Uranyl peroxide nanoclusters at high-pressure
U60 ([UO2(O2)(OH)]60 60- in water) is a uranyl peroxide nanocluster with a fullerene topology and O h symmetry. U60 clusters can exist in crystalline solids or in liquids; however, little is known of their behavior at high pressures. We compressed the U60-bearing material: Li68K12(OH)20[UO2(O2)(OH)]...
Ausführliche Beschreibung
Autor*in: |
Katlyn M Turner [verfasserIn] |
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Artikel |
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Englisch |
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2017 |
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Übergeordnetes Werk: |
Enthalten in: Journal of materials research - Warrendale, Pa. : Materials Research Society, 1986, 32(2017), 19, Seite 3679 |
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Übergeordnetes Werk: |
volume:32 ; year:2017 ; number:19 ; pages:3679 |
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DOI / URN: |
10.1557/jmr.2017.301 |
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Katalog-ID: |
OLC1997912589 |
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520 | |a U60 ([UO2(O2)(OH)]60 60- in water) is a uranyl peroxide nanocluster with a fullerene topology and O h symmetry. U60 clusters can exist in crystalline solids or in liquids; however, little is known of their behavior at high pressures. We compressed the U60-bearing material: Li68K12(OH)20[UO2(O2)(OH)]60(H2O)310 ( [formula omitted: see PDF] ; a = 37.884 ᅢ ) in a diamond anvil cell to determine its response to increasing pressure. Three length scales and corresponding structural features contribute to the compression response: uranyl peroxide bonds (<0.5 nm), isolated single nanoclusters (2.5 nm), and the long-range periodicity of nanoclusters within the solid (>3.7 nm). Li68K12(OH)20[UO2(O2)(OH)]60(H2O)310 transformed to a tetragonal structure below 2 GPa and irreversibly amorphized between 9.6 and 13 GPa. The bulk modulus of the tetragonal U60-bearing material was 25 ± 2 GPa. The pressure-induced amorphous phase contained intact U60 clusters, which were preserved beyond the loss of long-range periodicity. The persistence of U60 clusters at high pressure may have been enhanced by the interaction between U60 nanoclusters and the alcohol pressure medium. Once formed, U60 nanoclusters persist regardless of their associated long-range ordering--in crystals, amorphous solids, or solutions. | ||
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10.1557/jmr.2017.301 doi PQ20171228 (DE-627)OLC1997912589 (DE-599)GBVOLC1997912589 (PRQ)p937-5a02ca17fa14988b614e2c4b9d3558201c098d4cf97ee77065ce9472a2c3e4750 (KEY)0153552820170000032001903679uranylperoxidenanoclustersathighpressure DE-627 ger DE-627 rakwb eng 670 DE-600 VA 5350 AVZ rvk 51.00 bkl Katlyn M Turner verfasserin aut Uranyl peroxide nanoclusters at high-pressure 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier U60 ([UO2(O2)(OH)]60 60- in water) is a uranyl peroxide nanocluster with a fullerene topology and O h symmetry. U60 clusters can exist in crystalline solids or in liquids; however, little is known of their behavior at high pressures. We compressed the U60-bearing material: Li68K12(OH)20[UO2(O2)(OH)]60(H2O)310 ( [formula omitted: see PDF] ; a = 37.884 ᅢ ) in a diamond anvil cell to determine its response to increasing pressure. Three length scales and corresponding structural features contribute to the compression response: uranyl peroxide bonds (<0.5 nm), isolated single nanoclusters (2.5 nm), and the long-range periodicity of nanoclusters within the solid (>3.7 nm). Li68K12(OH)20[UO2(O2)(OH)]60(H2O)310 transformed to a tetragonal structure below 2 GPa and irreversibly amorphized between 9.6 and 13 GPa. The bulk modulus of the tetragonal U60-bearing material was 25 ± 2 GPa. The pressure-induced amorphous phase contained intact U60 clusters, which were preserved beyond the loss of long-range periodicity. The persistence of U60 clusters at high pressure may have been enhanced by the interaction between U60 nanoclusters and the alcohol pressure medium. Once formed, U60 nanoclusters persist regardless of their associated long-range ordering--in crystals, amorphous solids, or solutions. Clusters Laboratories Diamonds Earth science Environmental engineering Amorphization Amorphous materials Materials research Nuclear power plants Fullerenes Uranium Nuclear fuels Bulk modulus Ethanol Jennifer E S Szymanowski oth Fuxiang Zhang oth Yu Lin oth Brendan T McGrail oth Wendy L Mao oth Peter C Burns oth Rodney C Ewing oth Enthalten in Journal of materials research Warrendale, Pa. : Materials Research Society, 1986 32(2017), 19, Seite 3679 (DE-627)129206288 (DE-600)54876-5 (DE-576)01445744X 0884-2914 nnns volume:32 year:2017 number:19 pages:3679 http://dx.doi.org/10.1557/jmr.2017.301 Volltext https://search.proquest.com/docview/1961491557 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_21 GBV_ILN_24 GBV_ILN_70 GBV_ILN_2005 GBV_ILN_2020 GBV_ILN_4126 GBV_ILN_4319 GBV_ILN_4323 VA 5350 51.00 AVZ AR 32 2017 19 3679 |
spelling |
10.1557/jmr.2017.301 doi PQ20171228 (DE-627)OLC1997912589 (DE-599)GBVOLC1997912589 (PRQ)p937-5a02ca17fa14988b614e2c4b9d3558201c098d4cf97ee77065ce9472a2c3e4750 (KEY)0153552820170000032001903679uranylperoxidenanoclustersathighpressure DE-627 ger DE-627 rakwb eng 670 DE-600 VA 5350 AVZ rvk 51.00 bkl Katlyn M Turner verfasserin aut Uranyl peroxide nanoclusters at high-pressure 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier U60 ([UO2(O2)(OH)]60 60- in water) is a uranyl peroxide nanocluster with a fullerene topology and O h symmetry. U60 clusters can exist in crystalline solids or in liquids; however, little is known of their behavior at high pressures. We compressed the U60-bearing material: Li68K12(OH)20[UO2(O2)(OH)]60(H2O)310 ( [formula omitted: see PDF] ; a = 37.884 ᅢ ) in a diamond anvil cell to determine its response to increasing pressure. Three length scales and corresponding structural features contribute to the compression response: uranyl peroxide bonds (<0.5 nm), isolated single nanoclusters (2.5 nm), and the long-range periodicity of nanoclusters within the solid (>3.7 nm). Li68K12(OH)20[UO2(O2)(OH)]60(H2O)310 transformed to a tetragonal structure below 2 GPa and irreversibly amorphized between 9.6 and 13 GPa. The bulk modulus of the tetragonal U60-bearing material was 25 ± 2 GPa. The pressure-induced amorphous phase contained intact U60 clusters, which were preserved beyond the loss of long-range periodicity. The persistence of U60 clusters at high pressure may have been enhanced by the interaction between U60 nanoclusters and the alcohol pressure medium. Once formed, U60 nanoclusters persist regardless of their associated long-range ordering--in crystals, amorphous solids, or solutions. Clusters Laboratories Diamonds Earth science Environmental engineering Amorphization Amorphous materials Materials research Nuclear power plants Fullerenes Uranium Nuclear fuels Bulk modulus Ethanol Jennifer E S Szymanowski oth Fuxiang Zhang oth Yu Lin oth Brendan T McGrail oth Wendy L Mao oth Peter C Burns oth Rodney C Ewing oth Enthalten in Journal of materials research Warrendale, Pa. : Materials Research Society, 1986 32(2017), 19, Seite 3679 (DE-627)129206288 (DE-600)54876-5 (DE-576)01445744X 0884-2914 nnns volume:32 year:2017 number:19 pages:3679 http://dx.doi.org/10.1557/jmr.2017.301 Volltext https://search.proquest.com/docview/1961491557 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_21 GBV_ILN_24 GBV_ILN_70 GBV_ILN_2005 GBV_ILN_2020 GBV_ILN_4126 GBV_ILN_4319 GBV_ILN_4323 VA 5350 51.00 AVZ AR 32 2017 19 3679 |
allfields_unstemmed |
10.1557/jmr.2017.301 doi PQ20171228 (DE-627)OLC1997912589 (DE-599)GBVOLC1997912589 (PRQ)p937-5a02ca17fa14988b614e2c4b9d3558201c098d4cf97ee77065ce9472a2c3e4750 (KEY)0153552820170000032001903679uranylperoxidenanoclustersathighpressure DE-627 ger DE-627 rakwb eng 670 DE-600 VA 5350 AVZ rvk 51.00 bkl Katlyn M Turner verfasserin aut Uranyl peroxide nanoclusters at high-pressure 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier U60 ([UO2(O2)(OH)]60 60- in water) is a uranyl peroxide nanocluster with a fullerene topology and O h symmetry. U60 clusters can exist in crystalline solids or in liquids; however, little is known of their behavior at high pressures. We compressed the U60-bearing material: Li68K12(OH)20[UO2(O2)(OH)]60(H2O)310 ( [formula omitted: see PDF] ; a = 37.884 ᅢ ) in a diamond anvil cell to determine its response to increasing pressure. Three length scales and corresponding structural features contribute to the compression response: uranyl peroxide bonds (<0.5 nm), isolated single nanoclusters (2.5 nm), and the long-range periodicity of nanoclusters within the solid (>3.7 nm). Li68K12(OH)20[UO2(O2)(OH)]60(H2O)310 transformed to a tetragonal structure below 2 GPa and irreversibly amorphized between 9.6 and 13 GPa. The bulk modulus of the tetragonal U60-bearing material was 25 ± 2 GPa. The pressure-induced amorphous phase contained intact U60 clusters, which were preserved beyond the loss of long-range periodicity. The persistence of U60 clusters at high pressure may have been enhanced by the interaction between U60 nanoclusters and the alcohol pressure medium. Once formed, U60 nanoclusters persist regardless of their associated long-range ordering--in crystals, amorphous solids, or solutions. Clusters Laboratories Diamonds Earth science Environmental engineering Amorphization Amorphous materials Materials research Nuclear power plants Fullerenes Uranium Nuclear fuels Bulk modulus Ethanol Jennifer E S Szymanowski oth Fuxiang Zhang oth Yu Lin oth Brendan T McGrail oth Wendy L Mao oth Peter C Burns oth Rodney C Ewing oth Enthalten in Journal of materials research Warrendale, Pa. : Materials Research Society, 1986 32(2017), 19, Seite 3679 (DE-627)129206288 (DE-600)54876-5 (DE-576)01445744X 0884-2914 nnns volume:32 year:2017 number:19 pages:3679 http://dx.doi.org/10.1557/jmr.2017.301 Volltext https://search.proquest.com/docview/1961491557 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_21 GBV_ILN_24 GBV_ILN_70 GBV_ILN_2005 GBV_ILN_2020 GBV_ILN_4126 GBV_ILN_4319 GBV_ILN_4323 VA 5350 51.00 AVZ AR 32 2017 19 3679 |
allfieldsGer |
10.1557/jmr.2017.301 doi PQ20171228 (DE-627)OLC1997912589 (DE-599)GBVOLC1997912589 (PRQ)p937-5a02ca17fa14988b614e2c4b9d3558201c098d4cf97ee77065ce9472a2c3e4750 (KEY)0153552820170000032001903679uranylperoxidenanoclustersathighpressure DE-627 ger DE-627 rakwb eng 670 DE-600 VA 5350 AVZ rvk 51.00 bkl Katlyn M Turner verfasserin aut Uranyl peroxide nanoclusters at high-pressure 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier U60 ([UO2(O2)(OH)]60 60- in water) is a uranyl peroxide nanocluster with a fullerene topology and O h symmetry. U60 clusters can exist in crystalline solids or in liquids; however, little is known of their behavior at high pressures. We compressed the U60-bearing material: Li68K12(OH)20[UO2(O2)(OH)]60(H2O)310 ( [formula omitted: see PDF] ; a = 37.884 ᅢ ) in a diamond anvil cell to determine its response to increasing pressure. Three length scales and corresponding structural features contribute to the compression response: uranyl peroxide bonds (<0.5 nm), isolated single nanoclusters (2.5 nm), and the long-range periodicity of nanoclusters within the solid (>3.7 nm). Li68K12(OH)20[UO2(O2)(OH)]60(H2O)310 transformed to a tetragonal structure below 2 GPa and irreversibly amorphized between 9.6 and 13 GPa. The bulk modulus of the tetragonal U60-bearing material was 25 ± 2 GPa. The pressure-induced amorphous phase contained intact U60 clusters, which were preserved beyond the loss of long-range periodicity. The persistence of U60 clusters at high pressure may have been enhanced by the interaction between U60 nanoclusters and the alcohol pressure medium. Once formed, U60 nanoclusters persist regardless of their associated long-range ordering--in crystals, amorphous solids, or solutions. Clusters Laboratories Diamonds Earth science Environmental engineering Amorphization Amorphous materials Materials research Nuclear power plants Fullerenes Uranium Nuclear fuels Bulk modulus Ethanol Jennifer E S Szymanowski oth Fuxiang Zhang oth Yu Lin oth Brendan T McGrail oth Wendy L Mao oth Peter C Burns oth Rodney C Ewing oth Enthalten in Journal of materials research Warrendale, Pa. : Materials Research Society, 1986 32(2017), 19, Seite 3679 (DE-627)129206288 (DE-600)54876-5 (DE-576)01445744X 0884-2914 nnns volume:32 year:2017 number:19 pages:3679 http://dx.doi.org/10.1557/jmr.2017.301 Volltext https://search.proquest.com/docview/1961491557 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_21 GBV_ILN_24 GBV_ILN_70 GBV_ILN_2005 GBV_ILN_2020 GBV_ILN_4126 GBV_ILN_4319 GBV_ILN_4323 VA 5350 51.00 AVZ AR 32 2017 19 3679 |
allfieldsSound |
10.1557/jmr.2017.301 doi PQ20171228 (DE-627)OLC1997912589 (DE-599)GBVOLC1997912589 (PRQ)p937-5a02ca17fa14988b614e2c4b9d3558201c098d4cf97ee77065ce9472a2c3e4750 (KEY)0153552820170000032001903679uranylperoxidenanoclustersathighpressure DE-627 ger DE-627 rakwb eng 670 DE-600 VA 5350 AVZ rvk 51.00 bkl Katlyn M Turner verfasserin aut Uranyl peroxide nanoclusters at high-pressure 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier U60 ([UO2(O2)(OH)]60 60- in water) is a uranyl peroxide nanocluster with a fullerene topology and O h symmetry. U60 clusters can exist in crystalline solids or in liquids; however, little is known of their behavior at high pressures. We compressed the U60-bearing material: Li68K12(OH)20[UO2(O2)(OH)]60(H2O)310 ( [formula omitted: see PDF] ; a = 37.884 ᅢ ) in a diamond anvil cell to determine its response to increasing pressure. Three length scales and corresponding structural features contribute to the compression response: uranyl peroxide bonds (<0.5 nm), isolated single nanoclusters (2.5 nm), and the long-range periodicity of nanoclusters within the solid (>3.7 nm). Li68K12(OH)20[UO2(O2)(OH)]60(H2O)310 transformed to a tetragonal structure below 2 GPa and irreversibly amorphized between 9.6 and 13 GPa. The bulk modulus of the tetragonal U60-bearing material was 25 ± 2 GPa. The pressure-induced amorphous phase contained intact U60 clusters, which were preserved beyond the loss of long-range periodicity. The persistence of U60 clusters at high pressure may have been enhanced by the interaction between U60 nanoclusters and the alcohol pressure medium. Once formed, U60 nanoclusters persist regardless of their associated long-range ordering--in crystals, amorphous solids, or solutions. Clusters Laboratories Diamonds Earth science Environmental engineering Amorphization Amorphous materials Materials research Nuclear power plants Fullerenes Uranium Nuclear fuels Bulk modulus Ethanol Jennifer E S Szymanowski oth Fuxiang Zhang oth Yu Lin oth Brendan T McGrail oth Wendy L Mao oth Peter C Burns oth Rodney C Ewing oth Enthalten in Journal of materials research Warrendale, Pa. : Materials Research Society, 1986 32(2017), 19, Seite 3679 (DE-627)129206288 (DE-600)54876-5 (DE-576)01445744X 0884-2914 nnns volume:32 year:2017 number:19 pages:3679 http://dx.doi.org/10.1557/jmr.2017.301 Volltext https://search.proquest.com/docview/1961491557 GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC GBV_ILN_21 GBV_ILN_24 GBV_ILN_70 GBV_ILN_2005 GBV_ILN_2020 GBV_ILN_4126 GBV_ILN_4319 GBV_ILN_4323 VA 5350 51.00 AVZ AR 32 2017 19 3679 |
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U60 clusters can exist in crystalline solids or in liquids; however, little is known of their behavior at high pressures. We compressed the U60-bearing material: Li68K12(OH)20[UO2(O2)(OH)]60(H2O)310 ( [formula omitted: see PDF] ; a = 37.884 ᅢ ) in a diamond anvil cell to determine its response to increasing pressure. Three length scales and corresponding structural features contribute to the compression response: uranyl peroxide bonds (<0.5 nm), isolated single nanoclusters (2.5 nm), and the long-range periodicity of nanoclusters within the solid (>3.7 nm). Li68K12(OH)20[UO2(O2)(OH)]60(H2O)310 transformed to a tetragonal structure below 2 GPa and irreversibly amorphized between 9.6 and 13 GPa. The bulk modulus of the tetragonal U60-bearing material was 25 ± 2 GPa. The pressure-induced amorphous phase contained intact U60 clusters, which were preserved beyond the loss of long-range periodicity. The persistence of U60 clusters at high pressure may have been enhanced by the interaction between U60 nanoclusters and the alcohol pressure medium. 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U60 ([UO2(O2)(OH)]60 60- in water) is a uranyl peroxide nanocluster with a fullerene topology and O h symmetry. U60 clusters can exist in crystalline solids or in liquids; however, little is known of their behavior at high pressures. We compressed the U60-bearing material: Li68K12(OH)20[UO2(O2)(OH)]60(H2O)310 ( [formula omitted: see PDF] ; a = 37.884 ᅢ ) in a diamond anvil cell to determine its response to increasing pressure. Three length scales and corresponding structural features contribute to the compression response: uranyl peroxide bonds (<0.5 nm), isolated single nanoclusters (2.5 nm), and the long-range periodicity of nanoclusters within the solid (>3.7 nm). Li68K12(OH)20[UO2(O2)(OH)]60(H2O)310 transformed to a tetragonal structure below 2 GPa and irreversibly amorphized between 9.6 and 13 GPa. The bulk modulus of the tetragonal U60-bearing material was 25 ± 2 GPa. The pressure-induced amorphous phase contained intact U60 clusters, which were preserved beyond the loss of long-range periodicity. The persistence of U60 clusters at high pressure may have been enhanced by the interaction between U60 nanoclusters and the alcohol pressure medium. Once formed, U60 nanoclusters persist regardless of their associated long-range ordering--in crystals, amorphous solids, or solutions. |
abstractGer |
U60 ([UO2(O2)(OH)]60 60- in water) is a uranyl peroxide nanocluster with a fullerene topology and O h symmetry. U60 clusters can exist in crystalline solids or in liquids; however, little is known of their behavior at high pressures. We compressed the U60-bearing material: Li68K12(OH)20[UO2(O2)(OH)]60(H2O)310 ( [formula omitted: see PDF] ; a = 37.884 ᅢ ) in a diamond anvil cell to determine its response to increasing pressure. Three length scales and corresponding structural features contribute to the compression response: uranyl peroxide bonds (<0.5 nm), isolated single nanoclusters (2.5 nm), and the long-range periodicity of nanoclusters within the solid (>3.7 nm). Li68K12(OH)20[UO2(O2)(OH)]60(H2O)310 transformed to a tetragonal structure below 2 GPa and irreversibly amorphized between 9.6 and 13 GPa. The bulk modulus of the tetragonal U60-bearing material was 25 ± 2 GPa. The pressure-induced amorphous phase contained intact U60 clusters, which were preserved beyond the loss of long-range periodicity. The persistence of U60 clusters at high pressure may have been enhanced by the interaction between U60 nanoclusters and the alcohol pressure medium. Once formed, U60 nanoclusters persist regardless of their associated long-range ordering--in crystals, amorphous solids, or solutions. |
abstract_unstemmed |
U60 ([UO2(O2)(OH)]60 60- in water) is a uranyl peroxide nanocluster with a fullerene topology and O h symmetry. U60 clusters can exist in crystalline solids or in liquids; however, little is known of their behavior at high pressures. We compressed the U60-bearing material: Li68K12(OH)20[UO2(O2)(OH)]60(H2O)310 ( [formula omitted: see PDF] ; a = 37.884 ᅢ ) in a diamond anvil cell to determine its response to increasing pressure. Three length scales and corresponding structural features contribute to the compression response: uranyl peroxide bonds (<0.5 nm), isolated single nanoclusters (2.5 nm), and the long-range periodicity of nanoclusters within the solid (>3.7 nm). Li68K12(OH)20[UO2(O2)(OH)]60(H2O)310 transformed to a tetragonal structure below 2 GPa and irreversibly amorphized between 9.6 and 13 GPa. The bulk modulus of the tetragonal U60-bearing material was 25 ± 2 GPa. The pressure-induced amorphous phase contained intact U60 clusters, which were preserved beyond the loss of long-range periodicity. The persistence of U60 clusters at high pressure may have been enhanced by the interaction between U60 nanoclusters and the alcohol pressure medium. Once formed, U60 nanoclusters persist regardless of their associated long-range ordering--in crystals, amorphous solids, or solutions. |
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