Synthesis and Crystal Structure of Mixed-valence Hexanuclear Manganase Oxide Complex, Hexakis($ μ_{2} $-pivalato)-tetrakis($ μ_{3} $-pivalato)-mono(pyridine)-tris(pivalic acid)-bis($ μ_{4} $-oxo)dimanganese(III) tetramanganase(II)
Abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9,040(4)...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Sarı, Musa [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2009 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media, LLC 2009 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of chemical crystallography - Springer US, 1994, 39(2009), 8 vom: 03. März, Seite 549-552 |
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| Übergeordnetes Werk: |
volume:39 ; year:2009 ; number:8 ; day:03 ; month:03 ; pages:549-552 |
| Links: |
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| DOI / URN: |
10.1007/s10870-009-9527-y |
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| Katalog-ID: |
OLC2036717543 |
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| 100 | 1 | |a Sarı, Musa |e verfasserin |4 aut | |
| 245 | 1 | 0 | |a Synthesis and Crystal Structure of Mixed-valence Hexanuclear Manganase Oxide Complex, Hexakis($ μ_{2} $-pivalato)-tetrakis($ μ_{3} $-pivalato)-mono(pyridine)-tris(pivalic acid)-bis($ μ_{4} $-oxo)dimanganese(III) tetramanganase(II) |
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| 520 | |a Abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9,040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ μ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ μ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions. Index abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ µ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ µ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions. | ||
| 650 | 4 | |a Mixed-valence | |
| 650 | 4 | |a Hexanuclear structure | |
| 650 | 4 | |a Clusters | |
| 650 | 4 | |a Crystal structure | |
| 700 | 1 | |a Poyraz, Mehmet |4 aut | |
| 700 | 1 | |a Büyükgüngör, Orhan |4 aut | |
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10.1007/s10870-009-9527-y doi (DE-627)OLC2036717543 (DE-He213)s10870-009-9527-y-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Sarı, Musa verfasserin aut Synthesis and Crystal Structure of Mixed-valence Hexanuclear Manganase Oxide Complex, Hexakis($ μ_{2} $-pivalato)-tetrakis($ μ_{3} $-pivalato)-mono(pyridine)-tris(pivalic acid)-bis($ μ_{4} $-oxo)dimanganese(III) tetramanganase(II) 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2009 Abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9,040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ μ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ μ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions. Index abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ µ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ µ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions. Mixed-valence Hexanuclear structure Clusters Crystal structure Poyraz, Mehmet aut Büyükgüngör, Orhan aut Enthalten in Journal of chemical crystallography Springer US, 1994 39(2009), 8 vom: 03. März, Seite 549-552 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:39 year:2009 number:8 day:03 month:03 pages:549-552 https://doi.org/10.1007/s10870-009-9527-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012 AR 39 2009 8 03 03 549-552 |
| spelling |
10.1007/s10870-009-9527-y doi (DE-627)OLC2036717543 (DE-He213)s10870-009-9527-y-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Sarı, Musa verfasserin aut Synthesis and Crystal Structure of Mixed-valence Hexanuclear Manganase Oxide Complex, Hexakis($ μ_{2} $-pivalato)-tetrakis($ μ_{3} $-pivalato)-mono(pyridine)-tris(pivalic acid)-bis($ μ_{4} $-oxo)dimanganese(III) tetramanganase(II) 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2009 Abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9,040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ μ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ μ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions. Index abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ µ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ µ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions. Mixed-valence Hexanuclear structure Clusters Crystal structure Poyraz, Mehmet aut Büyükgüngör, Orhan aut Enthalten in Journal of chemical crystallography Springer US, 1994 39(2009), 8 vom: 03. März, Seite 549-552 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:39 year:2009 number:8 day:03 month:03 pages:549-552 https://doi.org/10.1007/s10870-009-9527-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012 AR 39 2009 8 03 03 549-552 |
| allfields_unstemmed |
10.1007/s10870-009-9527-y doi (DE-627)OLC2036717543 (DE-He213)s10870-009-9527-y-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Sarı, Musa verfasserin aut Synthesis and Crystal Structure of Mixed-valence Hexanuclear Manganase Oxide Complex, Hexakis($ μ_{2} $-pivalato)-tetrakis($ μ_{3} $-pivalato)-mono(pyridine)-tris(pivalic acid)-bis($ μ_{4} $-oxo)dimanganese(III) tetramanganase(II) 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2009 Abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9,040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ μ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ μ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions. Index abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ µ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ µ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions. Mixed-valence Hexanuclear structure Clusters Crystal structure Poyraz, Mehmet aut Büyükgüngör, Orhan aut Enthalten in Journal of chemical crystallography Springer US, 1994 39(2009), 8 vom: 03. März, Seite 549-552 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:39 year:2009 number:8 day:03 month:03 pages:549-552 https://doi.org/10.1007/s10870-009-9527-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012 AR 39 2009 8 03 03 549-552 |
| allfieldsGer |
10.1007/s10870-009-9527-y doi (DE-627)OLC2036717543 (DE-He213)s10870-009-9527-y-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Sarı, Musa verfasserin aut Synthesis and Crystal Structure of Mixed-valence Hexanuclear Manganase Oxide Complex, Hexakis($ μ_{2} $-pivalato)-tetrakis($ μ_{3} $-pivalato)-mono(pyridine)-tris(pivalic acid)-bis($ μ_{4} $-oxo)dimanganese(III) tetramanganase(II) 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2009 Abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9,040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ μ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ μ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions. Index abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ µ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ µ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions. Mixed-valence Hexanuclear structure Clusters Crystal structure Poyraz, Mehmet aut Büyükgüngör, Orhan aut Enthalten in Journal of chemical crystallography Springer US, 1994 39(2009), 8 vom: 03. März, Seite 549-552 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:39 year:2009 number:8 day:03 month:03 pages:549-552 https://doi.org/10.1007/s10870-009-9527-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012 AR 39 2009 8 03 03 549-552 |
| allfieldsSound |
10.1007/s10870-009-9527-y doi (DE-627)OLC2036717543 (DE-He213)s10870-009-9527-y-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Sarı, Musa verfasserin aut Synthesis and Crystal Structure of Mixed-valence Hexanuclear Manganase Oxide Complex, Hexakis($ μ_{2} $-pivalato)-tetrakis($ μ_{3} $-pivalato)-mono(pyridine)-tris(pivalic acid)-bis($ μ_{4} $-oxo)dimanganese(III) tetramanganase(II) 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2009 Abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9,040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ μ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ μ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions. Index abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ µ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ µ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions. Mixed-valence Hexanuclear structure Clusters Crystal structure Poyraz, Mehmet aut Büyükgüngör, Orhan aut Enthalten in Journal of chemical crystallography Springer US, 1994 39(2009), 8 vom: 03. März, Seite 549-552 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:39 year:2009 number:8 day:03 month:03 pages:549-552 https://doi.org/10.1007/s10870-009-9527-y lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012 AR 39 2009 8 03 03 549-552 |
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This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9,040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ μ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ μ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions. Index abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ µ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ µ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Mixed-valence</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Hexanuclear structure</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Clusters</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Crystal structure</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Poyraz, Mehmet</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Büyükgüngör, Orhan</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of chemical crystallography</subfield><subfield code="d">Springer US, 1994</subfield><subfield code="g">39(2009), 8 vom: 03. 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Sarı, Musa |
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Sarı, Musa ddc 540 ssgn 13 misc Mixed-valence misc Hexanuclear structure misc Clusters misc Crystal structure Synthesis and Crystal Structure of Mixed-valence Hexanuclear Manganase Oxide Complex, Hexakis($ μ_{2} $-pivalato)-tetrakis($ μ_{3} $-pivalato)-mono(pyridine)-tris(pivalic acid)-bis($ μ_{4} $-oxo)dimanganese(III) tetramanganase(II) |
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Synthesis and Crystal Structure of Mixed-valence Hexanuclear Manganase Oxide Complex, Hexakis($ μ_{2} $-pivalato)-tetrakis($ μ_{3} $-pivalato)-mono(pyridine)-tris(pivalic acid)-bis($ μ_{4} $-oxo)dimanganese(III) tetramanganase(II) |
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Synthesis and Crystal Structure of Mixed-valence Hexanuclear Manganase Oxide Complex, Hexakis($ μ_{2} $-pivalato)-tetrakis($ μ_{3} $-pivalato)-mono(pyridine)-tris(pivalic acid)-bis($ μ_{4} $-oxo)dimanganese(III) tetramanganase(II) |
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Sarı, Musa Poyraz, Mehmet Büyükgüngör, Orhan |
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synthesis and crystal structure of mixed-valence hexanuclear manganase oxide complex, hexakis($ μ_{2} $-pivalato)-tetrakis($ μ_{3} $-pivalato)-mono(pyridine)-tris(pivalic acid)-bis($ μ_{4} $-oxo)dimanganese(iii) tetramanganase(ii) |
| title_auth |
Synthesis and Crystal Structure of Mixed-valence Hexanuclear Manganase Oxide Complex, Hexakis($ μ_{2} $-pivalato)-tetrakis($ μ_{3} $-pivalato)-mono(pyridine)-tris(pivalic acid)-bis($ μ_{4} $-oxo)dimanganese(III) tetramanganase(II) |
| abstract |
Abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9,040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ μ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ μ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions. Index abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ µ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ µ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions. © Springer Science+Business Media, LLC 2009 |
| abstractGer |
Abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9,040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ μ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ μ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions. Index abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ µ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ µ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions. © Springer Science+Business Media, LLC 2009 |
| abstract_unstemmed |
Abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9,040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ μ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ μ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions. Index abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ µ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ µ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions. © Springer Science+Business Media, LLC 2009 |
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Synthesis and Crystal Structure of Mixed-valence Hexanuclear Manganase Oxide Complex, Hexakis($ μ_{2} $-pivalato)-tetrakis($ μ_{3} $-pivalato)-mono(pyridine)-tris(pivalic acid)-bis($ μ_{4} $-oxo)dimanganese(III) tetramanganase(II) |
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This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9,040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ μ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ μ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions. Index abstract The complex, [$ Mn_{6} $$ O_{2} $($ OOCCMe_{3} $)10($ HOOCCMe_{3} $)3(py)], has a hexanuclear structure with a $ Mn_{6} $$ O_{2} $ core. This complex crystallizes in the monoclinic space group $ P2_{1} $/n with a = 17.757(5) Å, b = 27.413(5) Å, c = 22.348(5) Å, β = 90.233(5)°, V = 9040(4) $ Å^{3} $ and Z = 4. It contains a [$ Mn_{6} $$ O_{2} $]10+ core that can be described as two edge-sharing $ Mn_{4} $ tetrahedra at the centre of each of which tetrahedron lies a $ µ_{4} $-$ O^{2−} $ ion. All Mn atoms are six-coordinate and possess distorted octahedral geometry. $ Mn_{4} $ exhibits butterfly arrangement with both $ µ_{4} $-O atoms on the same side of the molecule. The complex is mixed-valence $$ \left( {{\text{Mn}}^{\text{II}}_{ 4} {\text{Mn}}^{\text{III}}_{ 2} } \right) $$, and the $ Mn^{III} $ centers are assigned as the two central metal ions bridged by two $ O^{2−} $ ions.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Mixed-valence</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Hexanuclear structure</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Clusters</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Crystal structure</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Poyraz, Mehmet</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Büyükgüngör, Orhan</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of chemical crystallography</subfield><subfield code="d">Springer US, 1994</subfield><subfield code="g">39(2009), 8 vom: 03. März, Seite 549-552</subfield><subfield code="w">(DE-627)182237877</subfield><subfield code="w">(DE-600)1189288-2</subfield><subfield code="w">(DE-576)039053679</subfield><subfield code="x">1074-1542</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:39</subfield><subfield code="g">year:2009</subfield><subfield code="g">number:8</subfield><subfield code="g">day:03</subfield><subfield code="g">month:03</subfield><subfield code="g">pages:549-552</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s10870-009-9527-y</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-GEO</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-DE-84</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OPC-GGO</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">39</subfield><subfield code="j">2009</subfield><subfield code="e">8</subfield><subfield code="b">03</subfield><subfield code="c">03</subfield><subfield code="h">549-552</subfield></datafield></record></collection>
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