Almost complete peritectic reaction in YBa2(Cu1−xFex)3O7−δ crystallization involving nanosized primary phase
Study on peritectic reaction is a matter of significant importance in materials science, which generally involves in the solidification of most functional oxide materials, for example, the YB a 2 Cu 3 O 7−δ (Y123) superconductor could be grown via a reaction of Y 2 BaCuO 5 (Y211) + Liquid→Y123. Due...
Ausführliche Beschreibung
Autor*in: |
Qian, Jun [verfasserIn] |
---|
Format: |
Artikel |
---|---|
Sprache: |
Englisch |
Erschienen: |
2017 |
---|
Rechteinformationen: |
Nutzungsrecht: © 2017 The American Ceramic Society |
---|
Schlagwörter: |
---|
Übergeordnetes Werk: |
Enthalten in: Journal of the American Ceramic Society - Malden [u.a.] : Blackwell Publishing, 1918, 100(2017), 5, Seite 1804-1813 |
---|---|
Übergeordnetes Werk: |
volume:100 ; year:2017 ; number:5 ; pages:1804-1813 |
Links: |
---|
DOI / URN: |
10.1111/jace.14765 |
---|
Katalog-ID: |
OLC1994799382 |
---|
LEADER | 01000caa a2200265 4500 | ||
---|---|---|---|
001 | OLC1994799382 | ||
003 | DE-627 | ||
005 | 20230715055125.0 | ||
007 | tu | ||
008 | 170721s2017 xx ||||| 00| ||eng c | ||
024 | 7 | |a 10.1111/jace.14765 |2 doi | |
028 | 5 | 2 | |a PQ20170901 |
035 | |a (DE-627)OLC1994799382 | ||
035 | |a (DE-599)GBVOLC1994799382 | ||
035 | |a (PRQ)s1382-b1d770b3bb4d2fc2c1d2643ab76cc084e63c1aab6ec16165906ecf1cd9efd4180 | ||
035 | |a (KEY)0108608120170000100000501804almostcompleteperitecticreactioninyba2cu1xfex3o7cr | ||
040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
041 | |a eng | ||
082 | 0 | 4 | |a 660 |q DE-101 |
100 | 1 | |a Qian, Jun |e verfasserin |4 aut | |
245 | 1 | 0 | |a Almost complete peritectic reaction in YBa2(Cu1−xFex)3O7−δ crystallization involving nanosized primary phase |
264 | 1 | |c 2017 | |
336 | |a Text |b txt |2 rdacontent | ||
337 | |a ohne Hilfsmittel zu benutzen |b n |2 rdamedia | ||
338 | |a Band |b nc |2 rdacarrier | ||
520 | |a Study on peritectic reaction is a matter of significant importance in materials science, which generally involves in the solidification of most functional oxide materials, for example, the YB a 2 Cu 3 O 7−δ (Y123) superconductor could be grown via a reaction of Y 2 BaCuO 5 (Y211) + Liquid→Y123. Due to its crystallization characteristic, the growth of those materials does not entirely proceed, which severely impedes the development of industrialized process. Thus the realization of a complete peritectic reaction is an interesting issue for both theory and experiment. Here, we report an almost complete peritectic reaction occurring in the growth of YBa 2 (Cu 1− x Fe x ) 3 O 7−δ crystals using modified melt‐growth. Our findings remarkably show that Y211 almost fully reacted with liquid to generate Y123, remaining approximately 1 vol%, evidently lower than that in the normal case. The nature of this unconventional phenomenon is clarified that the Fe‐doping elevates the nucleation barrier in the peritectic melting of Y123 and causes a massive homogeneous nucleation catastrophe, leading to nanosized and dispersive Y211 particles, which readily and almost fully dissolve in the subsequent peritectic solidification of Y123. Most importantly, the new conception derived from this work is promising for reviving other functional materials, which are disregarded due to their incomplete peritectic reactions. | ||
540 | |a Nutzungsrecht: © 2017 The American Ceramic Society | ||
650 | 4 | |a superconductor | |
650 | 4 | |a yttrium compounds | |
650 | 4 | |a nucleation | |
650 | 4 | |a nanoparticles | |
650 | 4 | |a chemical doping | |
700 | 1 | |a Fan, Wenshuo |4 oth | |
700 | 1 | |a Du, Gehai |4 oth | |
700 | 1 | |a Li, Haochen |4 oth | |
700 | 1 | |a Xiang, Hui |4 oth | |
700 | 1 | |a Hussain, Ghulam |4 oth | |
700 | 1 | |a Liu, Yan |4 oth | |
700 | 1 | |a Cui, Xiangxiang |4 oth | |
700 | 1 | |a Diko, Pavel |4 oth | |
700 | 1 | |a Yao, Xin |4 oth | |
700 | 1 | |a Zou, Zhiqiang |4 oth | |
773 | 0 | 8 | |i Enthalten in |t Journal of the American Ceramic Society |d Malden [u.a.] : Blackwell Publishing, 1918 |g 100(2017), 5, Seite 1804-1813 |w (DE-627)129550272 |w (DE-600)219232-9 |w (DE-576)015003671 |x 0002-7820 |7 nnns |
773 | 1 | 8 | |g volume:100 |g year:2017 |g number:5 |g pages:1804-1813 |
856 | 4 | 1 | |u http://dx.doi.org/10.1111/jace.14765 |3 Volltext |
856 | 4 | 2 | |u http://onlinelibrary.wiley.com/doi/10.1111/jace.14765/abstract |
912 | |a GBV_USEFLAG_A | ||
912 | |a SYSFLAG_A | ||
912 | |a GBV_OLC | ||
912 | |a SSG-OLC-TEC | ||
912 | |a SSG-OLC-CHE | ||
912 | |a SSG-OLC-PHA | ||
912 | |a SSG-OLC-DE-84 | ||
912 | |a GBV_ILN_22 | ||
912 | |a GBV_ILN_70 | ||
912 | |a GBV_ILN_2004 | ||
912 | |a GBV_ILN_2014 | ||
951 | |a AR | ||
952 | |d 100 |j 2017 |e 5 |h 1804-1813 |
author_variant |
j q jq |
---|---|
matchkey_str |
article:00027820:2017----::lotopeeeietcecinnb2uxe37rsalztoivl |
hierarchy_sort_str |
2017 |
publishDate |
2017 |
allfields |
10.1111/jace.14765 doi PQ20170901 (DE-627)OLC1994799382 (DE-599)GBVOLC1994799382 (PRQ)s1382-b1d770b3bb4d2fc2c1d2643ab76cc084e63c1aab6ec16165906ecf1cd9efd4180 (KEY)0108608120170000100000501804almostcompleteperitecticreactioninyba2cu1xfex3o7cr DE-627 ger DE-627 rakwb eng 660 DE-101 Qian, Jun verfasserin aut Almost complete peritectic reaction in YBa2(Cu1−xFex)3O7−δ crystallization involving nanosized primary phase 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Study on peritectic reaction is a matter of significant importance in materials science, which generally involves in the solidification of most functional oxide materials, for example, the YB a 2 Cu 3 O 7−δ (Y123) superconductor could be grown via a reaction of Y 2 BaCuO 5 (Y211) + Liquid→Y123. Due to its crystallization characteristic, the growth of those materials does not entirely proceed, which severely impedes the development of industrialized process. Thus the realization of a complete peritectic reaction is an interesting issue for both theory and experiment. Here, we report an almost complete peritectic reaction occurring in the growth of YBa 2 (Cu 1− x Fe x ) 3 O 7−δ crystals using modified melt‐growth. Our findings remarkably show that Y211 almost fully reacted with liquid to generate Y123, remaining approximately 1 vol%, evidently lower than that in the normal case. The nature of this unconventional phenomenon is clarified that the Fe‐doping elevates the nucleation barrier in the peritectic melting of Y123 and causes a massive homogeneous nucleation catastrophe, leading to nanosized and dispersive Y211 particles, which readily and almost fully dissolve in the subsequent peritectic solidification of Y123. Most importantly, the new conception derived from this work is promising for reviving other functional materials, which are disregarded due to their incomplete peritectic reactions. Nutzungsrecht: © 2017 The American Ceramic Society superconductor yttrium compounds nucleation nanoparticles chemical doping Fan, Wenshuo oth Du, Gehai oth Li, Haochen oth Xiang, Hui oth Hussain, Ghulam oth Liu, Yan oth Cui, Xiangxiang oth Diko, Pavel oth Yao, Xin oth Zou, Zhiqiang oth Enthalten in Journal of the American Ceramic Society Malden [u.a.] : Blackwell Publishing, 1918 100(2017), 5, Seite 1804-1813 (DE-627)129550272 (DE-600)219232-9 (DE-576)015003671 0002-7820 nnns volume:100 year:2017 number:5 pages:1804-1813 http://dx.doi.org/10.1111/jace.14765 Volltext http://onlinelibrary.wiley.com/doi/10.1111/jace.14765/abstract GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_22 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2014 AR 100 2017 5 1804-1813 |
spelling |
10.1111/jace.14765 doi PQ20170901 (DE-627)OLC1994799382 (DE-599)GBVOLC1994799382 (PRQ)s1382-b1d770b3bb4d2fc2c1d2643ab76cc084e63c1aab6ec16165906ecf1cd9efd4180 (KEY)0108608120170000100000501804almostcompleteperitecticreactioninyba2cu1xfex3o7cr DE-627 ger DE-627 rakwb eng 660 DE-101 Qian, Jun verfasserin aut Almost complete peritectic reaction in YBa2(Cu1−xFex)3O7−δ crystallization involving nanosized primary phase 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Study on peritectic reaction is a matter of significant importance in materials science, which generally involves in the solidification of most functional oxide materials, for example, the YB a 2 Cu 3 O 7−δ (Y123) superconductor could be grown via a reaction of Y 2 BaCuO 5 (Y211) + Liquid→Y123. Due to its crystallization characteristic, the growth of those materials does not entirely proceed, which severely impedes the development of industrialized process. Thus the realization of a complete peritectic reaction is an interesting issue for both theory and experiment. Here, we report an almost complete peritectic reaction occurring in the growth of YBa 2 (Cu 1− x Fe x ) 3 O 7−δ crystals using modified melt‐growth. Our findings remarkably show that Y211 almost fully reacted with liquid to generate Y123, remaining approximately 1 vol%, evidently lower than that in the normal case. The nature of this unconventional phenomenon is clarified that the Fe‐doping elevates the nucleation barrier in the peritectic melting of Y123 and causes a massive homogeneous nucleation catastrophe, leading to nanosized and dispersive Y211 particles, which readily and almost fully dissolve in the subsequent peritectic solidification of Y123. Most importantly, the new conception derived from this work is promising for reviving other functional materials, which are disregarded due to their incomplete peritectic reactions. Nutzungsrecht: © 2017 The American Ceramic Society superconductor yttrium compounds nucleation nanoparticles chemical doping Fan, Wenshuo oth Du, Gehai oth Li, Haochen oth Xiang, Hui oth Hussain, Ghulam oth Liu, Yan oth Cui, Xiangxiang oth Diko, Pavel oth Yao, Xin oth Zou, Zhiqiang oth Enthalten in Journal of the American Ceramic Society Malden [u.a.] : Blackwell Publishing, 1918 100(2017), 5, Seite 1804-1813 (DE-627)129550272 (DE-600)219232-9 (DE-576)015003671 0002-7820 nnns volume:100 year:2017 number:5 pages:1804-1813 http://dx.doi.org/10.1111/jace.14765 Volltext http://onlinelibrary.wiley.com/doi/10.1111/jace.14765/abstract GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_22 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2014 AR 100 2017 5 1804-1813 |
allfields_unstemmed |
10.1111/jace.14765 doi PQ20170901 (DE-627)OLC1994799382 (DE-599)GBVOLC1994799382 (PRQ)s1382-b1d770b3bb4d2fc2c1d2643ab76cc084e63c1aab6ec16165906ecf1cd9efd4180 (KEY)0108608120170000100000501804almostcompleteperitecticreactioninyba2cu1xfex3o7cr DE-627 ger DE-627 rakwb eng 660 DE-101 Qian, Jun verfasserin aut Almost complete peritectic reaction in YBa2(Cu1−xFex)3O7−δ crystallization involving nanosized primary phase 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Study on peritectic reaction is a matter of significant importance in materials science, which generally involves in the solidification of most functional oxide materials, for example, the YB a 2 Cu 3 O 7−δ (Y123) superconductor could be grown via a reaction of Y 2 BaCuO 5 (Y211) + Liquid→Y123. Due to its crystallization characteristic, the growth of those materials does not entirely proceed, which severely impedes the development of industrialized process. Thus the realization of a complete peritectic reaction is an interesting issue for both theory and experiment. Here, we report an almost complete peritectic reaction occurring in the growth of YBa 2 (Cu 1− x Fe x ) 3 O 7−δ crystals using modified melt‐growth. Our findings remarkably show that Y211 almost fully reacted with liquid to generate Y123, remaining approximately 1 vol%, evidently lower than that in the normal case. The nature of this unconventional phenomenon is clarified that the Fe‐doping elevates the nucleation barrier in the peritectic melting of Y123 and causes a massive homogeneous nucleation catastrophe, leading to nanosized and dispersive Y211 particles, which readily and almost fully dissolve in the subsequent peritectic solidification of Y123. Most importantly, the new conception derived from this work is promising for reviving other functional materials, which are disregarded due to their incomplete peritectic reactions. Nutzungsrecht: © 2017 The American Ceramic Society superconductor yttrium compounds nucleation nanoparticles chemical doping Fan, Wenshuo oth Du, Gehai oth Li, Haochen oth Xiang, Hui oth Hussain, Ghulam oth Liu, Yan oth Cui, Xiangxiang oth Diko, Pavel oth Yao, Xin oth Zou, Zhiqiang oth Enthalten in Journal of the American Ceramic Society Malden [u.a.] : Blackwell Publishing, 1918 100(2017), 5, Seite 1804-1813 (DE-627)129550272 (DE-600)219232-9 (DE-576)015003671 0002-7820 nnns volume:100 year:2017 number:5 pages:1804-1813 http://dx.doi.org/10.1111/jace.14765 Volltext http://onlinelibrary.wiley.com/doi/10.1111/jace.14765/abstract GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_22 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2014 AR 100 2017 5 1804-1813 |
allfieldsGer |
10.1111/jace.14765 doi PQ20170901 (DE-627)OLC1994799382 (DE-599)GBVOLC1994799382 (PRQ)s1382-b1d770b3bb4d2fc2c1d2643ab76cc084e63c1aab6ec16165906ecf1cd9efd4180 (KEY)0108608120170000100000501804almostcompleteperitecticreactioninyba2cu1xfex3o7cr DE-627 ger DE-627 rakwb eng 660 DE-101 Qian, Jun verfasserin aut Almost complete peritectic reaction in YBa2(Cu1−xFex)3O7−δ crystallization involving nanosized primary phase 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Study on peritectic reaction is a matter of significant importance in materials science, which generally involves in the solidification of most functional oxide materials, for example, the YB a 2 Cu 3 O 7−δ (Y123) superconductor could be grown via a reaction of Y 2 BaCuO 5 (Y211) + Liquid→Y123. Due to its crystallization characteristic, the growth of those materials does not entirely proceed, which severely impedes the development of industrialized process. Thus the realization of a complete peritectic reaction is an interesting issue for both theory and experiment. Here, we report an almost complete peritectic reaction occurring in the growth of YBa 2 (Cu 1− x Fe x ) 3 O 7−δ crystals using modified melt‐growth. Our findings remarkably show that Y211 almost fully reacted with liquid to generate Y123, remaining approximately 1 vol%, evidently lower than that in the normal case. The nature of this unconventional phenomenon is clarified that the Fe‐doping elevates the nucleation barrier in the peritectic melting of Y123 and causes a massive homogeneous nucleation catastrophe, leading to nanosized and dispersive Y211 particles, which readily and almost fully dissolve in the subsequent peritectic solidification of Y123. Most importantly, the new conception derived from this work is promising for reviving other functional materials, which are disregarded due to their incomplete peritectic reactions. Nutzungsrecht: © 2017 The American Ceramic Society superconductor yttrium compounds nucleation nanoparticles chemical doping Fan, Wenshuo oth Du, Gehai oth Li, Haochen oth Xiang, Hui oth Hussain, Ghulam oth Liu, Yan oth Cui, Xiangxiang oth Diko, Pavel oth Yao, Xin oth Zou, Zhiqiang oth Enthalten in Journal of the American Ceramic Society Malden [u.a.] : Blackwell Publishing, 1918 100(2017), 5, Seite 1804-1813 (DE-627)129550272 (DE-600)219232-9 (DE-576)015003671 0002-7820 nnns volume:100 year:2017 number:5 pages:1804-1813 http://dx.doi.org/10.1111/jace.14765 Volltext http://onlinelibrary.wiley.com/doi/10.1111/jace.14765/abstract GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_22 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2014 AR 100 2017 5 1804-1813 |
allfieldsSound |
10.1111/jace.14765 doi PQ20170901 (DE-627)OLC1994799382 (DE-599)GBVOLC1994799382 (PRQ)s1382-b1d770b3bb4d2fc2c1d2643ab76cc084e63c1aab6ec16165906ecf1cd9efd4180 (KEY)0108608120170000100000501804almostcompleteperitecticreactioninyba2cu1xfex3o7cr DE-627 ger DE-627 rakwb eng 660 DE-101 Qian, Jun verfasserin aut Almost complete peritectic reaction in YBa2(Cu1−xFex)3O7−δ crystallization involving nanosized primary phase 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Study on peritectic reaction is a matter of significant importance in materials science, which generally involves in the solidification of most functional oxide materials, for example, the YB a 2 Cu 3 O 7−δ (Y123) superconductor could be grown via a reaction of Y 2 BaCuO 5 (Y211) + Liquid→Y123. Due to its crystallization characteristic, the growth of those materials does not entirely proceed, which severely impedes the development of industrialized process. Thus the realization of a complete peritectic reaction is an interesting issue for both theory and experiment. Here, we report an almost complete peritectic reaction occurring in the growth of YBa 2 (Cu 1− x Fe x ) 3 O 7−δ crystals using modified melt‐growth. Our findings remarkably show that Y211 almost fully reacted with liquid to generate Y123, remaining approximately 1 vol%, evidently lower than that in the normal case. The nature of this unconventional phenomenon is clarified that the Fe‐doping elevates the nucleation barrier in the peritectic melting of Y123 and causes a massive homogeneous nucleation catastrophe, leading to nanosized and dispersive Y211 particles, which readily and almost fully dissolve in the subsequent peritectic solidification of Y123. Most importantly, the new conception derived from this work is promising for reviving other functional materials, which are disregarded due to their incomplete peritectic reactions. Nutzungsrecht: © 2017 The American Ceramic Society superconductor yttrium compounds nucleation nanoparticles chemical doping Fan, Wenshuo oth Du, Gehai oth Li, Haochen oth Xiang, Hui oth Hussain, Ghulam oth Liu, Yan oth Cui, Xiangxiang oth Diko, Pavel oth Yao, Xin oth Zou, Zhiqiang oth Enthalten in Journal of the American Ceramic Society Malden [u.a.] : Blackwell Publishing, 1918 100(2017), 5, Seite 1804-1813 (DE-627)129550272 (DE-600)219232-9 (DE-576)015003671 0002-7820 nnns volume:100 year:2017 number:5 pages:1804-1813 http://dx.doi.org/10.1111/jace.14765 Volltext http://onlinelibrary.wiley.com/doi/10.1111/jace.14765/abstract GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_22 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2014 AR 100 2017 5 1804-1813 |
language |
English |
source |
Enthalten in Journal of the American Ceramic Society 100(2017), 5, Seite 1804-1813 volume:100 year:2017 number:5 pages:1804-1813 |
sourceStr |
Enthalten in Journal of the American Ceramic Society 100(2017), 5, Seite 1804-1813 volume:100 year:2017 number:5 pages:1804-1813 |
format_phy_str_mv |
Article |
institution |
findex.gbv.de |
topic_facet |
superconductor yttrium compounds nucleation nanoparticles chemical doping |
dewey-raw |
660 |
isfreeaccess_bool |
false |
container_title |
Journal of the American Ceramic Society |
authorswithroles_txt_mv |
Qian, Jun @@aut@@ Fan, Wenshuo @@oth@@ Du, Gehai @@oth@@ Li, Haochen @@oth@@ Xiang, Hui @@oth@@ Hussain, Ghulam @@oth@@ Liu, Yan @@oth@@ Cui, Xiangxiang @@oth@@ Diko, Pavel @@oth@@ Yao, Xin @@oth@@ Zou, Zhiqiang @@oth@@ |
publishDateDaySort_date |
2017-01-01T00:00:00Z |
hierarchy_top_id |
129550272 |
dewey-sort |
3660 |
id |
OLC1994799382 |
language_de |
englisch |
fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a2200265 4500</leader><controlfield tag="001">OLC1994799382</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230715055125.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">170721s2017 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1111/jace.14765</subfield><subfield code="2">doi</subfield></datafield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">PQ20170901</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC1994799382</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVOLC1994799382</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(PRQ)s1382-b1d770b3bb4d2fc2c1d2643ab76cc084e63c1aab6ec16165906ecf1cd9efd4180</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(KEY)0108608120170000100000501804almostcompleteperitecticreactioninyba2cu1xfex3o7cr</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">DE-101</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Qian, Jun</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Almost complete peritectic reaction in YBa2(Cu1−xFex)3O7−δ crystallization involving nanosized primary phase</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2017</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Study on peritectic reaction is a matter of significant importance in materials science, which generally involves in the solidification of most functional oxide materials, for example, the YB a 2 Cu 3 O 7−δ (Y123) superconductor could be grown via a reaction of Y 2 BaCuO 5 (Y211) + Liquid→Y123. Due to its crystallization characteristic, the growth of those materials does not entirely proceed, which severely impedes the development of industrialized process. Thus the realization of a complete peritectic reaction is an interesting issue for both theory and experiment. Here, we report an almost complete peritectic reaction occurring in the growth of YBa 2 (Cu 1− x Fe x ) 3 O 7−δ crystals using modified melt‐growth. Our findings remarkably show that Y211 almost fully reacted with liquid to generate Y123, remaining approximately 1 vol%, evidently lower than that in the normal case. The nature of this unconventional phenomenon is clarified that the Fe‐doping elevates the nucleation barrier in the peritectic melting of Y123 and causes a massive homogeneous nucleation catastrophe, leading to nanosized and dispersive Y211 particles, which readily and almost fully dissolve in the subsequent peritectic solidification of Y123. Most importantly, the new conception derived from this work is promising for reviving other functional materials, which are disregarded due to their incomplete peritectic reactions.</subfield></datafield><datafield tag="540" ind1=" " ind2=" "><subfield code="a">Nutzungsrecht: © 2017 The American Ceramic Society</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">superconductor</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">yttrium compounds</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">nucleation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">nanoparticles</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">chemical doping</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Fan, Wenshuo</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Du, Gehai</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Li, Haochen</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Xiang, Hui</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Hussain, Ghulam</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Liu, Yan</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Cui, Xiangxiang</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Diko, Pavel</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yao, Xin</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zou, Zhiqiang</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of the American Ceramic Society</subfield><subfield code="d">Malden [u.a.] : Blackwell Publishing, 1918</subfield><subfield code="g">100(2017), 5, Seite 1804-1813</subfield><subfield code="w">(DE-627)129550272</subfield><subfield code="w">(DE-600)219232-9</subfield><subfield code="w">(DE-576)015003671</subfield><subfield code="x">0002-7820</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:100</subfield><subfield code="g">year:2017</subfield><subfield code="g">number:5</subfield><subfield code="g">pages:1804-1813</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">http://dx.doi.org/10.1111/jace.14765</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">http://onlinelibrary.wiley.com/doi/10.1111/jace.14765/abstract</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-DE-84</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">100</subfield><subfield code="j">2017</subfield><subfield code="e">5</subfield><subfield code="h">1804-1813</subfield></datafield></record></collection>
|
author |
Qian, Jun |
spellingShingle |
Qian, Jun ddc 660 misc superconductor misc yttrium compounds misc nucleation misc nanoparticles misc chemical doping Almost complete peritectic reaction in YBa2(Cu1−xFex)3O7−δ crystallization involving nanosized primary phase |
authorStr |
Qian, Jun |
ppnlink_with_tag_str_mv |
@@773@@(DE-627)129550272 |
format |
Article |
dewey-ones |
660 - Chemical engineering |
delete_txt_mv |
keep |
author_role |
aut |
collection |
OLC |
remote_str |
false |
illustrated |
Not Illustrated |
issn |
0002-7820 |
topic_title |
660 DE-101 Almost complete peritectic reaction in YBa2(Cu1−xFex)3O7−δ crystallization involving nanosized primary phase superconductor yttrium compounds nucleation nanoparticles chemical doping |
topic |
ddc 660 misc superconductor misc yttrium compounds misc nucleation misc nanoparticles misc chemical doping |
topic_unstemmed |
ddc 660 misc superconductor misc yttrium compounds misc nucleation misc nanoparticles misc chemical doping |
topic_browse |
ddc 660 misc superconductor misc yttrium compounds misc nucleation misc nanoparticles misc chemical doping |
format_facet |
Aufsätze Gedruckte Aufsätze |
format_main_str_mv |
Text Zeitschrift/Artikel |
carriertype_str_mv |
nc |
author2_variant |
w f wf g d gd h l hl h x hx g h gh y l yl x c xc p d pd x y xy z z zz |
hierarchy_parent_title |
Journal of the American Ceramic Society |
hierarchy_parent_id |
129550272 |
dewey-tens |
660 - Chemical engineering |
hierarchy_top_title |
Journal of the American Ceramic Society |
isfreeaccess_txt |
false |
familylinks_str_mv |
(DE-627)129550272 (DE-600)219232-9 (DE-576)015003671 |
title |
Almost complete peritectic reaction in YBa2(Cu1−xFex)3O7−δ crystallization involving nanosized primary phase |
ctrlnum |
(DE-627)OLC1994799382 (DE-599)GBVOLC1994799382 (PRQ)s1382-b1d770b3bb4d2fc2c1d2643ab76cc084e63c1aab6ec16165906ecf1cd9efd4180 (KEY)0108608120170000100000501804almostcompleteperitecticreactioninyba2cu1xfex3o7cr |
title_full |
Almost complete peritectic reaction in YBa2(Cu1−xFex)3O7−δ crystallization involving nanosized primary phase |
author_sort |
Qian, Jun |
journal |
Journal of the American Ceramic Society |
journalStr |
Journal of the American Ceramic Society |
lang_code |
eng |
isOA_bool |
false |
dewey-hundreds |
600 - Technology |
recordtype |
marc |
publishDateSort |
2017 |
contenttype_str_mv |
txt |
container_start_page |
1804 |
author_browse |
Qian, Jun |
container_volume |
100 |
class |
660 DE-101 |
format_se |
Aufsätze |
author-letter |
Qian, Jun |
doi_str_mv |
10.1111/jace.14765 |
dewey-full |
660 |
title_sort |
almost complete peritectic reaction in yba2(cu1−xfex)3o7−δ crystallization involving nanosized primary phase |
title_auth |
Almost complete peritectic reaction in YBa2(Cu1−xFex)3O7−δ crystallization involving nanosized primary phase |
abstract |
Study on peritectic reaction is a matter of significant importance in materials science, which generally involves in the solidification of most functional oxide materials, for example, the YB a 2 Cu 3 O 7−δ (Y123) superconductor could be grown via a reaction of Y 2 BaCuO 5 (Y211) + Liquid→Y123. Due to its crystallization characteristic, the growth of those materials does not entirely proceed, which severely impedes the development of industrialized process. Thus the realization of a complete peritectic reaction is an interesting issue for both theory and experiment. Here, we report an almost complete peritectic reaction occurring in the growth of YBa 2 (Cu 1− x Fe x ) 3 O 7−δ crystals using modified melt‐growth. Our findings remarkably show that Y211 almost fully reacted with liquid to generate Y123, remaining approximately 1 vol%, evidently lower than that in the normal case. The nature of this unconventional phenomenon is clarified that the Fe‐doping elevates the nucleation barrier in the peritectic melting of Y123 and causes a massive homogeneous nucleation catastrophe, leading to nanosized and dispersive Y211 particles, which readily and almost fully dissolve in the subsequent peritectic solidification of Y123. Most importantly, the new conception derived from this work is promising for reviving other functional materials, which are disregarded due to their incomplete peritectic reactions. |
abstractGer |
Study on peritectic reaction is a matter of significant importance in materials science, which generally involves in the solidification of most functional oxide materials, for example, the YB a 2 Cu 3 O 7−δ (Y123) superconductor could be grown via a reaction of Y 2 BaCuO 5 (Y211) + Liquid→Y123. Due to its crystallization characteristic, the growth of those materials does not entirely proceed, which severely impedes the development of industrialized process. Thus the realization of a complete peritectic reaction is an interesting issue for both theory and experiment. Here, we report an almost complete peritectic reaction occurring in the growth of YBa 2 (Cu 1− x Fe x ) 3 O 7−δ crystals using modified melt‐growth. Our findings remarkably show that Y211 almost fully reacted with liquid to generate Y123, remaining approximately 1 vol%, evidently lower than that in the normal case. The nature of this unconventional phenomenon is clarified that the Fe‐doping elevates the nucleation barrier in the peritectic melting of Y123 and causes a massive homogeneous nucleation catastrophe, leading to nanosized and dispersive Y211 particles, which readily and almost fully dissolve in the subsequent peritectic solidification of Y123. Most importantly, the new conception derived from this work is promising for reviving other functional materials, which are disregarded due to their incomplete peritectic reactions. |
abstract_unstemmed |
Study on peritectic reaction is a matter of significant importance in materials science, which generally involves in the solidification of most functional oxide materials, for example, the YB a 2 Cu 3 O 7−δ (Y123) superconductor could be grown via a reaction of Y 2 BaCuO 5 (Y211) + Liquid→Y123. Due to its crystallization characteristic, the growth of those materials does not entirely proceed, which severely impedes the development of industrialized process. Thus the realization of a complete peritectic reaction is an interesting issue for both theory and experiment. Here, we report an almost complete peritectic reaction occurring in the growth of YBa 2 (Cu 1− x Fe x ) 3 O 7−δ crystals using modified melt‐growth. Our findings remarkably show that Y211 almost fully reacted with liquid to generate Y123, remaining approximately 1 vol%, evidently lower than that in the normal case. The nature of this unconventional phenomenon is clarified that the Fe‐doping elevates the nucleation barrier in the peritectic melting of Y123 and causes a massive homogeneous nucleation catastrophe, leading to nanosized and dispersive Y211 particles, which readily and almost fully dissolve in the subsequent peritectic solidification of Y123. Most importantly, the new conception derived from this work is promising for reviving other functional materials, which are disregarded due to their incomplete peritectic reactions. |
collection_details |
GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_22 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2014 |
container_issue |
5 |
title_short |
Almost complete peritectic reaction in YBa2(Cu1−xFex)3O7−δ crystallization involving nanosized primary phase |
url |
http://dx.doi.org/10.1111/jace.14765 http://onlinelibrary.wiley.com/doi/10.1111/jace.14765/abstract |
remote_bool |
false |
author2 |
Fan, Wenshuo Du, Gehai Li, Haochen Xiang, Hui Hussain, Ghulam Liu, Yan Cui, Xiangxiang Diko, Pavel Yao, Xin Zou, Zhiqiang |
author2Str |
Fan, Wenshuo Du, Gehai Li, Haochen Xiang, Hui Hussain, Ghulam Liu, Yan Cui, Xiangxiang Diko, Pavel Yao, Xin Zou, Zhiqiang |
ppnlink |
129550272 |
mediatype_str_mv |
n |
isOA_txt |
false |
hochschulschrift_bool |
false |
author2_role |
oth oth oth oth oth oth oth oth oth oth |
doi_str |
10.1111/jace.14765 |
up_date |
2024-07-03T19:17:00.881Z |
_version_ |
1803586603196612609 |
fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a2200265 4500</leader><controlfield tag="001">OLC1994799382</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230715055125.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">170721s2017 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1111/jace.14765</subfield><subfield code="2">doi</subfield></datafield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">PQ20170901</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC1994799382</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVOLC1994799382</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(PRQ)s1382-b1d770b3bb4d2fc2c1d2643ab76cc084e63c1aab6ec16165906ecf1cd9efd4180</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(KEY)0108608120170000100000501804almostcompleteperitecticreactioninyba2cu1xfex3o7cr</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">DE-101</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Qian, Jun</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Almost complete peritectic reaction in YBa2(Cu1−xFex)3O7−δ crystallization involving nanosized primary phase</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2017</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Study on peritectic reaction is a matter of significant importance in materials science, which generally involves in the solidification of most functional oxide materials, for example, the YB a 2 Cu 3 O 7−δ (Y123) superconductor could be grown via a reaction of Y 2 BaCuO 5 (Y211) + Liquid→Y123. Due to its crystallization characteristic, the growth of those materials does not entirely proceed, which severely impedes the development of industrialized process. Thus the realization of a complete peritectic reaction is an interesting issue for both theory and experiment. Here, we report an almost complete peritectic reaction occurring in the growth of YBa 2 (Cu 1− x Fe x ) 3 O 7−δ crystals using modified melt‐growth. Our findings remarkably show that Y211 almost fully reacted with liquid to generate Y123, remaining approximately 1 vol%, evidently lower than that in the normal case. The nature of this unconventional phenomenon is clarified that the Fe‐doping elevates the nucleation barrier in the peritectic melting of Y123 and causes a massive homogeneous nucleation catastrophe, leading to nanosized and dispersive Y211 particles, which readily and almost fully dissolve in the subsequent peritectic solidification of Y123. Most importantly, the new conception derived from this work is promising for reviving other functional materials, which are disregarded due to their incomplete peritectic reactions.</subfield></datafield><datafield tag="540" ind1=" " ind2=" "><subfield code="a">Nutzungsrecht: © 2017 The American Ceramic Society</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">superconductor</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">yttrium compounds</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">nucleation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">nanoparticles</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">chemical doping</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Fan, Wenshuo</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Du, Gehai</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Li, Haochen</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Xiang, Hui</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Hussain, Ghulam</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Liu, Yan</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Cui, Xiangxiang</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Diko, Pavel</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Yao, Xin</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zou, Zhiqiang</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of the American Ceramic Society</subfield><subfield code="d">Malden [u.a.] : Blackwell Publishing, 1918</subfield><subfield code="g">100(2017), 5, Seite 1804-1813</subfield><subfield code="w">(DE-627)129550272</subfield><subfield code="w">(DE-600)219232-9</subfield><subfield code="w">(DE-576)015003671</subfield><subfield code="x">0002-7820</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:100</subfield><subfield code="g">year:2017</subfield><subfield code="g">number:5</subfield><subfield code="g">pages:1804-1813</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">http://dx.doi.org/10.1111/jace.14765</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">http://onlinelibrary.wiley.com/doi/10.1111/jace.14765/abstract</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-DE-84</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_22</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2004</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2014</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">100</subfield><subfield code="j">2017</subfield><subfield code="e">5</subfield><subfield code="h">1804-1813</subfield></datafield></record></collection>
|
score |
7.400337 |