Synthesis and Properties of Redox-Active Polyimides with 3,5-Bis(trifluoromethyl)- or 3,5-Dimethyl-Substituted Triphenylamine Groups
Two series of novel redox-active polyimides 8a-8f and 9a-9f were prepared through a conventional two-step procedure from six commercially available tetracarboxylic dianhydrides with 3,5-bis(trifluoromethyl)-4′,4″-diaminotriphenylamine and 3,5-dimethyl-4′,4″-diaminotriphenylamine, respectively. All t...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Hsiao, Sheng-Huei [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2017 |
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| Rechteinformationen: |
Nutzungsrecht: © 2017 Taylor & Francis 2017 |
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| Schlagwörter: |
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| Übergeordnetes Werk: |
Enthalten in: Polymer plastics technology and engineering - New York, NY : Dekker, 1973, 56(2017), 12, Seite 1274 |
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| Übergeordnetes Werk: |
volume:56 ; year:2017 ; number:12 ; pages:1274 |
| Links: |
|---|
| DOI / URN: |
10.1080/03602559.2016.1269263 |
|---|
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OLC1995851019 |
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| 520 | |a Two series of novel redox-active polyimides 8a-8f and 9a-9f were prepared through a conventional two-step procedure from six commercially available tetracarboxylic dianhydrides with 3,5-bis(trifluoromethyl)-4′,4″-diaminotriphenylamine and 3,5-dimethyl-4′,4″-diaminotriphenylamine, respectively. All the polyimides were amorphous and most of them could afford flexible and tough films with good thermal and mechanical properties. Cyclic voltammograms of the polyimides 9a-9f showed reversible redox waves with half-wave potentials (E 1/2 ) in the range 1.12−1.25 V versus Ag/AgCl in acetonitrile solution. The polymer films revealed good electrochemical and electrochromic stability, with a color change from neutral pale yellowish to blue doped form at applied potentials ranging from 0 to 1.70 V. | ||
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| 650 | 4 | |a polyimides | |
| 650 | 4 | |a electrochromism | |
| 650 | 4 | |a Electrochemistry | |
| 650 | 4 | |a redox polymers | |
| 650 | 4 | |a Polymeric films | |
| 650 | 4 | |a Dianhydrides | |
| 650 | 4 | |a Thermodynamic properties | |
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10.1080/03602559.2016.1269263 doi PQ20170901 (DE-627)OLC1995851019 (DE-599)GBVOLC1995851019 (PRQ)i1132-d9548691ef49fa0d7dc6fea6abe0a0594ae4bbc9e3736eac44377dc3e49f85890 (KEY)0031677620170000056001201274synthesisandpropertiesofredoxactivepolyimideswith3 DE-627 ger DE-627 rakwb eng 670 DNB Hsiao, Sheng-Huei verfasserin aut Synthesis and Properties of Redox-Active Polyimides with 3,5-Bis(trifluoromethyl)- or 3,5-Dimethyl-Substituted Triphenylamine Groups 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Two series of novel redox-active polyimides 8a-8f and 9a-9f were prepared through a conventional two-step procedure from six commercially available tetracarboxylic dianhydrides with 3,5-bis(trifluoromethyl)-4′,4″-diaminotriphenylamine and 3,5-dimethyl-4′,4″-diaminotriphenylamine, respectively. All the polyimides were amorphous and most of them could afford flexible and tough films with good thermal and mechanical properties. Cyclic voltammograms of the polyimides 9a-9f showed reversible redox waves with half-wave potentials (E 1/2 ) in the range 1.12−1.25 V versus Ag/AgCl in acetonitrile solution. The polymer films revealed good electrochemical and electrochromic stability, with a color change from neutral pale yellowish to blue doped form at applied potentials ranging from 0 to 1.70 V. Nutzungsrecht: © 2017 Taylor & Francis 2017 triphenylamine polyimides electrochromism Electrochemistry redox polymers Polymeric films Dianhydrides Thermodynamic properties Electrochromism Acetonitrile Dimethyl Mechanical properties Polyimide resins Wu, Chien-Nan oth Enthalten in Polymer plastics technology and engineering New York, NY : Dekker, 1973 56(2017), 12, Seite 1274 (DE-627)129391735 (DE-600)184907-4 (DE-576)01477688X 0360-2559 nnns volume:56 year:2017 number:12 pages:1274 http://dx.doi.org/10.1080/03602559.2016.1269263 Volltext http://www.tandfonline.com/doi/abs/10.1080/03602559.2016.1269263 https://search.proquest.com/docview/1929742862 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 56 2017 12 1274 |
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10.1080/03602559.2016.1269263 doi PQ20170901 (DE-627)OLC1995851019 (DE-599)GBVOLC1995851019 (PRQ)i1132-d9548691ef49fa0d7dc6fea6abe0a0594ae4bbc9e3736eac44377dc3e49f85890 (KEY)0031677620170000056001201274synthesisandpropertiesofredoxactivepolyimideswith3 DE-627 ger DE-627 rakwb eng 670 DNB Hsiao, Sheng-Huei verfasserin aut Synthesis and Properties of Redox-Active Polyimides with 3,5-Bis(trifluoromethyl)- or 3,5-Dimethyl-Substituted Triphenylamine Groups 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Two series of novel redox-active polyimides 8a-8f and 9a-9f were prepared through a conventional two-step procedure from six commercially available tetracarboxylic dianhydrides with 3,5-bis(trifluoromethyl)-4′,4″-diaminotriphenylamine and 3,5-dimethyl-4′,4″-diaminotriphenylamine, respectively. All the polyimides were amorphous and most of them could afford flexible and tough films with good thermal and mechanical properties. Cyclic voltammograms of the polyimides 9a-9f showed reversible redox waves with half-wave potentials (E 1/2 ) in the range 1.12−1.25 V versus Ag/AgCl in acetonitrile solution. The polymer films revealed good electrochemical and electrochromic stability, with a color change from neutral pale yellowish to blue doped form at applied potentials ranging from 0 to 1.70 V. Nutzungsrecht: © 2017 Taylor & Francis 2017 triphenylamine polyimides electrochromism Electrochemistry redox polymers Polymeric films Dianhydrides Thermodynamic properties Electrochromism Acetonitrile Dimethyl Mechanical properties Polyimide resins Wu, Chien-Nan oth Enthalten in Polymer plastics technology and engineering New York, NY : Dekker, 1973 56(2017), 12, Seite 1274 (DE-627)129391735 (DE-600)184907-4 (DE-576)01477688X 0360-2559 nnns volume:56 year:2017 number:12 pages:1274 http://dx.doi.org/10.1080/03602559.2016.1269263 Volltext http://www.tandfonline.com/doi/abs/10.1080/03602559.2016.1269263 https://search.proquest.com/docview/1929742862 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 56 2017 12 1274 |
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670 DNB Synthesis and Properties of Redox-Active Polyimides with 3,5-Bis(trifluoromethyl)- or 3,5-Dimethyl-Substituted Triphenylamine Groups triphenylamine polyimides electrochromism Electrochemistry redox polymers Polymeric films Dianhydrides Thermodynamic properties Electrochromism Acetonitrile Dimethyl Mechanical properties Polyimide resins |
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ddc 670 misc triphenylamine misc polyimides misc electrochromism misc Electrochemistry misc redox polymers misc Polymeric films misc Dianhydrides misc Thermodynamic properties misc Electrochromism misc Acetonitrile misc Dimethyl misc Mechanical properties misc Polyimide resins |
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ddc 670 misc triphenylamine misc polyimides misc electrochromism misc Electrochemistry misc redox polymers misc Polymeric films misc Dianhydrides misc Thermodynamic properties misc Electrochromism misc Acetonitrile misc Dimethyl misc Mechanical properties misc Polyimide resins |
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Synthesis and Properties of Redox-Active Polyimides with 3,5-Bis(trifluoromethyl)- or 3,5-Dimethyl-Substituted Triphenylamine Groups |
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Synthesis and Properties of Redox-Active Polyimides with 3,5-Bis(trifluoromethyl)- or 3,5-Dimethyl-Substituted Triphenylamine Groups |
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Hsiao, Sheng-Huei |
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synthesis and properties of redox-active polyimides with 3,5-bis(trifluoromethyl)- or 3,5-dimethyl-substituted triphenylamine groups |
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Synthesis and Properties of Redox-Active Polyimides with 3,5-Bis(trifluoromethyl)- or 3,5-Dimethyl-Substituted Triphenylamine Groups |
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Two series of novel redox-active polyimides 8a-8f and 9a-9f were prepared through a conventional two-step procedure from six commercially available tetracarboxylic dianhydrides with 3,5-bis(trifluoromethyl)-4′,4″-diaminotriphenylamine and 3,5-dimethyl-4′,4″-diaminotriphenylamine, respectively. All the polyimides were amorphous and most of them could afford flexible and tough films with good thermal and mechanical properties. Cyclic voltammograms of the polyimides 9a-9f showed reversible redox waves with half-wave potentials (E 1/2 ) in the range 1.12−1.25 V versus Ag/AgCl in acetonitrile solution. The polymer films revealed good electrochemical and electrochromic stability, with a color change from neutral pale yellowish to blue doped form at applied potentials ranging from 0 to 1.70 V. |
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Two series of novel redox-active polyimides 8a-8f and 9a-9f were prepared through a conventional two-step procedure from six commercially available tetracarboxylic dianhydrides with 3,5-bis(trifluoromethyl)-4′,4″-diaminotriphenylamine and 3,5-dimethyl-4′,4″-diaminotriphenylamine, respectively. All the polyimides were amorphous and most of them could afford flexible and tough films with good thermal and mechanical properties. Cyclic voltammograms of the polyimides 9a-9f showed reversible redox waves with half-wave potentials (E 1/2 ) in the range 1.12−1.25 V versus Ag/AgCl in acetonitrile solution. The polymer films revealed good electrochemical and electrochromic stability, with a color change from neutral pale yellowish to blue doped form at applied potentials ranging from 0 to 1.70 V. |
| abstract_unstemmed |
Two series of novel redox-active polyimides 8a-8f and 9a-9f were prepared through a conventional two-step procedure from six commercially available tetracarboxylic dianhydrides with 3,5-bis(trifluoromethyl)-4′,4″-diaminotriphenylamine and 3,5-dimethyl-4′,4″-diaminotriphenylamine, respectively. All the polyimides were amorphous and most of them could afford flexible and tough films with good thermal and mechanical properties. Cyclic voltammograms of the polyimides 9a-9f showed reversible redox waves with half-wave potentials (E 1/2 ) in the range 1.12−1.25 V versus Ag/AgCl in acetonitrile solution. The polymer films revealed good electrochemical and electrochromic stability, with a color change from neutral pale yellowish to blue doped form at applied potentials ranging from 0 to 1.70 V. |
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Synthesis and Properties of Redox-Active Polyimides with 3,5-Bis(trifluoromethyl)- or 3,5-Dimethyl-Substituted Triphenylamine Groups |
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