Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines
Three difunctional benzoxazines were synthesized from cresol isomers ( o ‐, m ‐, and p ‐methylphenols), 1,3‐bis(3‐aminopropyl)‐1,1,3,3‐tetramethyldisiloxane, and formaldehyde. The ring‐opening polymerization temperature decreases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group f...
Ausführliche Beschreibung
Autor*in: |
Liu, Yanfang [verfasserIn] |
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Sprache: |
Englisch |
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2017 |
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Rechteinformationen: |
Nutzungsrecht: © 2017 Wiley Periodicals, Inc. |
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Übergeordnetes Werk: |
Enthalten in: Journal of applied polymer science - Hoboken, NJ [u.a.] : Wiley InterScience, 1959, 134(2017), 42 |
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Übergeordnetes Werk: |
volume:134 ; year:2017 ; number:42 |
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DOI / URN: |
10.1002/app.45443 |
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520 | |a Three difunctional benzoxazines were synthesized from cresol isomers ( o ‐, m ‐, and p ‐methylphenols), 1,3‐bis(3‐aminopropyl)‐1,1,3,3‐tetramethyldisiloxane, and formaldehyde. The ring‐opening polymerization temperature decreases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the benzoxazine monomers, whereas the glass transition temperature increases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the resultant polybenzoxazines. In addition, the polybenzoxazines exhibit one‐way dual‐shape‐memory behavior in response to changes in temperature, and the shape‐memory effects are evaluated by tensile and bending tests with a temperature program based on glass transition temperature. The o ‐ and p ‐cresol‐based polybenzoxazines exhibit higher shape‐memory performance than their m ‐cresol‐based analogue/counterpart. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45443. | ||
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650 | 4 | |a Monomers | |
650 | 4 | |a Polymerization | |
650 | 4 | |a Glass transition temperature | |
650 | 4 | |a Shape memory | |
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10.1002/app.45443 doi PQ20171228 (DE-627)OLC1997754460 (DE-599)GBVOLC1997754460 (PRQ)p1691-444dfdb1dafd7dc1fb39f3e465d8e64d1b34714a32387f617f5738967a8132153 (KEY)0117731120170000134004200000effectofmethylpositiononthedynamicmechanicalandsha DE-627 ger DE-627 rakwb eng 540 DE-600 35.80 bkl 51.70 bkl Liu, Yanfang verfasserin aut Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Three difunctional benzoxazines were synthesized from cresol isomers ( o ‐, m ‐, and p ‐methylphenols), 1,3‐bis(3‐aminopropyl)‐1,1,3,3‐tetramethyldisiloxane, and formaldehyde. The ring‐opening polymerization temperature decreases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the benzoxazine monomers, whereas the glass transition temperature increases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the resultant polybenzoxazines. In addition, the polybenzoxazines exhibit one‐way dual‐shape‐memory behavior in response to changes in temperature, and the shape‐memory effects are evaluated by tensile and bending tests with a temperature program based on glass transition temperature. The o ‐ and p ‐cresol‐based polybenzoxazines exhibit higher shape‐memory performance than their m ‐cresol‐based analogue/counterpart. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45443. Nutzungsrecht: © 2017 Wiley Periodicals, Inc. thermal properties stimuli‐sensitive polymers thermosets structure–property relationships glass transition Monomers Polymerization Glass transition temperature Shape memory Temperature Formaldehyde Bend tests Polybenzoxazines Benzoxazines Isomers Song, Shuning oth Su, Xuehui oth Wang, Aiqing oth Shen, Shanshan oth Li, Cuiyun oth Enthalten in Journal of applied polymer science Hoboken, NJ [u.a.] : Wiley InterScience, 1959 134(2017), 42 (DE-627)129595799 (DE-600)240694-9 (DE-576)015088812 0021-8995 nnns volume:134 year:2017 number:42 http://dx.doi.org/10.1002/app.45443 Volltext http://onlinelibrary.wiley.com/doi/10.1002/app.45443/abstract https://search.proquest.com/docview/1924533470 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 35.80 AVZ 51.70 AVZ AR 134 2017 42 |
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10.1002/app.45443 doi PQ20171228 (DE-627)OLC1997754460 (DE-599)GBVOLC1997754460 (PRQ)p1691-444dfdb1dafd7dc1fb39f3e465d8e64d1b34714a32387f617f5738967a8132153 (KEY)0117731120170000134004200000effectofmethylpositiononthedynamicmechanicalandsha DE-627 ger DE-627 rakwb eng 540 DE-600 35.80 bkl 51.70 bkl Liu, Yanfang verfasserin aut Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Three difunctional benzoxazines were synthesized from cresol isomers ( o ‐, m ‐, and p ‐methylphenols), 1,3‐bis(3‐aminopropyl)‐1,1,3,3‐tetramethyldisiloxane, and formaldehyde. The ring‐opening polymerization temperature decreases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the benzoxazine monomers, whereas the glass transition temperature increases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the resultant polybenzoxazines. In addition, the polybenzoxazines exhibit one‐way dual‐shape‐memory behavior in response to changes in temperature, and the shape‐memory effects are evaluated by tensile and bending tests with a temperature program based on glass transition temperature. The o ‐ and p ‐cresol‐based polybenzoxazines exhibit higher shape‐memory performance than their m ‐cresol‐based analogue/counterpart. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45443. Nutzungsrecht: © 2017 Wiley Periodicals, Inc. thermal properties stimuli‐sensitive polymers thermosets structure–property relationships glass transition Monomers Polymerization Glass transition temperature Shape memory Temperature Formaldehyde Bend tests Polybenzoxazines Benzoxazines Isomers Song, Shuning oth Su, Xuehui oth Wang, Aiqing oth Shen, Shanshan oth Li, Cuiyun oth Enthalten in Journal of applied polymer science Hoboken, NJ [u.a.] : Wiley InterScience, 1959 134(2017), 42 (DE-627)129595799 (DE-600)240694-9 (DE-576)015088812 0021-8995 nnns volume:134 year:2017 number:42 http://dx.doi.org/10.1002/app.45443 Volltext http://onlinelibrary.wiley.com/doi/10.1002/app.45443/abstract https://search.proquest.com/docview/1924533470 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 35.80 AVZ 51.70 AVZ AR 134 2017 42 |
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10.1002/app.45443 doi PQ20171228 (DE-627)OLC1997754460 (DE-599)GBVOLC1997754460 (PRQ)p1691-444dfdb1dafd7dc1fb39f3e465d8e64d1b34714a32387f617f5738967a8132153 (KEY)0117731120170000134004200000effectofmethylpositiononthedynamicmechanicalandsha DE-627 ger DE-627 rakwb eng 540 DE-600 35.80 bkl 51.70 bkl Liu, Yanfang verfasserin aut Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Three difunctional benzoxazines were synthesized from cresol isomers ( o ‐, m ‐, and p ‐methylphenols), 1,3‐bis(3‐aminopropyl)‐1,1,3,3‐tetramethyldisiloxane, and formaldehyde. The ring‐opening polymerization temperature decreases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the benzoxazine monomers, whereas the glass transition temperature increases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the resultant polybenzoxazines. In addition, the polybenzoxazines exhibit one‐way dual‐shape‐memory behavior in response to changes in temperature, and the shape‐memory effects are evaluated by tensile and bending tests with a temperature program based on glass transition temperature. The o ‐ and p ‐cresol‐based polybenzoxazines exhibit higher shape‐memory performance than their m ‐cresol‐based analogue/counterpart. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45443. Nutzungsrecht: © 2017 Wiley Periodicals, Inc. thermal properties stimuli‐sensitive polymers thermosets structure–property relationships glass transition Monomers Polymerization Glass transition temperature Shape memory Temperature Formaldehyde Bend tests Polybenzoxazines Benzoxazines Isomers Song, Shuning oth Su, Xuehui oth Wang, Aiqing oth Shen, Shanshan oth Li, Cuiyun oth Enthalten in Journal of applied polymer science Hoboken, NJ [u.a.] : Wiley InterScience, 1959 134(2017), 42 (DE-627)129595799 (DE-600)240694-9 (DE-576)015088812 0021-8995 nnns volume:134 year:2017 number:42 http://dx.doi.org/10.1002/app.45443 Volltext http://onlinelibrary.wiley.com/doi/10.1002/app.45443/abstract https://search.proquest.com/docview/1924533470 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 35.80 AVZ 51.70 AVZ AR 134 2017 42 |
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10.1002/app.45443 doi PQ20171228 (DE-627)OLC1997754460 (DE-599)GBVOLC1997754460 (PRQ)p1691-444dfdb1dafd7dc1fb39f3e465d8e64d1b34714a32387f617f5738967a8132153 (KEY)0117731120170000134004200000effectofmethylpositiononthedynamicmechanicalandsha DE-627 ger DE-627 rakwb eng 540 DE-600 35.80 bkl 51.70 bkl Liu, Yanfang verfasserin aut Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Three difunctional benzoxazines were synthesized from cresol isomers ( o ‐, m ‐, and p ‐methylphenols), 1,3‐bis(3‐aminopropyl)‐1,1,3,3‐tetramethyldisiloxane, and formaldehyde. The ring‐opening polymerization temperature decreases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the benzoxazine monomers, whereas the glass transition temperature increases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the resultant polybenzoxazines. In addition, the polybenzoxazines exhibit one‐way dual‐shape‐memory behavior in response to changes in temperature, and the shape‐memory effects are evaluated by tensile and bending tests with a temperature program based on glass transition temperature. The o ‐ and p ‐cresol‐based polybenzoxazines exhibit higher shape‐memory performance than their m ‐cresol‐based analogue/counterpart. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45443. Nutzungsrecht: © 2017 Wiley Periodicals, Inc. thermal properties stimuli‐sensitive polymers thermosets structure–property relationships glass transition Monomers Polymerization Glass transition temperature Shape memory Temperature Formaldehyde Bend tests Polybenzoxazines Benzoxazines Isomers Song, Shuning oth Su, Xuehui oth Wang, Aiqing oth Shen, Shanshan oth Li, Cuiyun oth Enthalten in Journal of applied polymer science Hoboken, NJ [u.a.] : Wiley InterScience, 1959 134(2017), 42 (DE-627)129595799 (DE-600)240694-9 (DE-576)015088812 0021-8995 nnns volume:134 year:2017 number:42 http://dx.doi.org/10.1002/app.45443 Volltext http://onlinelibrary.wiley.com/doi/10.1002/app.45443/abstract https://search.proquest.com/docview/1924533470 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 35.80 AVZ 51.70 AVZ AR 134 2017 42 |
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10.1002/app.45443 doi PQ20171228 (DE-627)OLC1997754460 (DE-599)GBVOLC1997754460 (PRQ)p1691-444dfdb1dafd7dc1fb39f3e465d8e64d1b34714a32387f617f5738967a8132153 (KEY)0117731120170000134004200000effectofmethylpositiononthedynamicmechanicalandsha DE-627 ger DE-627 rakwb eng 540 DE-600 35.80 bkl 51.70 bkl Liu, Yanfang verfasserin aut Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Three difunctional benzoxazines were synthesized from cresol isomers ( o ‐, m ‐, and p ‐methylphenols), 1,3‐bis(3‐aminopropyl)‐1,1,3,3‐tetramethyldisiloxane, and formaldehyde. The ring‐opening polymerization temperature decreases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the benzoxazine monomers, whereas the glass transition temperature increases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the resultant polybenzoxazines. In addition, the polybenzoxazines exhibit one‐way dual‐shape‐memory behavior in response to changes in temperature, and the shape‐memory effects are evaluated by tensile and bending tests with a temperature program based on glass transition temperature. The o ‐ and p ‐cresol‐based polybenzoxazines exhibit higher shape‐memory performance than their m ‐cresol‐based analogue/counterpart. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45443. Nutzungsrecht: © 2017 Wiley Periodicals, Inc. thermal properties stimuli‐sensitive polymers thermosets structure–property relationships glass transition Monomers Polymerization Glass transition temperature Shape memory Temperature Formaldehyde Bend tests Polybenzoxazines Benzoxazines Isomers Song, Shuning oth Su, Xuehui oth Wang, Aiqing oth Shen, Shanshan oth Li, Cuiyun oth Enthalten in Journal of applied polymer science Hoboken, NJ [u.a.] : Wiley InterScience, 1959 134(2017), 42 (DE-627)129595799 (DE-600)240694-9 (DE-576)015088812 0021-8995 nnns volume:134 year:2017 number:42 http://dx.doi.org/10.1002/app.45443 Volltext http://onlinelibrary.wiley.com/doi/10.1002/app.45443/abstract https://search.proquest.com/docview/1924533470 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 35.80 AVZ 51.70 AVZ AR 134 2017 42 |
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Liu, Yanfang ddc 540 bkl 35.80 bkl 51.70 misc thermal properties misc stimuli‐sensitive polymers misc thermosets misc structure–property relationships misc glass transition misc Monomers misc Polymerization misc Glass transition temperature misc Shape memory misc Temperature misc Formaldehyde misc Bend tests misc Polybenzoxazines misc Benzoxazines misc Isomers Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines |
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540 DE-600 35.80 bkl 51.70 bkl Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines thermal properties stimuli‐sensitive polymers thermosets structure–property relationships glass transition Monomers Polymerization Glass transition temperature Shape memory Temperature Formaldehyde Bend tests Polybenzoxazines Benzoxazines Isomers |
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ddc 540 bkl 35.80 bkl 51.70 misc thermal properties misc stimuli‐sensitive polymers misc thermosets misc structure–property relationships misc glass transition misc Monomers misc Polymerization misc Glass transition temperature misc Shape memory misc Temperature misc Formaldehyde misc Bend tests misc Polybenzoxazines misc Benzoxazines misc Isomers |
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ddc 540 bkl 35.80 bkl 51.70 misc thermal properties misc stimuli‐sensitive polymers misc thermosets misc structure–property relationships misc glass transition misc Monomers misc Polymerization misc Glass transition temperature misc Shape memory misc Temperature misc Formaldehyde misc Bend tests misc Polybenzoxazines misc Benzoxazines misc Isomers |
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ddc 540 bkl 35.80 bkl 51.70 misc thermal properties misc stimuli‐sensitive polymers misc thermosets misc structure–property relationships misc glass transition misc Monomers misc Polymerization misc Glass transition temperature misc Shape memory misc Temperature misc Formaldehyde misc Bend tests misc Polybenzoxazines misc Benzoxazines misc Isomers |
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Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines |
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effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines |
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Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines |
abstract |
Three difunctional benzoxazines were synthesized from cresol isomers ( o ‐, m ‐, and p ‐methylphenols), 1,3‐bis(3‐aminopropyl)‐1,1,3,3‐tetramethyldisiloxane, and formaldehyde. The ring‐opening polymerization temperature decreases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the benzoxazine monomers, whereas the glass transition temperature increases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the resultant polybenzoxazines. In addition, the polybenzoxazines exhibit one‐way dual‐shape‐memory behavior in response to changes in temperature, and the shape‐memory effects are evaluated by tensile and bending tests with a temperature program based on glass transition temperature. The o ‐ and p ‐cresol‐based polybenzoxazines exhibit higher shape‐memory performance than their m ‐cresol‐based analogue/counterpart. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45443. |
abstractGer |
Three difunctional benzoxazines were synthesized from cresol isomers ( o ‐, m ‐, and p ‐methylphenols), 1,3‐bis(3‐aminopropyl)‐1,1,3,3‐tetramethyldisiloxane, and formaldehyde. The ring‐opening polymerization temperature decreases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the benzoxazine monomers, whereas the glass transition temperature increases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the resultant polybenzoxazines. In addition, the polybenzoxazines exhibit one‐way dual‐shape‐memory behavior in response to changes in temperature, and the shape‐memory effects are evaluated by tensile and bending tests with a temperature program based on glass transition temperature. The o ‐ and p ‐cresol‐based polybenzoxazines exhibit higher shape‐memory performance than their m ‐cresol‐based analogue/counterpart. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45443. |
abstract_unstemmed |
Three difunctional benzoxazines were synthesized from cresol isomers ( o ‐, m ‐, and p ‐methylphenols), 1,3‐bis(3‐aminopropyl)‐1,1,3,3‐tetramethyldisiloxane, and formaldehyde. The ring‐opening polymerization temperature decreases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the benzoxazine monomers, whereas the glass transition temperature increases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the resultant polybenzoxazines. In addition, the polybenzoxazines exhibit one‐way dual‐shape‐memory behavior in response to changes in temperature, and the shape‐memory effects are evaluated by tensile and bending tests with a temperature program based on glass transition temperature. The o ‐ and p ‐cresol‐based polybenzoxazines exhibit higher shape‐memory performance than their m ‐cresol‐based analogue/counterpart. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45443. |
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title_short |
Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines |
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