Reaction behavior of the Collman reagent towards the nitrosyl carbonyls [CoNO(CO)3] and [Fe(NO)2(CO)2]

Reactions of the Collman reagent, Na [Fe(CO) ]·1.5 dioxane, towards the nitrosyl carbonyls [CoNO(CO) ] and [Fe(NO) (CO) ] in THF as the solvent at room temperature were investigated. Thereby a quick transfer of one nitrosyl ligand from the nitrosyl carbonyl molecule to the iron carbonyl metalate was...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Hans-Christian Böttcher [verfasserIn] Wolfgang Beck

Format:	Artikel
Sprache:	Englisch

Erschienen:	2017

Schlagwörter:	carbonyl metalates cobalt nitrosyl complexes iron

Systematik:	VA 8360

Übergeordnetes Werk:	Enthalten in: Zeitschrift für Naturforschung. B, Chemical sciences - Berlin : de Gruyter, 1947, 72(2017), 6, Seite 457-460
Übergeordnetes Werk:	volume:72 ; year:2017 ; number:6 ; pages:457-460

Links:	Volltext Link aufrufen

DOI / URN:	10.1515/znb-2017-0029

Katalog-ID:	OLC1994360178

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520			\|a Reactions of the Collman reagent, Na [Fe(CO) ]·1.5 dioxane, towards the nitrosyl carbonyls [CoNO(CO) ] and [Fe(NO) (CO) ] in THF as the solvent at room temperature were investigated. Thereby a quick transfer of one nitrosyl ligand from the nitrosyl carbonyl molecule to the iron carbonyl metalate was observed. The reaction with the cobalt compound afforded in high yields the well-known species [Co(CO) and [FeNO(CO) isolated by addition of two equivalents of [PPN] Cl ([PPN] = bis(triphenylphosphane)iminium cation) and characterized by their known IR spectra, by elemental analysis and their characteristic colors and melting points. In the reaction of the Collman reagent with [Fe(NO) (CO) ] a clean transformation to the tricarbonylnitrosylferrate(1−) as the only formed product was observed.
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matchkey_str	article:09320776:2017----::ecineairfhclmnegntwrshntoycroy
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publishDate	2017
allfields	10.1515/znb-2017-0029 doi PQ20170721 (DE-627)OLC1994360178 (DE-599)GBVOLC1994360178 (PRQ)w882-1d46b59f7a30ba9131f47ff239e44e62a5b481d1fed4bd87d67ba4ace33e7e350 (KEY)0044353020170000072000600457reactionbehaviorofthecollmanreagenttowardsthenitro DE-627 ger DE-627 rakwb eng 540 DNB VA 8360 AVZ rvk Hans-Christian Böttcher verfasserin aut Reaction behavior of the Collman reagent towards the nitrosyl carbonyls [CoNO(CO)3] and [Fe(NO)2(CO)2] 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Reactions of the Collman reagent, Na [Fe(CO) ]·1.5 dioxane, towards the nitrosyl carbonyls [CoNO(CO) ] and [Fe(NO) (CO) ] in THF as the solvent at room temperature were investigated. Thereby a quick transfer of one nitrosyl ligand from the nitrosyl carbonyl molecule to the iron carbonyl metalate was observed. The reaction with the cobalt compound afforded in high yields the well-known species [Co(CO) and [FeNO(CO) isolated by addition of two equivalents of [PPN] Cl ([PPN] = bis(triphenylphosphane)iminium cation) and characterized by their known IR spectra, by elemental analysis and their characteristic colors and melting points. In the reaction of the Collman reagent with [Fe(NO) (CO) ] a clean transformation to the tricarbonylnitrosylferrate(1−) as the only formed product was observed. carbonyl metalates cobalt nitrosyl complexes iron Wolfgang Beck oth Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Berlin : de Gruyter, 1947 72(2017), 6, Seite 457-460 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:72 year:2017 number:6 pages:457-460 http://dx.doi.org/10.1515/znb-2017-0029 Volltext http://www.degruyter.com/doi/10.1515/znb-2017-0029 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OLC-DE-84 SSG-OPC-FOR GBV_ILN_24 GBV_ILN_59 GBV_ILN_70 GBV_ILN_121 GBV_ILN_267 GBV_ILN_2010 GBV_ILN_2015 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4125 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4320 VA 8360 AR 72 2017 6 457-460
spelling	10.1515/znb-2017-0029 doi PQ20170721 (DE-627)OLC1994360178 (DE-599)GBVOLC1994360178 (PRQ)w882-1d46b59f7a30ba9131f47ff239e44e62a5b481d1fed4bd87d67ba4ace33e7e350 (KEY)0044353020170000072000600457reactionbehaviorofthecollmanreagenttowardsthenitro DE-627 ger DE-627 rakwb eng 540 DNB VA 8360 AVZ rvk Hans-Christian Böttcher verfasserin aut Reaction behavior of the Collman reagent towards the nitrosyl carbonyls [CoNO(CO)3] and [Fe(NO)2(CO)2] 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Reactions of the Collman reagent, Na [Fe(CO) ]·1.5 dioxane, towards the nitrosyl carbonyls [CoNO(CO) ] and [Fe(NO) (CO) ] in THF as the solvent at room temperature were investigated. Thereby a quick transfer of one nitrosyl ligand from the nitrosyl carbonyl molecule to the iron carbonyl metalate was observed. The reaction with the cobalt compound afforded in high yields the well-known species [Co(CO) and [FeNO(CO) isolated by addition of two equivalents of [PPN] Cl ([PPN] = bis(triphenylphosphane)iminium cation) and characterized by their known IR spectra, by elemental analysis and their characteristic colors and melting points. In the reaction of the Collman reagent with [Fe(NO) (CO) ] a clean transformation to the tricarbonylnitrosylferrate(1−) as the only formed product was observed. carbonyl metalates cobalt nitrosyl complexes iron Wolfgang Beck oth Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Berlin : de Gruyter, 1947 72(2017), 6, Seite 457-460 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:72 year:2017 number:6 pages:457-460 http://dx.doi.org/10.1515/znb-2017-0029 Volltext http://www.degruyter.com/doi/10.1515/znb-2017-0029 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OLC-DE-84 SSG-OPC-FOR GBV_ILN_24 GBV_ILN_59 GBV_ILN_70 GBV_ILN_121 GBV_ILN_267 GBV_ILN_2010 GBV_ILN_2015 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4125 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4320 VA 8360 AR 72 2017 6 457-460
allfields_unstemmed	10.1515/znb-2017-0029 doi PQ20170721 (DE-627)OLC1994360178 (DE-599)GBVOLC1994360178 (PRQ)w882-1d46b59f7a30ba9131f47ff239e44e62a5b481d1fed4bd87d67ba4ace33e7e350 (KEY)0044353020170000072000600457reactionbehaviorofthecollmanreagenttowardsthenitro DE-627 ger DE-627 rakwb eng 540 DNB VA 8360 AVZ rvk Hans-Christian Böttcher verfasserin aut Reaction behavior of the Collman reagent towards the nitrosyl carbonyls [CoNO(CO)3] and [Fe(NO)2(CO)2] 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Reactions of the Collman reagent, Na [Fe(CO) ]·1.5 dioxane, towards the nitrosyl carbonyls [CoNO(CO) ] and [Fe(NO) (CO) ] in THF as the solvent at room temperature were investigated. Thereby a quick transfer of one nitrosyl ligand from the nitrosyl carbonyl molecule to the iron carbonyl metalate was observed. The reaction with the cobalt compound afforded in high yields the well-known species [Co(CO) and [FeNO(CO) isolated by addition of two equivalents of [PPN] Cl ([PPN] = bis(triphenylphosphane)iminium cation) and characterized by their known IR spectra, by elemental analysis and their characteristic colors and melting points. In the reaction of the Collman reagent with [Fe(NO) (CO) ] a clean transformation to the tricarbonylnitrosylferrate(1−) as the only formed product was observed. carbonyl metalates cobalt nitrosyl complexes iron Wolfgang Beck oth Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Berlin : de Gruyter, 1947 72(2017), 6, Seite 457-460 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:72 year:2017 number:6 pages:457-460 http://dx.doi.org/10.1515/znb-2017-0029 Volltext http://www.degruyter.com/doi/10.1515/znb-2017-0029 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OLC-DE-84 SSG-OPC-FOR GBV_ILN_24 GBV_ILN_59 GBV_ILN_70 GBV_ILN_121 GBV_ILN_267 GBV_ILN_2010 GBV_ILN_2015 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4125 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4320 VA 8360 AR 72 2017 6 457-460
allfieldsGer	10.1515/znb-2017-0029 doi PQ20170721 (DE-627)OLC1994360178 (DE-599)GBVOLC1994360178 (PRQ)w882-1d46b59f7a30ba9131f47ff239e44e62a5b481d1fed4bd87d67ba4ace33e7e350 (KEY)0044353020170000072000600457reactionbehaviorofthecollmanreagenttowardsthenitro DE-627 ger DE-627 rakwb eng 540 DNB VA 8360 AVZ rvk Hans-Christian Böttcher verfasserin aut Reaction behavior of the Collman reagent towards the nitrosyl carbonyls [CoNO(CO)3] and [Fe(NO)2(CO)2] 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Reactions of the Collman reagent, Na [Fe(CO) ]·1.5 dioxane, towards the nitrosyl carbonyls [CoNO(CO) ] and [Fe(NO) (CO) ] in THF as the solvent at room temperature were investigated. Thereby a quick transfer of one nitrosyl ligand from the nitrosyl carbonyl molecule to the iron carbonyl metalate was observed. The reaction with the cobalt compound afforded in high yields the well-known species [Co(CO) and [FeNO(CO) isolated by addition of two equivalents of [PPN] Cl ([PPN] = bis(triphenylphosphane)iminium cation) and characterized by their known IR spectra, by elemental analysis and their characteristic colors and melting points. In the reaction of the Collman reagent with [Fe(NO) (CO) ] a clean transformation to the tricarbonylnitrosylferrate(1−) as the only formed product was observed. carbonyl metalates cobalt nitrosyl complexes iron Wolfgang Beck oth Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Berlin : de Gruyter, 1947 72(2017), 6, Seite 457-460 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:72 year:2017 number:6 pages:457-460 http://dx.doi.org/10.1515/znb-2017-0029 Volltext http://www.degruyter.com/doi/10.1515/znb-2017-0029 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OLC-DE-84 SSG-OPC-FOR GBV_ILN_24 GBV_ILN_59 GBV_ILN_70 GBV_ILN_121 GBV_ILN_267 GBV_ILN_2010 GBV_ILN_2015 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4125 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4320 VA 8360 AR 72 2017 6 457-460
allfieldsSound	10.1515/znb-2017-0029 doi PQ20170721 (DE-627)OLC1994360178 (DE-599)GBVOLC1994360178 (PRQ)w882-1d46b59f7a30ba9131f47ff239e44e62a5b481d1fed4bd87d67ba4ace33e7e350 (KEY)0044353020170000072000600457reactionbehaviorofthecollmanreagenttowardsthenitro DE-627 ger DE-627 rakwb eng 540 DNB VA 8360 AVZ rvk Hans-Christian Böttcher verfasserin aut Reaction behavior of the Collman reagent towards the nitrosyl carbonyls [CoNO(CO)3] and [Fe(NO)2(CO)2] 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Reactions of the Collman reagent, Na [Fe(CO) ]·1.5 dioxane, towards the nitrosyl carbonyls [CoNO(CO) ] and [Fe(NO) (CO) ] in THF as the solvent at room temperature were investigated. Thereby a quick transfer of one nitrosyl ligand from the nitrosyl carbonyl molecule to the iron carbonyl metalate was observed. The reaction with the cobalt compound afforded in high yields the well-known species [Co(CO) and [FeNO(CO) isolated by addition of two equivalents of [PPN] Cl ([PPN] = bis(triphenylphosphane)iminium cation) and characterized by their known IR spectra, by elemental analysis and their characteristic colors and melting points. In the reaction of the Collman reagent with [Fe(NO) (CO) ] a clean transformation to the tricarbonylnitrosylferrate(1−) as the only formed product was observed. carbonyl metalates cobalt nitrosyl complexes iron Wolfgang Beck oth Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences Berlin : de Gruyter, 1947 72(2017), 6, Seite 457-460 (DE-627)129307386 (DE-600)124635-5 (DE-576)014504928 0932-0776 nnns volume:72 year:2017 number:6 pages:457-460 http://dx.doi.org/10.1515/znb-2017-0029 Volltext http://www.degruyter.com/doi/10.1515/znb-2017-0029 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-FOR SSG-OLC-DE-84 SSG-OPC-FOR GBV_ILN_24 GBV_ILN_59 GBV_ILN_70 GBV_ILN_121 GBV_ILN_267 GBV_ILN_2010 GBV_ILN_2015 GBV_ILN_2021 GBV_ILN_4012 GBV_ILN_4125 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4320 VA 8360 AR 72 2017 6 457-460
language	English
source	Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences 72(2017), 6, Seite 457-460 volume:72 year:2017 number:6 pages:457-460
sourceStr	Enthalten in Zeitschrift für Naturforschung. B, Chemical sciences 72(2017), 6, Seite 457-460 volume:72 year:2017 number:6 pages:457-460
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	carbonyl metalates cobalt nitrosyl complexes iron
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container_title	Zeitschrift für Naturforschung. B, Chemical sciences
authorswithroles_txt_mv	Hans-Christian Böttcher @@aut@@ Wolfgang Beck @@oth@@
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author	Hans-Christian Böttcher
spellingShingle	Hans-Christian Böttcher ddc 540 rvk VA 8360 misc carbonyl metalates misc cobalt misc nitrosyl complexes misc iron Reaction behavior of the Collman reagent towards the nitrosyl carbonyls [CoNO(CO)3] and [Fe(NO)2(CO)2]
authorStr	Hans-Christian Böttcher
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topic_title	540 DNB VA 8360 AVZ rvk Reaction behavior of the Collman reagent towards the nitrosyl carbonyls [CoNO(CO)3] and [Fe(NO)2(CO)2] carbonyl metalates cobalt nitrosyl complexes iron
topic	ddc 540 rvk VA 8360 misc carbonyl metalates misc cobalt misc nitrosyl complexes misc iron
topic_unstemmed	ddc 540 rvk VA 8360 misc carbonyl metalates misc cobalt misc nitrosyl complexes misc iron
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title	Reaction behavior of the Collman reagent towards the nitrosyl carbonyls [CoNO(CO)3] and [Fe(NO)2(CO)2]
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title_full	Reaction behavior of the Collman reagent towards the nitrosyl carbonyls [CoNO(CO)3] and [Fe(NO)2(CO)2]
author_sort	Hans-Christian Böttcher
journal	Zeitschrift für Naturforschung. B, Chemical sciences
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title_sort	reaction behavior of the collman reagent towards the nitrosyl carbonyls [cono(co)3] and [fe(no)2(co)2]
title_auth	Reaction behavior of the Collman reagent towards the nitrosyl carbonyls [CoNO(CO)3] and [Fe(NO)2(CO)2]
abstract	Reactions of the Collman reagent, Na [Fe(CO) ]·1.5 dioxane, towards the nitrosyl carbonyls [CoNO(CO) ] and [Fe(NO) (CO) ] in THF as the solvent at room temperature were investigated. Thereby a quick transfer of one nitrosyl ligand from the nitrosyl carbonyl molecule to the iron carbonyl metalate was observed. The reaction with the cobalt compound afforded in high yields the well-known species [Co(CO) and [FeNO(CO) isolated by addition of two equivalents of [PPN] Cl ([PPN] = bis(triphenylphosphane)iminium cation) and characterized by their known IR spectra, by elemental analysis and their characteristic colors and melting points. In the reaction of the Collman reagent with [Fe(NO) (CO) ] a clean transformation to the tricarbonylnitrosylferrate(1−) as the only formed product was observed.
abstractGer	Reactions of the Collman reagent, Na [Fe(CO) ]·1.5 dioxane, towards the nitrosyl carbonyls [CoNO(CO) ] and [Fe(NO) (CO) ] in THF as the solvent at room temperature were investigated. Thereby a quick transfer of one nitrosyl ligand from the nitrosyl carbonyl molecule to the iron carbonyl metalate was observed. The reaction with the cobalt compound afforded in high yields the well-known species [Co(CO) and [FeNO(CO) isolated by addition of two equivalents of [PPN] Cl ([PPN] = bis(triphenylphosphane)iminium cation) and characterized by their known IR spectra, by elemental analysis and their characteristic colors and melting points. In the reaction of the Collman reagent with [Fe(NO) (CO) ] a clean transformation to the tricarbonylnitrosylferrate(1−) as the only formed product was observed.
abstract_unstemmed	Reactions of the Collman reagent, Na [Fe(CO) ]·1.5 dioxane, towards the nitrosyl carbonyls [CoNO(CO) ] and [Fe(NO) (CO) ] in THF as the solvent at room temperature were investigated. Thereby a quick transfer of one nitrosyl ligand from the nitrosyl carbonyl molecule to the iron carbonyl metalate was observed. The reaction with the cobalt compound afforded in high yields the well-known species [Co(CO) and [FeNO(CO) isolated by addition of two equivalents of [PPN] Cl ([PPN] = bis(triphenylphosphane)iminium cation) and characterized by their known IR spectra, by elemental analysis and their characteristic colors and melting points. In the reaction of the Collman reagent with [Fe(NO) (CO) ] a clean transformation to the tricarbonylnitrosylferrate(1−) as the only formed product was observed.
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container_issue	6
title_short	Reaction behavior of the Collman reagent towards the nitrosyl carbonyls [CoNO(CO)3] and [Fe(NO)2(CO)2]
url	http://dx.doi.org/10.1515/znb-2017-0029 http://www.degruyter.com/doi/10.1515/znb-2017-0029
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up_date	2024-07-03T17:32:10.193Z
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