Electric-field control of tri-state phase transformation with a selective dual-ion switch
Materials can be transformed from one crystalline phase to another by using an electric field to control ion transfer, in a process that can be harnessed in applications such as batteries1, smart windows2 and fuel cells3. Increasing the number of transferrable ion species and of accessible crystalli...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Lu, Nianpeng [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2017 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Nature - London : Macmillan Publishers Limited, part of Springer Nature, 1869, 546(2017), 7656, Seite 124 |
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| Übergeordnetes Werk: |
volume:546 ; year:2017 ; number:7656 ; pages:124 |
| Links: |
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| DOI / URN: |
10.1038/nature22389 |
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OLC1994626704 |
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| 245 | 1 | 0 | |a Electric-field control of tri-state phase transformation with a selective dual-ion switch |
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| 520 | |a Materials can be transformed from one crystalline phase to another by using an electric field to control ion transfer, in a process that can be harnessed in applications such as batteries1, smart windows2 and fuel cells3. Increasing the number of transferrable ion species and of accessible crystalline phases could in principle greatly enrich material functionality. However, studies have so far focused mainly on the evolution and control of single ionic species (for example, oxygen, hydrogen or lithium ions4-10). Here we describe the reversible and non-volatile electric-field control of dual-ion (oxygen and hydrogen) phase transformations, with associated electrochromic2 and magnetoelectric11 effects. We show that controlling the insertion and extraction of oxygen and hydrogen ions independently of each other can direct reversible phase transformations among three different material phases: the perovskite SrCoO^sub 3-δ^ (ref. 12), the brownmillerite SrCoO^sub 2.5^ (ref. 13), and a hitherto-unexplored phase, HSrCoO^sub 2.5^. By analysing the distinct optical absorption properties of these phases, we demonstrate selective manipulation of spectral transparency in the visible-light and infrared regions, revealing a dual-band electrochromic effect that could see application in smart windows2,9. Moreover, the starkly different magnetic and electric properties of the three phases-HSrCoO^sub 2.5^ is a weakly ferromagnetic insulator, SrCoO^sub 3-δ^ is a ferromagnetic metal12, and SrCoO^sub 2.5^ is an antiferromagnetic insulator13-enable an unusual form of magnetoelectric coupling, allowing electric-field control of three different magnetic ground states. These findings open up opportunities for the electric-field control of multistate phase transformations with rich functionalities. | ||
| 650 | 4 | |a Phase transformations (Statistical physics) | |
| 650 | 4 | |a Electric fields | |
| 650 | 4 | |a Control | |
| 650 | 4 | |a Usage | |
| 650 | 4 | |a Transformation | |
| 650 | 4 | |a Extraction | |
| 650 | 4 | |a Ferromagnetism | |
| 650 | 4 | |a Optical properties | |
| 650 | 4 | |a Fuels | |
| 650 | 4 | |a Hydrogen | |
| 650 | 4 | |a Spectra | |
| 650 | 4 | |a Brownmillerite | |
| 650 | 4 | |a Accessibility | |
| 650 | 4 | |a Hydrogen ions | |
| 650 | 4 | |a Materials science | |
| 650 | 4 | |a Crystal structure | |
| 650 | 4 | |a Absorption | |
| 650 | 4 | |a Enrichment | |
| 650 | 4 | |a Lithium | |
| 650 | 4 | |a Transparency | |
| 650 | 4 | |a Biological evolution | |
| 650 | 4 | |a Ions | |
| 650 | 4 | |a Condensed matter physics | |
| 650 | 4 | |a Phase transformations | |
| 650 | 4 | |a Infrared radiation | |
| 650 | 4 | |a Electric field | |
| 650 | 4 | |a Oxygen | |
| 650 | 4 | |a Coupling | |
| 650 | 4 | |a Magnetic properties | |
| 650 | 4 | |a Antiferromagnetism | |
| 650 | 4 | |a Insertion | |
| 650 | 4 | |a Electrochromism | |
| 650 | 4 | |a Calcium aluminum ferrite | |
| 650 | 4 | |a Evolution | |
| 700 | 1 | |a Zhang, Pengfei |4 oth | |
| 700 | 1 | |a Zhang, Qinghua |4 oth | |
| 700 | 1 | |a Qiao, Ruimin |4 oth | |
| 700 | 1 | |a He, Qing |4 oth | |
| 700 | 1 | |a Li, Hao-Bo |4 oth | |
| 700 | 1 | |a Wang, Yujia |4 oth | |
| 700 | 1 | |a Guo, Jingwen |4 oth | |
| 700 | 1 | |a Zhang, Ding |4 oth | |
| 700 | 1 | |a Duan, Zheng |4 oth | |
| 700 | 1 | |a Li, Zhuolu |4 oth | |
| 700 | 1 | |a Wang, Meng |4 oth | |
| 700 | 1 | |a Yang, Shuzhen |4 oth | |
| 700 | 1 | |a Yan, Mingzhe |4 oth | |
| 700 | 1 | |a Arenholz, Elke |4 oth | |
| 700 | 1 | |a Zhou, Shuyun |4 oth | |
| 700 | 1 | |a Yang, Wanli |4 oth | |
| 700 | 1 | |a Gu, Lin |4 oth | |
| 700 | 1 | |a Nan, Ce-Wen |4 oth | |
| 700 | 1 | |a Wu, Jian |4 oth | |
| 700 | 1 | |a Tokura, Yoshinori |4 oth | |
| 700 | 1 | |a Yu, Pu |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |t Nature |d London : Macmillan Publishers Limited, part of Springer Nature, 1869 |g 546(2017), 7656, Seite 124 |w (DE-627)129292834 |w (DE-600)120714-3 |w (DE-576)014473941 |x 0028-0836 |7 nnns |
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| 856 | 4 | 1 | |u http://dx.doi.org/10.1038/nature22389 |3 Volltext |
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10.1038/nature22389 doi PQ20171125 (DE-627)OLC1994626704 (DE-599)GBVOLC1994626704 (PRQ)g1460-7bc06428e85c100a2f87285b6704e906b0fb2e72ccd288b007dc6d59354c1a6b0 (KEY)0072945020170000546765600124electricfieldcontroloftristatephasetransformationw DE-627 ger DE-627 rakwb eng 070 500 DE-101 500 AVZ BIODIV fid Lu, Nianpeng verfasserin aut Electric-field control of tri-state phase transformation with a selective dual-ion switch 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Materials can be transformed from one crystalline phase to another by using an electric field to control ion transfer, in a process that can be harnessed in applications such as batteries1, smart windows2 and fuel cells3. Increasing the number of transferrable ion species and of accessible crystalline phases could in principle greatly enrich material functionality. However, studies have so far focused mainly on the evolution and control of single ionic species (for example, oxygen, hydrogen or lithium ions4-10). Here we describe the reversible and non-volatile electric-field control of dual-ion (oxygen and hydrogen) phase transformations, with associated electrochromic2 and magnetoelectric11 effects. We show that controlling the insertion and extraction of oxygen and hydrogen ions independently of each other can direct reversible phase transformations among three different material phases: the perovskite SrCoO^sub 3-δ^ (ref. 12), the brownmillerite SrCoO^sub 2.5^ (ref. 13), and a hitherto-unexplored phase, HSrCoO^sub 2.5^. By analysing the distinct optical absorption properties of these phases, we demonstrate selective manipulation of spectral transparency in the visible-light and infrared regions, revealing a dual-band electrochromic effect that could see application in smart windows2,9. Moreover, the starkly different magnetic and electric properties of the three phases-HSrCoO^sub 2.5^ is a weakly ferromagnetic insulator, SrCoO^sub 3-δ^ is a ferromagnetic metal12, and SrCoO^sub 2.5^ is an antiferromagnetic insulator13-enable an unusual form of magnetoelectric coupling, allowing electric-field control of three different magnetic ground states. These findings open up opportunities for the electric-field control of multistate phase transformations with rich functionalities. Phase transformations (Statistical physics) Electric fields Control Usage Transformation Extraction Ferromagnetism Optical properties Fuels Hydrogen Spectra Brownmillerite Accessibility Hydrogen ions Materials science Crystal structure Absorption Enrichment Lithium Transparency Biological evolution Ions Condensed matter physics Phase transformations Infrared radiation Electric field Oxygen Coupling Magnetic properties Antiferromagnetism Insertion Electrochromism Calcium aluminum ferrite Evolution Zhang, Pengfei oth Zhang, Qinghua oth Qiao, Ruimin oth He, Qing oth Li, Hao-Bo oth Wang, Yujia oth Guo, Jingwen oth Zhang, Ding oth Duan, Zheng oth Li, Zhuolu oth Wang, Meng oth Yang, Shuzhen oth Yan, Mingzhe oth Arenholz, Elke oth Zhou, Shuyun oth Yang, Wanli oth Gu, Lin oth Nan, Ce-Wen oth Wu, Jian oth Tokura, Yoshinori oth Yu, Pu oth Enthalten in Nature London : Macmillan Publishers Limited, part of Springer Nature, 1869 546(2017), 7656, Seite 124 (DE-627)129292834 (DE-600)120714-3 (DE-576)014473941 0028-0836 nnns volume:546 year:2017 number:7656 pages:124 http://dx.doi.org/10.1038/nature22389 Volltext https://search.proquest.com/docview/1906107469 GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-FOR SSG-OLC-SPO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-FOR GBV_ILN_11 GBV_ILN_22 GBV_ILN_40 GBV_ILN_47 GBV_ILN_55 GBV_ILN_59 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_101 GBV_ILN_110 GBV_ILN_120 GBV_ILN_135 GBV_ILN_154 GBV_ILN_168 GBV_ILN_170 GBV_ILN_171 GBV_ILN_211 GBV_ILN_252 GBV_ILN_290 GBV_ILN_294 GBV_ILN_601 GBV_ILN_647 GBV_ILN_754 GBV_ILN_2001 GBV_ILN_2002 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2016 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2026 GBV_ILN_2095 GBV_ILN_2116 GBV_ILN_2120 GBV_ILN_2121 GBV_ILN_2219 GBV_ILN_2221 GBV_ILN_2279 GBV_ILN_2286 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4125 GBV_ILN_4219 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4314 GBV_ILN_4317 GBV_ILN_4320 GBV_ILN_4324 AR 546 2017 7656 124 |
| spelling |
10.1038/nature22389 doi PQ20171125 (DE-627)OLC1994626704 (DE-599)GBVOLC1994626704 (PRQ)g1460-7bc06428e85c100a2f87285b6704e906b0fb2e72ccd288b007dc6d59354c1a6b0 (KEY)0072945020170000546765600124electricfieldcontroloftristatephasetransformationw DE-627 ger DE-627 rakwb eng 070 500 DE-101 500 AVZ BIODIV fid Lu, Nianpeng verfasserin aut Electric-field control of tri-state phase transformation with a selective dual-ion switch 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Materials can be transformed from one crystalline phase to another by using an electric field to control ion transfer, in a process that can be harnessed in applications such as batteries1, smart windows2 and fuel cells3. Increasing the number of transferrable ion species and of accessible crystalline phases could in principle greatly enrich material functionality. However, studies have so far focused mainly on the evolution and control of single ionic species (for example, oxygen, hydrogen or lithium ions4-10). Here we describe the reversible and non-volatile electric-field control of dual-ion (oxygen and hydrogen) phase transformations, with associated electrochromic2 and magnetoelectric11 effects. We show that controlling the insertion and extraction of oxygen and hydrogen ions independently of each other can direct reversible phase transformations among three different material phases: the perovskite SrCoO^sub 3-δ^ (ref. 12), the brownmillerite SrCoO^sub 2.5^ (ref. 13), and a hitherto-unexplored phase, HSrCoO^sub 2.5^. By analysing the distinct optical absorption properties of these phases, we demonstrate selective manipulation of spectral transparency in the visible-light and infrared regions, revealing a dual-band electrochromic effect that could see application in smart windows2,9. Moreover, the starkly different magnetic and electric properties of the three phases-HSrCoO^sub 2.5^ is a weakly ferromagnetic insulator, SrCoO^sub 3-δ^ is a ferromagnetic metal12, and SrCoO^sub 2.5^ is an antiferromagnetic insulator13-enable an unusual form of magnetoelectric coupling, allowing electric-field control of three different magnetic ground states. These findings open up opportunities for the electric-field control of multistate phase transformations with rich functionalities. Phase transformations (Statistical physics) Electric fields Control Usage Transformation Extraction Ferromagnetism Optical properties Fuels Hydrogen Spectra Brownmillerite Accessibility Hydrogen ions Materials science Crystal structure Absorption Enrichment Lithium Transparency Biological evolution Ions Condensed matter physics Phase transformations Infrared radiation Electric field Oxygen Coupling Magnetic properties Antiferromagnetism Insertion Electrochromism Calcium aluminum ferrite Evolution Zhang, Pengfei oth Zhang, Qinghua oth Qiao, Ruimin oth He, Qing oth Li, Hao-Bo oth Wang, Yujia oth Guo, Jingwen oth Zhang, Ding oth Duan, Zheng oth Li, Zhuolu oth Wang, Meng oth Yang, Shuzhen oth Yan, Mingzhe oth Arenholz, Elke oth Zhou, Shuyun oth Yang, Wanli oth Gu, Lin oth Nan, Ce-Wen oth Wu, Jian oth Tokura, Yoshinori oth Yu, Pu oth Enthalten in Nature London : Macmillan Publishers Limited, part of Springer Nature, 1869 546(2017), 7656, Seite 124 (DE-627)129292834 (DE-600)120714-3 (DE-576)014473941 0028-0836 nnns volume:546 year:2017 number:7656 pages:124 http://dx.doi.org/10.1038/nature22389 Volltext https://search.proquest.com/docview/1906107469 GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-FOR SSG-OLC-SPO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-FOR GBV_ILN_11 GBV_ILN_22 GBV_ILN_40 GBV_ILN_47 GBV_ILN_55 GBV_ILN_59 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_101 GBV_ILN_110 GBV_ILN_120 GBV_ILN_135 GBV_ILN_154 GBV_ILN_168 GBV_ILN_170 GBV_ILN_171 GBV_ILN_211 GBV_ILN_252 GBV_ILN_290 GBV_ILN_294 GBV_ILN_601 GBV_ILN_647 GBV_ILN_754 GBV_ILN_2001 GBV_ILN_2002 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2016 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2026 GBV_ILN_2095 GBV_ILN_2116 GBV_ILN_2120 GBV_ILN_2121 GBV_ILN_2219 GBV_ILN_2221 GBV_ILN_2279 GBV_ILN_2286 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4125 GBV_ILN_4219 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4314 GBV_ILN_4317 GBV_ILN_4320 GBV_ILN_4324 AR 546 2017 7656 124 |
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10.1038/nature22389 doi PQ20171125 (DE-627)OLC1994626704 (DE-599)GBVOLC1994626704 (PRQ)g1460-7bc06428e85c100a2f87285b6704e906b0fb2e72ccd288b007dc6d59354c1a6b0 (KEY)0072945020170000546765600124electricfieldcontroloftristatephasetransformationw DE-627 ger DE-627 rakwb eng 070 500 DE-101 500 AVZ BIODIV fid Lu, Nianpeng verfasserin aut Electric-field control of tri-state phase transformation with a selective dual-ion switch 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Materials can be transformed from one crystalline phase to another by using an electric field to control ion transfer, in a process that can be harnessed in applications such as batteries1, smart windows2 and fuel cells3. Increasing the number of transferrable ion species and of accessible crystalline phases could in principle greatly enrich material functionality. However, studies have so far focused mainly on the evolution and control of single ionic species (for example, oxygen, hydrogen or lithium ions4-10). Here we describe the reversible and non-volatile electric-field control of dual-ion (oxygen and hydrogen) phase transformations, with associated electrochromic2 and magnetoelectric11 effects. We show that controlling the insertion and extraction of oxygen and hydrogen ions independently of each other can direct reversible phase transformations among three different material phases: the perovskite SrCoO^sub 3-δ^ (ref. 12), the brownmillerite SrCoO^sub 2.5^ (ref. 13), and a hitherto-unexplored phase, HSrCoO^sub 2.5^. By analysing the distinct optical absorption properties of these phases, we demonstrate selective manipulation of spectral transparency in the visible-light and infrared regions, revealing a dual-band electrochromic effect that could see application in smart windows2,9. Moreover, the starkly different magnetic and electric properties of the three phases-HSrCoO^sub 2.5^ is a weakly ferromagnetic insulator, SrCoO^sub 3-δ^ is a ferromagnetic metal12, and SrCoO^sub 2.5^ is an antiferromagnetic insulator13-enable an unusual form of magnetoelectric coupling, allowing electric-field control of three different magnetic ground states. These findings open up opportunities for the electric-field control of multistate phase transformations with rich functionalities. Phase transformations (Statistical physics) Electric fields Control Usage Transformation Extraction Ferromagnetism Optical properties Fuels Hydrogen Spectra Brownmillerite Accessibility Hydrogen ions Materials science Crystal structure Absorption Enrichment Lithium Transparency Biological evolution Ions Condensed matter physics Phase transformations Infrared radiation Electric field Oxygen Coupling Magnetic properties Antiferromagnetism Insertion Electrochromism Calcium aluminum ferrite Evolution Zhang, Pengfei oth Zhang, Qinghua oth Qiao, Ruimin oth He, Qing oth Li, Hao-Bo oth Wang, Yujia oth Guo, Jingwen oth Zhang, Ding oth Duan, Zheng oth Li, Zhuolu oth Wang, Meng oth Yang, Shuzhen oth Yan, Mingzhe oth Arenholz, Elke oth Zhou, Shuyun oth Yang, Wanli oth Gu, Lin oth Nan, Ce-Wen oth Wu, Jian oth Tokura, Yoshinori oth Yu, Pu oth Enthalten in Nature London : Macmillan Publishers Limited, part of Springer Nature, 1869 546(2017), 7656, Seite 124 (DE-627)129292834 (DE-600)120714-3 (DE-576)014473941 0028-0836 nnns volume:546 year:2017 number:7656 pages:124 http://dx.doi.org/10.1038/nature22389 Volltext https://search.proquest.com/docview/1906107469 GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-FOR SSG-OLC-SPO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-FOR GBV_ILN_11 GBV_ILN_22 GBV_ILN_40 GBV_ILN_47 GBV_ILN_55 GBV_ILN_59 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_101 GBV_ILN_110 GBV_ILN_120 GBV_ILN_135 GBV_ILN_154 GBV_ILN_168 GBV_ILN_170 GBV_ILN_171 GBV_ILN_211 GBV_ILN_252 GBV_ILN_290 GBV_ILN_294 GBV_ILN_601 GBV_ILN_647 GBV_ILN_754 GBV_ILN_2001 GBV_ILN_2002 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2016 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2026 GBV_ILN_2095 GBV_ILN_2116 GBV_ILN_2120 GBV_ILN_2121 GBV_ILN_2219 GBV_ILN_2221 GBV_ILN_2279 GBV_ILN_2286 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4125 GBV_ILN_4219 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4314 GBV_ILN_4317 GBV_ILN_4320 GBV_ILN_4324 AR 546 2017 7656 124 |
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10.1038/nature22389 doi PQ20171125 (DE-627)OLC1994626704 (DE-599)GBVOLC1994626704 (PRQ)g1460-7bc06428e85c100a2f87285b6704e906b0fb2e72ccd288b007dc6d59354c1a6b0 (KEY)0072945020170000546765600124electricfieldcontroloftristatephasetransformationw DE-627 ger DE-627 rakwb eng 070 500 DE-101 500 AVZ BIODIV fid Lu, Nianpeng verfasserin aut Electric-field control of tri-state phase transformation with a selective dual-ion switch 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Materials can be transformed from one crystalline phase to another by using an electric field to control ion transfer, in a process that can be harnessed in applications such as batteries1, smart windows2 and fuel cells3. Increasing the number of transferrable ion species and of accessible crystalline phases could in principle greatly enrich material functionality. However, studies have so far focused mainly on the evolution and control of single ionic species (for example, oxygen, hydrogen or lithium ions4-10). Here we describe the reversible and non-volatile electric-field control of dual-ion (oxygen and hydrogen) phase transformations, with associated electrochromic2 and magnetoelectric11 effects. We show that controlling the insertion and extraction of oxygen and hydrogen ions independently of each other can direct reversible phase transformations among three different material phases: the perovskite SrCoO^sub 3-δ^ (ref. 12), the brownmillerite SrCoO^sub 2.5^ (ref. 13), and a hitherto-unexplored phase, HSrCoO^sub 2.5^. By analysing the distinct optical absorption properties of these phases, we demonstrate selective manipulation of spectral transparency in the visible-light and infrared regions, revealing a dual-band electrochromic effect that could see application in smart windows2,9. Moreover, the starkly different magnetic and electric properties of the three phases-HSrCoO^sub 2.5^ is a weakly ferromagnetic insulator, SrCoO^sub 3-δ^ is a ferromagnetic metal12, and SrCoO^sub 2.5^ is an antiferromagnetic insulator13-enable an unusual form of magnetoelectric coupling, allowing electric-field control of three different magnetic ground states. These findings open up opportunities for the electric-field control of multistate phase transformations with rich functionalities. Phase transformations (Statistical physics) Electric fields Control Usage Transformation Extraction Ferromagnetism Optical properties Fuels Hydrogen Spectra Brownmillerite Accessibility Hydrogen ions Materials science Crystal structure Absorption Enrichment Lithium Transparency Biological evolution Ions Condensed matter physics Phase transformations Infrared radiation Electric field Oxygen Coupling Magnetic properties Antiferromagnetism Insertion Electrochromism Calcium aluminum ferrite Evolution Zhang, Pengfei oth Zhang, Qinghua oth Qiao, Ruimin oth He, Qing oth Li, Hao-Bo oth Wang, Yujia oth Guo, Jingwen oth Zhang, Ding oth Duan, Zheng oth Li, Zhuolu oth Wang, Meng oth Yang, Shuzhen oth Yan, Mingzhe oth Arenholz, Elke oth Zhou, Shuyun oth Yang, Wanli oth Gu, Lin oth Nan, Ce-Wen oth Wu, Jian oth Tokura, Yoshinori oth Yu, Pu oth Enthalten in Nature London : Macmillan Publishers Limited, part of Springer Nature, 1869 546(2017), 7656, Seite 124 (DE-627)129292834 (DE-600)120714-3 (DE-576)014473941 0028-0836 nnns volume:546 year:2017 number:7656 pages:124 http://dx.doi.org/10.1038/nature22389 Volltext https://search.proquest.com/docview/1906107469 GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-FOR SSG-OLC-SPO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-FOR GBV_ILN_11 GBV_ILN_22 GBV_ILN_40 GBV_ILN_47 GBV_ILN_55 GBV_ILN_59 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_101 GBV_ILN_110 GBV_ILN_120 GBV_ILN_135 GBV_ILN_154 GBV_ILN_168 GBV_ILN_170 GBV_ILN_171 GBV_ILN_211 GBV_ILN_252 GBV_ILN_290 GBV_ILN_294 GBV_ILN_601 GBV_ILN_647 GBV_ILN_754 GBV_ILN_2001 GBV_ILN_2002 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2016 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2026 GBV_ILN_2095 GBV_ILN_2116 GBV_ILN_2120 GBV_ILN_2121 GBV_ILN_2219 GBV_ILN_2221 GBV_ILN_2279 GBV_ILN_2286 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4125 GBV_ILN_4219 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4314 GBV_ILN_4317 GBV_ILN_4320 GBV_ILN_4324 AR 546 2017 7656 124 |
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10.1038/nature22389 doi PQ20171125 (DE-627)OLC1994626704 (DE-599)GBVOLC1994626704 (PRQ)g1460-7bc06428e85c100a2f87285b6704e906b0fb2e72ccd288b007dc6d59354c1a6b0 (KEY)0072945020170000546765600124electricfieldcontroloftristatephasetransformationw DE-627 ger DE-627 rakwb eng 070 500 DE-101 500 AVZ BIODIV fid Lu, Nianpeng verfasserin aut Electric-field control of tri-state phase transformation with a selective dual-ion switch 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Materials can be transformed from one crystalline phase to another by using an electric field to control ion transfer, in a process that can be harnessed in applications such as batteries1, smart windows2 and fuel cells3. Increasing the number of transferrable ion species and of accessible crystalline phases could in principle greatly enrich material functionality. However, studies have so far focused mainly on the evolution and control of single ionic species (for example, oxygen, hydrogen or lithium ions4-10). Here we describe the reversible and non-volatile electric-field control of dual-ion (oxygen and hydrogen) phase transformations, with associated electrochromic2 and magnetoelectric11 effects. We show that controlling the insertion and extraction of oxygen and hydrogen ions independently of each other can direct reversible phase transformations among three different material phases: the perovskite SrCoO^sub 3-δ^ (ref. 12), the brownmillerite SrCoO^sub 2.5^ (ref. 13), and a hitherto-unexplored phase, HSrCoO^sub 2.5^. By analysing the distinct optical absorption properties of these phases, we demonstrate selective manipulation of spectral transparency in the visible-light and infrared regions, revealing a dual-band electrochromic effect that could see application in smart windows2,9. Moreover, the starkly different magnetic and electric properties of the three phases-HSrCoO^sub 2.5^ is a weakly ferromagnetic insulator, SrCoO^sub 3-δ^ is a ferromagnetic metal12, and SrCoO^sub 2.5^ is an antiferromagnetic insulator13-enable an unusual form of magnetoelectric coupling, allowing electric-field control of three different magnetic ground states. These findings open up opportunities for the electric-field control of multistate phase transformations with rich functionalities. Phase transformations (Statistical physics) Electric fields Control Usage Transformation Extraction Ferromagnetism Optical properties Fuels Hydrogen Spectra Brownmillerite Accessibility Hydrogen ions Materials science Crystal structure Absorption Enrichment Lithium Transparency Biological evolution Ions Condensed matter physics Phase transformations Infrared radiation Electric field Oxygen Coupling Magnetic properties Antiferromagnetism Insertion Electrochromism Calcium aluminum ferrite Evolution Zhang, Pengfei oth Zhang, Qinghua oth Qiao, Ruimin oth He, Qing oth Li, Hao-Bo oth Wang, Yujia oth Guo, Jingwen oth Zhang, Ding oth Duan, Zheng oth Li, Zhuolu oth Wang, Meng oth Yang, Shuzhen oth Yan, Mingzhe oth Arenholz, Elke oth Zhou, Shuyun oth Yang, Wanli oth Gu, Lin oth Nan, Ce-Wen oth Wu, Jian oth Tokura, Yoshinori oth Yu, Pu oth Enthalten in Nature London : Macmillan Publishers Limited, part of Springer Nature, 1869 546(2017), 7656, Seite 124 (DE-627)129292834 (DE-600)120714-3 (DE-576)014473941 0028-0836 nnns volume:546 year:2017 number:7656 pages:124 http://dx.doi.org/10.1038/nature22389 Volltext https://search.proquest.com/docview/1906107469 GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-MAT SSG-OLC-FOR SSG-OLC-SPO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-FOR GBV_ILN_11 GBV_ILN_22 GBV_ILN_40 GBV_ILN_47 GBV_ILN_55 GBV_ILN_59 GBV_ILN_60 GBV_ILN_62 GBV_ILN_69 GBV_ILN_70 GBV_ILN_73 GBV_ILN_101 GBV_ILN_110 GBV_ILN_120 GBV_ILN_135 GBV_ILN_154 GBV_ILN_168 GBV_ILN_170 GBV_ILN_171 GBV_ILN_211 GBV_ILN_252 GBV_ILN_290 GBV_ILN_294 GBV_ILN_601 GBV_ILN_647 GBV_ILN_754 GBV_ILN_2001 GBV_ILN_2002 GBV_ILN_2005 GBV_ILN_2007 GBV_ILN_2008 GBV_ILN_2016 GBV_ILN_2018 GBV_ILN_2020 GBV_ILN_2026 GBV_ILN_2095 GBV_ILN_2116 GBV_ILN_2120 GBV_ILN_2121 GBV_ILN_2219 GBV_ILN_2221 GBV_ILN_2279 GBV_ILN_2286 GBV_ILN_4012 GBV_ILN_4035 GBV_ILN_4125 GBV_ILN_4219 GBV_ILN_4251 GBV_ILN_4277 GBV_ILN_4302 GBV_ILN_4305 GBV_ILN_4313 GBV_ILN_4314 GBV_ILN_4317 GBV_ILN_4320 GBV_ILN_4324 AR 546 2017 7656 124 |
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Phase transformations (Statistical physics) Electric fields Control Usage Transformation Extraction Ferromagnetism Optical properties Fuels Hydrogen Spectra Brownmillerite Accessibility Hydrogen ions Materials science Crystal structure Absorption Enrichment Lithium Transparency Biological evolution Ions Condensed matter physics Phase transformations Infrared radiation Electric field Oxygen Coupling Magnetic properties Antiferromagnetism Insertion Electrochromism Calcium aluminum ferrite Evolution |
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Lu, Nianpeng @@aut@@ Zhang, Pengfei @@oth@@ Zhang, Qinghua @@oth@@ Qiao, Ruimin @@oth@@ He, Qing @@oth@@ Li, Hao-Bo @@oth@@ Wang, Yujia @@oth@@ Guo, Jingwen @@oth@@ Zhang, Ding @@oth@@ Duan, Zheng @@oth@@ Li, Zhuolu @@oth@@ Wang, Meng @@oth@@ Yang, Shuzhen @@oth@@ Yan, Mingzhe @@oth@@ Arenholz, Elke @@oth@@ Zhou, Shuyun @@oth@@ Yang, Wanli @@oth@@ Gu, Lin @@oth@@ Nan, Ce-Wen @@oth@@ Wu, Jian @@oth@@ Tokura, Yoshinori @@oth@@ Yu, Pu @@oth@@ |
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Lu, Nianpeng ddc 070 ddc 500 fid BIODIV misc Phase transformations (Statistical physics) misc Electric fields misc Control misc Usage misc Transformation misc Extraction misc Ferromagnetism misc Optical properties misc Fuels misc Hydrogen misc Spectra misc Brownmillerite misc Accessibility misc Hydrogen ions misc Materials science misc Crystal structure misc Absorption misc Enrichment misc Lithium misc Transparency misc Biological evolution misc Ions misc Condensed matter physics misc Phase transformations misc Infrared radiation misc Electric field misc Oxygen misc Coupling misc Magnetic properties misc Antiferromagnetism misc Insertion misc Electrochromism misc Calcium aluminum ferrite misc Evolution Electric-field control of tri-state phase transformation with a selective dual-ion switch |
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070 500 DE-101 500 AVZ BIODIV fid Electric-field control of tri-state phase transformation with a selective dual-ion switch Phase transformations (Statistical physics) Electric fields Control Usage Transformation Extraction Ferromagnetism Optical properties Fuels Hydrogen Spectra Brownmillerite Accessibility Hydrogen ions Materials science Crystal structure Absorption Enrichment Lithium Transparency Biological evolution Ions Condensed matter physics Phase transformations Infrared radiation Electric field Oxygen Coupling Magnetic properties Antiferromagnetism Insertion Electrochromism Calcium aluminum ferrite Evolution |
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electric-field control of tri-state phase transformation with a selective dual-ion switch |
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Electric-field control of tri-state phase transformation with a selective dual-ion switch |
| abstract |
Materials can be transformed from one crystalline phase to another by using an electric field to control ion transfer, in a process that can be harnessed in applications such as batteries1, smart windows2 and fuel cells3. Increasing the number of transferrable ion species and of accessible crystalline phases could in principle greatly enrich material functionality. However, studies have so far focused mainly on the evolution and control of single ionic species (for example, oxygen, hydrogen or lithium ions4-10). Here we describe the reversible and non-volatile electric-field control of dual-ion (oxygen and hydrogen) phase transformations, with associated electrochromic2 and magnetoelectric11 effects. We show that controlling the insertion and extraction of oxygen and hydrogen ions independently of each other can direct reversible phase transformations among three different material phases: the perovskite SrCoO^sub 3-δ^ (ref. 12), the brownmillerite SrCoO^sub 2.5^ (ref. 13), and a hitherto-unexplored phase, HSrCoO^sub 2.5^. By analysing the distinct optical absorption properties of these phases, we demonstrate selective manipulation of spectral transparency in the visible-light and infrared regions, revealing a dual-band electrochromic effect that could see application in smart windows2,9. Moreover, the starkly different magnetic and electric properties of the three phases-HSrCoO^sub 2.5^ is a weakly ferromagnetic insulator, SrCoO^sub 3-δ^ is a ferromagnetic metal12, and SrCoO^sub 2.5^ is an antiferromagnetic insulator13-enable an unusual form of magnetoelectric coupling, allowing electric-field control of three different magnetic ground states. These findings open up opportunities for the electric-field control of multistate phase transformations with rich functionalities. |
| abstractGer |
Materials can be transformed from one crystalline phase to another by using an electric field to control ion transfer, in a process that can be harnessed in applications such as batteries1, smart windows2 and fuel cells3. Increasing the number of transferrable ion species and of accessible crystalline phases could in principle greatly enrich material functionality. However, studies have so far focused mainly on the evolution and control of single ionic species (for example, oxygen, hydrogen or lithium ions4-10). Here we describe the reversible and non-volatile electric-field control of dual-ion (oxygen and hydrogen) phase transformations, with associated electrochromic2 and magnetoelectric11 effects. We show that controlling the insertion and extraction of oxygen and hydrogen ions independently of each other can direct reversible phase transformations among three different material phases: the perovskite SrCoO^sub 3-δ^ (ref. 12), the brownmillerite SrCoO^sub 2.5^ (ref. 13), and a hitherto-unexplored phase, HSrCoO^sub 2.5^. By analysing the distinct optical absorption properties of these phases, we demonstrate selective manipulation of spectral transparency in the visible-light and infrared regions, revealing a dual-band electrochromic effect that could see application in smart windows2,9. Moreover, the starkly different magnetic and electric properties of the three phases-HSrCoO^sub 2.5^ is a weakly ferromagnetic insulator, SrCoO^sub 3-δ^ is a ferromagnetic metal12, and SrCoO^sub 2.5^ is an antiferromagnetic insulator13-enable an unusual form of magnetoelectric coupling, allowing electric-field control of three different magnetic ground states. These findings open up opportunities for the electric-field control of multistate phase transformations with rich functionalities. |
| abstract_unstemmed |
Materials can be transformed from one crystalline phase to another by using an electric field to control ion transfer, in a process that can be harnessed in applications such as batteries1, smart windows2 and fuel cells3. Increasing the number of transferrable ion species and of accessible crystalline phases could in principle greatly enrich material functionality. However, studies have so far focused mainly on the evolution and control of single ionic species (for example, oxygen, hydrogen or lithium ions4-10). Here we describe the reversible and non-volatile electric-field control of dual-ion (oxygen and hydrogen) phase transformations, with associated electrochromic2 and magnetoelectric11 effects. We show that controlling the insertion and extraction of oxygen and hydrogen ions independently of each other can direct reversible phase transformations among three different material phases: the perovskite SrCoO^sub 3-δ^ (ref. 12), the brownmillerite SrCoO^sub 2.5^ (ref. 13), and a hitherto-unexplored phase, HSrCoO^sub 2.5^. By analysing the distinct optical absorption properties of these phases, we demonstrate selective manipulation of spectral transparency in the visible-light and infrared regions, revealing a dual-band electrochromic effect that could see application in smart windows2,9. Moreover, the starkly different magnetic and electric properties of the three phases-HSrCoO^sub 2.5^ is a weakly ferromagnetic insulator, SrCoO^sub 3-δ^ is a ferromagnetic metal12, and SrCoO^sub 2.5^ is an antiferromagnetic insulator13-enable an unusual form of magnetoelectric coupling, allowing electric-field control of three different magnetic ground states. These findings open up opportunities for the electric-field control of multistate phase transformations with rich functionalities. |
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<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a2200265 4500</leader><controlfield tag="001">OLC1994626704</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230715054413.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">170721s2017 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1038/nature22389</subfield><subfield code="2">doi</subfield></datafield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">PQ20171125</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC1994626704</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVOLC1994626704</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(PRQ)g1460-7bc06428e85c100a2f87285b6704e906b0fb2e72ccd288b007dc6d59354c1a6b0</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(KEY)0072945020170000546765600124electricfieldcontroloftristatephasetransformationw</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">070</subfield><subfield code="a">500</subfield><subfield code="q">DE-101</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">500</subfield><subfield code="q">AVZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">BIODIV</subfield><subfield code="2">fid</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Lu, Nianpeng</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Electric-field control of tri-state phase transformation with a selective dual-ion switch</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2017</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Materials can be transformed from one crystalline phase to another by using an electric field to control ion transfer, in a process that can be harnessed in applications such as batteries1, smart windows2 and fuel cells3. Increasing the number of transferrable ion species and of accessible crystalline phases could in principle greatly enrich material functionality. However, studies have so far focused mainly on the evolution and control of single ionic species (for example, oxygen, hydrogen or lithium ions4-10). Here we describe the reversible and non-volatile electric-field control of dual-ion (oxygen and hydrogen) phase transformations, with associated electrochromic2 and magnetoelectric11 effects. We show that controlling the insertion and extraction of oxygen and hydrogen ions independently of each other can direct reversible phase transformations among three different material phases: the perovskite SrCoO^sub 3-δ^ (ref. 12), the brownmillerite SrCoO^sub 2.5^ (ref. 13), and a hitherto-unexplored phase, HSrCoO^sub 2.5^. By analysing the distinct optical absorption properties of these phases, we demonstrate selective manipulation of spectral transparency in the visible-light and infrared regions, revealing a dual-band electrochromic effect that could see application in smart windows2,9. Moreover, the starkly different magnetic and electric properties of the three phases-HSrCoO^sub 2.5^ is a weakly ferromagnetic insulator, SrCoO^sub 3-δ^ is a ferromagnetic metal12, and SrCoO^sub 2.5^ is an antiferromagnetic insulator13-enable an unusual form of magnetoelectric coupling, allowing electric-field control of three different magnetic ground states. 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