Photoluminescence properties and charge compensation investigations of novel orange-emitting $ Eu^{3+} $ doped $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $) phosphors
Abstract A series of polycrystalline $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $):$ Eu^{3+} $ orange emitting phosphors were synthesized by a conventional high-temperature solid-state reaction. The phase formation was confirmed by X-ray power diffraction analysis. The excitation spectra show a strong...
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Gespeichert in:
| Autor*in: |
Wang, Nenghuo [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2016 |
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| Anmerkung: |
© Springer Science+Business Media New York 2016 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of materials science / Materials in electronics - Springer US, 1990, 27(2016), 7 vom: 08. März, Seite 6681-6689 |
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| Übergeordnetes Werk: |
volume:27 ; year:2016 ; number:7 ; day:08 ; month:03 ; pages:6681-6689 |
| Links: |
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| DOI / URN: |
10.1007/s10854-016-4615-1 |
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| Katalog-ID: |
OLC2026304408 |
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| 245 | 1 | 0 | |a Photoluminescence properties and charge compensation investigations of novel orange-emitting $ Eu^{3+} $ doped $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $) phosphors |
| 264 | 1 | |c 2016 | |
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| 520 | |a Abstract A series of polycrystalline $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $):$ Eu^{3+} $ orange emitting phosphors were synthesized by a conventional high-temperature solid-state reaction. The phase formation was confirmed by X-ray power diffraction analysis. The excitation spectra show a strong host absorption indicating an efficient energy transfer process from $ O^{2−} $ to $ Eu^{3+} $ ions. Upon NUV radiation, the phosphors showed strong red emission around 610 nm (5$ D_{0} $ → 7$ F_{2} $) and orange emission around 591 nm (5$ D_{0} $ → 7$ F_{1} $), but the 5$ D_{1,2,3} $ emission nearly can not be seen. Compared with the luminescence properties of $ Li^{+} $, $ Na^{+} $, and $ K^{+} $ co-doped samples, we deduced that $ Na^{+} $ ions probably prefer to dope into the intrinsic Na vacancies rather than $ Ca^{2+} $ ions vacancies in $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $) crystal. Thermal stability properties, quantum efficiency and chromaticity coordinates of the phosphors have been investigated for the potential application in white LEDs. | ||
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| 700 | 1 | |a Chen, Junhua |4 aut | |
| 700 | 1 | |a Wang, Jianqing |4 aut | |
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| 700 | 1 | |a Yi, Shuangping |4 aut | |
| 700 | 1 | |a Zhu, Yanjuan |4 aut | |
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10.1007/s10854-016-4615-1 doi (DE-627)OLC2026304408 (DE-He213)s10854-016-4615-1-p DE-627 ger DE-627 rakwb eng 600 670 620 VZ Wang, Nenghuo verfasserin aut Photoluminescence properties and charge compensation investigations of novel orange-emitting $ Eu^{3+} $ doped $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $) phosphors 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2016 Abstract A series of polycrystalline $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $):$ Eu^{3+} $ orange emitting phosphors were synthesized by a conventional high-temperature solid-state reaction. The phase formation was confirmed by X-ray power diffraction analysis. The excitation spectra show a strong host absorption indicating an efficient energy transfer process from $ O^{2−} $ to $ Eu^{3+} $ ions. Upon NUV radiation, the phosphors showed strong red emission around 610 nm (5$ D_{0} $ → 7$ F_{2} $) and orange emission around 591 nm (5$ D_{0} $ → 7$ F_{1} $), but the 5$ D_{1,2,3} $ emission nearly can not be seen. Compared with the luminescence properties of $ Li^{+} $, $ Na^{+} $, and $ K^{+} $ co-doped samples, we deduced that $ Na^{+} $ ions probably prefer to dope into the intrinsic Na vacancies rather than $ Ca^{2+} $ ions vacancies in $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $) crystal. Thermal stability properties, quantum efficiency and chromaticity coordinates of the phosphors have been investigated for the potential application in white LEDs. Dope Sample Charge Compensation Charge Transfer Band Efficient Energy Transfer Oxygen Ligand Zhao, Weiren aut Chen, Junhua aut Wang, Jianqing aut Meng, Yingjun aut Yi, Shuangping aut Zhu, Yanjuan aut Enthalten in Journal of materials science / Materials in electronics Springer US, 1990 27(2016), 7 vom: 08. März, Seite 6681-6689 (DE-627)130863289 (DE-600)1030929-9 (DE-576)023106719 0957-4522 nnns volume:27 year:2016 number:7 day:08 month:03 pages:6681-6689 https://doi.org/10.1007/s10854-016-4615-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_30 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 27 2016 7 08 03 6681-6689 |
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10.1007/s10854-016-4615-1 doi (DE-627)OLC2026304408 (DE-He213)s10854-016-4615-1-p DE-627 ger DE-627 rakwb eng 600 670 620 VZ Wang, Nenghuo verfasserin aut Photoluminescence properties and charge compensation investigations of novel orange-emitting $ Eu^{3+} $ doped $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $) phosphors 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2016 Abstract A series of polycrystalline $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $):$ Eu^{3+} $ orange emitting phosphors were synthesized by a conventional high-temperature solid-state reaction. The phase formation was confirmed by X-ray power diffraction analysis. The excitation spectra show a strong host absorption indicating an efficient energy transfer process from $ O^{2−} $ to $ Eu^{3+} $ ions. Upon NUV radiation, the phosphors showed strong red emission around 610 nm (5$ D_{0} $ → 7$ F_{2} $) and orange emission around 591 nm (5$ D_{0} $ → 7$ F_{1} $), but the 5$ D_{1,2,3} $ emission nearly can not be seen. Compared with the luminescence properties of $ Li^{+} $, $ Na^{+} $, and $ K^{+} $ co-doped samples, we deduced that $ Na^{+} $ ions probably prefer to dope into the intrinsic Na vacancies rather than $ Ca^{2+} $ ions vacancies in $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $) crystal. Thermal stability properties, quantum efficiency and chromaticity coordinates of the phosphors have been investigated for the potential application in white LEDs. Dope Sample Charge Compensation Charge Transfer Band Efficient Energy Transfer Oxygen Ligand Zhao, Weiren aut Chen, Junhua aut Wang, Jianqing aut Meng, Yingjun aut Yi, Shuangping aut Zhu, Yanjuan aut Enthalten in Journal of materials science / Materials in electronics Springer US, 1990 27(2016), 7 vom: 08. März, Seite 6681-6689 (DE-627)130863289 (DE-600)1030929-9 (DE-576)023106719 0957-4522 nnns volume:27 year:2016 number:7 day:08 month:03 pages:6681-6689 https://doi.org/10.1007/s10854-016-4615-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_30 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 27 2016 7 08 03 6681-6689 |
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10.1007/s10854-016-4615-1 doi (DE-627)OLC2026304408 (DE-He213)s10854-016-4615-1-p DE-627 ger DE-627 rakwb eng 600 670 620 VZ Wang, Nenghuo verfasserin aut Photoluminescence properties and charge compensation investigations of novel orange-emitting $ Eu^{3+} $ doped $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $) phosphors 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2016 Abstract A series of polycrystalline $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $):$ Eu^{3+} $ orange emitting phosphors were synthesized by a conventional high-temperature solid-state reaction. The phase formation was confirmed by X-ray power diffraction analysis. The excitation spectra show a strong host absorption indicating an efficient energy transfer process from $ O^{2−} $ to $ Eu^{3+} $ ions. Upon NUV radiation, the phosphors showed strong red emission around 610 nm (5$ D_{0} $ → 7$ F_{2} $) and orange emission around 591 nm (5$ D_{0} $ → 7$ F_{1} $), but the 5$ D_{1,2,3} $ emission nearly can not be seen. Compared with the luminescence properties of $ Li^{+} $, $ Na^{+} $, and $ K^{+} $ co-doped samples, we deduced that $ Na^{+} $ ions probably prefer to dope into the intrinsic Na vacancies rather than $ Ca^{2+} $ ions vacancies in $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $) crystal. Thermal stability properties, quantum efficiency and chromaticity coordinates of the phosphors have been investigated for the potential application in white LEDs. Dope Sample Charge Compensation Charge Transfer Band Efficient Energy Transfer Oxygen Ligand Zhao, Weiren aut Chen, Junhua aut Wang, Jianqing aut Meng, Yingjun aut Yi, Shuangping aut Zhu, Yanjuan aut Enthalten in Journal of materials science / Materials in electronics Springer US, 1990 27(2016), 7 vom: 08. März, Seite 6681-6689 (DE-627)130863289 (DE-600)1030929-9 (DE-576)023106719 0957-4522 nnns volume:27 year:2016 number:7 day:08 month:03 pages:6681-6689 https://doi.org/10.1007/s10854-016-4615-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_30 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 27 2016 7 08 03 6681-6689 |
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10.1007/s10854-016-4615-1 doi (DE-627)OLC2026304408 (DE-He213)s10854-016-4615-1-p DE-627 ger DE-627 rakwb eng 600 670 620 VZ Wang, Nenghuo verfasserin aut Photoluminescence properties and charge compensation investigations of novel orange-emitting $ Eu^{3+} $ doped $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $) phosphors 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2016 Abstract A series of polycrystalline $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $):$ Eu^{3+} $ orange emitting phosphors were synthesized by a conventional high-temperature solid-state reaction. The phase formation was confirmed by X-ray power diffraction analysis. The excitation spectra show a strong host absorption indicating an efficient energy transfer process from $ O^{2−} $ to $ Eu^{3+} $ ions. Upon NUV radiation, the phosphors showed strong red emission around 610 nm (5$ D_{0} $ → 7$ F_{2} $) and orange emission around 591 nm (5$ D_{0} $ → 7$ F_{1} $), but the 5$ D_{1,2,3} $ emission nearly can not be seen. Compared with the luminescence properties of $ Li^{+} $, $ Na^{+} $, and $ K^{+} $ co-doped samples, we deduced that $ Na^{+} $ ions probably prefer to dope into the intrinsic Na vacancies rather than $ Ca^{2+} $ ions vacancies in $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $) crystal. Thermal stability properties, quantum efficiency and chromaticity coordinates of the phosphors have been investigated for the potential application in white LEDs. Dope Sample Charge Compensation Charge Transfer Band Efficient Energy Transfer Oxygen Ligand Zhao, Weiren aut Chen, Junhua aut Wang, Jianqing aut Meng, Yingjun aut Yi, Shuangping aut Zhu, Yanjuan aut Enthalten in Journal of materials science / Materials in electronics Springer US, 1990 27(2016), 7 vom: 08. März, Seite 6681-6689 (DE-627)130863289 (DE-600)1030929-9 (DE-576)023106719 0957-4522 nnns volume:27 year:2016 number:7 day:08 month:03 pages:6681-6689 https://doi.org/10.1007/s10854-016-4615-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_30 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 27 2016 7 08 03 6681-6689 |
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10.1007/s10854-016-4615-1 doi (DE-627)OLC2026304408 (DE-He213)s10854-016-4615-1-p DE-627 ger DE-627 rakwb eng 600 670 620 VZ Wang, Nenghuo verfasserin aut Photoluminescence properties and charge compensation investigations of novel orange-emitting $ Eu^{3+} $ doped $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $) phosphors 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2016 Abstract A series of polycrystalline $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $):$ Eu^{3+} $ orange emitting phosphors were synthesized by a conventional high-temperature solid-state reaction. The phase formation was confirmed by X-ray power diffraction analysis. The excitation spectra show a strong host absorption indicating an efficient energy transfer process from $ O^{2−} $ to $ Eu^{3+} $ ions. Upon NUV radiation, the phosphors showed strong red emission around 610 nm (5$ D_{0} $ → 7$ F_{2} $) and orange emission around 591 nm (5$ D_{0} $ → 7$ F_{1} $), but the 5$ D_{1,2,3} $ emission nearly can not be seen. Compared with the luminescence properties of $ Li^{+} $, $ Na^{+} $, and $ K^{+} $ co-doped samples, we deduced that $ Na^{+} $ ions probably prefer to dope into the intrinsic Na vacancies rather than $ Ca^{2+} $ ions vacancies in $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $) crystal. Thermal stability properties, quantum efficiency and chromaticity coordinates of the phosphors have been investigated for the potential application in white LEDs. Dope Sample Charge Compensation Charge Transfer Band Efficient Energy Transfer Oxygen Ligand Zhao, Weiren aut Chen, Junhua aut Wang, Jianqing aut Meng, Yingjun aut Yi, Shuangping aut Zhu, Yanjuan aut Enthalten in Journal of materials science / Materials in electronics Springer US, 1990 27(2016), 7 vom: 08. März, Seite 6681-6689 (DE-627)130863289 (DE-600)1030929-9 (DE-576)023106719 0957-4522 nnns volume:27 year:2016 number:7 day:08 month:03 pages:6681-6689 https://doi.org/10.1007/s10854-016-4615-1 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_30 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2005 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4305 GBV_ILN_4323 AR 27 2016 7 08 03 6681-6689 |
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Wang, Nenghuo @@aut@@ Zhao, Weiren @@aut@@ Chen, Junhua @@aut@@ Wang, Jianqing @@aut@@ Meng, Yingjun @@aut@@ Yi, Shuangping @@aut@@ Zhu, Yanjuan @@aut@@ |
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Photoluminescence properties and charge compensation investigations of novel orange-emitting $ Eu^{3+} $ doped $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $) phosphors |
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Photoluminescence properties and charge compensation investigations of novel orange-emitting $ Eu^{3+} $ doped $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $) phosphors |
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photoluminescence properties and charge compensation investigations of novel orange-emitting $ eu^{3+} $ doped $ na_{4} $$ ca_{4} $($ si_{6} $$ o_{18} $) phosphors |
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Photoluminescence properties and charge compensation investigations of novel orange-emitting $ Eu^{3+} $ doped $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $) phosphors |
| abstract |
Abstract A series of polycrystalline $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $):$ Eu^{3+} $ orange emitting phosphors were synthesized by a conventional high-temperature solid-state reaction. The phase formation was confirmed by X-ray power diffraction analysis. The excitation spectra show a strong host absorption indicating an efficient energy transfer process from $ O^{2−} $ to $ Eu^{3+} $ ions. Upon NUV radiation, the phosphors showed strong red emission around 610 nm (5$ D_{0} $ → 7$ F_{2} $) and orange emission around 591 nm (5$ D_{0} $ → 7$ F_{1} $), but the 5$ D_{1,2,3} $ emission nearly can not be seen. Compared with the luminescence properties of $ Li^{+} $, $ Na^{+} $, and $ K^{+} $ co-doped samples, we deduced that $ Na^{+} $ ions probably prefer to dope into the intrinsic Na vacancies rather than $ Ca^{2+} $ ions vacancies in $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $) crystal. Thermal stability properties, quantum efficiency and chromaticity coordinates of the phosphors have been investigated for the potential application in white LEDs. © Springer Science+Business Media New York 2016 |
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Abstract A series of polycrystalline $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $):$ Eu^{3+} $ orange emitting phosphors were synthesized by a conventional high-temperature solid-state reaction. The phase formation was confirmed by X-ray power diffraction analysis. The excitation spectra show a strong host absorption indicating an efficient energy transfer process from $ O^{2−} $ to $ Eu^{3+} $ ions. Upon NUV radiation, the phosphors showed strong red emission around 610 nm (5$ D_{0} $ → 7$ F_{2} $) and orange emission around 591 nm (5$ D_{0} $ → 7$ F_{1} $), but the 5$ D_{1,2,3} $ emission nearly can not be seen. Compared with the luminescence properties of $ Li^{+} $, $ Na^{+} $, and $ K^{+} $ co-doped samples, we deduced that $ Na^{+} $ ions probably prefer to dope into the intrinsic Na vacancies rather than $ Ca^{2+} $ ions vacancies in $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $) crystal. Thermal stability properties, quantum efficiency and chromaticity coordinates of the phosphors have been investigated for the potential application in white LEDs. © Springer Science+Business Media New York 2016 |
| abstract_unstemmed |
Abstract A series of polycrystalline $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $):$ Eu^{3+} $ orange emitting phosphors were synthesized by a conventional high-temperature solid-state reaction. The phase formation was confirmed by X-ray power diffraction analysis. The excitation spectra show a strong host absorption indicating an efficient energy transfer process from $ O^{2−} $ to $ Eu^{3+} $ ions. Upon NUV radiation, the phosphors showed strong red emission around 610 nm (5$ D_{0} $ → 7$ F_{2} $) and orange emission around 591 nm (5$ D_{0} $ → 7$ F_{1} $), but the 5$ D_{1,2,3} $ emission nearly can not be seen. Compared with the luminescence properties of $ Li^{+} $, $ Na^{+} $, and $ K^{+} $ co-doped samples, we deduced that $ Na^{+} $ ions probably prefer to dope into the intrinsic Na vacancies rather than $ Ca^{2+} $ ions vacancies in $ Na_{4} $$ Ca_{4} $($ Si_{6} $$ O_{18} $) crystal. Thermal stability properties, quantum efficiency and chromaticity coordinates of the phosphors have been investigated for the potential application in white LEDs. © Springer Science+Business Media New York 2016 |
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