An approach to estimate the activation energies of fragmentation occurring in quadrupole collision cell of the mass spectrometer
The classical semi‐quantitative Rice‐Ramsperger‐Kassel (RRK) theory was used for the calculation of the internal energy dependent reaction rate coefficient of the collision‐induced dissociation (CID) reaction in tandem mass spectrometry (MS/MS). The survival yield (SY) was determined by the reaction...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Kuki, Ákos [verfasserIn] |
|---|
| Format: |
Artikel |
|---|---|
| Sprache: |
Englisch |
| Erschienen: |
2017 |
|---|
| Rechteinformationen: |
Nutzungsrecht: Copyright © 2017 John Wiley & Sons, Ltd. |
|---|
| Schlagwörter: |
|---|
| Übergeordnetes Werk: |
Enthalten in: Journal of mass spectrometry - Chichester [u.a.] : Wiley, 1995, 52(2017), 10, Seite 672-680 |
|---|---|
| Übergeordnetes Werk: |
volume:52 ; year:2017 ; number:10 ; pages:672-680 |
| Links: |
|---|
| DOI / URN: |
10.1002/jms.3971 |
|---|
| Katalog-ID: |
OLC1997382784 |
|---|
| LEADER | 01000caa a2200265 4500 | ||
|---|---|---|---|
| 001 | OLC1997382784 | ||
| 003 | DE-627 | ||
| 005 | 20230715073522.0 | ||
| 007 | tu | ||
| 008 | 171125s2017 xx ||||| 00| ||eng c | ||
| 024 | 7 | |a 10.1002/jms.3971 |2 doi | |
| 028 | 5 | 2 | |a PQ20171125 |
| 035 | |a (DE-627)OLC1997382784 | ||
| 035 | |a (DE-599)GBVOLC1997382784 | ||
| 035 | |a (PRQ)p951-ad9256b180b83b262ae22a7e12c03672754e9b5fbd63511b8bb9d5b7161cb5c43 | ||
| 035 | |a (KEY)0065495720170000052001000672approachtoestimatetheactivationenergiesoffragmenta | ||
| 040 | |a DE-627 |b ger |c DE-627 |e rakwb | ||
| 041 | |a eng | ||
| 082 | 0 | 4 | |a 570 |a 540 |a 530 |q DE-600 |
| 084 | |a BIODIV |2 fid | ||
| 100 | 1 | |a Kuki, Ákos |e verfasserin |4 aut | |
| 245 | 1 | 3 | |a An approach to estimate the activation energies of fragmentation occurring in quadrupole collision cell of the mass spectrometer |
| 264 | 1 | |c 2017 | |
| 336 | |a Text |b txt |2 rdacontent | ||
| 337 | |a ohne Hilfsmittel zu benutzen |b n |2 rdamedia | ||
| 338 | |a Band |b nc |2 rdacarrier | ||
| 520 | |a The classical semi‐quantitative Rice‐Ramsperger‐Kassel (RRK) theory was used for the calculation of the internal energy dependent reaction rate coefficient of the collision‐induced dissociation (CID) reaction in tandem mass spectrometry (MS/MS). The survival yield (SY) was determined by the reaction rate equation for the unimolecular dissociation of the precursor ion. The parameters of the rate equation and the RRK model were approximated based on the instrumental conditions. We used the RRK equation for the description of the basic behavior of the fragmentation reactions and for the estimation of the internal energy of the precursor ion. The critical energies for fragmentation ( E o ) of various molecules were estimated and compared with those reported in the literature. The model was extended by taking into account the initial internal energy distribution of the ions created in the ion source. It must be emphasized that our approach provides only a crude estimate for E o . | ||
| 540 | |a Nutzungsrecht: Copyright © 2017 John Wiley & Sons, Ltd. | ||
| 650 | 4 | |a collision cell | |
| 650 | 4 | |a collision‐induced dissociation | |
| 650 | 4 | |a survival yield | |
| 650 | 4 | |a tandem mass spectrometry | |
| 650 | 4 | |a RRK model | |
| 650 | 4 | |a Yield | |
| 650 | 4 | |a Mathematical models | |
| 650 | 4 | |a Energy | |
| 650 | 4 | |a Dissociation | |
| 650 | 4 | |a Mass spectrometry | |
| 650 | 4 | |a Energy distribution | |
| 650 | 4 | |a Molecules | |
| 650 | 4 | |a Internal energy | |
| 650 | 4 | |a Energy of dissociation | |
| 650 | 4 | |a Mass spectroscopy | |
| 650 | 4 | |a Quadrupoles | |
| 650 | 4 | |a Fragmentation | |
| 700 | 1 | |a Nagy, Lajos |4 oth | |
| 700 | 1 | |a Zsuga, Miklós |4 oth | |
| 700 | 1 | |a Kéki, Sándor |4 oth | |
| 773 | 0 | 8 | |i Enthalten in |t Journal of mass spectrometry |d Chichester [u.a.] : Wiley, 1995 |g 52(2017), 10, Seite 672-680 |w (DE-627)182631915 |w (DE-600)1221763-3 |w (DE-576)04390775X |x 1076-5174 |7 nnns |
| 773 | 1 | 8 | |g volume:52 |g year:2017 |g number:10 |g pages:672-680 |
| 856 | 4 | 1 | |u http://dx.doi.org/10.1002/jms.3971 |3 Volltext |
| 856 | 4 | 2 | |u http://onlinelibrary.wiley.com/doi/10.1002/jms.3971/abstract |
| 856 | 4 | 2 | |u https://search.proquest.com/docview/1955821971 |
| 912 | |a GBV_USEFLAG_A | ||
| 912 | |a SYSFLAG_A | ||
| 912 | |a GBV_OLC | ||
| 912 | |a FID-BIODIV | ||
| 912 | |a SSG-OLC-PHY | ||
| 912 | |a SSG-OLC-CHE | ||
| 912 | |a SSG-OLC-PHA | ||
| 912 | |a SSG-OLC-DE-84 | ||
| 912 | |a GBV_ILN_70 | ||
| 951 | |a AR | ||
| 952 | |d 52 |j 2017 |e 10 |h 672-680 | ||
| author_variant |
á k ák |
|---|---|
| matchkey_str |
article:10765174:2017----::nprahosiaehatvtoeegeofamnaincurniqarplcl |
| hierarchy_sort_str |
2017 |
| publishDate |
2017 |
| allfields |
10.1002/jms.3971 doi PQ20171125 (DE-627)OLC1997382784 (DE-599)GBVOLC1997382784 (PRQ)p951-ad9256b180b83b262ae22a7e12c03672754e9b5fbd63511b8bb9d5b7161cb5c43 (KEY)0065495720170000052001000672approachtoestimatetheactivationenergiesoffragmenta DE-627 ger DE-627 rakwb eng 570 540 530 DE-600 BIODIV fid Kuki, Ákos verfasserin aut An approach to estimate the activation energies of fragmentation occurring in quadrupole collision cell of the mass spectrometer 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier The classical semi‐quantitative Rice‐Ramsperger‐Kassel (RRK) theory was used for the calculation of the internal energy dependent reaction rate coefficient of the collision‐induced dissociation (CID) reaction in tandem mass spectrometry (MS/MS). The survival yield (SY) was determined by the reaction rate equation for the unimolecular dissociation of the precursor ion. The parameters of the rate equation and the RRK model were approximated based on the instrumental conditions. We used the RRK equation for the description of the basic behavior of the fragmentation reactions and for the estimation of the internal energy of the precursor ion. The critical energies for fragmentation ( E o ) of various molecules were estimated and compared with those reported in the literature. The model was extended by taking into account the initial internal energy distribution of the ions created in the ion source. It must be emphasized that our approach provides only a crude estimate for E o . Nutzungsrecht: Copyright © 2017 John Wiley & Sons, Ltd. collision cell collision‐induced dissociation survival yield tandem mass spectrometry RRK model Yield Mathematical models Energy Dissociation Mass spectrometry Energy distribution Molecules Internal energy Energy of dissociation Mass spectroscopy Quadrupoles Fragmentation Nagy, Lajos oth Zsuga, Miklós oth Kéki, Sándor oth Enthalten in Journal of mass spectrometry Chichester [u.a.] : Wiley, 1995 52(2017), 10, Seite 672-680 (DE-627)182631915 (DE-600)1221763-3 (DE-576)04390775X 1076-5174 nnns volume:52 year:2017 number:10 pages:672-680 http://dx.doi.org/10.1002/jms.3971 Volltext http://onlinelibrary.wiley.com/doi/10.1002/jms.3971/abstract https://search.proquest.com/docview/1955821971 GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 52 2017 10 672-680 |
| spelling |
10.1002/jms.3971 doi PQ20171125 (DE-627)OLC1997382784 (DE-599)GBVOLC1997382784 (PRQ)p951-ad9256b180b83b262ae22a7e12c03672754e9b5fbd63511b8bb9d5b7161cb5c43 (KEY)0065495720170000052001000672approachtoestimatetheactivationenergiesoffragmenta DE-627 ger DE-627 rakwb eng 570 540 530 DE-600 BIODIV fid Kuki, Ákos verfasserin aut An approach to estimate the activation energies of fragmentation occurring in quadrupole collision cell of the mass spectrometer 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier The classical semi‐quantitative Rice‐Ramsperger‐Kassel (RRK) theory was used for the calculation of the internal energy dependent reaction rate coefficient of the collision‐induced dissociation (CID) reaction in tandem mass spectrometry (MS/MS). The survival yield (SY) was determined by the reaction rate equation for the unimolecular dissociation of the precursor ion. The parameters of the rate equation and the RRK model were approximated based on the instrumental conditions. We used the RRK equation for the description of the basic behavior of the fragmentation reactions and for the estimation of the internal energy of the precursor ion. The critical energies for fragmentation ( E o ) of various molecules were estimated and compared with those reported in the literature. The model was extended by taking into account the initial internal energy distribution of the ions created in the ion source. It must be emphasized that our approach provides only a crude estimate for E o . Nutzungsrecht: Copyright © 2017 John Wiley & Sons, Ltd. collision cell collision‐induced dissociation survival yield tandem mass spectrometry RRK model Yield Mathematical models Energy Dissociation Mass spectrometry Energy distribution Molecules Internal energy Energy of dissociation Mass spectroscopy Quadrupoles Fragmentation Nagy, Lajos oth Zsuga, Miklós oth Kéki, Sándor oth Enthalten in Journal of mass spectrometry Chichester [u.a.] : Wiley, 1995 52(2017), 10, Seite 672-680 (DE-627)182631915 (DE-600)1221763-3 (DE-576)04390775X 1076-5174 nnns volume:52 year:2017 number:10 pages:672-680 http://dx.doi.org/10.1002/jms.3971 Volltext http://onlinelibrary.wiley.com/doi/10.1002/jms.3971/abstract https://search.proquest.com/docview/1955821971 GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 52 2017 10 672-680 |
| allfields_unstemmed |
10.1002/jms.3971 doi PQ20171125 (DE-627)OLC1997382784 (DE-599)GBVOLC1997382784 (PRQ)p951-ad9256b180b83b262ae22a7e12c03672754e9b5fbd63511b8bb9d5b7161cb5c43 (KEY)0065495720170000052001000672approachtoestimatetheactivationenergiesoffragmenta DE-627 ger DE-627 rakwb eng 570 540 530 DE-600 BIODIV fid Kuki, Ákos verfasserin aut An approach to estimate the activation energies of fragmentation occurring in quadrupole collision cell of the mass spectrometer 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier The classical semi‐quantitative Rice‐Ramsperger‐Kassel (RRK) theory was used for the calculation of the internal energy dependent reaction rate coefficient of the collision‐induced dissociation (CID) reaction in tandem mass spectrometry (MS/MS). The survival yield (SY) was determined by the reaction rate equation for the unimolecular dissociation of the precursor ion. The parameters of the rate equation and the RRK model were approximated based on the instrumental conditions. We used the RRK equation for the description of the basic behavior of the fragmentation reactions and for the estimation of the internal energy of the precursor ion. The critical energies for fragmentation ( E o ) of various molecules were estimated and compared with those reported in the literature. The model was extended by taking into account the initial internal energy distribution of the ions created in the ion source. It must be emphasized that our approach provides only a crude estimate for E o . Nutzungsrecht: Copyright © 2017 John Wiley & Sons, Ltd. collision cell collision‐induced dissociation survival yield tandem mass spectrometry RRK model Yield Mathematical models Energy Dissociation Mass spectrometry Energy distribution Molecules Internal energy Energy of dissociation Mass spectroscopy Quadrupoles Fragmentation Nagy, Lajos oth Zsuga, Miklós oth Kéki, Sándor oth Enthalten in Journal of mass spectrometry Chichester [u.a.] : Wiley, 1995 52(2017), 10, Seite 672-680 (DE-627)182631915 (DE-600)1221763-3 (DE-576)04390775X 1076-5174 nnns volume:52 year:2017 number:10 pages:672-680 http://dx.doi.org/10.1002/jms.3971 Volltext http://onlinelibrary.wiley.com/doi/10.1002/jms.3971/abstract https://search.proquest.com/docview/1955821971 GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 52 2017 10 672-680 |
| allfieldsGer |
10.1002/jms.3971 doi PQ20171125 (DE-627)OLC1997382784 (DE-599)GBVOLC1997382784 (PRQ)p951-ad9256b180b83b262ae22a7e12c03672754e9b5fbd63511b8bb9d5b7161cb5c43 (KEY)0065495720170000052001000672approachtoestimatetheactivationenergiesoffragmenta DE-627 ger DE-627 rakwb eng 570 540 530 DE-600 BIODIV fid Kuki, Ákos verfasserin aut An approach to estimate the activation energies of fragmentation occurring in quadrupole collision cell of the mass spectrometer 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier The classical semi‐quantitative Rice‐Ramsperger‐Kassel (RRK) theory was used for the calculation of the internal energy dependent reaction rate coefficient of the collision‐induced dissociation (CID) reaction in tandem mass spectrometry (MS/MS). The survival yield (SY) was determined by the reaction rate equation for the unimolecular dissociation of the precursor ion. The parameters of the rate equation and the RRK model were approximated based on the instrumental conditions. We used the RRK equation for the description of the basic behavior of the fragmentation reactions and for the estimation of the internal energy of the precursor ion. The critical energies for fragmentation ( E o ) of various molecules were estimated and compared with those reported in the literature. The model was extended by taking into account the initial internal energy distribution of the ions created in the ion source. It must be emphasized that our approach provides only a crude estimate for E o . Nutzungsrecht: Copyright © 2017 John Wiley & Sons, Ltd. collision cell collision‐induced dissociation survival yield tandem mass spectrometry RRK model Yield Mathematical models Energy Dissociation Mass spectrometry Energy distribution Molecules Internal energy Energy of dissociation Mass spectroscopy Quadrupoles Fragmentation Nagy, Lajos oth Zsuga, Miklós oth Kéki, Sándor oth Enthalten in Journal of mass spectrometry Chichester [u.a.] : Wiley, 1995 52(2017), 10, Seite 672-680 (DE-627)182631915 (DE-600)1221763-3 (DE-576)04390775X 1076-5174 nnns volume:52 year:2017 number:10 pages:672-680 http://dx.doi.org/10.1002/jms.3971 Volltext http://onlinelibrary.wiley.com/doi/10.1002/jms.3971/abstract https://search.proquest.com/docview/1955821971 GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 52 2017 10 672-680 |
| allfieldsSound |
10.1002/jms.3971 doi PQ20171125 (DE-627)OLC1997382784 (DE-599)GBVOLC1997382784 (PRQ)p951-ad9256b180b83b262ae22a7e12c03672754e9b5fbd63511b8bb9d5b7161cb5c43 (KEY)0065495720170000052001000672approachtoestimatetheactivationenergiesoffragmenta DE-627 ger DE-627 rakwb eng 570 540 530 DE-600 BIODIV fid Kuki, Ákos verfasserin aut An approach to estimate the activation energies of fragmentation occurring in quadrupole collision cell of the mass spectrometer 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier The classical semi‐quantitative Rice‐Ramsperger‐Kassel (RRK) theory was used for the calculation of the internal energy dependent reaction rate coefficient of the collision‐induced dissociation (CID) reaction in tandem mass spectrometry (MS/MS). The survival yield (SY) was determined by the reaction rate equation for the unimolecular dissociation of the precursor ion. The parameters of the rate equation and the RRK model were approximated based on the instrumental conditions. We used the RRK equation for the description of the basic behavior of the fragmentation reactions and for the estimation of the internal energy of the precursor ion. The critical energies for fragmentation ( E o ) of various molecules were estimated and compared with those reported in the literature. The model was extended by taking into account the initial internal energy distribution of the ions created in the ion source. It must be emphasized that our approach provides only a crude estimate for E o . Nutzungsrecht: Copyright © 2017 John Wiley & Sons, Ltd. collision cell collision‐induced dissociation survival yield tandem mass spectrometry RRK model Yield Mathematical models Energy Dissociation Mass spectrometry Energy distribution Molecules Internal energy Energy of dissociation Mass spectroscopy Quadrupoles Fragmentation Nagy, Lajos oth Zsuga, Miklós oth Kéki, Sándor oth Enthalten in Journal of mass spectrometry Chichester [u.a.] : Wiley, 1995 52(2017), 10, Seite 672-680 (DE-627)182631915 (DE-600)1221763-3 (DE-576)04390775X 1076-5174 nnns volume:52 year:2017 number:10 pages:672-680 http://dx.doi.org/10.1002/jms.3971 Volltext http://onlinelibrary.wiley.com/doi/10.1002/jms.3971/abstract https://search.proquest.com/docview/1955821971 GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 AR 52 2017 10 672-680 |
| language |
English |
| source |
Enthalten in Journal of mass spectrometry 52(2017), 10, Seite 672-680 volume:52 year:2017 number:10 pages:672-680 |
| sourceStr |
Enthalten in Journal of mass spectrometry 52(2017), 10, Seite 672-680 volume:52 year:2017 number:10 pages:672-680 |
| format_phy_str_mv |
Article |
| institution |
findex.gbv.de |
| topic_facet |
collision cell collision‐induced dissociation survival yield tandem mass spectrometry RRK model Yield Mathematical models Energy Dissociation Mass spectrometry Energy distribution Molecules Internal energy Energy of dissociation Mass spectroscopy Quadrupoles Fragmentation |
| dewey-raw |
570 |
| isfreeaccess_bool |
false |
| container_title |
Journal of mass spectrometry |
| authorswithroles_txt_mv |
Kuki, Ákos @@aut@@ Nagy, Lajos @@oth@@ Zsuga, Miklós @@oth@@ Kéki, Sándor @@oth@@ |
| publishDateDaySort_date |
2017-01-01T00:00:00Z |
| hierarchy_top_id |
182631915 |
| dewey-sort |
3570 |
| id |
OLC1997382784 |
| language_de |
englisch |
| fullrecord |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a2200265 4500</leader><controlfield tag="001">OLC1997382784</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230715073522.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">171125s2017 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1002/jms.3971</subfield><subfield code="2">doi</subfield></datafield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">PQ20171125</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC1997382784</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVOLC1997382784</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(PRQ)p951-ad9256b180b83b262ae22a7e12c03672754e9b5fbd63511b8bb9d5b7161cb5c43</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(KEY)0065495720170000052001000672approachtoestimatetheactivationenergiesoffragmenta</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">570</subfield><subfield code="a">540</subfield><subfield code="a">530</subfield><subfield code="q">DE-600</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">BIODIV</subfield><subfield code="2">fid</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Kuki, Ákos</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="3"><subfield code="a">An approach to estimate the activation energies of fragmentation occurring in quadrupole collision cell of the mass spectrometer</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2017</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The classical semi‐quantitative Rice‐Ramsperger‐Kassel (RRK) theory was used for the calculation of the internal energy dependent reaction rate coefficient of the collision‐induced dissociation (CID) reaction in tandem mass spectrometry (MS/MS). The survival yield (SY) was determined by the reaction rate equation for the unimolecular dissociation of the precursor ion. The parameters of the rate equation and the RRK model were approximated based on the instrumental conditions. We used the RRK equation for the description of the basic behavior of the fragmentation reactions and for the estimation of the internal energy of the precursor ion. The critical energies for fragmentation ( E o ) of various molecules were estimated and compared with those reported in the literature. The model was extended by taking into account the initial internal energy distribution of the ions created in the ion source. It must be emphasized that our approach provides only a crude estimate for E o .</subfield></datafield><datafield tag="540" ind1=" " ind2=" "><subfield code="a">Nutzungsrecht: Copyright © 2017 John Wiley & Sons, Ltd.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">collision cell</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">collision‐induced dissociation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">survival yield</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">tandem mass spectrometry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">RRK model</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Yield</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Mathematical models</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Energy</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Dissociation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Mass spectrometry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Energy distribution</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Molecules</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Internal energy</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Energy of dissociation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Mass spectroscopy</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Quadrupoles</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Fragmentation</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Nagy, Lajos</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zsuga, Miklós</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kéki, Sándor</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of mass spectrometry</subfield><subfield code="d">Chichester [u.a.] : Wiley, 1995</subfield><subfield code="g">52(2017), 10, Seite 672-680</subfield><subfield code="w">(DE-627)182631915</subfield><subfield code="w">(DE-600)1221763-3</subfield><subfield code="w">(DE-576)04390775X</subfield><subfield code="x">1076-5174</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:52</subfield><subfield code="g">year:2017</subfield><subfield code="g">number:10</subfield><subfield code="g">pages:672-680</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">http://dx.doi.org/10.1002/jms.3971</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">http://onlinelibrary.wiley.com/doi/10.1002/jms.3971/abstract</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">https://search.proquest.com/docview/1955821971</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">FID-BIODIV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHY</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-DE-84</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">52</subfield><subfield code="j">2017</subfield><subfield code="e">10</subfield><subfield code="h">672-680</subfield></datafield></record></collection>
|
| author |
Kuki, Ákos |
| spellingShingle |
Kuki, Ákos ddc 570 fid BIODIV misc collision cell misc collision‐induced dissociation misc survival yield misc tandem mass spectrometry misc RRK model misc Yield misc Mathematical models misc Energy misc Dissociation misc Mass spectrometry misc Energy distribution misc Molecules misc Internal energy misc Energy of dissociation misc Mass spectroscopy misc Quadrupoles misc Fragmentation An approach to estimate the activation energies of fragmentation occurring in quadrupole collision cell of the mass spectrometer |
| authorStr |
Kuki, Ákos |
| ppnlink_with_tag_str_mv |
@@773@@(DE-627)182631915 |
| format |
Article |
| dewey-ones |
570 - Life sciences; biology 540 - Chemistry & allied sciences 530 - Physics |
| delete_txt_mv |
keep |
| author_role |
aut |
| collection |
OLC |
| remote_str |
false |
| illustrated |
Not Illustrated |
| issn |
1076-5174 |
| topic_title |
570 540 530 DE-600 BIODIV fid An approach to estimate the activation energies of fragmentation occurring in quadrupole collision cell of the mass spectrometer collision cell collision‐induced dissociation survival yield tandem mass spectrometry RRK model Yield Mathematical models Energy Dissociation Mass spectrometry Energy distribution Molecules Internal energy Energy of dissociation Mass spectroscopy Quadrupoles Fragmentation |
| topic |
ddc 570 fid BIODIV misc collision cell misc collision‐induced dissociation misc survival yield misc tandem mass spectrometry misc RRK model misc Yield misc Mathematical models misc Energy misc Dissociation misc Mass spectrometry misc Energy distribution misc Molecules misc Internal energy misc Energy of dissociation misc Mass spectroscopy misc Quadrupoles misc Fragmentation |
| topic_unstemmed |
ddc 570 fid BIODIV misc collision cell misc collision‐induced dissociation misc survival yield misc tandem mass spectrometry misc RRK model misc Yield misc Mathematical models misc Energy misc Dissociation misc Mass spectrometry misc Energy distribution misc Molecules misc Internal energy misc Energy of dissociation misc Mass spectroscopy misc Quadrupoles misc Fragmentation |
| topic_browse |
ddc 570 fid BIODIV misc collision cell misc collision‐induced dissociation misc survival yield misc tandem mass spectrometry misc RRK model misc Yield misc Mathematical models misc Energy misc Dissociation misc Mass spectrometry misc Energy distribution misc Molecules misc Internal energy misc Energy of dissociation misc Mass spectroscopy misc Quadrupoles misc Fragmentation |
| format_facet |
Aufsätze Gedruckte Aufsätze |
| format_main_str_mv |
Text Zeitschrift/Artikel |
| carriertype_str_mv |
nc |
| author2_variant |
l n ln m z mz s k sk |
| hierarchy_parent_title |
Journal of mass spectrometry |
| hierarchy_parent_id |
182631915 |
| dewey-tens |
570 - Life sciences; biology 540 - Chemistry 530 - Physics |
| hierarchy_top_title |
Journal of mass spectrometry |
| isfreeaccess_txt |
false |
| familylinks_str_mv |
(DE-627)182631915 (DE-600)1221763-3 (DE-576)04390775X |
| title |
An approach to estimate the activation energies of fragmentation occurring in quadrupole collision cell of the mass spectrometer |
| ctrlnum |
(DE-627)OLC1997382784 (DE-599)GBVOLC1997382784 (PRQ)p951-ad9256b180b83b262ae22a7e12c03672754e9b5fbd63511b8bb9d5b7161cb5c43 (KEY)0065495720170000052001000672approachtoestimatetheactivationenergiesoffragmenta |
| title_full |
An approach to estimate the activation energies of fragmentation occurring in quadrupole collision cell of the mass spectrometer |
| author_sort |
Kuki, Ákos |
| journal |
Journal of mass spectrometry |
| journalStr |
Journal of mass spectrometry |
| lang_code |
eng |
| isOA_bool |
false |
| dewey-hundreds |
500 - Science |
| recordtype |
marc |
| publishDateSort |
2017 |
| contenttype_str_mv |
txt |
| container_start_page |
672 |
| author_browse |
Kuki, Ákos |
| container_volume |
52 |
| class |
570 540 530 DE-600 BIODIV fid |
| format_se |
Aufsätze |
| author-letter |
Kuki, Ákos |
| doi_str_mv |
10.1002/jms.3971 |
| dewey-full |
570 540 530 |
| title_sort |
approach to estimate the activation energies of fragmentation occurring in quadrupole collision cell of the mass spectrometer |
| title_auth |
An approach to estimate the activation energies of fragmentation occurring in quadrupole collision cell of the mass spectrometer |
| abstract |
The classical semi‐quantitative Rice‐Ramsperger‐Kassel (RRK) theory was used for the calculation of the internal energy dependent reaction rate coefficient of the collision‐induced dissociation (CID) reaction in tandem mass spectrometry (MS/MS). The survival yield (SY) was determined by the reaction rate equation for the unimolecular dissociation of the precursor ion. The parameters of the rate equation and the RRK model were approximated based on the instrumental conditions. We used the RRK equation for the description of the basic behavior of the fragmentation reactions and for the estimation of the internal energy of the precursor ion. The critical energies for fragmentation ( E o ) of various molecules were estimated and compared with those reported in the literature. The model was extended by taking into account the initial internal energy distribution of the ions created in the ion source. It must be emphasized that our approach provides only a crude estimate for E o . |
| abstractGer |
The classical semi‐quantitative Rice‐Ramsperger‐Kassel (RRK) theory was used for the calculation of the internal energy dependent reaction rate coefficient of the collision‐induced dissociation (CID) reaction in tandem mass spectrometry (MS/MS). The survival yield (SY) was determined by the reaction rate equation for the unimolecular dissociation of the precursor ion. The parameters of the rate equation and the RRK model were approximated based on the instrumental conditions. We used the RRK equation for the description of the basic behavior of the fragmentation reactions and for the estimation of the internal energy of the precursor ion. The critical energies for fragmentation ( E o ) of various molecules were estimated and compared with those reported in the literature. The model was extended by taking into account the initial internal energy distribution of the ions created in the ion source. It must be emphasized that our approach provides only a crude estimate for E o . |
| abstract_unstemmed |
The classical semi‐quantitative Rice‐Ramsperger‐Kassel (RRK) theory was used for the calculation of the internal energy dependent reaction rate coefficient of the collision‐induced dissociation (CID) reaction in tandem mass spectrometry (MS/MS). The survival yield (SY) was determined by the reaction rate equation for the unimolecular dissociation of the precursor ion. The parameters of the rate equation and the RRK model were approximated based on the instrumental conditions. We used the RRK equation for the description of the basic behavior of the fragmentation reactions and for the estimation of the internal energy of the precursor ion. The critical energies for fragmentation ( E o ) of various molecules were estimated and compared with those reported in the literature. The model was extended by taking into account the initial internal energy distribution of the ions created in the ion source. It must be emphasized that our approach provides only a crude estimate for E o . |
| collection_details |
GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 |
| container_issue |
10 |
| title_short |
An approach to estimate the activation energies of fragmentation occurring in quadrupole collision cell of the mass spectrometer |
| url |
http://dx.doi.org/10.1002/jms.3971 http://onlinelibrary.wiley.com/doi/10.1002/jms.3971/abstract https://search.proquest.com/docview/1955821971 |
| remote_bool |
false |
| author2 |
Nagy, Lajos Zsuga, Miklós Kéki, Sándor |
| author2Str |
Nagy, Lajos Zsuga, Miklós Kéki, Sándor |
| ppnlink |
182631915 |
| mediatype_str_mv |
n |
| isOA_txt |
false |
| hochschulschrift_bool |
false |
| author2_role |
oth oth oth |
| doi_str |
10.1002/jms.3971 |
| up_date |
2024-07-04T02:47:21.951Z |
| _version_ |
1803614936847351808 |
| fullrecord_marcxml |
<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a2200265 4500</leader><controlfield tag="001">OLC1997382784</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230715073522.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">171125s2017 xx ||||| 00| ||eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1002/jms.3971</subfield><subfield code="2">doi</subfield></datafield><datafield tag="028" ind1="5" ind2="2"><subfield code="a">PQ20171125</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC1997382784</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-599)GBVOLC1997382784</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(PRQ)p951-ad9256b180b83b262ae22a7e12c03672754e9b5fbd63511b8bb9d5b7161cb5c43</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(KEY)0065495720170000052001000672approachtoestimatetheactivationenergiesoffragmenta</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">570</subfield><subfield code="a">540</subfield><subfield code="a">530</subfield><subfield code="q">DE-600</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">BIODIV</subfield><subfield code="2">fid</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Kuki, Ákos</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="3"><subfield code="a">An approach to estimate the activation energies of fragmentation occurring in quadrupole collision cell of the mass spectrometer</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2017</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">The classical semi‐quantitative Rice‐Ramsperger‐Kassel (RRK) theory was used for the calculation of the internal energy dependent reaction rate coefficient of the collision‐induced dissociation (CID) reaction in tandem mass spectrometry (MS/MS). The survival yield (SY) was determined by the reaction rate equation for the unimolecular dissociation of the precursor ion. The parameters of the rate equation and the RRK model were approximated based on the instrumental conditions. We used the RRK equation for the description of the basic behavior of the fragmentation reactions and for the estimation of the internal energy of the precursor ion. The critical energies for fragmentation ( E o ) of various molecules were estimated and compared with those reported in the literature. The model was extended by taking into account the initial internal energy distribution of the ions created in the ion source. It must be emphasized that our approach provides only a crude estimate for E o .</subfield></datafield><datafield tag="540" ind1=" " ind2=" "><subfield code="a">Nutzungsrecht: Copyright © 2017 John Wiley & Sons, Ltd.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">collision cell</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">collision‐induced dissociation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">survival yield</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">tandem mass spectrometry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">RRK model</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Yield</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Mathematical models</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Energy</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Dissociation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Mass spectrometry</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Energy distribution</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Molecules</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Internal energy</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Energy of dissociation</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Mass spectroscopy</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Quadrupoles</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Fragmentation</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Nagy, Lajos</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Zsuga, Miklós</subfield><subfield code="4">oth</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Kéki, Sándor</subfield><subfield code="4">oth</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of mass spectrometry</subfield><subfield code="d">Chichester [u.a.] : Wiley, 1995</subfield><subfield code="g">52(2017), 10, Seite 672-680</subfield><subfield code="w">(DE-627)182631915</subfield><subfield code="w">(DE-600)1221763-3</subfield><subfield code="w">(DE-576)04390775X</subfield><subfield code="x">1076-5174</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:52</subfield><subfield code="g">year:2017</subfield><subfield code="g">number:10</subfield><subfield code="g">pages:672-680</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">http://dx.doi.org/10.1002/jms.3971</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">http://onlinelibrary.wiley.com/doi/10.1002/jms.3971/abstract</subfield></datafield><datafield tag="856" ind1="4" ind2="2"><subfield code="u">https://search.proquest.com/docview/1955821971</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">FID-BIODIV</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHY</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-DE-84</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">52</subfield><subfield code="j">2017</subfield><subfield code="e">10</subfield><subfield code="h">672-680</subfield></datafield></record></collection>
|
| score |
7.399952 |