Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines

Three difunctional benzoxazines were synthesized from cresol isomers ( o ‐, m ‐, and p ‐methylphenols), 1,3‐bis(3‐aminopropyl)‐1,1,3,3‐tetramethyldisiloxane, and formaldehyde. The ring‐opening polymerization temperature decreases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group f...
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Autor*in:	Liu, Yanfang [verfasserIn] Song, Shuning Su, Xuehui Wang, Aiqing Shen, Shanshan Li, Cuiyun

Format:	Artikel
Sprache:	Englisch

Erschienen:	2017

Rechteinformationen:	Nutzungsrecht: © 2017 Wiley Periodicals, Inc.

Schlagwörter:	thermal properties stimuli‐sensitive polymers thermosets structure–property relationships glass transition Monomers Polymerization Glass transition temperature Shape memory Temperature Formaldehyde Bend tests Polybenzoxazines Benzoxazines Isomers

Übergeordnetes Werk:	Enthalten in: Journal of applied polymer science - Hoboken, NJ [u.a.] : Wiley InterScience, 1959, 134(2017), 42
Übergeordnetes Werk:	volume:134 ; year:2017 ; number:42

Links:	Volltext Link aufrufen Link aufrufen

DOI / URN:	10.1002/app.45443

Katalog-ID:	OLC1997754460

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520			\|a Three difunctional benzoxazines were synthesized from cresol isomers ( o ‐, m ‐, and p ‐methylphenols), 1,3‐bis(3‐aminopropyl)‐1,1,3,3‐tetramethyldisiloxane, and formaldehyde. The ring‐opening polymerization temperature decreases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the benzoxazine monomers, whereas the glass transition temperature increases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the resultant polybenzoxazines. In addition, the polybenzoxazines exhibit one‐way dual‐shape‐memory behavior in response to changes in temperature, and the shape‐memory effects are evaluated by tensile and bending tests with a temperature program based on glass transition temperature. The o ‐ and p ‐cresol‐based polybenzoxazines exhibit higher shape‐memory performance than their m ‐cresol‐based analogue/counterpart. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45443.
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650		4	\|a thermal properties
650		4	\|a stimuli‐sensitive polymers
650		4	\|a thermosets
650		4	\|a structure–property relationships
650		4	\|a glass transition
650		4	\|a Monomers
650		4	\|a Polymerization
650		4	\|a Glass transition temperature
650		4	\|a Shape memory
650		4	\|a Temperature
650		4	\|a Formaldehyde
650		4	\|a Bend tests
650		4	\|a Polybenzoxazines
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650		4	\|a Isomers
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spelling	10.1002/app.45443 doi PQ20171228 (DE-627)OLC1997754460 (DE-599)GBVOLC1997754460 (PRQ)p1691-444dfdb1dafd7dc1fb39f3e465d8e64d1b34714a32387f617f5738967a8132153 (KEY)0117731120170000134004200000effectofmethylpositiononthedynamicmechanicalandsha DE-627 ger DE-627 rakwb eng 540 DE-600 35.80 bkl 51.70 bkl Liu, Yanfang verfasserin aut Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Three difunctional benzoxazines were synthesized from cresol isomers ( o ‐, m ‐, and p ‐methylphenols), 1,3‐bis(3‐aminopropyl)‐1,1,3,3‐tetramethyldisiloxane, and formaldehyde. The ring‐opening polymerization temperature decreases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the benzoxazine monomers, whereas the glass transition temperature increases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the resultant polybenzoxazines. In addition, the polybenzoxazines exhibit one‐way dual‐shape‐memory behavior in response to changes in temperature, and the shape‐memory effects are evaluated by tensile and bending tests with a temperature program based on glass transition temperature. The o ‐ and p ‐cresol‐based polybenzoxazines exhibit higher shape‐memory performance than their m ‐cresol‐based analogue/counterpart. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45443. Nutzungsrecht: © 2017 Wiley Periodicals, Inc. thermal properties stimuli‐sensitive polymers thermosets structure–property relationships glass transition Monomers Polymerization Glass transition temperature Shape memory Temperature Formaldehyde Bend tests Polybenzoxazines Benzoxazines Isomers Song, Shuning oth Su, Xuehui oth Wang, Aiqing oth Shen, Shanshan oth Li, Cuiyun oth Enthalten in Journal of applied polymer science Hoboken, NJ [u.a.] : Wiley InterScience, 1959 134(2017), 42 (DE-627)129595799 (DE-600)240694-9 (DE-576)015088812 0021-8995 nnns volume:134 year:2017 number:42 http://dx.doi.org/10.1002/app.45443 Volltext http://onlinelibrary.wiley.com/doi/10.1002/app.45443/abstract https://search.proquest.com/docview/1924533470 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 35.80 AVZ 51.70 AVZ AR 134 2017 42
allfields_unstemmed	10.1002/app.45443 doi PQ20171228 (DE-627)OLC1997754460 (DE-599)GBVOLC1997754460 (PRQ)p1691-444dfdb1dafd7dc1fb39f3e465d8e64d1b34714a32387f617f5738967a8132153 (KEY)0117731120170000134004200000effectofmethylpositiononthedynamicmechanicalandsha DE-627 ger DE-627 rakwb eng 540 DE-600 35.80 bkl 51.70 bkl Liu, Yanfang verfasserin aut Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Three difunctional benzoxazines were synthesized from cresol isomers ( o ‐, m ‐, and p ‐methylphenols), 1,3‐bis(3‐aminopropyl)‐1,1,3,3‐tetramethyldisiloxane, and formaldehyde. The ring‐opening polymerization temperature decreases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the benzoxazine monomers, whereas the glass transition temperature increases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the resultant polybenzoxazines. In addition, the polybenzoxazines exhibit one‐way dual‐shape‐memory behavior in response to changes in temperature, and the shape‐memory effects are evaluated by tensile and bending tests with a temperature program based on glass transition temperature. The o ‐ and p ‐cresol‐based polybenzoxazines exhibit higher shape‐memory performance than their m ‐cresol‐based analogue/counterpart. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45443. Nutzungsrecht: © 2017 Wiley Periodicals, Inc. thermal properties stimuli‐sensitive polymers thermosets structure–property relationships glass transition Monomers Polymerization Glass transition temperature Shape memory Temperature Formaldehyde Bend tests Polybenzoxazines Benzoxazines Isomers Song, Shuning oth Su, Xuehui oth Wang, Aiqing oth Shen, Shanshan oth Li, Cuiyun oth Enthalten in Journal of applied polymer science Hoboken, NJ [u.a.] : Wiley InterScience, 1959 134(2017), 42 (DE-627)129595799 (DE-600)240694-9 (DE-576)015088812 0021-8995 nnns volume:134 year:2017 number:42 http://dx.doi.org/10.1002/app.45443 Volltext http://onlinelibrary.wiley.com/doi/10.1002/app.45443/abstract https://search.proquest.com/docview/1924533470 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 35.80 AVZ 51.70 AVZ AR 134 2017 42
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allfieldsSound	10.1002/app.45443 doi PQ20171228 (DE-627)OLC1997754460 (DE-599)GBVOLC1997754460 (PRQ)p1691-444dfdb1dafd7dc1fb39f3e465d8e64d1b34714a32387f617f5738967a8132153 (KEY)0117731120170000134004200000effectofmethylpositiononthedynamicmechanicalandsha DE-627 ger DE-627 rakwb eng 540 DE-600 35.80 bkl 51.70 bkl Liu, Yanfang verfasserin aut Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier Three difunctional benzoxazines were synthesized from cresol isomers ( o ‐, m ‐, and p ‐methylphenols), 1,3‐bis(3‐aminopropyl)‐1,1,3,3‐tetramethyldisiloxane, and formaldehyde. The ring‐opening polymerization temperature decreases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the benzoxazine monomers, whereas the glass transition temperature increases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the resultant polybenzoxazines. In addition, the polybenzoxazines exhibit one‐way dual‐shape‐memory behavior in response to changes in temperature, and the shape‐memory effects are evaluated by tensile and bending tests with a temperature program based on glass transition temperature. The o ‐ and p ‐cresol‐based polybenzoxazines exhibit higher shape‐memory performance than their m ‐cresol‐based analogue/counterpart. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45443. Nutzungsrecht: © 2017 Wiley Periodicals, Inc. thermal properties stimuli‐sensitive polymers thermosets structure–property relationships glass transition Monomers Polymerization Glass transition temperature Shape memory Temperature Formaldehyde Bend tests Polybenzoxazines Benzoxazines Isomers Song, Shuning oth Su, Xuehui oth Wang, Aiqing oth Shen, Shanshan oth Li, Cuiyun oth Enthalten in Journal of applied polymer science Hoboken, NJ [u.a.] : Wiley InterScience, 1959 134(2017), 42 (DE-627)129595799 (DE-600)240694-9 (DE-576)015088812 0021-8995 nnns volume:134 year:2017 number:42 http://dx.doi.org/10.1002/app.45443 Volltext http://onlinelibrary.wiley.com/doi/10.1002/app.45443/abstract https://search.proquest.com/docview/1924533470 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE SSG-OLC-PHA SSG-OLC-DE-84 GBV_ILN_70 35.80 AVZ 51.70 AVZ AR 134 2017 42
language	English
source	Enthalten in Journal of applied polymer science 134(2017), 42 volume:134 year:2017 number:42
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topic_facet	thermal properties stimuli‐sensitive polymers thermosets structure–property relationships glass transition Monomers Polymerization Glass transition temperature Shape memory Temperature Formaldehyde Bend tests Polybenzoxazines Benzoxazines Isomers
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author	Liu, Yanfang
spellingShingle	Liu, Yanfang ddc 540 bkl 35.80 bkl 51.70 misc thermal properties misc stimuli‐sensitive polymers misc thermosets misc structure–property relationships misc glass transition misc Monomers misc Polymerization misc Glass transition temperature misc Shape memory misc Temperature misc Formaldehyde misc Bend tests misc Polybenzoxazines misc Benzoxazines misc Isomers Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines
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topic_title	540 DE-600 35.80 bkl 51.70 bkl Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines thermal properties stimuli‐sensitive polymers thermosets structure–property relationships glass transition Monomers Polymerization Glass transition temperature Shape memory Temperature Formaldehyde Bend tests Polybenzoxazines Benzoxazines Isomers
topic	ddc 540 bkl 35.80 bkl 51.70 misc thermal properties misc stimuli‐sensitive polymers misc thermosets misc structure–property relationships misc glass transition misc Monomers misc Polymerization misc Glass transition temperature misc Shape memory misc Temperature misc Formaldehyde misc Bend tests misc Polybenzoxazines misc Benzoxazines misc Isomers
topic_unstemmed	ddc 540 bkl 35.80 bkl 51.70 misc thermal properties misc stimuli‐sensitive polymers misc thermosets misc structure–property relationships misc glass transition misc Monomers misc Polymerization misc Glass transition temperature misc Shape memory misc Temperature misc Formaldehyde misc Bend tests misc Polybenzoxazines misc Benzoxazines misc Isomers
topic_browse	ddc 540 bkl 35.80 bkl 51.70 misc thermal properties misc stimuli‐sensitive polymers misc thermosets misc structure–property relationships misc glass transition misc Monomers misc Polymerization misc Glass transition temperature misc Shape memory misc Temperature misc Formaldehyde misc Bend tests misc Polybenzoxazines misc Benzoxazines misc Isomers
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title	Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines
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title_full	Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines
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title_sort	effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines
title_auth	Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines
abstract	Three difunctional benzoxazines were synthesized from cresol isomers ( o ‐, m ‐, and p ‐methylphenols), 1,3‐bis(3‐aminopropyl)‐1,1,3,3‐tetramethyldisiloxane, and formaldehyde. The ring‐opening polymerization temperature decreases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the benzoxazine monomers, whereas the glass transition temperature increases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the resultant polybenzoxazines. In addition, the polybenzoxazines exhibit one‐way dual‐shape‐memory behavior in response to changes in temperature, and the shape‐memory effects are evaluated by tensile and bending tests with a temperature program based on glass transition temperature. The o ‐ and p ‐cresol‐based polybenzoxazines exhibit higher shape‐memory performance than their m ‐cresol‐based analogue/counterpart. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45443.
abstractGer	Three difunctional benzoxazines were synthesized from cresol isomers ( o ‐, m ‐, and p ‐methylphenols), 1,3‐bis(3‐aminopropyl)‐1,1,3,3‐tetramethyldisiloxane, and formaldehyde. The ring‐opening polymerization temperature decreases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the benzoxazine monomers, whereas the glass transition temperature increases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the resultant polybenzoxazines. In addition, the polybenzoxazines exhibit one‐way dual‐shape‐memory behavior in response to changes in temperature, and the shape‐memory effects are evaluated by tensile and bending tests with a temperature program based on glass transition temperature. The o ‐ and p ‐cresol‐based polybenzoxazines exhibit higher shape‐memory performance than their m ‐cresol‐based analogue/counterpart. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45443.
abstract_unstemmed	Three difunctional benzoxazines were synthesized from cresol isomers ( o ‐, m ‐, and p ‐methylphenols), 1,3‐bis(3‐aminopropyl)‐1,1,3,3‐tetramethyldisiloxane, and formaldehyde. The ring‐opening polymerization temperature decreases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the benzoxazine monomers, whereas the glass transition temperature increases in the order of ortho ‐, para ‐, and meta ‐positions of methyl group for the resultant polybenzoxazines. In addition, the polybenzoxazines exhibit one‐way dual‐shape‐memory behavior in response to changes in temperature, and the shape‐memory effects are evaluated by tensile and bending tests with a temperature program based on glass transition temperature. The o ‐ and p ‐cresol‐based polybenzoxazines exhibit higher shape‐memory performance than their m ‐cresol‐based analogue/counterpart. © 2017 Wiley Periodicals, Inc. J. Appl. Polym. Sci. 2017 , 134 , 45443.
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container_issue	42
title_short	Effect of methyl position on the dynamic mechanical and shape‐memory properties of cresol‐based polybenzoxazines
url	http://dx.doi.org/10.1002/app.45443 http://onlinelibrary.wiley.com/doi/10.1002/app.45443/abstract https://search.proquest.com/docview/1924533470
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author2	Song, Shuning Su, Xuehui Wang, Aiqing Shen, Shanshan Li, Cuiyun
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up_date	2024-07-04T03:36:04.894Z
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