Raman spectroscopy and enhanced magnetic and dielectric properties of Pr and Ti codoped $ BiFeO_{3} $ ceramics
Abstract In this work, we have investigated the interplay between structure, magnetic and dielectric properties of ($ Bi_{1−x} $$ Pr_{x} $)($ Fe_{1−x} $$ Ti_{x} $)$ O_{3} $ ceramics (x = 0.03, 0.06 and 0.10) synthesised via solid state reaction method. X-ray diffraction and Raman studies exhibited t...
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Gespeichert in:
| Autor*in: |
Sati, Prakash Chandra [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2014 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media New York 2014 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of materials science / Materials in electronics - Springer US, 1990, 26(2014), 1 vom: 29. Okt., Seite 530-538 |
|---|---|
| Übergeordnetes Werk: |
volume:26 ; year:2014 ; number:1 ; day:29 ; month:10 ; pages:530-538 |
| Links: |
|---|
| DOI / URN: |
10.1007/s10854-014-2431-z |
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OLC202628184X |
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| 520 | |a Abstract In this work, we have investigated the interplay between structure, magnetic and dielectric properties of ($ Bi_{1−x} $$ Pr_{x} $)($ Fe_{1−x} $$ Ti_{x} $)$ O_{3} $ ceramics (x = 0.03, 0.06 and 0.10) synthesised via solid state reaction method. X-ray diffraction and Raman studies exhibited the structural transition from rhombohedral to orthorhombic phase for higher codoping concentration. Room and low temperatures weak ferromagnetic behaviour has been established from the splitting between field cooled and zero field cooled curves and electron spin resonance spectra. This weak ferromagnetism increases with increasing codoping concentration. X-ray photoelectron spectroscopy showed valence fluctuation between $ Fe^{3+} $/$ Fe^{2+} $ ions for lower codoping concentration while only $ Fe^{3+} $ ions are observed for higher codoping concentrations. The observed dielectric anomaly near Neel temperature becomes more prominent with increasing codoping which indicates the enhancement of magnetic and electric interactions. A correlation between shifts of Neel temperature with variation of Fe–O–Fe bond angle has been observed. | ||
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10.1007/s10854-014-2431-z doi (DE-627)OLC202628184X (DE-He213)s10854-014-2431-z-p DE-627 ger DE-627 rakwb eng 600 670 620 VZ Sati, Prakash Chandra verfasserin aut Raman spectroscopy and enhanced magnetic and dielectric properties of Pr and Ti codoped $ BiFeO_{3} $ ceramics 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2014 Abstract In this work, we have investigated the interplay between structure, magnetic and dielectric properties of ($ Bi_{1−x} $$ Pr_{x} $)($ Fe_{1−x} $$ Ti_{x} $)$ O_{3} $ ceramics (x = 0.03, 0.06 and 0.10) synthesised via solid state reaction method. X-ray diffraction and Raman studies exhibited the structural transition from rhombohedral to orthorhombic phase for higher codoping concentration. Room and low temperatures weak ferromagnetic behaviour has been established from the splitting between field cooled and zero field cooled curves and electron spin resonance spectra. This weak ferromagnetism increases with increasing codoping concentration. X-ray photoelectron spectroscopy showed valence fluctuation between $ Fe^{3+} $/$ Fe^{2+} $ ions for lower codoping concentration while only $ Fe^{3+} $ ions are observed for higher codoping concentrations. The observed dielectric anomaly near Neel temperature becomes more prominent with increasing codoping which indicates the enhancement of magnetic and electric interactions. A correlation between shifts of Neel temperature with variation of Fe–O–Fe bond angle has been observed. Electron Spin Resonance Electron Spin Resonance Spectrum BiFeO3 Field Cool Zero Field Cool Kumar, Manoj aut Chhoker, Sandeep aut Enthalten in Journal of materials science / Materials in electronics Springer US, 1990 26(2014), 1 vom: 29. Okt., Seite 530-538 (DE-627)130863289 (DE-600)1030929-9 (DE-576)023106719 0957-4522 nnns volume:26 year:2014 number:1 day:29 month:10 pages:530-538 https://doi.org/10.1007/s10854-014-2431-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_20 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 26 2014 1 29 10 530-538 |
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10.1007/s10854-014-2431-z doi (DE-627)OLC202628184X (DE-He213)s10854-014-2431-z-p DE-627 ger DE-627 rakwb eng 600 670 620 VZ Sati, Prakash Chandra verfasserin aut Raman spectroscopy and enhanced magnetic and dielectric properties of Pr and Ti codoped $ BiFeO_{3} $ ceramics 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2014 Abstract In this work, we have investigated the interplay between structure, magnetic and dielectric properties of ($ Bi_{1−x} $$ Pr_{x} $)($ Fe_{1−x} $$ Ti_{x} $)$ O_{3} $ ceramics (x = 0.03, 0.06 and 0.10) synthesised via solid state reaction method. X-ray diffraction and Raman studies exhibited the structural transition from rhombohedral to orthorhombic phase for higher codoping concentration. Room and low temperatures weak ferromagnetic behaviour has been established from the splitting between field cooled and zero field cooled curves and electron spin resonance spectra. This weak ferromagnetism increases with increasing codoping concentration. X-ray photoelectron spectroscopy showed valence fluctuation between $ Fe^{3+} $/$ Fe^{2+} $ ions for lower codoping concentration while only $ Fe^{3+} $ ions are observed for higher codoping concentrations. The observed dielectric anomaly near Neel temperature becomes more prominent with increasing codoping which indicates the enhancement of magnetic and electric interactions. A correlation between shifts of Neel temperature with variation of Fe–O–Fe bond angle has been observed. Electron Spin Resonance Electron Spin Resonance Spectrum BiFeO3 Field Cool Zero Field Cool Kumar, Manoj aut Chhoker, Sandeep aut Enthalten in Journal of materials science / Materials in electronics Springer US, 1990 26(2014), 1 vom: 29. Okt., Seite 530-538 (DE-627)130863289 (DE-600)1030929-9 (DE-576)023106719 0957-4522 nnns volume:26 year:2014 number:1 day:29 month:10 pages:530-538 https://doi.org/10.1007/s10854-014-2431-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_20 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 26 2014 1 29 10 530-538 |
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10.1007/s10854-014-2431-z doi (DE-627)OLC202628184X (DE-He213)s10854-014-2431-z-p DE-627 ger DE-627 rakwb eng 600 670 620 VZ Sati, Prakash Chandra verfasserin aut Raman spectroscopy and enhanced magnetic and dielectric properties of Pr and Ti codoped $ BiFeO_{3} $ ceramics 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2014 Abstract In this work, we have investigated the interplay between structure, magnetic and dielectric properties of ($ Bi_{1−x} $$ Pr_{x} $)($ Fe_{1−x} $$ Ti_{x} $)$ O_{3} $ ceramics (x = 0.03, 0.06 and 0.10) synthesised via solid state reaction method. X-ray diffraction and Raman studies exhibited the structural transition from rhombohedral to orthorhombic phase for higher codoping concentration. Room and low temperatures weak ferromagnetic behaviour has been established from the splitting between field cooled and zero field cooled curves and electron spin resonance spectra. This weak ferromagnetism increases with increasing codoping concentration. X-ray photoelectron spectroscopy showed valence fluctuation between $ Fe^{3+} $/$ Fe^{2+} $ ions for lower codoping concentration while only $ Fe^{3+} $ ions are observed for higher codoping concentrations. The observed dielectric anomaly near Neel temperature becomes more prominent with increasing codoping which indicates the enhancement of magnetic and electric interactions. A correlation between shifts of Neel temperature with variation of Fe–O–Fe bond angle has been observed. Electron Spin Resonance Electron Spin Resonance Spectrum BiFeO3 Field Cool Zero Field Cool Kumar, Manoj aut Chhoker, Sandeep aut Enthalten in Journal of materials science / Materials in electronics Springer US, 1990 26(2014), 1 vom: 29. Okt., Seite 530-538 (DE-627)130863289 (DE-600)1030929-9 (DE-576)023106719 0957-4522 nnns volume:26 year:2014 number:1 day:29 month:10 pages:530-538 https://doi.org/10.1007/s10854-014-2431-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_20 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 26 2014 1 29 10 530-538 |
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10.1007/s10854-014-2431-z doi (DE-627)OLC202628184X (DE-He213)s10854-014-2431-z-p DE-627 ger DE-627 rakwb eng 600 670 620 VZ Sati, Prakash Chandra verfasserin aut Raman spectroscopy and enhanced magnetic and dielectric properties of Pr and Ti codoped $ BiFeO_{3} $ ceramics 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2014 Abstract In this work, we have investigated the interplay between structure, magnetic and dielectric properties of ($ Bi_{1−x} $$ Pr_{x} $)($ Fe_{1−x} $$ Ti_{x} $)$ O_{3} $ ceramics (x = 0.03, 0.06 and 0.10) synthesised via solid state reaction method. X-ray diffraction and Raman studies exhibited the structural transition from rhombohedral to orthorhombic phase for higher codoping concentration. Room and low temperatures weak ferromagnetic behaviour has been established from the splitting between field cooled and zero field cooled curves and electron spin resonance spectra. This weak ferromagnetism increases with increasing codoping concentration. X-ray photoelectron spectroscopy showed valence fluctuation between $ Fe^{3+} $/$ Fe^{2+} $ ions for lower codoping concentration while only $ Fe^{3+} $ ions are observed for higher codoping concentrations. The observed dielectric anomaly near Neel temperature becomes more prominent with increasing codoping which indicates the enhancement of magnetic and electric interactions. A correlation between shifts of Neel temperature with variation of Fe–O–Fe bond angle has been observed. Electron Spin Resonance Electron Spin Resonance Spectrum BiFeO3 Field Cool Zero Field Cool Kumar, Manoj aut Chhoker, Sandeep aut Enthalten in Journal of materials science / Materials in electronics Springer US, 1990 26(2014), 1 vom: 29. Okt., Seite 530-538 (DE-627)130863289 (DE-600)1030929-9 (DE-576)023106719 0957-4522 nnns volume:26 year:2014 number:1 day:29 month:10 pages:530-538 https://doi.org/10.1007/s10854-014-2431-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_20 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 26 2014 1 29 10 530-538 |
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10.1007/s10854-014-2431-z doi (DE-627)OLC202628184X (DE-He213)s10854-014-2431-z-p DE-627 ger DE-627 rakwb eng 600 670 620 VZ Sati, Prakash Chandra verfasserin aut Raman spectroscopy and enhanced magnetic and dielectric properties of Pr and Ti codoped $ BiFeO_{3} $ ceramics 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2014 Abstract In this work, we have investigated the interplay between structure, magnetic and dielectric properties of ($ Bi_{1−x} $$ Pr_{x} $)($ Fe_{1−x} $$ Ti_{x} $)$ O_{3} $ ceramics (x = 0.03, 0.06 and 0.10) synthesised via solid state reaction method. X-ray diffraction and Raman studies exhibited the structural transition from rhombohedral to orthorhombic phase for higher codoping concentration. Room and low temperatures weak ferromagnetic behaviour has been established from the splitting between field cooled and zero field cooled curves and electron spin resonance spectra. This weak ferromagnetism increases with increasing codoping concentration. X-ray photoelectron spectroscopy showed valence fluctuation between $ Fe^{3+} $/$ Fe^{2+} $ ions for lower codoping concentration while only $ Fe^{3+} $ ions are observed for higher codoping concentrations. The observed dielectric anomaly near Neel temperature becomes more prominent with increasing codoping which indicates the enhancement of magnetic and electric interactions. A correlation between shifts of Neel temperature with variation of Fe–O–Fe bond angle has been observed. Electron Spin Resonance Electron Spin Resonance Spectrum BiFeO3 Field Cool Zero Field Cool Kumar, Manoj aut Chhoker, Sandeep aut Enthalten in Journal of materials science / Materials in electronics Springer US, 1990 26(2014), 1 vom: 29. Okt., Seite 530-538 (DE-627)130863289 (DE-600)1030929-9 (DE-576)023106719 0957-4522 nnns volume:26 year:2014 number:1 day:29 month:10 pages:530-538 https://doi.org/10.1007/s10854-014-2431-z lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_20 GBV_ILN_30 GBV_ILN_32 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 26 2014 1 29 10 530-538 |
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Raman spectroscopy and enhanced magnetic and dielectric properties of Pr and Ti codoped $ BiFeO_{3} $ ceramics |
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(DE-627)OLC202628184X (DE-He213)s10854-014-2431-z-p |
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Raman spectroscopy and enhanced magnetic and dielectric properties of Pr and Ti codoped $ BiFeO_{3} $ ceramics |
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Sati, Prakash Chandra |
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Journal of materials science / Materials in electronics |
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Journal of materials science / Materials in electronics |
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2014 |
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Sati, Prakash Chandra Kumar, Manoj Chhoker, Sandeep |
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26 |
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600 670 620 VZ |
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Sati, Prakash Chandra |
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10.1007/s10854-014-2431-z |
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600 670 620 |
| title_sort |
raman spectroscopy and enhanced magnetic and dielectric properties of pr and ti codoped $ bifeo_{3} $ ceramics |
| title_auth |
Raman spectroscopy and enhanced magnetic and dielectric properties of Pr and Ti codoped $ BiFeO_{3} $ ceramics |
| abstract |
Abstract In this work, we have investigated the interplay between structure, magnetic and dielectric properties of ($ Bi_{1−x} $$ Pr_{x} $)($ Fe_{1−x} $$ Ti_{x} $)$ O_{3} $ ceramics (x = 0.03, 0.06 and 0.10) synthesised via solid state reaction method. X-ray diffraction and Raman studies exhibited the structural transition from rhombohedral to orthorhombic phase for higher codoping concentration. Room and low temperatures weak ferromagnetic behaviour has been established from the splitting between field cooled and zero field cooled curves and electron spin resonance spectra. This weak ferromagnetism increases with increasing codoping concentration. X-ray photoelectron spectroscopy showed valence fluctuation between $ Fe^{3+} $/$ Fe^{2+} $ ions for lower codoping concentration while only $ Fe^{3+} $ ions are observed for higher codoping concentrations. The observed dielectric anomaly near Neel temperature becomes more prominent with increasing codoping which indicates the enhancement of magnetic and electric interactions. A correlation between shifts of Neel temperature with variation of Fe–O–Fe bond angle has been observed. © Springer Science+Business Media New York 2014 |
| abstractGer |
Abstract In this work, we have investigated the interplay between structure, magnetic and dielectric properties of ($ Bi_{1−x} $$ Pr_{x} $)($ Fe_{1−x} $$ Ti_{x} $)$ O_{3} $ ceramics (x = 0.03, 0.06 and 0.10) synthesised via solid state reaction method. X-ray diffraction and Raman studies exhibited the structural transition from rhombohedral to orthorhombic phase for higher codoping concentration. Room and low temperatures weak ferromagnetic behaviour has been established from the splitting between field cooled and zero field cooled curves and electron spin resonance spectra. This weak ferromagnetism increases with increasing codoping concentration. X-ray photoelectron spectroscopy showed valence fluctuation between $ Fe^{3+} $/$ Fe^{2+} $ ions for lower codoping concentration while only $ Fe^{3+} $ ions are observed for higher codoping concentrations. The observed dielectric anomaly near Neel temperature becomes more prominent with increasing codoping which indicates the enhancement of magnetic and electric interactions. A correlation between shifts of Neel temperature with variation of Fe–O–Fe bond angle has been observed. © Springer Science+Business Media New York 2014 |
| abstract_unstemmed |
Abstract In this work, we have investigated the interplay between structure, magnetic and dielectric properties of ($ Bi_{1−x} $$ Pr_{x} $)($ Fe_{1−x} $$ Ti_{x} $)$ O_{3} $ ceramics (x = 0.03, 0.06 and 0.10) synthesised via solid state reaction method. X-ray diffraction and Raman studies exhibited the structural transition from rhombohedral to orthorhombic phase for higher codoping concentration. Room and low temperatures weak ferromagnetic behaviour has been established from the splitting between field cooled and zero field cooled curves and electron spin resonance spectra. This weak ferromagnetism increases with increasing codoping concentration. X-ray photoelectron spectroscopy showed valence fluctuation between $ Fe^{3+} $/$ Fe^{2+} $ ions for lower codoping concentration while only $ Fe^{3+} $ ions are observed for higher codoping concentrations. The observed dielectric anomaly near Neel temperature becomes more prominent with increasing codoping which indicates the enhancement of magnetic and electric interactions. A correlation between shifts of Neel temperature with variation of Fe–O–Fe bond angle has been observed. © Springer Science+Business Media New York 2014 |
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Raman spectroscopy and enhanced magnetic and dielectric properties of Pr and Ti codoped $ BiFeO_{3} $ ceramics |
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