Effect of Zn substitution on the structure and magnetic properties of $ Sr_{0.1} $$ La_{0.45} $$ Ca_{0.45} $$ Fe_{11.7−x} $$ Zn_{x} $$ Co_{0.3} $$ O_{19} $ hexagonal ferrites
Abstract M-type strontium ferrites $ Sr_{0.1} $$ La_{0.45} $$ Ca_{0.45} $$ Fe_{11.7−x} $$ Zn_{x} $$ Co_{0.3} $$ O_{19} $ (x = 0, 0.05, 0.1, 0.15 and 0.2) were synthesized by ceramic process. The effects of Zn substitution on phase composition, microstructure, sublattice occupation and magnetic prope...
Ausführliche Beschreibung
Autor*in: |
Du, Jiao [verfasserIn] |
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Format: |
Artikel |
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Sprache: |
Englisch |
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2019 |
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Anmerkung: |
© Springer Science+Business Media, LLC, part of Springer Nature 2019 |
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Übergeordnetes Werk: |
Enthalten in: Journal of materials science / Materials in electronics - Springer US, 1990, 30(2019), 21 vom: 18. Okt., Seite 19618-19624 |
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Übergeordnetes Werk: |
volume:30 ; year:2019 ; number:21 ; day:18 ; month:10 ; pages:19618-19624 |
Links: |
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DOI / URN: |
10.1007/s10854-019-02335-4 |
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Katalog-ID: |
OLC2026379904 |
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520 | |a Abstract M-type strontium ferrites $ Sr_{0.1} $$ La_{0.45} $$ Ca_{0.45} $$ Fe_{11.7−x} $$ Zn_{x} $$ Co_{0.3} $$ O_{19} $ (x = 0, 0.05, 0.1, 0.15 and 0.2) were synthesized by ceramic process. The effects of Zn substitution on phase composition, microstructure, sublattice occupation and magnetic properties of the ferrites were systematically investigated using X-ray diffraction, field emission scanning electron microscopy, 57Fe Mössbauer spectroscopy and magnetic properties test instrument, respectively. The results showed that all the samples were single hexagonal ferrite phase with no observation of other phases, while the lattice constant a did not vary basically and the lattice constant c increased continuously with increase of the Zn substitution amount. Simultaneously, the FESEM micrographs showed that more platelet shaped grains were observed. Mössbauer spectra have revealed that $ Zn^{2+} $ ions occupied both 4f1 and 4f2 sites, but $ Zn^{2+} $ ions would prefer to occupying 4f2 site with increasing Zn substitution. In addition, the remanence (Br) of the sintered ferrites increased firstly and then decreased, while the intrinsic coercivity (Hcj) decreased continuously. The sintered ferrites with the optimal Zn doping level of x = 0.05 exhibited high magnetic properties, including Br= 439.7 mT, Hcj= 371.8 kA/m and (BH)max= 36.88 kJ/$ m^{3} $. | ||
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10.1007/s10854-019-02335-4 doi (DE-627)OLC2026379904 (DE-He213)s10854-019-02335-4-p DE-627 ger DE-627 rakwb eng 600 670 620 VZ Du, Jiao verfasserin aut Effect of Zn substitution on the structure and magnetic properties of $ Sr_{0.1} $$ La_{0.45} $$ Ca_{0.45} $$ Fe_{11.7−x} $$ Zn_{x} $$ Co_{0.3} $$ O_{19} $ hexagonal ferrites 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract M-type strontium ferrites $ Sr_{0.1} $$ La_{0.45} $$ Ca_{0.45} $$ Fe_{11.7−x} $$ Zn_{x} $$ Co_{0.3} $$ O_{19} $ (x = 0, 0.05, 0.1, 0.15 and 0.2) were synthesized by ceramic process. The effects of Zn substitution on phase composition, microstructure, sublattice occupation and magnetic properties of the ferrites were systematically investigated using X-ray diffraction, field emission scanning electron microscopy, 57Fe Mössbauer spectroscopy and magnetic properties test instrument, respectively. The results showed that all the samples were single hexagonal ferrite phase with no observation of other phases, while the lattice constant a did not vary basically and the lattice constant c increased continuously with increase of the Zn substitution amount. Simultaneously, the FESEM micrographs showed that more platelet shaped grains were observed. Mössbauer spectra have revealed that $ Zn^{2+} $ ions occupied both 4f1 and 4f2 sites, but $ Zn^{2+} $ ions would prefer to occupying 4f2 site with increasing Zn substitution. In addition, the remanence (Br) of the sintered ferrites increased firstly and then decreased, while the intrinsic coercivity (Hcj) decreased continuously. The sintered ferrites with the optimal Zn doping level of x = 0.05 exhibited high magnetic properties, including Br= 439.7 mT, Hcj= 371.8 kA/m and (BH)max= 36.88 kJ/$ m^{3} $. Lian, Lixian aut Liu, Ying aut Du, Yibo aut Enthalten in Journal of materials science / Materials in electronics Springer US, 1990 30(2019), 21 vom: 18. Okt., Seite 19618-19624 (DE-627)130863289 (DE-600)1030929-9 (DE-576)023106719 0957-4522 nnns volume:30 year:2019 number:21 day:18 month:10 pages:19618-19624 https://doi.org/10.1007/s10854-019-02335-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2015 AR 30 2019 21 18 10 19618-19624 |
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10.1007/s10854-019-02335-4 doi (DE-627)OLC2026379904 (DE-He213)s10854-019-02335-4-p DE-627 ger DE-627 rakwb eng 600 670 620 VZ Du, Jiao verfasserin aut Effect of Zn substitution on the structure and magnetic properties of $ Sr_{0.1} $$ La_{0.45} $$ Ca_{0.45} $$ Fe_{11.7−x} $$ Zn_{x} $$ Co_{0.3} $$ O_{19} $ hexagonal ferrites 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract M-type strontium ferrites $ Sr_{0.1} $$ La_{0.45} $$ Ca_{0.45} $$ Fe_{11.7−x} $$ Zn_{x} $$ Co_{0.3} $$ O_{19} $ (x = 0, 0.05, 0.1, 0.15 and 0.2) were synthesized by ceramic process. The effects of Zn substitution on phase composition, microstructure, sublattice occupation and magnetic properties of the ferrites were systematically investigated using X-ray diffraction, field emission scanning electron microscopy, 57Fe Mössbauer spectroscopy and magnetic properties test instrument, respectively. The results showed that all the samples were single hexagonal ferrite phase with no observation of other phases, while the lattice constant a did not vary basically and the lattice constant c increased continuously with increase of the Zn substitution amount. Simultaneously, the FESEM micrographs showed that more platelet shaped grains were observed. Mössbauer spectra have revealed that $ Zn^{2+} $ ions occupied both 4f1 and 4f2 sites, but $ Zn^{2+} $ ions would prefer to occupying 4f2 site with increasing Zn substitution. In addition, the remanence (Br) of the sintered ferrites increased firstly and then decreased, while the intrinsic coercivity (Hcj) decreased continuously. The sintered ferrites with the optimal Zn doping level of x = 0.05 exhibited high magnetic properties, including Br= 439.7 mT, Hcj= 371.8 kA/m and (BH)max= 36.88 kJ/$ m^{3} $. Lian, Lixian aut Liu, Ying aut Du, Yibo aut Enthalten in Journal of materials science / Materials in electronics Springer US, 1990 30(2019), 21 vom: 18. Okt., Seite 19618-19624 (DE-627)130863289 (DE-600)1030929-9 (DE-576)023106719 0957-4522 nnns volume:30 year:2019 number:21 day:18 month:10 pages:19618-19624 https://doi.org/10.1007/s10854-019-02335-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2015 AR 30 2019 21 18 10 19618-19624 |
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10.1007/s10854-019-02335-4 doi (DE-627)OLC2026379904 (DE-He213)s10854-019-02335-4-p DE-627 ger DE-627 rakwb eng 600 670 620 VZ Du, Jiao verfasserin aut Effect of Zn substitution on the structure and magnetic properties of $ Sr_{0.1} $$ La_{0.45} $$ Ca_{0.45} $$ Fe_{11.7−x} $$ Zn_{x} $$ Co_{0.3} $$ O_{19} $ hexagonal ferrites 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract M-type strontium ferrites $ Sr_{0.1} $$ La_{0.45} $$ Ca_{0.45} $$ Fe_{11.7−x} $$ Zn_{x} $$ Co_{0.3} $$ O_{19} $ (x = 0, 0.05, 0.1, 0.15 and 0.2) were synthesized by ceramic process. The effects of Zn substitution on phase composition, microstructure, sublattice occupation and magnetic properties of the ferrites were systematically investigated using X-ray diffraction, field emission scanning electron microscopy, 57Fe Mössbauer spectroscopy and magnetic properties test instrument, respectively. The results showed that all the samples were single hexagonal ferrite phase with no observation of other phases, while the lattice constant a did not vary basically and the lattice constant c increased continuously with increase of the Zn substitution amount. Simultaneously, the FESEM micrographs showed that more platelet shaped grains were observed. Mössbauer spectra have revealed that $ Zn^{2+} $ ions occupied both 4f1 and 4f2 sites, but $ Zn^{2+} $ ions would prefer to occupying 4f2 site with increasing Zn substitution. In addition, the remanence (Br) of the sintered ferrites increased firstly and then decreased, while the intrinsic coercivity (Hcj) decreased continuously. The sintered ferrites with the optimal Zn doping level of x = 0.05 exhibited high magnetic properties, including Br= 439.7 mT, Hcj= 371.8 kA/m and (BH)max= 36.88 kJ/$ m^{3} $. Lian, Lixian aut Liu, Ying aut Du, Yibo aut Enthalten in Journal of materials science / Materials in electronics Springer US, 1990 30(2019), 21 vom: 18. Okt., Seite 19618-19624 (DE-627)130863289 (DE-600)1030929-9 (DE-576)023106719 0957-4522 nnns volume:30 year:2019 number:21 day:18 month:10 pages:19618-19624 https://doi.org/10.1007/s10854-019-02335-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2015 AR 30 2019 21 18 10 19618-19624 |
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10.1007/s10854-019-02335-4 doi (DE-627)OLC2026379904 (DE-He213)s10854-019-02335-4-p DE-627 ger DE-627 rakwb eng 600 670 620 VZ Du, Jiao verfasserin aut Effect of Zn substitution on the structure and magnetic properties of $ Sr_{0.1} $$ La_{0.45} $$ Ca_{0.45} $$ Fe_{11.7−x} $$ Zn_{x} $$ Co_{0.3} $$ O_{19} $ hexagonal ferrites 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract M-type strontium ferrites $ Sr_{0.1} $$ La_{0.45} $$ Ca_{0.45} $$ Fe_{11.7−x} $$ Zn_{x} $$ Co_{0.3} $$ O_{19} $ (x = 0, 0.05, 0.1, 0.15 and 0.2) were synthesized by ceramic process. The effects of Zn substitution on phase composition, microstructure, sublattice occupation and magnetic properties of the ferrites were systematically investigated using X-ray diffraction, field emission scanning electron microscopy, 57Fe Mössbauer spectroscopy and magnetic properties test instrument, respectively. The results showed that all the samples were single hexagonal ferrite phase with no observation of other phases, while the lattice constant a did not vary basically and the lattice constant c increased continuously with increase of the Zn substitution amount. Simultaneously, the FESEM micrographs showed that more platelet shaped grains were observed. Mössbauer spectra have revealed that $ Zn^{2+} $ ions occupied both 4f1 and 4f2 sites, but $ Zn^{2+} $ ions would prefer to occupying 4f2 site with increasing Zn substitution. In addition, the remanence (Br) of the sintered ferrites increased firstly and then decreased, while the intrinsic coercivity (Hcj) decreased continuously. The sintered ferrites with the optimal Zn doping level of x = 0.05 exhibited high magnetic properties, including Br= 439.7 mT, Hcj= 371.8 kA/m and (BH)max= 36.88 kJ/$ m^{3} $. Lian, Lixian aut Liu, Ying aut Du, Yibo aut Enthalten in Journal of materials science / Materials in electronics Springer US, 1990 30(2019), 21 vom: 18. Okt., Seite 19618-19624 (DE-627)130863289 (DE-600)1030929-9 (DE-576)023106719 0957-4522 nnns volume:30 year:2019 number:21 day:18 month:10 pages:19618-19624 https://doi.org/10.1007/s10854-019-02335-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2015 AR 30 2019 21 18 10 19618-19624 |
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10.1007/s10854-019-02335-4 doi (DE-627)OLC2026379904 (DE-He213)s10854-019-02335-4-p DE-627 ger DE-627 rakwb eng 600 670 620 VZ Du, Jiao verfasserin aut Effect of Zn substitution on the structure and magnetic properties of $ Sr_{0.1} $$ La_{0.45} $$ Ca_{0.45} $$ Fe_{11.7−x} $$ Zn_{x} $$ Co_{0.3} $$ O_{19} $ hexagonal ferrites 2019 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC, part of Springer Nature 2019 Abstract M-type strontium ferrites $ Sr_{0.1} $$ La_{0.45} $$ Ca_{0.45} $$ Fe_{11.7−x} $$ Zn_{x} $$ Co_{0.3} $$ O_{19} $ (x = 0, 0.05, 0.1, 0.15 and 0.2) were synthesized by ceramic process. The effects of Zn substitution on phase composition, microstructure, sublattice occupation and magnetic properties of the ferrites were systematically investigated using X-ray diffraction, field emission scanning electron microscopy, 57Fe Mössbauer spectroscopy and magnetic properties test instrument, respectively. The results showed that all the samples were single hexagonal ferrite phase with no observation of other phases, while the lattice constant a did not vary basically and the lattice constant c increased continuously with increase of the Zn substitution amount. Simultaneously, the FESEM micrographs showed that more platelet shaped grains were observed. Mössbauer spectra have revealed that $ Zn^{2+} $ ions occupied both 4f1 and 4f2 sites, but $ Zn^{2+} $ ions would prefer to occupying 4f2 site with increasing Zn substitution. In addition, the remanence (Br) of the sintered ferrites increased firstly and then decreased, while the intrinsic coercivity (Hcj) decreased continuously. The sintered ferrites with the optimal Zn doping level of x = 0.05 exhibited high magnetic properties, including Br= 439.7 mT, Hcj= 371.8 kA/m and (BH)max= 36.88 kJ/$ m^{3} $. Lian, Lixian aut Liu, Ying aut Du, Yibo aut Enthalten in Journal of materials science / Materials in electronics Springer US, 1990 30(2019), 21 vom: 18. Okt., Seite 19618-19624 (DE-627)130863289 (DE-600)1030929-9 (DE-576)023106719 0957-4522 nnns volume:30 year:2019 number:21 day:18 month:10 pages:19618-19624 https://doi.org/10.1007/s10854-019-02335-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-PHY GBV_ILN_70 GBV_ILN_2004 GBV_ILN_2015 AR 30 2019 21 18 10 19618-19624 |
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Effect of Zn substitution on the structure and magnetic properties of $ Sr_{0.1} $$ La_{0.45} $$ Ca_{0.45} $$ Fe_{11.7−x} $$ Zn_{x} $$ Co_{0.3} $$ O_{19} $ hexagonal ferrites |
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title_full |
Effect of Zn substitution on the structure and magnetic properties of $ Sr_{0.1} $$ La_{0.45} $$ Ca_{0.45} $$ Fe_{11.7−x} $$ Zn_{x} $$ Co_{0.3} $$ O_{19} $ hexagonal ferrites |
author_sort |
Du, Jiao |
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Journal of materials science / Materials in electronics |
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Journal of materials science / Materials in electronics |
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eng |
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600 - Technology |
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2019 |
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19618 |
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Du, Jiao Lian, Lixian Liu, Ying Du, Yibo |
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600 670 620 VZ |
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Aufsätze |
author-letter |
Du, Jiao |
doi_str_mv |
10.1007/s10854-019-02335-4 |
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600 670 620 |
title_sort |
effect of zn substitution on the structure and magnetic properties of $ sr_{0.1} $$ la_{0.45} $$ ca_{0.45} $$ fe_{11.7−x} $$ zn_{x} $$ co_{0.3} $$ o_{19} $ hexagonal ferrites |
title_auth |
Effect of Zn substitution on the structure and magnetic properties of $ Sr_{0.1} $$ La_{0.45} $$ Ca_{0.45} $$ Fe_{11.7−x} $$ Zn_{x} $$ Co_{0.3} $$ O_{19} $ hexagonal ferrites |
abstract |
Abstract M-type strontium ferrites $ Sr_{0.1} $$ La_{0.45} $$ Ca_{0.45} $$ Fe_{11.7−x} $$ Zn_{x} $$ Co_{0.3} $$ O_{19} $ (x = 0, 0.05, 0.1, 0.15 and 0.2) were synthesized by ceramic process. The effects of Zn substitution on phase composition, microstructure, sublattice occupation and magnetic properties of the ferrites were systematically investigated using X-ray diffraction, field emission scanning electron microscopy, 57Fe Mössbauer spectroscopy and magnetic properties test instrument, respectively. The results showed that all the samples were single hexagonal ferrite phase with no observation of other phases, while the lattice constant a did not vary basically and the lattice constant c increased continuously with increase of the Zn substitution amount. Simultaneously, the FESEM micrographs showed that more platelet shaped grains were observed. Mössbauer spectra have revealed that $ Zn^{2+} $ ions occupied both 4f1 and 4f2 sites, but $ Zn^{2+} $ ions would prefer to occupying 4f2 site with increasing Zn substitution. In addition, the remanence (Br) of the sintered ferrites increased firstly and then decreased, while the intrinsic coercivity (Hcj) decreased continuously. The sintered ferrites with the optimal Zn doping level of x = 0.05 exhibited high magnetic properties, including Br= 439.7 mT, Hcj= 371.8 kA/m and (BH)max= 36.88 kJ/$ m^{3} $. © Springer Science+Business Media, LLC, part of Springer Nature 2019 |
abstractGer |
Abstract M-type strontium ferrites $ Sr_{0.1} $$ La_{0.45} $$ Ca_{0.45} $$ Fe_{11.7−x} $$ Zn_{x} $$ Co_{0.3} $$ O_{19} $ (x = 0, 0.05, 0.1, 0.15 and 0.2) were synthesized by ceramic process. The effects of Zn substitution on phase composition, microstructure, sublattice occupation and magnetic properties of the ferrites were systematically investigated using X-ray diffraction, field emission scanning electron microscopy, 57Fe Mössbauer spectroscopy and magnetic properties test instrument, respectively. The results showed that all the samples were single hexagonal ferrite phase with no observation of other phases, while the lattice constant a did not vary basically and the lattice constant c increased continuously with increase of the Zn substitution amount. Simultaneously, the FESEM micrographs showed that more platelet shaped grains were observed. Mössbauer spectra have revealed that $ Zn^{2+} $ ions occupied both 4f1 and 4f2 sites, but $ Zn^{2+} $ ions would prefer to occupying 4f2 site with increasing Zn substitution. In addition, the remanence (Br) of the sintered ferrites increased firstly and then decreased, while the intrinsic coercivity (Hcj) decreased continuously. The sintered ferrites with the optimal Zn doping level of x = 0.05 exhibited high magnetic properties, including Br= 439.7 mT, Hcj= 371.8 kA/m and (BH)max= 36.88 kJ/$ m^{3} $. © Springer Science+Business Media, LLC, part of Springer Nature 2019 |
abstract_unstemmed |
Abstract M-type strontium ferrites $ Sr_{0.1} $$ La_{0.45} $$ Ca_{0.45} $$ Fe_{11.7−x} $$ Zn_{x} $$ Co_{0.3} $$ O_{19} $ (x = 0, 0.05, 0.1, 0.15 and 0.2) were synthesized by ceramic process. The effects of Zn substitution on phase composition, microstructure, sublattice occupation and magnetic properties of the ferrites were systematically investigated using X-ray diffraction, field emission scanning electron microscopy, 57Fe Mössbauer spectroscopy and magnetic properties test instrument, respectively. The results showed that all the samples were single hexagonal ferrite phase with no observation of other phases, while the lattice constant a did not vary basically and the lattice constant c increased continuously with increase of the Zn substitution amount. Simultaneously, the FESEM micrographs showed that more platelet shaped grains were observed. Mössbauer spectra have revealed that $ Zn^{2+} $ ions occupied both 4f1 and 4f2 sites, but $ Zn^{2+} $ ions would prefer to occupying 4f2 site with increasing Zn substitution. In addition, the remanence (Br) of the sintered ferrites increased firstly and then decreased, while the intrinsic coercivity (Hcj) decreased continuously. The sintered ferrites with the optimal Zn doping level of x = 0.05 exhibited high magnetic properties, including Br= 439.7 mT, Hcj= 371.8 kA/m and (BH)max= 36.88 kJ/$ m^{3} $. © Springer Science+Business Media, LLC, part of Springer Nature 2019 |
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21 |
title_short |
Effect of Zn substitution on the structure and magnetic properties of $ Sr_{0.1} $$ La_{0.45} $$ Ca_{0.45} $$ Fe_{11.7−x} $$ Zn_{x} $$ Co_{0.3} $$ O_{19} $ hexagonal ferrites |
url |
https://doi.org/10.1007/s10854-019-02335-4 |
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Lian, Lixian Liu, Ying Du, Yibo |
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Lian, Lixian Liu, Ying Du, Yibo |
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