Physico-chemical characterisation of epoxy acrylate resin from jatropha seed oil
Purpose This paper aims to demonstrate the synthesis of polyesterification reaction of non-edible jatropha seed oil (JO) and acrylic acid, which leads to the production of acrylated epoxidised-based resin. To understand the physico-chemical characteristics when synthesis the JO-based epoxy acrylate,...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Salleh, Mek Zah [verfasserIn] |
|---|
| Format: |
Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2017 |
|---|
| Rechteinformationen: |
Nutzungsrecht: © Emerald Publishing Limited |
|---|
| Schlagwörter: |
|---|
| Übergeordnetes Werk: |
Enthalten in: Pigment & resin technology - London : Sawell, 1972, 46(2017), 6, Seite 485-495 |
|---|---|
| Übergeordnetes Werk: |
volume:46 ; year:2017 ; number:6 ; pages:485-495 |
| Links: |
|---|
| DOI / URN: |
10.1108/PRT-11-2016-0116 |
|---|
| Katalog-ID: |
OLC1996788825 |
|---|
| LEADER | 01000caa a2200265 4500 | ||
|---|---|---|---|
| 001 | OLC1996788825 | ||
| 003 | DE-627 | ||
| 005 | 20230515212143.0 | ||
| 007 | tu | ||
| 008 | 171125s2017 xx ||||| 00| ||eng c | ||
| 024 | 7 | |a 10.1108/PRT-11-2016-0116 |2 doi | |
| 028 | 5 | 2 | |a PQ20171228 |
| 035 | |a (DE-627)OLC1996788825 | ||
| 035 | |a (DE-599)GBVOLC1996788825 | ||
| 035 | |a (PRQ)e1568-957ae896ca0b863aab078a564f738b2c07d19948a045cbd0e32df57cac77bdc50 | ||
| 035 | |a (KEY)0010147820170000046000600485physicochemicalcharacterisationofepoxyacrylateresi | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 082 | 0 | 4 | |a 660 |q ZDB |
| 084 | |a 58.00 |2 bkl | ||
| 100 | 1 | |a Salleh, Mek Zah |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Physico-chemical characterisation of epoxy acrylate resin from jatropha seed oil |
| 264 | 1 | |c 2017 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ohne Hilfsmittel zu benutzen |b n |2 rdamedia | ||
| 338 | |a Band |b nc |2 rdacarrier | ||
| 520 | |a Purpose This paper aims to demonstrate the synthesis of polyesterification reaction of non-edible jatropha seed oil (JO) and acrylic acid, which leads to the production of acrylated epoxidised-based resin. To understand the physico-chemical characteristics when synthesis the JO-based epoxy acrylate, the effect of temperature on the reaction, concentration of acrylic acid and role of catalyst on reaction time and acid value were studied. Design/methodology/approach First, the double bond in JO was functionalised by epoxidation using the solvent-free performic method. The subsequent process was acrylation with acrylic acid using the base catalyst triethylamine and 4-methoxyphenol as an inhibitor respectively. The physico-chemical characteristics during the synthesis of the epoxy acrylate such as acid value was monitored and analysed. The formation of the epoxy and acrylate group was confirmed by a Fourier transform infrared spectroscopy spectra analysis and nuclear magnetic resonance analysis. Findings The optimum reaction condition was achieved at a ratio of epoxidised JO to acrylic acid of 1:1.5 and the reaction temperature of 110°C. This was indicated by the acid value reduction from 86 to 15 mg KOH/g sample at 6 hours. Practical implications The JO-based epoxy acrylate synthesised has a potential to be used in formulations the prepolymer resin for UV curable coating applications. The JO which is from natural resources and is sustainable raw materials that possible reduce the dependency on petroleum-based coating. Originality/value The epoxidised jatropha seed oil epoxy acrylate was synthesised, as a new type of oligomer resin that contains a reactive acrylate group, which can be alternative to petroleum-based coating and can used further in the formulation of the radiation curable coating. | ||
| 540 | |a Nutzungsrecht: © Emerald Publishing Limited | ||
| 650 | 4 | |a Epoxy compounds | |
| 650 | 4 | |a Chemical properties | |
| 650 | 4 | |a Vegetable oils | |
| 650 | 4 | |a Mechanical properties | |
| 650 | 4 | |a Acrylates | |
| 650 | 4 | |a Usage | |
| 650 | 4 | |a Euphorbiaceae | |
| 650 | 4 | |a Forest products | |
| 650 | 4 | |a Synthesis (chemistry) | |
| 650 | 4 | |a Infrared spectra | |
| 650 | 4 | |a Chemistry | |
| 650 | 4 | |a Acrylic resins | |
| 650 | 4 | |a Acrylic acid | |
| 650 | 4 | |a Edible | |
| 650 | 4 | |a Raw materials | |
| 650 | 4 | |a Epoxidation | |
| 650 | 4 | |a Volatile organic compounds--VOCs | |
| 650 | 4 | |a Catalysts | |
| 650 | 4 | |a Temperature effects | |
| 650 | 4 | |a Infrared analysis | |
| 650 | 4 | |a Seeds | |
| 650 | 4 | |a Coating | |
| 650 | 4 | |a Triethylamine | |
| 650 | 4 | |a Formulations | |
| 650 | 4 | |a Laboratories | |
| 650 | 4 | |a Chemical engineering | |
| 650 | 4 | |a Science | |
| 650 | 4 | |a Fourier transformation | |
| 650 | 4 | |a Reaction time | |
| 650 | 4 | |a Fourier transforms | |
| 650 | 4 | |a Natural resources | |
| 650 | 4 | |a Fatty acids | |
| 650 | 4 | |a Nuclear magnetic resonance | |
| 650 | 4 | |a Oils & fats | |
| 700 | 1 | |a Taib, Emiliana Rose Jusoh |4 oth | |
| 700 | 1 | |a Abdullah, Luqman Chuah |4 oth | |
| 700 | 1 | |a Aung, Min Min |4 oth | |
| 700 | 1 | |a Basri, Mahiran |4 oth | |
| 700 | 1 | |a Wong, Jia Li |4 oth | |
| 700 | 1 | |a Chee, Ching Yern |4 oth | |
| 700 | 1 | |a Mamat, Suhaini |4 oth | |
| 700 | 1 | |a Saalah, Sariah |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |t Pigment & resin technology |d London : Sawell, 1972 |g 46(2017), 6, Seite 485-495 |w (DE-627)129385700 |w (DE-600)183967-6 |w (DE-576)014772558 |x 0369-9420 |7 nnns |
| 773 | 1 | 8 | |g volume:46 |g year:2017 |g number:6 |g pages:485-495 |
| 856 | 4 | 1 | |u http://dx.doi.org/10.1108/PRT-11-2016-0116 |3 Volltext |
| 856 | 4 | 2 | |u http://www.emeraldinsight.com/doi/abs/10.1108/PRT-11-2016-0116 |
| 856 | 4 | 2 | |u https://search.proquest.com/docview/1945073464 |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a SYSFLAG_A | ||
| 912 | |a GBV_OLC | ||
| 912 | |a SSG-OLC-TEC | ||
| 912 | |a SSG-OLC-CHE | ||
| 912 | |a SSG-OLC-PHA | ||
| 912 | |a SSG-OLC-DE-84 | ||
| 912 | |a GBV_ILN_70 | ||
| 936 | b | k | |a 58.00 |q AVZ |
| 951 | |a AR | ||
| 952 | |d 46 |j 2017 |e 6 |h 485-495 | ||
| author_variant |
m z s mz mzs |
|---|---|
| matchkey_str |
article:03699420:2017----::hscceiacaatrstooeoycyaeei |
| hierarchy_sort_str |
2017 |
| bklnumber |
58.00 |
| publishDate |
2017 |
| allfields |
10.1108/PRT-11-2016-0116 doi PQ20171228 (DE-627)OLC1996788825 (DE-599)GBVOLC1996788825 (PRQ)e1568-957ae896ca0b863aab078a564f738b2c07d19948a045cbd0e32df57cac77bdc50 (KEY)0010147820170000046000600485physicochemicalcharacterisationofepoxyacrylateresi DE-627 ger DE-627 rakwb eng 660 ZDB 58.00 bkl Salleh, Mek Zah verfasserin aut Physico-chemical characterisation of epoxy acrylate resin from jatropha seed oil 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Purpose This paper aims to demonstrate the synthesis of polyesterification reaction of non-edible jatropha seed oil (JO) and acrylic acid, which leads to the production of acrylated epoxidised-based resin. To understand the physico-chemical characteristics when synthesis the JO-based epoxy acrylate, the effect of temperature on the reaction, concentration of acrylic acid and role of catalyst on reaction time and acid value were studied. Design/methodology/approach First, the double bond in JO was functionalised by epoxidation using the solvent-free performic method. The subsequent process was acrylation with acrylic acid using the base catalyst triethylamine and 4-methoxyphenol as an inhibitor respectively. The physico-chemical characteristics during the synthesis of the epoxy acrylate such as acid value was monitored and analysed. The formation of the epoxy and acrylate group was confirmed by a Fourier transform infrared spectroscopy spectra analysis and nuclear magnetic resonance analysis. Findings The optimum reaction condition was achieved at a ratio of epoxidised JO to acrylic acid of 1:1.5 and the reaction temperature of 110°C. This was indicated by the acid value reduction from 86 to 15 mg KOH/g sample at 6 hours. Practical implications The JO-based epoxy acrylate synthesised has a potential to be used in formulations the prepolymer resin for UV curable coating applications. The JO which is from natural resources and is sustainable raw materials that possible reduce the dependency on petroleum-based coating. Originality/value The epoxidised jatropha seed oil epoxy acrylate was synthesised, as a new type of oligomer resin that contains a reactive acrylate group, which can be alternative to petroleum-based coating and can used further in the formulation of the radiation curable coating. Nutzungsrecht: © Emerald Publishing Limited Epoxy compounds Chemical properties Vegetable oils Mechanical properties Acrylates Usage Euphorbiaceae Forest products Synthesis (chemistry) Infrared spectra Chemistry Acrylic resins Acrylic acid Edible Raw materials Epoxidation Volatile organic compounds--VOCs Catalysts Temperature effects Infrared analysis Seeds Coating Triethylamine Formulations Laboratories Chemical engineering Science Fourier transformation Reaction time Fourier transforms Natural resources Fatty acids Nuclear magnetic resonance Oils & fats Taib, Emiliana Rose Jusoh oth Abdullah, Luqman Chuah oth Aung, Min Min oth Basri, Mahiran oth Wong, Jia Li oth Chee, Ching Yern oth Mamat, Suhaini oth Saalah, Sariah oth Enthalten in Pigment & resin technology London : Sawell, 1972 46(2017), 6, Seite 485-495 (DE-627)129385700 (DE-600)183967-6 (DE-576)014772558 0369-9420 nnns volume:46 year:2017 number:6 pages:485-495 http://dx.doi.org/10.1108/PRT-11-2016-0116 Volltext http://www.emeraldinsight.com/doi/abs/10.1108/PRT-11-2016-0116 https://search.proquest.com/docview/1945073464 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 58.00 AVZ AR 46 2017 6 485-495 |
| spelling |
10.1108/PRT-11-2016-0116 doi PQ20171228 (DE-627)OLC1996788825 (DE-599)GBVOLC1996788825 (PRQ)e1568-957ae896ca0b863aab078a564f738b2c07d19948a045cbd0e32df57cac77bdc50 (KEY)0010147820170000046000600485physicochemicalcharacterisationofepoxyacrylateresi DE-627 ger DE-627 rakwb eng 660 ZDB 58.00 bkl Salleh, Mek Zah verfasserin aut Physico-chemical characterisation of epoxy acrylate resin from jatropha seed oil 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Purpose This paper aims to demonstrate the synthesis of polyesterification reaction of non-edible jatropha seed oil (JO) and acrylic acid, which leads to the production of acrylated epoxidised-based resin. To understand the physico-chemical characteristics when synthesis the JO-based epoxy acrylate, the effect of temperature on the reaction, concentration of acrylic acid and role of catalyst on reaction time and acid value were studied. Design/methodology/approach First, the double bond in JO was functionalised by epoxidation using the solvent-free performic method. The subsequent process was acrylation with acrylic acid using the base catalyst triethylamine and 4-methoxyphenol as an inhibitor respectively. The physico-chemical characteristics during the synthesis of the epoxy acrylate such as acid value was monitored and analysed. The formation of the epoxy and acrylate group was confirmed by a Fourier transform infrared spectroscopy spectra analysis and nuclear magnetic resonance analysis. Findings The optimum reaction condition was achieved at a ratio of epoxidised JO to acrylic acid of 1:1.5 and the reaction temperature of 110°C. This was indicated by the acid value reduction from 86 to 15 mg KOH/g sample at 6 hours. Practical implications The JO-based epoxy acrylate synthesised has a potential to be used in formulations the prepolymer resin for UV curable coating applications. The JO which is from natural resources and is sustainable raw materials that possible reduce the dependency on petroleum-based coating. Originality/value The epoxidised jatropha seed oil epoxy acrylate was synthesised, as a new type of oligomer resin that contains a reactive acrylate group, which can be alternative to petroleum-based coating and can used further in the formulation of the radiation curable coating. Nutzungsrecht: © Emerald Publishing Limited Epoxy compounds Chemical properties Vegetable oils Mechanical properties Acrylates Usage Euphorbiaceae Forest products Synthesis (chemistry) Infrared spectra Chemistry Acrylic resins Acrylic acid Edible Raw materials Epoxidation Volatile organic compounds--VOCs Catalysts Temperature effects Infrared analysis Seeds Coating Triethylamine Formulations Laboratories Chemical engineering Science Fourier transformation Reaction time Fourier transforms Natural resources Fatty acids Nuclear magnetic resonance Oils & fats Taib, Emiliana Rose Jusoh oth Abdullah, Luqman Chuah oth Aung, Min Min oth Basri, Mahiran oth Wong, Jia Li oth Chee, Ching Yern oth Mamat, Suhaini oth Saalah, Sariah oth Enthalten in Pigment & resin technology London : Sawell, 1972 46(2017), 6, Seite 485-495 (DE-627)129385700 (DE-600)183967-6 (DE-576)014772558 0369-9420 nnns volume:46 year:2017 number:6 pages:485-495 http://dx.doi.org/10.1108/PRT-11-2016-0116 Volltext http://www.emeraldinsight.com/doi/abs/10.1108/PRT-11-2016-0116 https://search.proquest.com/docview/1945073464 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 58.00 AVZ AR 46 2017 6 485-495 |
| allfields_unstemmed |
10.1108/PRT-11-2016-0116 doi PQ20171228 (DE-627)OLC1996788825 (DE-599)GBVOLC1996788825 (PRQ)e1568-957ae896ca0b863aab078a564f738b2c07d19948a045cbd0e32df57cac77bdc50 (KEY)0010147820170000046000600485physicochemicalcharacterisationofepoxyacrylateresi DE-627 ger DE-627 rakwb eng 660 ZDB 58.00 bkl Salleh, Mek Zah verfasserin aut Physico-chemical characterisation of epoxy acrylate resin from jatropha seed oil 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Purpose This paper aims to demonstrate the synthesis of polyesterification reaction of non-edible jatropha seed oil (JO) and acrylic acid, which leads to the production of acrylated epoxidised-based resin. To understand the physico-chemical characteristics when synthesis the JO-based epoxy acrylate, the effect of temperature on the reaction, concentration of acrylic acid and role of catalyst on reaction time and acid value were studied. Design/methodology/approach First, the double bond in JO was functionalised by epoxidation using the solvent-free performic method. The subsequent process was acrylation with acrylic acid using the base catalyst triethylamine and 4-methoxyphenol as an inhibitor respectively. The physico-chemical characteristics during the synthesis of the epoxy acrylate such as acid value was monitored and analysed. The formation of the epoxy and acrylate group was confirmed by a Fourier transform infrared spectroscopy spectra analysis and nuclear magnetic resonance analysis. Findings The optimum reaction condition was achieved at a ratio of epoxidised JO to acrylic acid of 1:1.5 and the reaction temperature of 110°C. This was indicated by the acid value reduction from 86 to 15 mg KOH/g sample at 6 hours. Practical implications The JO-based epoxy acrylate synthesised has a potential to be used in formulations the prepolymer resin for UV curable coating applications. The JO which is from natural resources and is sustainable raw materials that possible reduce the dependency on petroleum-based coating. Originality/value The epoxidised jatropha seed oil epoxy acrylate was synthesised, as a new type of oligomer resin that contains a reactive acrylate group, which can be alternative to petroleum-based coating and can used further in the formulation of the radiation curable coating. Nutzungsrecht: © Emerald Publishing Limited Epoxy compounds Chemical properties Vegetable oils Mechanical properties Acrylates Usage Euphorbiaceae Forest products Synthesis (chemistry) Infrared spectra Chemistry Acrylic resins Acrylic acid Edible Raw materials Epoxidation Volatile organic compounds--VOCs Catalysts Temperature effects Infrared analysis Seeds Coating Triethylamine Formulations Laboratories Chemical engineering Science Fourier transformation Reaction time Fourier transforms Natural resources Fatty acids Nuclear magnetic resonance Oils & fats Taib, Emiliana Rose Jusoh oth Abdullah, Luqman Chuah oth Aung, Min Min oth Basri, Mahiran oth Wong, Jia Li oth Chee, Ching Yern oth Mamat, Suhaini oth Saalah, Sariah oth Enthalten in Pigment & resin technology London : Sawell, 1972 46(2017), 6, Seite 485-495 (DE-627)129385700 (DE-600)183967-6 (DE-576)014772558 0369-9420 nnns volume:46 year:2017 number:6 pages:485-495 http://dx.doi.org/10.1108/PRT-11-2016-0116 Volltext http://www.emeraldinsight.com/doi/abs/10.1108/PRT-11-2016-0116 https://search.proquest.com/docview/1945073464 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 58.00 AVZ AR 46 2017 6 485-495 |
| allfieldsGer |
10.1108/PRT-11-2016-0116 doi PQ20171228 (DE-627)OLC1996788825 (DE-599)GBVOLC1996788825 (PRQ)e1568-957ae896ca0b863aab078a564f738b2c07d19948a045cbd0e32df57cac77bdc50 (KEY)0010147820170000046000600485physicochemicalcharacterisationofepoxyacrylateresi DE-627 ger DE-627 rakwb eng 660 ZDB 58.00 bkl Salleh, Mek Zah verfasserin aut Physico-chemical characterisation of epoxy acrylate resin from jatropha seed oil 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Purpose This paper aims to demonstrate the synthesis of polyesterification reaction of non-edible jatropha seed oil (JO) and acrylic acid, which leads to the production of acrylated epoxidised-based resin. To understand the physico-chemical characteristics when synthesis the JO-based epoxy acrylate, the effect of temperature on the reaction, concentration of acrylic acid and role of catalyst on reaction time and acid value were studied. Design/methodology/approach First, the double bond in JO was functionalised by epoxidation using the solvent-free performic method. The subsequent process was acrylation with acrylic acid using the base catalyst triethylamine and 4-methoxyphenol as an inhibitor respectively. The physico-chemical characteristics during the synthesis of the epoxy acrylate such as acid value was monitored and analysed. The formation of the epoxy and acrylate group was confirmed by a Fourier transform infrared spectroscopy spectra analysis and nuclear magnetic resonance analysis. Findings The optimum reaction condition was achieved at a ratio of epoxidised JO to acrylic acid of 1:1.5 and the reaction temperature of 110°C. This was indicated by the acid value reduction from 86 to 15 mg KOH/g sample at 6 hours. Practical implications The JO-based epoxy acrylate synthesised has a potential to be used in formulations the prepolymer resin for UV curable coating applications. The JO which is from natural resources and is sustainable raw materials that possible reduce the dependency on petroleum-based coating. Originality/value The epoxidised jatropha seed oil epoxy acrylate was synthesised, as a new type of oligomer resin that contains a reactive acrylate group, which can be alternative to petroleum-based coating and can used further in the formulation of the radiation curable coating. Nutzungsrecht: © Emerald Publishing Limited Epoxy compounds Chemical properties Vegetable oils Mechanical properties Acrylates Usage Euphorbiaceae Forest products Synthesis (chemistry) Infrared spectra Chemistry Acrylic resins Acrylic acid Edible Raw materials Epoxidation Volatile organic compounds--VOCs Catalysts Temperature effects Infrared analysis Seeds Coating Triethylamine Formulations Laboratories Chemical engineering Science Fourier transformation Reaction time Fourier transforms Natural resources Fatty acids Nuclear magnetic resonance Oils & fats Taib, Emiliana Rose Jusoh oth Abdullah, Luqman Chuah oth Aung, Min Min oth Basri, Mahiran oth Wong, Jia Li oth Chee, Ching Yern oth Mamat, Suhaini oth Saalah, Sariah oth Enthalten in Pigment & resin technology London : Sawell, 1972 46(2017), 6, Seite 485-495 (DE-627)129385700 (DE-600)183967-6 (DE-576)014772558 0369-9420 nnns volume:46 year:2017 number:6 pages:485-495 http://dx.doi.org/10.1108/PRT-11-2016-0116 Volltext http://www.emeraldinsight.com/doi/abs/10.1108/PRT-11-2016-0116 https://search.proquest.com/docview/1945073464 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 58.00 AVZ AR 46 2017 6 485-495 |
| allfieldsSound |
10.1108/PRT-11-2016-0116 doi PQ20171228 (DE-627)OLC1996788825 (DE-599)GBVOLC1996788825 (PRQ)e1568-957ae896ca0b863aab078a564f738b2c07d19948a045cbd0e32df57cac77bdc50 (KEY)0010147820170000046000600485physicochemicalcharacterisationofepoxyacrylateresi DE-627 ger DE-627 rakwb eng 660 ZDB 58.00 bkl Salleh, Mek Zah verfasserin aut Physico-chemical characterisation of epoxy acrylate resin from jatropha seed oil 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Purpose This paper aims to demonstrate the synthesis of polyesterification reaction of non-edible jatropha seed oil (JO) and acrylic acid, which leads to the production of acrylated epoxidised-based resin. To understand the physico-chemical characteristics when synthesis the JO-based epoxy acrylate, the effect of temperature on the reaction, concentration of acrylic acid and role of catalyst on reaction time and acid value were studied. Design/methodology/approach First, the double bond in JO was functionalised by epoxidation using the solvent-free performic method. The subsequent process was acrylation with acrylic acid using the base catalyst triethylamine and 4-methoxyphenol as an inhibitor respectively. The physico-chemical characteristics during the synthesis of the epoxy acrylate such as acid value was monitored and analysed. The formation of the epoxy and acrylate group was confirmed by a Fourier transform infrared spectroscopy spectra analysis and nuclear magnetic resonance analysis. Findings The optimum reaction condition was achieved at a ratio of epoxidised JO to acrylic acid of 1:1.5 and the reaction temperature of 110°C. This was indicated by the acid value reduction from 86 to 15 mg KOH/g sample at 6 hours. Practical implications The JO-based epoxy acrylate synthesised has a potential to be used in formulations the prepolymer resin for UV curable coating applications. The JO which is from natural resources and is sustainable raw materials that possible reduce the dependency on petroleum-based coating. Originality/value The epoxidised jatropha seed oil epoxy acrylate was synthesised, as a new type of oligomer resin that contains a reactive acrylate group, which can be alternative to petroleum-based coating and can used further in the formulation of the radiation curable coating. Nutzungsrecht: © Emerald Publishing Limited Epoxy compounds Chemical properties Vegetable oils Mechanical properties Acrylates Usage Euphorbiaceae Forest products Synthesis (chemistry) Infrared spectra Chemistry Acrylic resins Acrylic acid Edible Raw materials Epoxidation Volatile organic compounds--VOCs Catalysts Temperature effects Infrared analysis Seeds Coating Triethylamine Formulations Laboratories Chemical engineering Science Fourier transformation Reaction time Fourier transforms Natural resources Fatty acids Nuclear magnetic resonance Oils & fats Taib, Emiliana Rose Jusoh oth Abdullah, Luqman Chuah oth Aung, Min Min oth Basri, Mahiran oth Wong, Jia Li oth Chee, Ching Yern oth Mamat, Suhaini oth Saalah, Sariah oth Enthalten in Pigment & resin technology London : Sawell, 1972 46(2017), 6, Seite 485-495 (DE-627)129385700 (DE-600)183967-6 (DE-576)014772558 0369-9420 nnns volume:46 year:2017 number:6 pages:485-495 http://dx.doi.org/10.1108/PRT-11-2016-0116 Volltext http://www.emeraldinsight.com/doi/abs/10.1108/PRT-11-2016-0116 https://search.proquest.com/docview/1945073464 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 58.00 AVZ AR 46 2017 6 485-495 |
| language |
English |
| source |
Enthalten in Pigment & resin technology 46(2017), 6, Seite 485-495 volume:46 year:2017 number:6 pages:485-495 |
| sourceStr |
Enthalten in Pigment & resin technology 46(2017), 6, Seite 485-495 volume:46 year:2017 number:6 pages:485-495 |
| format_phy_str_mv |
Article |
| institution |
findex.gbv.de |
| topic_facet |
Epoxy compounds Chemical properties Vegetable oils Mechanical properties Acrylates Usage Euphorbiaceae Forest products Synthesis (chemistry) Infrared spectra Chemistry Acrylic resins Acrylic acid Edible Raw materials Epoxidation Volatile organic compounds--VOCs Catalysts Temperature effects Infrared analysis Seeds Coating Triethylamine Formulations Laboratories Chemical engineering Science Fourier transformation Reaction time Fourier transforms Natural resources Fatty acids Nuclear magnetic resonance Oils & fats |
| dewey-raw |
660 |
| isfreeaccess_bool |
false |
| container_title |
Pigment & resin technology |
| authorswithroles_txt_mv |
Salleh, Mek Zah @@aut@@ Taib, Emiliana Rose Jusoh @@oth@@ Abdullah, Luqman Chuah @@oth@@ Aung, Min Min @@oth@@ Basri, Mahiran @@oth@@ Wong, Jia Li @@oth@@ Chee, Ching Yern @@oth@@ Mamat, Suhaini @@oth@@ Saalah, Sariah @@oth@@ |
| publishDateDaySort_date |
2017-01-01T00:00:00Z |
| hierarchy_top_id |
129385700 |
| dewey-sort |
3660 |
| id |
OLC1996788825 |
| language_de |
englisch |
| fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a2200265 4500</leader><controlfield tag="001">OLC1996788825</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230515212143.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">171125s2017 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1108/PRT-11-2016-0116</subfield><subfield code="2">doi</subfield></datafield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">PQ20171228</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC1996788825</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVOLC1996788825</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(PRQ)e1568-957ae896ca0b863aab078a564f738b2c07d19948a045cbd0e32df57cac77bdc50</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(KEY)0010147820170000046000600485physicochemicalcharacterisationofepoxyacrylateresi</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">ZDB</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">58.00</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Salleh, Mek Zah</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Physico-chemical characterisation of epoxy acrylate resin from jatropha seed oil</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2017</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Purpose This paper aims to demonstrate the synthesis of polyesterification reaction of non-edible jatropha seed oil (JO) and acrylic acid, which leads to the production of acrylated epoxidised-based resin. To understand the physico-chemical characteristics when synthesis the JO-based epoxy acrylate, the effect of temperature on the reaction, concentration of acrylic acid and role of catalyst on reaction time and acid value were studied. Design/methodology/approach First, the double bond in JO was functionalised by epoxidation using the solvent-free performic method. The subsequent process was acrylation with acrylic acid using the base catalyst triethylamine and 4-methoxyphenol as an inhibitor respectively. The physico-chemical characteristics during the synthesis of the epoxy acrylate such as acid value was monitored and analysed. The formation of the epoxy and acrylate group was confirmed by a Fourier transform infrared spectroscopy spectra analysis and nuclear magnetic resonance analysis. Findings The optimum reaction condition was achieved at a ratio of epoxidised JO to acrylic acid of 1:1.5 and the reaction temperature of 110°C. This was indicated by the acid value reduction from 86 to 15 mg KOH/g sample at 6 hours. Practical implications The JO-based epoxy acrylate synthesised has a potential to be used in formulations the prepolymer resin for UV curable coating applications. The JO which is from natural resources and is sustainable raw materials that possible reduce the dependency on petroleum-based coating. Originality/value The epoxidised jatropha seed oil epoxy acrylate was synthesised, as a new type of oligomer resin that contains a reactive acrylate group, which can be alternative to petroleum-based coating and can used further in the formulation of the radiation curable coating.</subfield></datafield><datafield tag="540" ind1=" " ind2=" "><subfield code="a">Nutzungsrecht: © Emerald Publishing Limited</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Epoxy compounds</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Chemical properties</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Vegetable oils</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Mechanical properties</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Acrylates</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Usage</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Euphorbiaceae</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Forest products</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Synthesis (chemistry)</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Infrared spectra</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Chemistry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Acrylic resins</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Acrylic acid</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Edible</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Raw materials</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Epoxidation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Volatile organic compounds--VOCs</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Catalysts</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Temperature effects</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Infrared analysis</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Seeds</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Coating</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Triethylamine</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Formulations</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Laboratories</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Chemical engineering</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Science</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Fourier transformation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Reaction time</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Fourier transforms</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Natural resources</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Fatty acids</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Nuclear magnetic resonance</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Oils & fats</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Taib, Emiliana Rose Jusoh</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Abdullah, Luqman Chuah</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Aung, Min Min</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Basri, Mahiran</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wong, Jia Li</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Chee, Ching Yern</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Mamat, Suhaini</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Saalah, Sariah</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Pigment & resin technology</subfield><subfield code="d">London : Sawell, 1972</subfield><subfield code="g">46(2017), 6, Seite 485-495</subfield><subfield code="w">(DE-627)129385700</subfield><subfield code="w">(DE-600)183967-6</subfield><subfield code="w">(DE-576)014772558</subfield><subfield code="x">0369-9420</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:46</subfield><subfield code="g">year:2017</subfield><subfield code="g">number:6</subfield><subfield code="g">pages:485-495</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">http://dx.doi.org/10.1108/PRT-11-2016-0116</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">http://www.emeraldinsight.com/doi/abs/10.1108/PRT-11-2016-0116</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">https://search.proquest.com/docview/1945073464</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-DE-84</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">58.00</subfield><subfield code="q">AVZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">46</subfield><subfield code="j">2017</subfield><subfield code="e">6</subfield><subfield code="h">485-495</subfield></datafield></record></collection>
|
| author |
Salleh, Mek Zah |
| spellingShingle |
Salleh, Mek Zah ddc 660 bkl 58.00 misc Epoxy compounds misc Chemical properties misc Vegetable oils misc Mechanical properties misc Acrylates misc Usage misc Euphorbiaceae misc Forest products misc Synthesis (chemistry) misc Infrared spectra misc Chemistry misc Acrylic resins misc Acrylic acid misc Edible misc Raw materials misc Epoxidation misc Volatile organic compounds--VOCs misc Catalysts misc Temperature effects misc Infrared analysis misc Seeds misc Coating misc Triethylamine misc Formulations misc Laboratories misc Chemical engineering misc Science misc Fourier transformation misc Reaction time misc Fourier transforms misc Natural resources misc Fatty acids misc Nuclear magnetic resonance misc Oils & fats Physico-chemical characterisation of epoxy acrylate resin from jatropha seed oil |
| authorStr |
Salleh, Mek Zah |
| ppnlink_with_tag_str_mv |
@@773@@(DE-627)129385700 |
| format |
Article |
| dewey-ones |
660 - Chemical engineering |
| delete_txt_mv |
keep |
| author_role |
aut |
| collection |
OLC |
| remote_str |
false |
| illustrated |
Not Illustrated |
| issn |
0369-9420 |
| topic_title |
660 ZDB 58.00 bkl Physico-chemical characterisation of epoxy acrylate resin from jatropha seed oil Epoxy compounds Chemical properties Vegetable oils Mechanical properties Acrylates Usage Euphorbiaceae Forest products Synthesis (chemistry) Infrared spectra Chemistry Acrylic resins Acrylic acid Edible Raw materials Epoxidation Volatile organic compounds--VOCs Catalysts Temperature effects Infrared analysis Seeds Coating Triethylamine Formulations Laboratories Chemical engineering Science Fourier transformation Reaction time Fourier transforms Natural resources Fatty acids Nuclear magnetic resonance Oils & fats |
| topic |
ddc 660 bkl 58.00 misc Epoxy compounds misc Chemical properties misc Vegetable oils misc Mechanical properties misc Acrylates misc Usage misc Euphorbiaceae misc Forest products misc Synthesis (chemistry) misc Infrared spectra misc Chemistry misc Acrylic resins misc Acrylic acid misc Edible misc Raw materials misc Epoxidation misc Volatile organic compounds--VOCs misc Catalysts misc Temperature effects misc Infrared analysis misc Seeds misc Coating misc Triethylamine misc Formulations misc Laboratories misc Chemical engineering misc Science misc Fourier transformation misc Reaction time misc Fourier transforms misc Natural resources misc Fatty acids misc Nuclear magnetic resonance misc Oils & fats |
| topic_unstemmed |
ddc 660 bkl 58.00 misc Epoxy compounds misc Chemical properties misc Vegetable oils misc Mechanical properties misc Acrylates misc Usage misc Euphorbiaceae misc Forest products misc Synthesis (chemistry) misc Infrared spectra misc Chemistry misc Acrylic resins misc Acrylic acid misc Edible misc Raw materials misc Epoxidation misc Volatile organic compounds--VOCs misc Catalysts misc Temperature effects misc Infrared analysis misc Seeds misc Coating misc Triethylamine misc Formulations misc Laboratories misc Chemical engineering misc Science misc Fourier transformation misc Reaction time misc Fourier transforms misc Natural resources misc Fatty acids misc Nuclear magnetic resonance misc Oils & fats |
| topic_browse |
ddc 660 bkl 58.00 misc Epoxy compounds misc Chemical properties misc Vegetable oils misc Mechanical properties misc Acrylates misc Usage misc Euphorbiaceae misc Forest products misc Synthesis (chemistry) misc Infrared spectra misc Chemistry misc Acrylic resins misc Acrylic acid misc Edible misc Raw materials misc Epoxidation misc Volatile organic compounds--VOCs misc Catalysts misc Temperature effects misc Infrared analysis misc Seeds misc Coating misc Triethylamine misc Formulations misc Laboratories misc Chemical engineering misc Science misc Fourier transformation misc Reaction time misc Fourier transforms misc Natural resources misc Fatty acids misc Nuclear magnetic resonance misc Oils & fats |
| format_facet |
Aufsätze Gedruckte Aufsätze |
| format_main_str_mv |
Text Zeitschrift/Artikel |
| carriertype_str_mv |
nc |
| author2_variant |
e r j t erj erjt l c a lc lca m m a mm mma m b mb j l w jl jlw c y c cy cyc s m sm s s ss |
| hierarchy_parent_title |
Pigment & resin technology |
| hierarchy_parent_id |
129385700 |
| dewey-tens |
660 - Chemical engineering |
| hierarchy_top_title |
Pigment & resin technology |
| isfreeaccess_txt |
false |
| familylinks_str_mv |
(DE-627)129385700 (DE-600)183967-6 (DE-576)014772558 |
| title |
Physico-chemical characterisation of epoxy acrylate resin from jatropha seed oil |
| ctrlnum |
(DE-627)OLC1996788825 (DE-599)GBVOLC1996788825 (PRQ)e1568-957ae896ca0b863aab078a564f738b2c07d19948a045cbd0e32df57cac77bdc50 (KEY)0010147820170000046000600485physicochemicalcharacterisationofepoxyacrylateresi |
| title_full |
Physico-chemical characterisation of epoxy acrylate resin from jatropha seed oil |
| author_sort |
Salleh, Mek Zah |
| journal |
Pigment & resin technology |
| journalStr |
Pigment & resin technology |
| lang_code |
eng |
| isOA_bool |
false |
| dewey-hundreds |
600 - Technology |
| recordtype |
marc |
| publishDateSort |
2017 |
| contenttype_str_mv |
txt |
| container_start_page |
485 |
| author_browse |
Salleh, Mek Zah |
| container_volume |
46 |
| class |
660 ZDB 58.00 bkl |
| format_se |
Aufsätze |
| author-letter |
Salleh, Mek Zah |
| doi_str_mv |
10.1108/PRT-11-2016-0116 |
| dewey-full |
660 |
| title_sort |
physico-chemical characterisation of epoxy acrylate resin from jatropha seed oil |
| title_auth |
Physico-chemical characterisation of epoxy acrylate resin from jatropha seed oil |
| abstract |
Purpose This paper aims to demonstrate the synthesis of polyesterification reaction of non-edible jatropha seed oil (JO) and acrylic acid, which leads to the production of acrylated epoxidised-based resin. To understand the physico-chemical characteristics when synthesis the JO-based epoxy acrylate, the effect of temperature on the reaction, concentration of acrylic acid and role of catalyst on reaction time and acid value were studied. Design/methodology/approach First, the double bond in JO was functionalised by epoxidation using the solvent-free performic method. The subsequent process was acrylation with acrylic acid using the base catalyst triethylamine and 4-methoxyphenol as an inhibitor respectively. The physico-chemical characteristics during the synthesis of the epoxy acrylate such as acid value was monitored and analysed. The formation of the epoxy and acrylate group was confirmed by a Fourier transform infrared spectroscopy spectra analysis and nuclear magnetic resonance analysis. Findings The optimum reaction condition was achieved at a ratio of epoxidised JO to acrylic acid of 1:1.5 and the reaction temperature of 110°C. This was indicated by the acid value reduction from 86 to 15 mg KOH/g sample at 6 hours. Practical implications The JO-based epoxy acrylate synthesised has a potential to be used in formulations the prepolymer resin for UV curable coating applications. The JO which is from natural resources and is sustainable raw materials that possible reduce the dependency on petroleum-based coating. Originality/value The epoxidised jatropha seed oil epoxy acrylate was synthesised, as a new type of oligomer resin that contains a reactive acrylate group, which can be alternative to petroleum-based coating and can used further in the formulation of the radiation curable coating. |
| abstractGer |
Purpose This paper aims to demonstrate the synthesis of polyesterification reaction of non-edible jatropha seed oil (JO) and acrylic acid, which leads to the production of acrylated epoxidised-based resin. To understand the physico-chemical characteristics when synthesis the JO-based epoxy acrylate, the effect of temperature on the reaction, concentration of acrylic acid and role of catalyst on reaction time and acid value were studied. Design/methodology/approach First, the double bond in JO was functionalised by epoxidation using the solvent-free performic method. The subsequent process was acrylation with acrylic acid using the base catalyst triethylamine and 4-methoxyphenol as an inhibitor respectively. The physico-chemical characteristics during the synthesis of the epoxy acrylate such as acid value was monitored and analysed. The formation of the epoxy and acrylate group was confirmed by a Fourier transform infrared spectroscopy spectra analysis and nuclear magnetic resonance analysis. Findings The optimum reaction condition was achieved at a ratio of epoxidised JO to acrylic acid of 1:1.5 and the reaction temperature of 110°C. This was indicated by the acid value reduction from 86 to 15 mg KOH/g sample at 6 hours. Practical implications The JO-based epoxy acrylate synthesised has a potential to be used in formulations the prepolymer resin for UV curable coating applications. The JO which is from natural resources and is sustainable raw materials that possible reduce the dependency on petroleum-based coating. Originality/value The epoxidised jatropha seed oil epoxy acrylate was synthesised, as a new type of oligomer resin that contains a reactive acrylate group, which can be alternative to petroleum-based coating and can used further in the formulation of the radiation curable coating. |
| abstract_unstemmed |
Purpose This paper aims to demonstrate the synthesis of polyesterification reaction of non-edible jatropha seed oil (JO) and acrylic acid, which leads to the production of acrylated epoxidised-based resin. To understand the physico-chemical characteristics when synthesis the JO-based epoxy acrylate, the effect of temperature on the reaction, concentration of acrylic acid and role of catalyst on reaction time and acid value were studied. Design/methodology/approach First, the double bond in JO was functionalised by epoxidation using the solvent-free performic method. The subsequent process was acrylation with acrylic acid using the base catalyst triethylamine and 4-methoxyphenol as an inhibitor respectively. The physico-chemical characteristics during the synthesis of the epoxy acrylate such as acid value was monitored and analysed. The formation of the epoxy and acrylate group was confirmed by a Fourier transform infrared spectroscopy spectra analysis and nuclear magnetic resonance analysis. Findings The optimum reaction condition was achieved at a ratio of epoxidised JO to acrylic acid of 1:1.5 and the reaction temperature of 110°C. This was indicated by the acid value reduction from 86 to 15 mg KOH/g sample at 6 hours. Practical implications The JO-based epoxy acrylate synthesised has a potential to be used in formulations the prepolymer resin for UV curable coating applications. The JO which is from natural resources and is sustainable raw materials that possible reduce the dependency on petroleum-based coating. Originality/value The epoxidised jatropha seed oil epoxy acrylate was synthesised, as a new type of oligomer resin that contains a reactive acrylate group, which can be alternative to petroleum-based coating and can used further in the formulation of the radiation curable coating. |
| collection_details |
GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 |
| container_issue |
6 |
| title_short |
Physico-chemical characterisation of epoxy acrylate resin from jatropha seed oil |
| url |
http://dx.doi.org/10.1108/PRT-11-2016-0116 http://www.emeraldinsight.com/doi/abs/10.1108/PRT-11-2016-0116 https://search.proquest.com/docview/1945073464 |
| remote_bool |
false |
| author2 |
Taib, Emiliana Rose Jusoh Abdullah, Luqman Chuah Aung, Min Min Basri, Mahiran Wong, Jia Li Chee, Ching Yern Mamat, Suhaini Saalah, Sariah |
| author2Str |
Taib, Emiliana Rose Jusoh Abdullah, Luqman Chuah Aung, Min Min Basri, Mahiran Wong, Jia Li Chee, Ching Yern Mamat, Suhaini Saalah, Sariah |
| ppnlink |
129385700 |
| mediatype_str_mv |
n |
| isOA_txt |
false |
| hochschulschrift_bool |
false |
| author2_role |
oth oth oth oth oth oth oth oth |
| doi_str |
10.1108/PRT-11-2016-0116 |
| up_date |
2024-07-04T01:23:32.442Z |
| _version_ |
1803609663018631168 |
| fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a2200265 4500</leader><controlfield tag="001">OLC1996788825</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230515212143.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">171125s2017 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1108/PRT-11-2016-0116</subfield><subfield code="2">doi</subfield></datafield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">PQ20171228</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC1996788825</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVOLC1996788825</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(PRQ)e1568-957ae896ca0b863aab078a564f738b2c07d19948a045cbd0e32df57cac77bdc50</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(KEY)0010147820170000046000600485physicochemicalcharacterisationofepoxyacrylateresi</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">660</subfield><subfield code="q">ZDB</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">58.00</subfield><subfield code="2">bkl</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Salleh, Mek Zah</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Physico-chemical characterisation of epoxy acrylate resin from jatropha seed oil</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2017</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Purpose This paper aims to demonstrate the synthesis of polyesterification reaction of non-edible jatropha seed oil (JO) and acrylic acid, which leads to the production of acrylated epoxidised-based resin. To understand the physico-chemical characteristics when synthesis the JO-based epoxy acrylate, the effect of temperature on the reaction, concentration of acrylic acid and role of catalyst on reaction time and acid value were studied. Design/methodology/approach First, the double bond in JO was functionalised by epoxidation using the solvent-free performic method. The subsequent process was acrylation with acrylic acid using the base catalyst triethylamine and 4-methoxyphenol as an inhibitor respectively. The physico-chemical characteristics during the synthesis of the epoxy acrylate such as acid value was monitored and analysed. The formation of the epoxy and acrylate group was confirmed by a Fourier transform infrared spectroscopy spectra analysis and nuclear magnetic resonance analysis. Findings The optimum reaction condition was achieved at a ratio of epoxidised JO to acrylic acid of 1:1.5 and the reaction temperature of 110°C. This was indicated by the acid value reduction from 86 to 15 mg KOH/g sample at 6 hours. Practical implications The JO-based epoxy acrylate synthesised has a potential to be used in formulations the prepolymer resin for UV curable coating applications. The JO which is from natural resources and is sustainable raw materials that possible reduce the dependency on petroleum-based coating. Originality/value The epoxidised jatropha seed oil epoxy acrylate was synthesised, as a new type of oligomer resin that contains a reactive acrylate group, which can be alternative to petroleum-based coating and can used further in the formulation of the radiation curable coating.</subfield></datafield><datafield tag="540" ind1=" " ind2=" "><subfield code="a">Nutzungsrecht: © Emerald Publishing Limited</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Epoxy compounds</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Chemical properties</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Vegetable oils</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Mechanical properties</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Acrylates</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Usage</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Euphorbiaceae</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Forest products</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Synthesis (chemistry)</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Infrared spectra</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Chemistry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Acrylic resins</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Acrylic acid</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Edible</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Raw materials</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Epoxidation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Volatile organic compounds--VOCs</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Catalysts</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Temperature effects</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Infrared analysis</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Seeds</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Coating</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Triethylamine</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Formulations</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Laboratories</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Chemical engineering</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Science</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Fourier transformation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Reaction time</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Fourier transforms</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Natural resources</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Fatty acids</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Nuclear magnetic resonance</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Oils & fats</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Taib, Emiliana Rose Jusoh</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Abdullah, Luqman Chuah</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Aung, Min Min</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Basri, Mahiran</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wong, Jia Li</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Chee, Ching Yern</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Mamat, Suhaini</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Saalah, Sariah</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Pigment & resin technology</subfield><subfield code="d">London : Sawell, 1972</subfield><subfield code="g">46(2017), 6, Seite 485-495</subfield><subfield code="w">(DE-627)129385700</subfield><subfield code="w">(DE-600)183967-6</subfield><subfield code="w">(DE-576)014772558</subfield><subfield code="x">0369-9420</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:46</subfield><subfield code="g">year:2017</subfield><subfield code="g">number:6</subfield><subfield code="g">pages:485-495</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">http://dx.doi.org/10.1108/PRT-11-2016-0116</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">http://www.emeraldinsight.com/doi/abs/10.1108/PRT-11-2016-0116</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">https://search.proquest.com/docview/1945073464</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-TEC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-DE-84</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="936" ind1="b" ind2="k"><subfield code="a">58.00</subfield><subfield code="q">AVZ</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">46</subfield><subfield code="j">2017</subfield><subfield code="e">6</subfield><subfield code="h">485-495</subfield></datafield></record></collection>
|
| score |
7.4017944 |