Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes
Abstract Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (1), [Co(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (2) and [Co(bpmb)(CN)2]6[Mn(5-Clsalpn)]6·$ 24H_{2} $O·$ 8CH_{3} $CN (3) [$ bpmb^{2−} $= 1,2-bis(pyridine-2-carboxamido)-4-met...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Ni, ZhongHai [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2009 |
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| Schlagwörter: |
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| Anmerkung: |
© Science in China Press and Springer Berlin Heidelberg 2009 |
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| Übergeordnetes Werk: |
Enthalten in: Science in China / B - SP Science in China Press, 1989, 52(2009), 9 vom: Sept., Seite 1444-1450 |
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| Übergeordnetes Werk: |
volume:52 ; year:2009 ; number:9 ; month:09 ; pages:1444-1450 |
| Links: |
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| DOI / URN: |
10.1007/s11426-009-0162-4 |
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OLC2035793297 |
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| 520 | |a Abstract Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (1), [Co(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (2) and [Co(bpmb)(CN)2]6[Mn(5-Clsalpn)]6·$ 24H_{2} $O·$ 8CH_{3} $CN (3) [$ bpmb^{2−} $= 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate dianion; 5-$ Brsalpn^{2−} $ = N,N′-propylenebis(5-bromosalicylideneaminato) dianion; 5-$ Clsalpn^{2−} $ = N,N′-propylenebis(5-chlorosalicylideneaminato) dianion] have been synthesized and their crystal structures and magnetic properties have been investigated. The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)2]− anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. A best-fit to the magnetic susceptibility of the complex leads to a magnetic coupling constant of JCrMn = −2.65(6) $ cm^{−1} $ on the basis of a one-dimensional alternating chain model with the Hamiltonian $$. | ||
| 650 | 4 | |a polynuclear complex | |
| 650 | 4 | |a crystal structure | |
| 650 | 4 | |a magnetic property | |
| 650 | 4 | |a cyanide | |
| 650 | 4 | |a chromium | |
| 650 | 4 | |a manganese | |
| 700 | 1 | |a Zhang, LiFang |4 aut | |
| 700 | 1 | |a Cui, AiLi |4 aut | |
| 700 | 1 | |a Kou, HuiZhong |4 aut | |
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10.1007/s11426-009-0162-4 doi (DE-627)OLC2035793297 (DE-He213)s11426-009-0162-4-p DE-627 ger DE-627 rakwb eng 540 570 550 VZ 540 550 570 VZ 11 12 ssgn BIODIV DE-30 fid Ni, ZhongHai verfasserin aut Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Science in China Press and Springer Berlin Heidelberg 2009 Abstract Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (1), [Co(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (2) and [Co(bpmb)(CN)2]6[Mn(5-Clsalpn)]6·$ 24H_{2} $O·$ 8CH_{3} $CN (3) [$ bpmb^{2−} $= 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate dianion; 5-$ Brsalpn^{2−} $ = N,N′-propylenebis(5-bromosalicylideneaminato) dianion; 5-$ Clsalpn^{2−} $ = N,N′-propylenebis(5-chlorosalicylideneaminato) dianion] have been synthesized and their crystal structures and magnetic properties have been investigated. The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)2]− anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. A best-fit to the magnetic susceptibility of the complex leads to a magnetic coupling constant of JCrMn = −2.65(6) $ cm^{−1} $ on the basis of a one-dimensional alternating chain model with the Hamiltonian $$. polynuclear complex crystal structure magnetic property cyanide chromium manganese Zhang, LiFang aut Cui, AiLi aut Kou, HuiZhong aut Enthalten in Science in China / B SP Science in China Press, 1989 52(2009), 9 vom: Sept., Seite 1444-1450 (DE-627)130464953 (DE-600)740629-0 (DE-576)022978976 1006-9291 nnns volume:52 year:2009 number:9 month:09 pages:1444-1450 https://doi.org/10.1007/s11426-009-0162-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-OAS SSG-OLC-MFO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 AR 52 2009 9 09 1444-1450 |
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10.1007/s11426-009-0162-4 doi (DE-627)OLC2035793297 (DE-He213)s11426-009-0162-4-p DE-627 ger DE-627 rakwb eng 540 570 550 VZ 540 550 570 VZ 11 12 ssgn BIODIV DE-30 fid Ni, ZhongHai verfasserin aut Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Science in China Press and Springer Berlin Heidelberg 2009 Abstract Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (1), [Co(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (2) and [Co(bpmb)(CN)2]6[Mn(5-Clsalpn)]6·$ 24H_{2} $O·$ 8CH_{3} $CN (3) [$ bpmb^{2−} $= 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate dianion; 5-$ Brsalpn^{2−} $ = N,N′-propylenebis(5-bromosalicylideneaminato) dianion; 5-$ Clsalpn^{2−} $ = N,N′-propylenebis(5-chlorosalicylideneaminato) dianion] have been synthesized and their crystal structures and magnetic properties have been investigated. The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)2]− anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. A best-fit to the magnetic susceptibility of the complex leads to a magnetic coupling constant of JCrMn = −2.65(6) $ cm^{−1} $ on the basis of a one-dimensional alternating chain model with the Hamiltonian $$. polynuclear complex crystal structure magnetic property cyanide chromium manganese Zhang, LiFang aut Cui, AiLi aut Kou, HuiZhong aut Enthalten in Science in China / B SP Science in China Press, 1989 52(2009), 9 vom: Sept., Seite 1444-1450 (DE-627)130464953 (DE-600)740629-0 (DE-576)022978976 1006-9291 nnns volume:52 year:2009 number:9 month:09 pages:1444-1450 https://doi.org/10.1007/s11426-009-0162-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-OAS SSG-OLC-MFO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 AR 52 2009 9 09 1444-1450 |
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10.1007/s11426-009-0162-4 doi (DE-627)OLC2035793297 (DE-He213)s11426-009-0162-4-p DE-627 ger DE-627 rakwb eng 540 570 550 VZ 540 550 570 VZ 11 12 ssgn BIODIV DE-30 fid Ni, ZhongHai verfasserin aut Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Science in China Press and Springer Berlin Heidelberg 2009 Abstract Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (1), [Co(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (2) and [Co(bpmb)(CN)2]6[Mn(5-Clsalpn)]6·$ 24H_{2} $O·$ 8CH_{3} $CN (3) [$ bpmb^{2−} $= 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate dianion; 5-$ Brsalpn^{2−} $ = N,N′-propylenebis(5-bromosalicylideneaminato) dianion; 5-$ Clsalpn^{2−} $ = N,N′-propylenebis(5-chlorosalicylideneaminato) dianion] have been synthesized and their crystal structures and magnetic properties have been investigated. The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)2]− anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. A best-fit to the magnetic susceptibility of the complex leads to a magnetic coupling constant of JCrMn = −2.65(6) $ cm^{−1} $ on the basis of a one-dimensional alternating chain model with the Hamiltonian $$. polynuclear complex crystal structure magnetic property cyanide chromium manganese Zhang, LiFang aut Cui, AiLi aut Kou, HuiZhong aut Enthalten in Science in China / B SP Science in China Press, 1989 52(2009), 9 vom: Sept., Seite 1444-1450 (DE-627)130464953 (DE-600)740629-0 (DE-576)022978976 1006-9291 nnns volume:52 year:2009 number:9 month:09 pages:1444-1450 https://doi.org/10.1007/s11426-009-0162-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-OAS SSG-OLC-MFO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 AR 52 2009 9 09 1444-1450 |
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10.1007/s11426-009-0162-4 doi (DE-627)OLC2035793297 (DE-He213)s11426-009-0162-4-p DE-627 ger DE-627 rakwb eng 540 570 550 VZ 540 550 570 VZ 11 12 ssgn BIODIV DE-30 fid Ni, ZhongHai verfasserin aut Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Science in China Press and Springer Berlin Heidelberg 2009 Abstract Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (1), [Co(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (2) and [Co(bpmb)(CN)2]6[Mn(5-Clsalpn)]6·$ 24H_{2} $O·$ 8CH_{3} $CN (3) [$ bpmb^{2−} $= 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate dianion; 5-$ Brsalpn^{2−} $ = N,N′-propylenebis(5-bromosalicylideneaminato) dianion; 5-$ Clsalpn^{2−} $ = N,N′-propylenebis(5-chlorosalicylideneaminato) dianion] have been synthesized and their crystal structures and magnetic properties have been investigated. The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)2]− anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. A best-fit to the magnetic susceptibility of the complex leads to a magnetic coupling constant of JCrMn = −2.65(6) $ cm^{−1} $ on the basis of a one-dimensional alternating chain model with the Hamiltonian $$. polynuclear complex crystal structure magnetic property cyanide chromium manganese Zhang, LiFang aut Cui, AiLi aut Kou, HuiZhong aut Enthalten in Science in China / B SP Science in China Press, 1989 52(2009), 9 vom: Sept., Seite 1444-1450 (DE-627)130464953 (DE-600)740629-0 (DE-576)022978976 1006-9291 nnns volume:52 year:2009 number:9 month:09 pages:1444-1450 https://doi.org/10.1007/s11426-009-0162-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-OAS SSG-OLC-MFO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 AR 52 2009 9 09 1444-1450 |
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10.1007/s11426-009-0162-4 doi (DE-627)OLC2035793297 (DE-He213)s11426-009-0162-4-p DE-627 ger DE-627 rakwb eng 540 570 550 VZ 540 550 570 VZ 11 12 ssgn BIODIV DE-30 fid Ni, ZhongHai verfasserin aut Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Science in China Press and Springer Berlin Heidelberg 2009 Abstract Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (1), [Co(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (2) and [Co(bpmb)(CN)2]6[Mn(5-Clsalpn)]6·$ 24H_{2} $O·$ 8CH_{3} $CN (3) [$ bpmb^{2−} $= 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate dianion; 5-$ Brsalpn^{2−} $ = N,N′-propylenebis(5-bromosalicylideneaminato) dianion; 5-$ Clsalpn^{2−} $ = N,N′-propylenebis(5-chlorosalicylideneaminato) dianion] have been synthesized and their crystal structures and magnetic properties have been investigated. The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)2]− anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. A best-fit to the magnetic susceptibility of the complex leads to a magnetic coupling constant of JCrMn = −2.65(6) $ cm^{−1} $ on the basis of a one-dimensional alternating chain model with the Hamiltonian $$. polynuclear complex crystal structure magnetic property cyanide chromium manganese Zhang, LiFang aut Cui, AiLi aut Kou, HuiZhong aut Enthalten in Science in China / B SP Science in China Press, 1989 52(2009), 9 vom: Sept., Seite 1444-1450 (DE-627)130464953 (DE-600)740629-0 (DE-576)022978976 1006-9291 nnns volume:52 year:2009 number:9 month:09 pages:1444-1450 https://doi.org/10.1007/s11426-009-0162-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC FID-BIODIV SSG-OLC-PHY SSG-OLC-CHE SSG-OLC-OAS SSG-OLC-MFO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 AR 52 2009 9 09 1444-1450 |
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Enthalten in Science in China / B 52(2009), 9 vom: Sept., Seite 1444-1450 volume:52 year:2009 number:9 month:09 pages:1444-1450 |
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synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes |
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Synthesis, crystal structures and magnetic properties of cyanide-bridged macrocyclic complexes |
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Abstract Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (1), [Co(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (2) and [Co(bpmb)(CN)2]6[Mn(5-Clsalpn)]6·$ 24H_{2} $O·$ 8CH_{3} $CN (3) [$ bpmb^{2−} $= 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate dianion; 5-$ Brsalpn^{2−} $ = N,N′-propylenebis(5-bromosalicylideneaminato) dianion; 5-$ Clsalpn^{2−} $ = N,N′-propylenebis(5-chlorosalicylideneaminato) dianion] have been synthesized and their crystal structures and magnetic properties have been investigated. The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)2]− anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. A best-fit to the magnetic susceptibility of the complex leads to a magnetic coupling constant of JCrMn = −2.65(6) $ cm^{−1} $ on the basis of a one-dimensional alternating chain model with the Hamiltonian $$. © Science in China Press and Springer Berlin Heidelberg 2009 |
| abstractGer |
Abstract Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (1), [Co(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (2) and [Co(bpmb)(CN)2]6[Mn(5-Clsalpn)]6·$ 24H_{2} $O·$ 8CH_{3} $CN (3) [$ bpmb^{2−} $= 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate dianion; 5-$ Brsalpn^{2−} $ = N,N′-propylenebis(5-bromosalicylideneaminato) dianion; 5-$ Clsalpn^{2−} $ = N,N′-propylenebis(5-chlorosalicylideneaminato) dianion] have been synthesized and their crystal structures and magnetic properties have been investigated. The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)2]− anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. A best-fit to the magnetic susceptibility of the complex leads to a magnetic coupling constant of JCrMn = −2.65(6) $ cm^{−1} $ on the basis of a one-dimensional alternating chain model with the Hamiltonian $$. © Science in China Press and Springer Berlin Heidelberg 2009 |
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Abstract Three cyanide-bridged dodecanuclear macrocyclic wheel-like complexes [Cr(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (1), [Co(bpmb)(CN)2]6[Mn(5-Brsalpn)]6·$ 12H_{2} $O (2) and [Co(bpmb)(CN)2]6[Mn(5-Clsalpn)]6·$ 24H_{2} $O·$ 8CH_{3} $CN (3) [$ bpmb^{2−} $= 1,2-bis(pyridine-2-carboxamido)-4-methylbenzenate dianion; 5-$ Brsalpn^{2−} $ = N,N′-propylenebis(5-bromosalicylideneaminato) dianion; 5-$ Clsalpn^{2−} $ = N,N′-propylenebis(5-chlorosalicylideneaminato) dianion] have been synthesized and their crystal structures and magnetic properties have been investigated. The three compounds are structurally isomorphous and consist of alternating Mn(III)-Schiff base cations and [M(bpmb)(CN)2]− anions, generating cyanide-bridged nanosized dodecanuclear macrocyclic structures with an approximate diameter of 2 nm. The study of the magnetic properties of complex 1 reveals an antiferromagnetic interaction between the Cr(III) and Mn(III) ions through the cyanide bridges. A best-fit to the magnetic susceptibility of the complex leads to a magnetic coupling constant of JCrMn = −2.65(6) $ cm^{−1} $ on the basis of a one-dimensional alternating chain model with the Hamiltonian $$. © Science in China Press and Springer Berlin Heidelberg 2009 |
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