Hydrogen Bonding in the Water Stabilized Structure of the Modified Unsymmetrically Substituted Viologen Chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium Dichloride

Abstract The crystal structure of the modified unsymmetrically N,N′-substituted viologen chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridinium dichloride 0.75 hydrate (1) has been determined. Crystals are triclinic, space group P−1 with Z = 2 in a cell with a = 7.2550(1), b = 13.2038(5), c =...
Ausführliche Beschreibung

Gespeichert in:

Autor*in:	Smith, Graham [verfasserIn] Will, Geoffrey D. Wilson, Gregory J.

Format:	Artikel
Sprache:	Englisch

Erschienen:	2009

Schlagwörter:	Viologens 4,4′-Bipyridine dications Electron-transfer compounds Crystal structure Hydrogen bonding

Anmerkung:	© Springer Science+Business Media, LLC 2009

Übergeordnetes Werk:	Enthalten in: Journal of chemical crystallography - Springer US, 1994, 40(2009), 3 vom: 06. Okt., Seite 248-252
Übergeordnetes Werk:	volume:40 ; year:2009 ; number:3 ; day:06 ; month:10 ; pages:248-252

Links:	Volltext

DOI / URN:	10.1007/s10870-009-9642-9

Katalog-ID:	OLC203671823X

Internformat


LEADER	01000caa a22002652 4500
001	OLC203671823X
003	DE-627
005	20230516221138.0
007	tu
008	200819s2009 xx \|\|\|\|\| 00\| \|\|eng c
024	7		\|a 10.1007/s10870-009-9642-9 \|2 doi
035			\|a (DE-627)OLC203671823X
035			\|a (DE-He213)s10870-009-9642-9-p
040			\|a DE-627 \|b ger \|c DE-627 \|e rakwb
041			\|a eng
082	0	4	\|a 540 \|q VZ
084			\|a 13 \|2 ssgn
100	1		\|a Smith, Graham \|e verfasserin \|4 aut
245	1	0	\|a Hydrogen Bonding in the Water Stabilized Structure of the Modified Unsymmetrically Substituted Viologen Chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium Dichloride
264		1	\|c 2009
336			\|a Text \|b txt \|2 rdacontent
337			\|a ohne Hilfsmittel zu benutzen \|b n \|2 rdamedia
338			\|a Band \|b nc \|2 rdacarrier
500			\|a © Springer Science+Business Media, LLC 2009
520			\|a Abstract The crystal structure of the modified unsymmetrically N,N′-substituted viologen chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridinium dichloride 0.75 hydrate (1) has been determined. Crystals are triclinic, space group P−1 with Z = 2 in a cell with a = 7.2550(1), b = 13.2038(5), c = 18.5752(7) Å, α = 86.495(3), β = 83.527(2), γ = 88.921(2)°. The two independent but pseudo-symmetrically related cations in the asymmetric unit form one-dimensional hydrogen-bonded chains through short homomeric phosphonic acid O–H···O links [2.455(4), 2.464(4) Å] while two of the chloride anions are similarly strongly linked to phosphonic acid groups [O–H···Cl, 2.889(4), 2.896(4) Å]. The other two chloride anions together with the two water molecules of solvation (one with partial occupancy) form unusual cyclic hydrogen-bonded bis(Cl···water) dianion units which lie between the layers of bipyridylium rings of the cation chain structures with which they are weakly associated. Graphical Abstract The crystal structure determination of unsymmetrically substituted viologen N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium dichloride 0.75 hydrate shows the presence of strong intermolecular phosphonate O–H···O and O–H···Cl interactions together with unusual cyclic hydrogen-bonded bis(chloride···water) dianion units giving one-dimensional chain structures.
650		4	\|a Viologens
650		4	\|a 4,4′-Bipyridine dications
650		4	\|a Electron-transfer compounds
650		4	\|a Crystal structure
650		4	\|a Hydrogen bonding
700	1		\|a Will, Geoffrey D. \|4 aut
700	1		\|a Wilson, Gregory J. \|4 aut
773	0	8	\|i Enthalten in \|t Journal of chemical crystallography \|d Springer US, 1994 \|g 40(2009), 3 vom: 06. Okt., Seite 248-252 \|w (DE-627)182237877 \|w (DE-600)1189288-2 \|w (DE-576)039053679 \|x 1074-1542 \|7 nnns
773	1	8	\|g volume:40 \|g year:2009 \|g number:3 \|g day:06 \|g month:10 \|g pages:248-252
856	4	1	\|u https://doi.org/10.1007/s10870-009-9642-9 \|z lizenzpflichtig \|3 Volltext
912			\|a GBV_USEFLAG_A
912			\|a SYSFLAG_A
912			\|a GBV_OLC
912			\|a SSG-OLC-CHE
912			\|a SSG-OLC-GEO
912			\|a SSG-OLC-PHA
912			\|a SSG-OLC-DE-84
912			\|a SSG-OPC-GGO
912			\|a GBV_ILN_70
912			\|a GBV_ILN_2027
912			\|a GBV_ILN_4012
951			\|a AR
952			\|d 40 \|j 2009 \|e 3 \|b 06 \|c 10 \|h 248-252

Indexfelder

author_variant	g s gs g d w gd gdw g j w gj gjw
matchkey_str	article:10741542:2009----::yrgnodniteaesaiiesrcuefhmdfeusmerclyusiuevooecrmpoeehl2
hierarchy_sort_str	2009
publishDate	2009
allfields	10.1007/s10870-009-9642-9 doi (DE-627)OLC203671823X (DE-He213)s10870-009-9642-9-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Smith, Graham verfasserin aut Hydrogen Bonding in the Water Stabilized Structure of the Modified Unsymmetrically Substituted Viologen Chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium Dichloride 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2009 Abstract The crystal structure of the modified unsymmetrically N,N′-substituted viologen chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridinium dichloride 0.75 hydrate (1) has been determined. Crystals are triclinic, space group P−1 with Z = 2 in a cell with a = 7.2550(1), b = 13.2038(5), c = 18.5752(7) Å, α = 86.495(3), β = 83.527(2), γ = 88.921(2)°. The two independent but pseudo-symmetrically related cations in the asymmetric unit form one-dimensional hydrogen-bonded chains through short homomeric phosphonic acid O–H···O links [2.455(4), 2.464(4) Å] while two of the chloride anions are similarly strongly linked to phosphonic acid groups [O–H···Cl, 2.889(4), 2.896(4) Å]. The other two chloride anions together with the two water molecules of solvation (one with partial occupancy) form unusual cyclic hydrogen-bonded bis(Cl···water) dianion units which lie between the layers of bipyridylium rings of the cation chain structures with which they are weakly associated. Graphical Abstract The crystal structure determination of unsymmetrically substituted viologen N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium dichloride 0.75 hydrate shows the presence of strong intermolecular phosphonate O–H···O and O–H···Cl interactions together with unusual cyclic hydrogen-bonded bis(chloride···water) dianion units giving one-dimensional chain structures. Viologens 4,4′-Bipyridine dications Electron-transfer compounds Crystal structure Hydrogen bonding Will, Geoffrey D. aut Wilson, Gregory J. aut Enthalten in Journal of chemical crystallography Springer US, 1994 40(2009), 3 vom: 06. Okt., Seite 248-252 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:40 year:2009 number:3 day:06 month:10 pages:248-252 https://doi.org/10.1007/s10870-009-9642-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012 AR 40 2009 3 06 10 248-252
spelling	10.1007/s10870-009-9642-9 doi (DE-627)OLC203671823X (DE-He213)s10870-009-9642-9-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Smith, Graham verfasserin aut Hydrogen Bonding in the Water Stabilized Structure of the Modified Unsymmetrically Substituted Viologen Chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium Dichloride 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2009 Abstract The crystal structure of the modified unsymmetrically N,N′-substituted viologen chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridinium dichloride 0.75 hydrate (1) has been determined. Crystals are triclinic, space group P−1 with Z = 2 in a cell with a = 7.2550(1), b = 13.2038(5), c = 18.5752(7) Å, α = 86.495(3), β = 83.527(2), γ = 88.921(2)°. The two independent but pseudo-symmetrically related cations in the asymmetric unit form one-dimensional hydrogen-bonded chains through short homomeric phosphonic acid O–H···O links [2.455(4), 2.464(4) Å] while two of the chloride anions are similarly strongly linked to phosphonic acid groups [O–H···Cl, 2.889(4), 2.896(4) Å]. The other two chloride anions together with the two water molecules of solvation (one with partial occupancy) form unusual cyclic hydrogen-bonded bis(Cl···water) dianion units which lie between the layers of bipyridylium rings of the cation chain structures with which they are weakly associated. Graphical Abstract The crystal structure determination of unsymmetrically substituted viologen N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium dichloride 0.75 hydrate shows the presence of strong intermolecular phosphonate O–H···O and O–H···Cl interactions together with unusual cyclic hydrogen-bonded bis(chloride···water) dianion units giving one-dimensional chain structures. Viologens 4,4′-Bipyridine dications Electron-transfer compounds Crystal structure Hydrogen bonding Will, Geoffrey D. aut Wilson, Gregory J. aut Enthalten in Journal of chemical crystallography Springer US, 1994 40(2009), 3 vom: 06. Okt., Seite 248-252 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:40 year:2009 number:3 day:06 month:10 pages:248-252 https://doi.org/10.1007/s10870-009-9642-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012 AR 40 2009 3 06 10 248-252
allfields_unstemmed	10.1007/s10870-009-9642-9 doi (DE-627)OLC203671823X (DE-He213)s10870-009-9642-9-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Smith, Graham verfasserin aut Hydrogen Bonding in the Water Stabilized Structure of the Modified Unsymmetrically Substituted Viologen Chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium Dichloride 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2009 Abstract The crystal structure of the modified unsymmetrically N,N′-substituted viologen chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridinium dichloride 0.75 hydrate (1) has been determined. Crystals are triclinic, space group P−1 with Z = 2 in a cell with a = 7.2550(1), b = 13.2038(5), c = 18.5752(7) Å, α = 86.495(3), β = 83.527(2), γ = 88.921(2)°. The two independent but pseudo-symmetrically related cations in the asymmetric unit form one-dimensional hydrogen-bonded chains through short homomeric phosphonic acid O–H···O links [2.455(4), 2.464(4) Å] while two of the chloride anions are similarly strongly linked to phosphonic acid groups [O–H···Cl, 2.889(4), 2.896(4) Å]. The other two chloride anions together with the two water molecules of solvation (one with partial occupancy) form unusual cyclic hydrogen-bonded bis(Cl···water) dianion units which lie between the layers of bipyridylium rings of the cation chain structures with which they are weakly associated. Graphical Abstract The crystal structure determination of unsymmetrically substituted viologen N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium dichloride 0.75 hydrate shows the presence of strong intermolecular phosphonate O–H···O and O–H···Cl interactions together with unusual cyclic hydrogen-bonded bis(chloride···water) dianion units giving one-dimensional chain structures. Viologens 4,4′-Bipyridine dications Electron-transfer compounds Crystal structure Hydrogen bonding Will, Geoffrey D. aut Wilson, Gregory J. aut Enthalten in Journal of chemical crystallography Springer US, 1994 40(2009), 3 vom: 06. Okt., Seite 248-252 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:40 year:2009 number:3 day:06 month:10 pages:248-252 https://doi.org/10.1007/s10870-009-9642-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012 AR 40 2009 3 06 10 248-252
allfieldsGer	10.1007/s10870-009-9642-9 doi (DE-627)OLC203671823X (DE-He213)s10870-009-9642-9-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Smith, Graham verfasserin aut Hydrogen Bonding in the Water Stabilized Structure of the Modified Unsymmetrically Substituted Viologen Chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium Dichloride 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2009 Abstract The crystal structure of the modified unsymmetrically N,N′-substituted viologen chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridinium dichloride 0.75 hydrate (1) has been determined. Crystals are triclinic, space group P−1 with Z = 2 in a cell with a = 7.2550(1), b = 13.2038(5), c = 18.5752(7) Å, α = 86.495(3), β = 83.527(2), γ = 88.921(2)°. The two independent but pseudo-symmetrically related cations in the asymmetric unit form one-dimensional hydrogen-bonded chains through short homomeric phosphonic acid O–H···O links [2.455(4), 2.464(4) Å] while two of the chloride anions are similarly strongly linked to phosphonic acid groups [O–H···Cl, 2.889(4), 2.896(4) Å]. The other two chloride anions together with the two water molecules of solvation (one with partial occupancy) form unusual cyclic hydrogen-bonded bis(Cl···water) dianion units which lie between the layers of bipyridylium rings of the cation chain structures with which they are weakly associated. Graphical Abstract The crystal structure determination of unsymmetrically substituted viologen N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium dichloride 0.75 hydrate shows the presence of strong intermolecular phosphonate O–H···O and O–H···Cl interactions together with unusual cyclic hydrogen-bonded bis(chloride···water) dianion units giving one-dimensional chain structures. Viologens 4,4′-Bipyridine dications Electron-transfer compounds Crystal structure Hydrogen bonding Will, Geoffrey D. aut Wilson, Gregory J. aut Enthalten in Journal of chemical crystallography Springer US, 1994 40(2009), 3 vom: 06. Okt., Seite 248-252 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:40 year:2009 number:3 day:06 month:10 pages:248-252 https://doi.org/10.1007/s10870-009-9642-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012 AR 40 2009 3 06 10 248-252
allfieldsSound	10.1007/s10870-009-9642-9 doi (DE-627)OLC203671823X (DE-He213)s10870-009-9642-9-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Smith, Graham verfasserin aut Hydrogen Bonding in the Water Stabilized Structure of the Modified Unsymmetrically Substituted Viologen Chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium Dichloride 2009 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2009 Abstract The crystal structure of the modified unsymmetrically N,N′-substituted viologen chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridinium dichloride 0.75 hydrate (1) has been determined. Crystals are triclinic, space group P−1 with Z = 2 in a cell with a = 7.2550(1), b = 13.2038(5), c = 18.5752(7) Å, α = 86.495(3), β = 83.527(2), γ = 88.921(2)°. The two independent but pseudo-symmetrically related cations in the asymmetric unit form one-dimensional hydrogen-bonded chains through short homomeric phosphonic acid O–H···O links [2.455(4), 2.464(4) Å] while two of the chloride anions are similarly strongly linked to phosphonic acid groups [O–H···Cl, 2.889(4), 2.896(4) Å]. The other two chloride anions together with the two water molecules of solvation (one with partial occupancy) form unusual cyclic hydrogen-bonded bis(Cl···water) dianion units which lie between the layers of bipyridylium rings of the cation chain structures with which they are weakly associated. Graphical Abstract The crystal structure determination of unsymmetrically substituted viologen N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium dichloride 0.75 hydrate shows the presence of strong intermolecular phosphonate O–H···O and O–H···Cl interactions together with unusual cyclic hydrogen-bonded bis(chloride···water) dianion units giving one-dimensional chain structures. Viologens 4,4′-Bipyridine dications Electron-transfer compounds Crystal structure Hydrogen bonding Will, Geoffrey D. aut Wilson, Gregory J. aut Enthalten in Journal of chemical crystallography Springer US, 1994 40(2009), 3 vom: 06. Okt., Seite 248-252 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:40 year:2009 number:3 day:06 month:10 pages:248-252 https://doi.org/10.1007/s10870-009-9642-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012 AR 40 2009 3 06 10 248-252
language	English
source	Enthalten in Journal of chemical crystallography 40(2009), 3 vom: 06. Okt., Seite 248-252 volume:40 year:2009 number:3 day:06 month:10 pages:248-252
sourceStr	Enthalten in Journal of chemical crystallography 40(2009), 3 vom: 06. Okt., Seite 248-252 volume:40 year:2009 number:3 day:06 month:10 pages:248-252
format_phy_str_mv	Article
institution	findex.gbv.de
topic_facet	Viologens 4,4′-Bipyridine dications Electron-transfer compounds Crystal structure Hydrogen bonding
dewey-raw	540
isfreeaccess_bool	false
container_title	Journal of chemical crystallography
authorswithroles_txt_mv	Smith, Graham @@aut@@ Will, Geoffrey D. @@aut@@ Wilson, Gregory J. @@aut@@
publishDateDaySort_date	2009-10-06T00:00:00Z
hierarchy_top_id	182237877
dewey-sort	3540
id	OLC203671823X
language_de	englisch
fullrecord	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC203671823X</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230516221138.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200819s2009 xx \|\|\|\|\| 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10870-009-9642-9</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC203671823X</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)s10870-009-9642-9-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">13</subfield><subfield code="2">ssgn</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Smith, Graham</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Hydrogen Bonding in the Water Stabilized Structure of the Modified Unsymmetrically Substituted Viologen Chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium Dichloride</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2009</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Springer Science+Business Media, LLC 2009</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The crystal structure of the modified unsymmetrically N,N′-substituted viologen chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridinium dichloride 0.75 hydrate (1) has been determined. Crystals are triclinic, space group P−1 with Z = 2 in a cell with a = 7.2550(1), b = 13.2038(5), c = 18.5752(7) Å, α = 86.495(3), β = 83.527(2), γ = 88.921(2)°. The two independent but pseudo-symmetrically related cations in the asymmetric unit form one-dimensional hydrogen-bonded chains through short homomeric phosphonic acid O–H···O links [2.455(4), 2.464(4) Å] while two of the chloride anions are similarly strongly linked to phosphonic acid groups [O–H···Cl, 2.889(4), 2.896(4) Å]. The other two chloride anions together with the two water molecules of solvation (one with partial occupancy) form unusual cyclic hydrogen-bonded bis(Cl···water) dianion units which lie between the layers of bipyridylium rings of the cation chain structures with which they are weakly associated. Graphical Abstract The crystal structure determination of unsymmetrically substituted viologen N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium dichloride 0.75 hydrate shows the presence of strong intermolecular phosphonate O–H···O and O–H···Cl interactions together with unusual cyclic hydrogen-bonded bis(chloride···water) dianion units giving one-dimensional chain structures.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Viologens</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">4,4′-Bipyridine dications</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Electron-transfer compounds</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Crystal structure</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Hydrogen bonding</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Will, Geoffrey D.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wilson, Gregory J.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of chemical crystallography</subfield><subfield code="d">Springer US, 1994</subfield><subfield code="g">40(2009), 3 vom: 06. Okt., Seite 248-252</subfield><subfield code="w">(DE-627)182237877</subfield><subfield code="w">(DE-600)1189288-2</subfield><subfield code="w">(DE-576)039053679</subfield><subfield code="x">1074-1542</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:40</subfield><subfield code="g">year:2009</subfield><subfield code="g">number:3</subfield><subfield code="g">day:06</subfield><subfield code="g">month:10</subfield><subfield code="g">pages:248-252</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s10870-009-9642-9</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-GEO</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-DE-84</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OPC-GGO</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">40</subfield><subfield code="j">2009</subfield><subfield code="e">3</subfield><subfield code="b">06</subfield><subfield code="c">10</subfield><subfield code="h">248-252</subfield></datafield></record></collection>
author	Smith, Graham
spellingShingle	Smith, Graham ddc 540 ssgn 13 misc Viologens misc 4,4′-Bipyridine dications misc Electron-transfer compounds misc Crystal structure misc Hydrogen bonding Hydrogen Bonding in the Water Stabilized Structure of the Modified Unsymmetrically Substituted Viologen Chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium Dichloride
authorStr	Smith, Graham
ppnlink_with_tag_str_mv	@@773@@(DE-627)182237877
format	Article
dewey-ones	540 - Chemistry & allied sciences
delete_txt_mv	keep
author_role	aut aut aut
collection	OLC
remote_str	false
illustrated	Not Illustrated
issn	1074-1542
topic_title	540 VZ 13 ssgn Hydrogen Bonding in the Water Stabilized Structure of the Modified Unsymmetrically Substituted Viologen Chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium Dichloride Viologens 4,4′-Bipyridine dications Electron-transfer compounds Crystal structure Hydrogen bonding
topic	ddc 540 ssgn 13 misc Viologens misc 4,4′-Bipyridine dications misc Electron-transfer compounds misc Crystal structure misc Hydrogen bonding
topic_unstemmed	ddc 540 ssgn 13 misc Viologens misc 4,4′-Bipyridine dications misc Electron-transfer compounds misc Crystal structure misc Hydrogen bonding
topic_browse	ddc 540 ssgn 13 misc Viologens misc 4,4′-Bipyridine dications misc Electron-transfer compounds misc Crystal structure misc Hydrogen bonding
format_facet	Aufsätze Gedruckte Aufsätze
format_main_str_mv	Text Zeitschrift/Artikel
carriertype_str_mv	nc
hierarchy_parent_title	Journal of chemical crystallography
hierarchy_parent_id	182237877
dewey-tens	540 - Chemistry
hierarchy_top_title	Journal of chemical crystallography
isfreeaccess_txt	false
familylinks_str_mv	(DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679
title	Hydrogen Bonding in the Water Stabilized Structure of the Modified Unsymmetrically Substituted Viologen Chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium Dichloride
ctrlnum	(DE-627)OLC203671823X (DE-He213)s10870-009-9642-9-p
title_full	Hydrogen Bonding in the Water Stabilized Structure of the Modified Unsymmetrically Substituted Viologen Chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium Dichloride
author_sort	Smith, Graham
journal	Journal of chemical crystallography
journalStr	Journal of chemical crystallography
lang_code	eng
isOA_bool	false
dewey-hundreds	500 - Science
recordtype	marc
publishDateSort	2009
contenttype_str_mv	txt
container_start_page	248
author_browse	Smith, Graham Will, Geoffrey D. Wilson, Gregory J.
container_volume	40
class	540 VZ 13 ssgn
format_se	Aufsätze
author-letter	Smith, Graham
doi_str_mv	10.1007/s10870-009-9642-9
dewey-full	540
title_sort	hydrogen bonding in the water stabilized structure of the modified unsymmetrically substituted viologen chromophore, n-ethyl-n′-(2-phosphonoethyl)-4,4′-bipyridylium dichloride
title_auth	Hydrogen Bonding in the Water Stabilized Structure of the Modified Unsymmetrically Substituted Viologen Chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium Dichloride
abstract	Abstract The crystal structure of the modified unsymmetrically N,N′-substituted viologen chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridinium dichloride 0.75 hydrate (1) has been determined. Crystals are triclinic, space group P−1 with Z = 2 in a cell with a = 7.2550(1), b = 13.2038(5), c = 18.5752(7) Å, α = 86.495(3), β = 83.527(2), γ = 88.921(2)°. The two independent but pseudo-symmetrically related cations in the asymmetric unit form one-dimensional hydrogen-bonded chains through short homomeric phosphonic acid O–H···O links [2.455(4), 2.464(4) Å] while two of the chloride anions are similarly strongly linked to phosphonic acid groups [O–H···Cl, 2.889(4), 2.896(4) Å]. The other two chloride anions together with the two water molecules of solvation (one with partial occupancy) form unusual cyclic hydrogen-bonded bis(Cl···water) dianion units which lie between the layers of bipyridylium rings of the cation chain structures with which they are weakly associated. Graphical Abstract The crystal structure determination of unsymmetrically substituted viologen N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium dichloride 0.75 hydrate shows the presence of strong intermolecular phosphonate O–H···O and O–H···Cl interactions together with unusual cyclic hydrogen-bonded bis(chloride···water) dianion units giving one-dimensional chain structures. © Springer Science+Business Media, LLC 2009
abstractGer	Abstract The crystal structure of the modified unsymmetrically N,N′-substituted viologen chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridinium dichloride 0.75 hydrate (1) has been determined. Crystals are triclinic, space group P−1 with Z = 2 in a cell with a = 7.2550(1), b = 13.2038(5), c = 18.5752(7) Å, α = 86.495(3), β = 83.527(2), γ = 88.921(2)°. The two independent but pseudo-symmetrically related cations in the asymmetric unit form one-dimensional hydrogen-bonded chains through short homomeric phosphonic acid O–H···O links [2.455(4), 2.464(4) Å] while two of the chloride anions are similarly strongly linked to phosphonic acid groups [O–H···Cl, 2.889(4), 2.896(4) Å]. The other two chloride anions together with the two water molecules of solvation (one with partial occupancy) form unusual cyclic hydrogen-bonded bis(Cl···water) dianion units which lie between the layers of bipyridylium rings of the cation chain structures with which they are weakly associated. Graphical Abstract The crystal structure determination of unsymmetrically substituted viologen N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium dichloride 0.75 hydrate shows the presence of strong intermolecular phosphonate O–H···O and O–H···Cl interactions together with unusual cyclic hydrogen-bonded bis(chloride···water) dianion units giving one-dimensional chain structures. © Springer Science+Business Media, LLC 2009
abstract_unstemmed	Abstract The crystal structure of the modified unsymmetrically N,N′-substituted viologen chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridinium dichloride 0.75 hydrate (1) has been determined. Crystals are triclinic, space group P−1 with Z = 2 in a cell with a = 7.2550(1), b = 13.2038(5), c = 18.5752(7) Å, α = 86.495(3), β = 83.527(2), γ = 88.921(2)°. The two independent but pseudo-symmetrically related cations in the asymmetric unit form one-dimensional hydrogen-bonded chains through short homomeric phosphonic acid O–H···O links [2.455(4), 2.464(4) Å] while two of the chloride anions are similarly strongly linked to phosphonic acid groups [O–H···Cl, 2.889(4), 2.896(4) Å]. The other two chloride anions together with the two water molecules of solvation (one with partial occupancy) form unusual cyclic hydrogen-bonded bis(Cl···water) dianion units which lie between the layers of bipyridylium rings of the cation chain structures with which they are weakly associated. Graphical Abstract The crystal structure determination of unsymmetrically substituted viologen N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium dichloride 0.75 hydrate shows the presence of strong intermolecular phosphonate O–H···O and O–H···Cl interactions together with unusual cyclic hydrogen-bonded bis(chloride···water) dianion units giving one-dimensional chain structures. © Springer Science+Business Media, LLC 2009
collection_details	GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012
container_issue	3
title_short	Hydrogen Bonding in the Water Stabilized Structure of the Modified Unsymmetrically Substituted Viologen Chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium Dichloride
url	https://doi.org/10.1007/s10870-009-9642-9
remote_bool	false
author2	Will, Geoffrey D. Wilson, Gregory J.
author2Str	Will, Geoffrey D. Wilson, Gregory J.
ppnlink	182237877
mediatype_str_mv	n
isOA_txt	false
hochschulschrift_bool	false
doi_str	10.1007/s10870-009-9642-9
up_date	2024-07-04T04:01:52.833Z
_version_	1803619624904818688
fullrecord_marcxml	<?xml version="1.0" encoding="UTF-8"?><collection xmlns="http://www.loc.gov/MARC21/slim"><record><leader>01000caa a22002652 4500</leader><controlfield tag="001">OLC203671823X</controlfield><controlfield tag="003">DE-627</controlfield><controlfield tag="005">20230516221138.0</controlfield><controlfield tag="007">tu</controlfield><controlfield tag="008">200819s2009 xx \|\|\|\|\| 00\| \|\|eng c</controlfield><datafield tag="024" ind1="7" ind2=" "><subfield code="a">10.1007/s10870-009-9642-9</subfield><subfield code="2">doi</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-627)OLC203671823X</subfield></datafield><datafield tag="035" ind1=" " ind2=" "><subfield code="a">(DE-He213)s10870-009-9642-9-p</subfield></datafield><datafield tag="040" ind1=" " ind2=" "><subfield code="a">DE-627</subfield><subfield code="b">ger</subfield><subfield code="c">DE-627</subfield><subfield code="e">rakwb</subfield></datafield><datafield tag="041" ind1=" " ind2=" "><subfield code="a">eng</subfield></datafield><datafield tag="082" ind1="0" ind2="4"><subfield code="a">540</subfield><subfield code="q">VZ</subfield></datafield><datafield tag="084" ind1=" " ind2=" "><subfield code="a">13</subfield><subfield code="2">ssgn</subfield></datafield><datafield tag="100" ind1="1" ind2=" "><subfield code="a">Smith, Graham</subfield><subfield code="e">verfasserin</subfield><subfield code="4">aut</subfield></datafield><datafield tag="245" ind1="1" ind2="0"><subfield code="a">Hydrogen Bonding in the Water Stabilized Structure of the Modified Unsymmetrically Substituted Viologen Chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium Dichloride</subfield></datafield><datafield tag="264" ind1=" " ind2="1"><subfield code="c">2009</subfield></datafield><datafield tag="336" ind1=" " ind2=" "><subfield code="a">Text</subfield><subfield code="b">txt</subfield><subfield code="2">rdacontent</subfield></datafield><datafield tag="337" ind1=" " ind2=" "><subfield code="a">ohne Hilfsmittel zu benutzen</subfield><subfield code="b">n</subfield><subfield code="2">rdamedia</subfield></datafield><datafield tag="338" ind1=" " ind2=" "><subfield code="a">Band</subfield><subfield code="b">nc</subfield><subfield code="2">rdacarrier</subfield></datafield><datafield tag="500" ind1=" " ind2=" "><subfield code="a">© Springer Science+Business Media, LLC 2009</subfield></datafield><datafield tag="520" ind1=" " ind2=" "><subfield code="a">Abstract The crystal structure of the modified unsymmetrically N,N′-substituted viologen chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridinium dichloride 0.75 hydrate (1) has been determined. Crystals are triclinic, space group P−1 with Z = 2 in a cell with a = 7.2550(1), b = 13.2038(5), c = 18.5752(7) Å, α = 86.495(3), β = 83.527(2), γ = 88.921(2)°. The two independent but pseudo-symmetrically related cations in the asymmetric unit form one-dimensional hydrogen-bonded chains through short homomeric phosphonic acid O–H···O links [2.455(4), 2.464(4) Å] while two of the chloride anions are similarly strongly linked to phosphonic acid groups [O–H···Cl, 2.889(4), 2.896(4) Å]. The other two chloride anions together with the two water molecules of solvation (one with partial occupancy) form unusual cyclic hydrogen-bonded bis(Cl···water) dianion units which lie between the layers of bipyridylium rings of the cation chain structures with which they are weakly associated. Graphical Abstract The crystal structure determination of unsymmetrically substituted viologen N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium dichloride 0.75 hydrate shows the presence of strong intermolecular phosphonate O–H···O and O–H···Cl interactions together with unusual cyclic hydrogen-bonded bis(chloride···water) dianion units giving one-dimensional chain structures.</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Viologens</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">4,4′-Bipyridine dications</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Electron-transfer compounds</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Crystal structure</subfield></datafield><datafield tag="650" ind1=" " ind2="4"><subfield code="a">Hydrogen bonding</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Will, Geoffrey D.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="700" ind1="1" ind2=" "><subfield code="a">Wilson, Gregory J.</subfield><subfield code="4">aut</subfield></datafield><datafield tag="773" ind1="0" ind2="8"><subfield code="i">Enthalten in</subfield><subfield code="t">Journal of chemical crystallography</subfield><subfield code="d">Springer US, 1994</subfield><subfield code="g">40(2009), 3 vom: 06. Okt., Seite 248-252</subfield><subfield code="w">(DE-627)182237877</subfield><subfield code="w">(DE-600)1189288-2</subfield><subfield code="w">(DE-576)039053679</subfield><subfield code="x">1074-1542</subfield><subfield code="7">nnns</subfield></datafield><datafield tag="773" ind1="1" ind2="8"><subfield code="g">volume:40</subfield><subfield code="g">year:2009</subfield><subfield code="g">number:3</subfield><subfield code="g">day:06</subfield><subfield code="g">month:10</subfield><subfield code="g">pages:248-252</subfield></datafield><datafield tag="856" ind1="4" ind2="1"><subfield code="u">https://doi.org/10.1007/s10870-009-9642-9</subfield><subfield code="z">lizenzpflichtig</subfield><subfield code="3">Volltext</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_USEFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SYSFLAG_A</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_OLC</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-CHE</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-GEO</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-PHA</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OLC-DE-84</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">SSG-OPC-GGO</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_70</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_2027</subfield></datafield><datafield tag="912" ind1=" " ind2=" "><subfield code="a">GBV_ILN_4012</subfield></datafield><datafield tag="951" ind1=" " ind2=" "><subfield code="a">AR</subfield></datafield><datafield tag="952" ind1=" " ind2=" "><subfield code="d">40</subfield><subfield code="j">2009</subfield><subfield code="e">3</subfield><subfield code="b">06</subfield><subfield code="c">10</subfield><subfield code="h">248-252</subfield></datafield></record></collection>
score	7.4015617

Nicht das Richtige dabei?

Schreiben Sie uns!

Hydrogen Bonding in the Water Stabilized Structure of the Modified Unsymmetrically Substituted Viologen Chromophore, N-ethyl-N′-(2-phosphonoethyl)-4,4′-bipyridylium Dichloride

Nicht das Richtige dabei?

Zugang & Verfügbarkeit

Vorhandene Bände

Nicht das Richtige dabei?