Kinetics of the thermal degradation mechanisms in urea-formaldehyde cellulose composites filled with zinc particles
Abstract This paper reports a study on the structural characterization, thermal stability, and thermal degradation kinetics of urea-formaldehyde cellulose (UFC) composites filled with zinc particles. Structural characterization of UFC/Zn composites carried out by SEM, XRD and FTIR analyses reveals t...
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| Autor*in: |
Arshad, Muhammad Azeem [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2017 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media New York 2017 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of materials science / Materials in electronics - Springer US, 1990, 28(2017), 16 vom: 27. Apr., Seite 11832-11845 |
|---|---|
| Übergeordnetes Werk: |
volume:28 ; year:2017 ; number:16 ; day:27 ; month:04 ; pages:11832-11845 |
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| DOI / URN: |
10.1007/s10854-017-6991-6 |
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OLC202632753X |
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| 520 | |a Abstract This paper reports a study on the structural characterization, thermal stability, and thermal degradation kinetics of urea-formaldehyde cellulose (UFC) composites filled with zinc particles. Structural characterization of UFC/Zn composites carried out by SEM, XRD and FTIR analyses reveals that the composites are fairly homogenous, and the interactions between UFC and zinc in the composites are physical in nature. Afterwards, measurements of inherent thermal stabilities, probing reaction complexity, and thermal degradation kinetics of UFC/Zn composites have been carried out. The integral procedure decompositions temperature elucidates significantly higher thermal stabilities of UFC/Zn composites. Isoconversional kinetic analysis suggests multi-step reaction pathways of UFC/Zn composites in terms of the substantial variations in their activation energies with the reaction advancement. Advanced reaction model determination methodology with the help of an innovative kinetic function F(α, T) reveals that the thermal degradation of UFC goes to completion by following complicated multi-step nucleation/growth mechanisms. A detailed account of the mechanistic information regarding to the thermal degradation processes taking place in UFC/Zn composites is given and discussed in the present study. | ||
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10.1007/s10854-017-6991-6 doi (DE-627)OLC202632753X (DE-He213)s10854-017-6991-6-p DE-627 ger DE-627 rakwb eng 600 670 620 VZ Arshad, Muhammad Azeem verfasserin aut Kinetics of the thermal degradation mechanisms in urea-formaldehyde cellulose composites filled with zinc particles 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2017 Abstract This paper reports a study on the structural characterization, thermal stability, and thermal degradation kinetics of urea-formaldehyde cellulose (UFC) composites filled with zinc particles. Structural characterization of UFC/Zn composites carried out by SEM, XRD and FTIR analyses reveals that the composites are fairly homogenous, and the interactions between UFC and zinc in the composites are physical in nature. Afterwards, measurements of inherent thermal stabilities, probing reaction complexity, and thermal degradation kinetics of UFC/Zn composites have been carried out. The integral procedure decompositions temperature elucidates significantly higher thermal stabilities of UFC/Zn composites. Isoconversional kinetic analysis suggests multi-step reaction pathways of UFC/Zn composites in terms of the substantial variations in their activation energies with the reaction advancement. Advanced reaction model determination methodology with the help of an innovative kinetic function F(α, T) reveals that the thermal degradation of UFC goes to completion by following complicated multi-step nucleation/growth mechanisms. A detailed account of the mechanistic information regarding to the thermal degradation processes taking place in UFC/Zn composites is given and discussed in the present study. Thermal Degradation Thermal Degradation Behavior Thermal Degradation Process Zinc Particle Thermoanalytical Data Maaroufi, AbdelKrim aut Benavente, Rosario aut Pinto, Gabriel aut Enthalten in Journal of materials science / Materials in electronics Springer US, 1990 28(2017), 16 vom: 27. Apr., Seite 11832-11845 (DE-627)130863289 (DE-600)1030929-9 (DE-576)023106719 0957-4522 nnns volume:28 year:2017 number:16 day:27 month:04 pages:11832-11845 https://doi.org/10.1007/s10854-017-6991-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_30 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4323 AR 28 2017 16 27 04 11832-11845 |
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10.1007/s10854-017-6991-6 doi (DE-627)OLC202632753X (DE-He213)s10854-017-6991-6-p DE-627 ger DE-627 rakwb eng 600 670 620 VZ Arshad, Muhammad Azeem verfasserin aut Kinetics of the thermal degradation mechanisms in urea-formaldehyde cellulose composites filled with zinc particles 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2017 Abstract This paper reports a study on the structural characterization, thermal stability, and thermal degradation kinetics of urea-formaldehyde cellulose (UFC) composites filled with zinc particles. Structural characterization of UFC/Zn composites carried out by SEM, XRD and FTIR analyses reveals that the composites are fairly homogenous, and the interactions between UFC and zinc in the composites are physical in nature. Afterwards, measurements of inherent thermal stabilities, probing reaction complexity, and thermal degradation kinetics of UFC/Zn composites have been carried out. The integral procedure decompositions temperature elucidates significantly higher thermal stabilities of UFC/Zn composites. Isoconversional kinetic analysis suggests multi-step reaction pathways of UFC/Zn composites in terms of the substantial variations in their activation energies with the reaction advancement. Advanced reaction model determination methodology with the help of an innovative kinetic function F(α, T) reveals that the thermal degradation of UFC goes to completion by following complicated multi-step nucleation/growth mechanisms. A detailed account of the mechanistic information regarding to the thermal degradation processes taking place in UFC/Zn composites is given and discussed in the present study. Thermal Degradation Thermal Degradation Behavior Thermal Degradation Process Zinc Particle Thermoanalytical Data Maaroufi, AbdelKrim aut Benavente, Rosario aut Pinto, Gabriel aut Enthalten in Journal of materials science / Materials in electronics Springer US, 1990 28(2017), 16 vom: 27. Apr., Seite 11832-11845 (DE-627)130863289 (DE-600)1030929-9 (DE-576)023106719 0957-4522 nnns volume:28 year:2017 number:16 day:27 month:04 pages:11832-11845 https://doi.org/10.1007/s10854-017-6991-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_30 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4323 AR 28 2017 16 27 04 11832-11845 |
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10.1007/s10854-017-6991-6 doi (DE-627)OLC202632753X (DE-He213)s10854-017-6991-6-p DE-627 ger DE-627 rakwb eng 600 670 620 VZ Arshad, Muhammad Azeem verfasserin aut Kinetics of the thermal degradation mechanisms in urea-formaldehyde cellulose composites filled with zinc particles 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2017 Abstract This paper reports a study on the structural characterization, thermal stability, and thermal degradation kinetics of urea-formaldehyde cellulose (UFC) composites filled with zinc particles. Structural characterization of UFC/Zn composites carried out by SEM, XRD and FTIR analyses reveals that the composites are fairly homogenous, and the interactions between UFC and zinc in the composites are physical in nature. Afterwards, measurements of inherent thermal stabilities, probing reaction complexity, and thermal degradation kinetics of UFC/Zn composites have been carried out. The integral procedure decompositions temperature elucidates significantly higher thermal stabilities of UFC/Zn composites. Isoconversional kinetic analysis suggests multi-step reaction pathways of UFC/Zn composites in terms of the substantial variations in their activation energies with the reaction advancement. Advanced reaction model determination methodology with the help of an innovative kinetic function F(α, T) reveals that the thermal degradation of UFC goes to completion by following complicated multi-step nucleation/growth mechanisms. A detailed account of the mechanistic information regarding to the thermal degradation processes taking place in UFC/Zn composites is given and discussed in the present study. Thermal Degradation Thermal Degradation Behavior Thermal Degradation Process Zinc Particle Thermoanalytical Data Maaroufi, AbdelKrim aut Benavente, Rosario aut Pinto, Gabriel aut Enthalten in Journal of materials science / Materials in electronics Springer US, 1990 28(2017), 16 vom: 27. Apr., Seite 11832-11845 (DE-627)130863289 (DE-600)1030929-9 (DE-576)023106719 0957-4522 nnns volume:28 year:2017 number:16 day:27 month:04 pages:11832-11845 https://doi.org/10.1007/s10854-017-6991-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_30 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4323 AR 28 2017 16 27 04 11832-11845 |
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10.1007/s10854-017-6991-6 doi (DE-627)OLC202632753X (DE-He213)s10854-017-6991-6-p DE-627 ger DE-627 rakwb eng 600 670 620 VZ Arshad, Muhammad Azeem verfasserin aut Kinetics of the thermal degradation mechanisms in urea-formaldehyde cellulose composites filled with zinc particles 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2017 Abstract This paper reports a study on the structural characterization, thermal stability, and thermal degradation kinetics of urea-formaldehyde cellulose (UFC) composites filled with zinc particles. Structural characterization of UFC/Zn composites carried out by SEM, XRD and FTIR analyses reveals that the composites are fairly homogenous, and the interactions between UFC and zinc in the composites are physical in nature. Afterwards, measurements of inherent thermal stabilities, probing reaction complexity, and thermal degradation kinetics of UFC/Zn composites have been carried out. The integral procedure decompositions temperature elucidates significantly higher thermal stabilities of UFC/Zn composites. Isoconversional kinetic analysis suggests multi-step reaction pathways of UFC/Zn composites in terms of the substantial variations in their activation energies with the reaction advancement. Advanced reaction model determination methodology with the help of an innovative kinetic function F(α, T) reveals that the thermal degradation of UFC goes to completion by following complicated multi-step nucleation/growth mechanisms. A detailed account of the mechanistic information regarding to the thermal degradation processes taking place in UFC/Zn composites is given and discussed in the present study. Thermal Degradation Thermal Degradation Behavior Thermal Degradation Process Zinc Particle Thermoanalytical Data Maaroufi, AbdelKrim aut Benavente, Rosario aut Pinto, Gabriel aut Enthalten in Journal of materials science / Materials in electronics Springer US, 1990 28(2017), 16 vom: 27. Apr., Seite 11832-11845 (DE-627)130863289 (DE-600)1030929-9 (DE-576)023106719 0957-4522 nnns volume:28 year:2017 number:16 day:27 month:04 pages:11832-11845 https://doi.org/10.1007/s10854-017-6991-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_30 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4323 AR 28 2017 16 27 04 11832-11845 |
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10.1007/s10854-017-6991-6 doi (DE-627)OLC202632753X (DE-He213)s10854-017-6991-6-p DE-627 ger DE-627 rakwb eng 600 670 620 VZ Arshad, Muhammad Azeem verfasserin aut Kinetics of the thermal degradation mechanisms in urea-formaldehyde cellulose composites filled with zinc particles 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2017 Abstract This paper reports a study on the structural characterization, thermal stability, and thermal degradation kinetics of urea-formaldehyde cellulose (UFC) composites filled with zinc particles. Structural characterization of UFC/Zn composites carried out by SEM, XRD and FTIR analyses reveals that the composites are fairly homogenous, and the interactions between UFC and zinc in the composites are physical in nature. Afterwards, measurements of inherent thermal stabilities, probing reaction complexity, and thermal degradation kinetics of UFC/Zn composites have been carried out. The integral procedure decompositions temperature elucidates significantly higher thermal stabilities of UFC/Zn composites. Isoconversional kinetic analysis suggests multi-step reaction pathways of UFC/Zn composites in terms of the substantial variations in their activation energies with the reaction advancement. Advanced reaction model determination methodology with the help of an innovative kinetic function F(α, T) reveals that the thermal degradation of UFC goes to completion by following complicated multi-step nucleation/growth mechanisms. A detailed account of the mechanistic information regarding to the thermal degradation processes taking place in UFC/Zn composites is given and discussed in the present study. Thermal Degradation Thermal Degradation Behavior Thermal Degradation Process Zinc Particle Thermoanalytical Data Maaroufi, AbdelKrim aut Benavente, Rosario aut Pinto, Gabriel aut Enthalten in Journal of materials science / Materials in electronics Springer US, 1990 28(2017), 16 vom: 27. Apr., Seite 11832-11845 (DE-627)130863289 (DE-600)1030929-9 (DE-576)023106719 0957-4522 nnns volume:28 year:2017 number:16 day:27 month:04 pages:11832-11845 https://doi.org/10.1007/s10854-017-6991-6 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_30 GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2015 GBV_ILN_4046 GBV_ILN_4323 AR 28 2017 16 27 04 11832-11845 |
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Arshad, Muhammad Azeem Maaroufi, AbdelKrim Benavente, Rosario Pinto, Gabriel |
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Arshad, Muhammad Azeem |
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10.1007/s10854-017-6991-6 |
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600 670 620 |
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kinetics of the thermal degradation mechanisms in urea-formaldehyde cellulose composites filled with zinc particles |
| title_auth |
Kinetics of the thermal degradation mechanisms in urea-formaldehyde cellulose composites filled with zinc particles |
| abstract |
Abstract This paper reports a study on the structural characterization, thermal stability, and thermal degradation kinetics of urea-formaldehyde cellulose (UFC) composites filled with zinc particles. Structural characterization of UFC/Zn composites carried out by SEM, XRD and FTIR analyses reveals that the composites are fairly homogenous, and the interactions between UFC and zinc in the composites are physical in nature. Afterwards, measurements of inherent thermal stabilities, probing reaction complexity, and thermal degradation kinetics of UFC/Zn composites have been carried out. The integral procedure decompositions temperature elucidates significantly higher thermal stabilities of UFC/Zn composites. Isoconversional kinetic analysis suggests multi-step reaction pathways of UFC/Zn composites in terms of the substantial variations in their activation energies with the reaction advancement. Advanced reaction model determination methodology with the help of an innovative kinetic function F(α, T) reveals that the thermal degradation of UFC goes to completion by following complicated multi-step nucleation/growth mechanisms. A detailed account of the mechanistic information regarding to the thermal degradation processes taking place in UFC/Zn composites is given and discussed in the present study. © Springer Science+Business Media New York 2017 |
| abstractGer |
Abstract This paper reports a study on the structural characterization, thermal stability, and thermal degradation kinetics of urea-formaldehyde cellulose (UFC) composites filled with zinc particles. Structural characterization of UFC/Zn composites carried out by SEM, XRD and FTIR analyses reveals that the composites are fairly homogenous, and the interactions between UFC and zinc in the composites are physical in nature. Afterwards, measurements of inherent thermal stabilities, probing reaction complexity, and thermal degradation kinetics of UFC/Zn composites have been carried out. The integral procedure decompositions temperature elucidates significantly higher thermal stabilities of UFC/Zn composites. Isoconversional kinetic analysis suggests multi-step reaction pathways of UFC/Zn composites in terms of the substantial variations in their activation energies with the reaction advancement. Advanced reaction model determination methodology with the help of an innovative kinetic function F(α, T) reveals that the thermal degradation of UFC goes to completion by following complicated multi-step nucleation/growth mechanisms. A detailed account of the mechanistic information regarding to the thermal degradation processes taking place in UFC/Zn composites is given and discussed in the present study. © Springer Science+Business Media New York 2017 |
| abstract_unstemmed |
Abstract This paper reports a study on the structural characterization, thermal stability, and thermal degradation kinetics of urea-formaldehyde cellulose (UFC) composites filled with zinc particles. Structural characterization of UFC/Zn composites carried out by SEM, XRD and FTIR analyses reveals that the composites are fairly homogenous, and the interactions between UFC and zinc in the composites are physical in nature. Afterwards, measurements of inherent thermal stabilities, probing reaction complexity, and thermal degradation kinetics of UFC/Zn composites have been carried out. The integral procedure decompositions temperature elucidates significantly higher thermal stabilities of UFC/Zn composites. Isoconversional kinetic analysis suggests multi-step reaction pathways of UFC/Zn composites in terms of the substantial variations in their activation energies with the reaction advancement. Advanced reaction model determination methodology with the help of an innovative kinetic function F(α, T) reveals that the thermal degradation of UFC goes to completion by following complicated multi-step nucleation/growth mechanisms. A detailed account of the mechanistic information regarding to the thermal degradation processes taking place in UFC/Zn composites is given and discussed in the present study. © Springer Science+Business Media New York 2017 |
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16 |
| title_short |
Kinetics of the thermal degradation mechanisms in urea-formaldehyde cellulose composites filled with zinc particles |
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https://doi.org/10.1007/s10854-017-6991-6 |
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Maaroufi, AbdelKrim Benavente, Rosario Pinto, Gabriel |
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