-5 (DE-576)023057149 0935-9648 nnns volume:29 year:2017 number:18 http://dx.doi.org/10.1002/adma.201606860 Volltext http://onlinelibrary.wiley.com/doi/10.1002/adma.201606860/abstract GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_95 GBV_ILN_267 GBV_ILN_2004 GBV_ILN_2016 GBV_ILN_2018 GBV_ILN_2095 GBV_ILN_4306 UA 1538 AR 29 2017 18 |
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10.1002/adma.201606860 doi PQ20170501 (DE-627)OLC1993178120 (DE-599)GBVOLC1993178120 (PRQ)s740-64fd0936ae1603a6bf1cb55688dd6b06d90494446809a673147355479fefd1c43 (KEY)0178503620170000029001800000tuningthesolidelectrolyteinterphaseforselectivelia DE-627 ger DE-627 rakwb eng 620 540 DE-101 540 AVZ UA 1538 AVZ rvk Soto, Fernando A verfasserin aut Tuning the Solid Electrolyte Interphase for Selective Li‐ and Na‐Ion Storage in Hard Carbon 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Solid‐electrolyte interphase (SEI) films with controllable properties are highly desirable for improving battery performance. In this paper, a combined experimental and theoretical approach is used to study SEI films formed on hard carbon in Li‐ and Na‐ion batteries. It is shown that a stable SEI layer can be designed by precycling an electrode in a desired Li‐ or Na‐based electrolyte, and that ionic transport can be kinetically controlled. Selective Li‐ and Na‐based SEI membranes are produced using Li‐ or Na‐based electrolytes, respectively. The Na‐based SEI allows easy transport of Li ions, while the Li‐based SEI shuts off Na‐ion transport. Na‐ion storage can be manipulated by tuning the SEI layer with film‐forming electrolyte additives, or by preforming an SEI layer on the electrode surface. The Na specific capacity can be controlled to < 25 mAh g −1 ; ≈ 1/10 of the normal capacity (250 mAh g −1 ). Unusual selective/preferential transport of Li ions is demonstrated by preforming an SEI layer on the electrode surface and corroborated with a mixed electrolyte. This work may provide new guidance for preparing good ion‐selective conductors using electrochemical approaches. Selective Li‐ and Na‐based solid‐electrolyte interphase (SEI) membranes can be designed by precycling an electrode in a desired Li‐ or Na‐based electrolyte. Na‐based SEI membranes allow easy transport of Li ions, while Li‐based SEI membranes shut off Na‐ion transport. Therefore, Na‐ion storage in hard carbon can be controlled by tuning the SEI layer, while Li‐ion intercalation is not affected. Nutzungsrecht: © 2017 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim Na‐ion batteries Li‐ion batteries solid‐electrolyte interphase selective ion transfer Yan, Pengfei oth Engelhard, Mark H oth Marzouk, Asma oth Wang, Chongmin oth Xu, Guiliang oth Chen, Zonghai oth Amine, Khalil oth Liu, Jun oth Sprenkle, Vincent L oth El‐Mellouhi, Fedwa oth Balbuena, Perla B oth Li, Xiaolin oth Enthalten in Advanced materials Weinheim : Wiley-VCH Verl., 1988 29(2017), 18 (DE-627)130815152 (DE-600)1012489-5 (DE-576)023057149 0935-9648 nnns volume:29 year:2017 number:18 http://dx.doi.org/10.1002/adma.201606860 Volltext http://onlinelibrary.wiley.com/doi/10.1002/adma.201606860/abstract GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_95 GBV_ILN_267 GBV_ILN_2004 GBV_ILN_2016 GBV_ILN_2018 GBV_ILN_2095 GBV_ILN_4306 UA 1538 AR 29 2017 18 |
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10.1002/adma.201606860 doi PQ20170501 (DE-627)OLC1993178120 (DE-599)GBVOLC1993178120 (PRQ)s740-64fd0936ae1603a6bf1cb55688dd6b06d90494446809a673147355479fefd1c43 (KEY)0178503620170000029001800000tuningthesolidelectrolyteinterphaseforselectivelia DE-627 ger DE-627 rakwb eng 620 540 DE-101 540 AVZ UA 1538 AVZ rvk Soto, Fernando A verfasserin aut Tuning the Solid Electrolyte Interphase for Selective Li‐ and Na‐Ion Storage in Hard Carbon 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Solid‐electrolyte interphase (SEI) films with controllable properties are highly desirable for improving battery performance. In this paper, a combined experimental and theoretical approach is used to study SEI films formed on hard carbon in Li‐ and Na‐ion batteries. It is shown that a stable SEI layer can be designed by precycling an electrode in a desired Li‐ or Na‐based electrolyte, and that ionic transport can be kinetically controlled. Selective Li‐ and Na‐based SEI membranes are produced using Li‐ or Na‐based electrolytes, respectively. The Na‐based SEI allows easy transport of Li ions, while the Li‐based SEI shuts off Na‐ion transport. Na‐ion storage can be manipulated by tuning the SEI layer with film‐forming electrolyte additives, or by preforming an SEI layer on the electrode surface. The Na specific capacity can be controlled to < 25 mAh g −1 ; ≈ 1/10 of the normal capacity (250 mAh g −1 ). Unusual selective/preferential transport of Li ions is demonstrated by preforming an SEI layer on the electrode surface and corroborated with a mixed electrolyte. This work may provide new guidance for preparing good ion‐selective conductors using electrochemical approaches. Selective Li‐ and Na‐based solid‐electrolyte interphase (SEI) membranes can be designed by precycling an electrode in a desired Li‐ or Na‐based electrolyte. Na‐based SEI membranes allow easy transport of Li ions, while Li‐based SEI membranes shut off Na‐ion transport. Therefore, Na‐ion storage in hard carbon can be controlled by tuning the SEI layer, while Li‐ion intercalation is not affected. Nutzungsrecht: © 2017 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim Na‐ion batteries Li‐ion batteries solid‐electrolyte interphase selective ion transfer Yan, Pengfei oth Engelhard, Mark H oth Marzouk, Asma oth Wang, Chongmin oth Xu, Guiliang oth Chen, Zonghai oth Amine, Khalil oth Liu, Jun oth Sprenkle, Vincent L oth El‐Mellouhi, Fedwa oth Balbuena, Perla B oth Li, Xiaolin oth Enthalten in Advanced materials Weinheim : Wiley-VCH Verl., 1988 29(2017), 18 (DE-627)130815152 (DE-600)1012489-5 (DE-576)023057149 0935-9648 nnns volume:29 year:2017 number:18 http://dx.doi.org/10.1002/adma.201606860 Volltext http://onlinelibrary.wiley.com/doi/10.1002/adma.201606860/abstract GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 GBV_ILN_95 GBV_ILN_267 GBV_ILN_2004 GBV_ILN_2016 GBV_ILN_2018 GBV_ILN_2095 GBV_ILN_4306 UA 1538 AR 29 2017 18 |
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Soto, Fernando A @@aut@@ Yan, Pengfei @@oth@@ Engelhard, Mark H @@oth@@ Marzouk, Asma @@oth@@ Wang, Chongmin @@oth@@ Xu, Guiliang @@oth@@ Chen, Zonghai @@oth@@ Amine, Khalil @@oth@@ Liu, Jun @@oth@@ Sprenkle, Vincent L @@oth@@ El‐Mellouhi, Fedwa @@oth@@ Balbuena, Perla B @@oth@@ Li, Xiaolin @@oth@@ |
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Soto, Fernando A |
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tuning the solid electrolyte interphase for selective li‐ and na‐ion storage in hard carbon |
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Tuning the Solid Electrolyte Interphase for Selective Li‐ and Na‐Ion Storage in Hard Carbon |
| abstract |
Solid‐electrolyte interphase (SEI) films with controllable properties are highly desirable for improving battery performance. In this paper, a combined experimental and theoretical approach is used to study SEI films formed on hard carbon in Li‐ and Na‐ion batteries. It is shown that a stable SEI layer can be designed by precycling an electrode in a desired Li‐ or Na‐based electrolyte, and that ionic transport can be kinetically controlled. Selective Li‐ and Na‐based SEI membranes are produced using Li‐ or Na‐based electrolytes, respectively. The Na‐based SEI allows easy transport of Li ions, while the Li‐based SEI shuts off Na‐ion transport. Na‐ion storage can be manipulated by tuning the SEI layer with film‐forming electrolyte additives, or by preforming an SEI layer on the electrode surface. The Na specific capacity can be controlled to < 25 mAh g −1 ; ≈ 1/10 of the normal capacity (250 mAh g −1 ). Unusual selective/preferential transport of Li ions is demonstrated by preforming an SEI layer on the electrode surface and corroborated with a mixed electrolyte. This work may provide new guidance for preparing good ion‐selective conductors using electrochemical approaches. Selective Li‐ and Na‐based solid‐electrolyte interphase (SEI) membranes can be designed by precycling an electrode in a desired Li‐ or Na‐based electrolyte. Na‐based SEI membranes allow easy transport of Li ions, while Li‐based SEI membranes shut off Na‐ion transport. Therefore, Na‐ion storage in hard carbon can be controlled by tuning the SEI layer, while Li‐ion intercalation is not affected. |
| abstractGer |
Solid‐electrolyte interphase (SEI) films with controllable properties are highly desirable for improving battery performance. In this paper, a combined experimental and theoretical approach is used to study SEI films formed on hard carbon in Li‐ and Na‐ion batteries. It is shown that a stable SEI layer can be designed by precycling an electrode in a desired Li‐ or Na‐based electrolyte, and that ionic transport can be kinetically controlled. Selective Li‐ and Na‐based SEI membranes are produced using Li‐ or Na‐based electrolytes, respectively. The Na‐based SEI allows easy transport of Li ions, while the Li‐based SEI shuts off Na‐ion transport. Na‐ion storage can be manipulated by tuning the SEI layer with film‐forming electrolyte additives, or by preforming an SEI layer on the electrode surface. The Na specific capacity can be controlled to < 25 mAh g −1 ; ≈ 1/10 of the normal capacity (250 mAh g −1 ). Unusual selective/preferential transport of Li ions is demonstrated by preforming an SEI layer on the electrode surface and corroborated with a mixed electrolyte. This work may provide new guidance for preparing good ion‐selective conductors using electrochemical approaches. Selective Li‐ and Na‐based solid‐electrolyte interphase (SEI) membranes can be designed by precycling an electrode in a desired Li‐ or Na‐based electrolyte. Na‐based SEI membranes allow easy transport of Li ions, while Li‐based SEI membranes shut off Na‐ion transport. Therefore, Na‐ion storage in hard carbon can be controlled by tuning the SEI layer, while Li‐ion intercalation is not affected. |
| abstract_unstemmed |
Solid‐electrolyte interphase (SEI) films with controllable properties are highly desirable for improving battery performance. In this paper, a combined experimental and theoretical approach is used to study SEI films formed on hard carbon in Li‐ and Na‐ion batteries. It is shown that a stable SEI layer can be designed by precycling an electrode in a desired Li‐ or Na‐based electrolyte, and that ionic transport can be kinetically controlled. Selective Li‐ and Na‐based SEI membranes are produced using Li‐ or Na‐based electrolytes, respectively. The Na‐based SEI allows easy transport of Li ions, while the Li‐based SEI shuts off Na‐ion transport. Na‐ion storage can be manipulated by tuning the SEI layer with film‐forming electrolyte additives, or by preforming an SEI layer on the electrode surface. The Na specific capacity can be controlled to < 25 mAh g −1 ; ≈ 1/10 of the normal capacity (250 mAh g −1 ). Unusual selective/preferential transport of Li ions is demonstrated by preforming an SEI layer on the electrode surface and corroborated with a mixed electrolyte. This work may provide new guidance for preparing good ion‐selective conductors using electrochemical approaches. Selective Li‐ and Na‐based solid‐electrolyte interphase (SEI) membranes can be designed by precycling an electrode in a desired Li‐ or Na‐based electrolyte. Na‐based SEI membranes allow easy transport of Li ions, while Li‐based SEI membranes shut off Na‐ion transport. Therefore, Na‐ion storage in hard carbon can be controlled by tuning the SEI layer, while Li‐ion intercalation is not affected. |
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Tuning the Solid Electrolyte Interphase for Selective Li‐ and Na‐Ion Storage in Hard Carbon |
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Yan, Pengfei Engelhard, Mark H Marzouk, Asma Wang, Chongmin Xu, Guiliang Chen, Zonghai Amine, Khalil Liu, Jun Sprenkle, Vincent L El‐Mellouhi, Fedwa Balbuena, Perla B Li, Xiaolin |
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Yan, Pengfei Engelhard, Mark H Marzouk, Asma Wang, Chongmin Xu, Guiliang Chen, Zonghai Amine, Khalil Liu, Jun Sprenkle, Vincent L El‐Mellouhi, Fedwa Balbuena, Perla B Li, Xiaolin |
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In this paper, a combined experimental and theoretical approach is used to study SEI films formed on hard carbon in Li‐ and Na‐ion batteries. It is shown that a stable SEI layer can be designed by precycling an electrode in a desired Li‐ or Na‐based electrolyte, and that ionic transport can be kinetically controlled. Selective Li‐ and Na‐based SEI membranes are produced using Li‐ or Na‐based electrolytes, respectively. The Na‐based SEI allows easy transport of Li ions, while the Li‐based SEI shuts off Na‐ion transport. Na‐ion storage can be manipulated by tuning the SEI layer with film‐forming electrolyte additives, or by preforming an SEI layer on the electrode surface. The Na specific capacity can be controlled to < 25 mAh g −1 ; ≈ 1/10 of the normal capacity (250 mAh g −1 ). Unusual selective/preferential transport of Li ions is demonstrated by preforming an SEI layer on the electrode surface and corroborated with a mixed electrolyte. This work may provide new guidance for preparing good ion‐selective conductors using electrochemical approaches. Selective Li‐ and Na‐based solid‐electrolyte interphase (SEI) membranes can be designed by precycling an electrode in a desired Li‐ or Na‐based electrolyte. Na‐based SEI membranes allow easy transport of Li ions, while Li‐based SEI membranes shut off Na‐ion transport. Therefore, Na‐ion storage in hard carbon can be controlled by tuning the SEI layer, while Li‐ion intercalation is not affected.</subfield></datafield><datafield tag="540" ind1=" " ind2=" "><subfield code="a">Nutzungsrecht: © 2017 WILEY‐VCH Verlag GmbH & Co. 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