A Square Grid Coordination Polymer from Tetrahedral Metal Ions and Angular Dicarboxylate Ligands
Abstract The title compound, {[$ NH_{2} $($ CH_{3} $)2]4[Zn($ C_{8} $$ H_{4} $$ O_{5} $)2]($ SO_{4} $)}n, is a coordination polymer based on mononuclear Zn($ O_{2} $C)4 unit and 5-hydroxyisophthalate linker. The 120° arrangement of the two carboxyl groups of the ligand effectively cancels out the te...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Chun, Hyungphil [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2010 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media, LLC 2010 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of chemical crystallography - Springer US, 1994, 41(2010), 4 vom: 12. Dez., Seite 537-540 |
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| Übergeordnetes Werk: |
volume:41 ; year:2010 ; number:4 ; day:12 ; month:12 ; pages:537-540 |
| Links: |
|---|
| DOI / URN: |
10.1007/s10870-010-9916-2 |
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OLC2036720994 |
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| 245 | 1 | 0 | |a A Square Grid Coordination Polymer from Tetrahedral Metal Ions and Angular Dicarboxylate Ligands |
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| 520 | |a Abstract The title compound, {[$ NH_{2} $($ CH_{3} $)2]4[Zn($ C_{8} $$ H_{4} $$ O_{5} $)2]($ SO_{4} $)}n, is a coordination polymer based on mononuclear Zn($ O_{2} $C)4 unit and 5-hydroxyisophthalate linker. The 120° arrangement of the two carboxyl groups of the ligand effectively cancels out the tetrahedral coordination angles around $ Zn^{2+} $ ion and results in a two-dimensional (2D) square grid network. The surplus cations and anions balancing the extra charges of the framework form hydrogen bonds with carboxyl and hydroxyl groups of adjacent 2D layers. As a result, straight open channels are formed along a direction perpendicular to the 2D layers. Graphical Abstract The combination of tetrahedral $ Zn^{2+} $ ions and angular dicarboxylate ligands leads to square-grid type layers that form straight open channels by interlayer stacking. | ||
| 650 | 4 | |a Coordination polymer | |
| 650 | 4 | |a Dicarboxylate | |
| 650 | 4 | |a Square grid | |
| 650 | 4 | |a Zn(II) | |
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10.1007/s10870-010-9916-2 doi (DE-627)OLC2036720994 (DE-He213)s10870-010-9916-2-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Chun, Hyungphil verfasserin aut A Square Grid Coordination Polymer from Tetrahedral Metal Ions and Angular Dicarboxylate Ligands 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2010 Abstract The title compound, {[$ NH_{2} $($ CH_{3} $)2]4[Zn($ C_{8} $$ H_{4} $$ O_{5} $)2]($ SO_{4} $)}n, is a coordination polymer based on mononuclear Zn($ O_{2} $C)4 unit and 5-hydroxyisophthalate linker. The 120° arrangement of the two carboxyl groups of the ligand effectively cancels out the tetrahedral coordination angles around $ Zn^{2+} $ ion and results in a two-dimensional (2D) square grid network. The surplus cations and anions balancing the extra charges of the framework form hydrogen bonds with carboxyl and hydroxyl groups of adjacent 2D layers. As a result, straight open channels are formed along a direction perpendicular to the 2D layers. Graphical Abstract The combination of tetrahedral $ Zn^{2+} $ ions and angular dicarboxylate ligands leads to square-grid type layers that form straight open channels by interlayer stacking. Coordination polymer Dicarboxylate Square grid Zn(II) Enthalten in Journal of chemical crystallography Springer US, 1994 41(2010), 4 vom: 12. Dez., Seite 537-540 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:41 year:2010 number:4 day:12 month:12 pages:537-540 https://doi.org/10.1007/s10870-010-9916-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012 AR 41 2010 4 12 12 537-540 |
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10.1007/s10870-010-9916-2 doi (DE-627)OLC2036720994 (DE-He213)s10870-010-9916-2-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Chun, Hyungphil verfasserin aut A Square Grid Coordination Polymer from Tetrahedral Metal Ions and Angular Dicarboxylate Ligands 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2010 Abstract The title compound, {[$ NH_{2} $($ CH_{3} $)2]4[Zn($ C_{8} $$ H_{4} $$ O_{5} $)2]($ SO_{4} $)}n, is a coordination polymer based on mononuclear Zn($ O_{2} $C)4 unit and 5-hydroxyisophthalate linker. The 120° arrangement of the two carboxyl groups of the ligand effectively cancels out the tetrahedral coordination angles around $ Zn^{2+} $ ion and results in a two-dimensional (2D) square grid network. The surplus cations and anions balancing the extra charges of the framework form hydrogen bonds with carboxyl and hydroxyl groups of adjacent 2D layers. As a result, straight open channels are formed along a direction perpendicular to the 2D layers. Graphical Abstract The combination of tetrahedral $ Zn^{2+} $ ions and angular dicarboxylate ligands leads to square-grid type layers that form straight open channels by interlayer stacking. Coordination polymer Dicarboxylate Square grid Zn(II) Enthalten in Journal of chemical crystallography Springer US, 1994 41(2010), 4 vom: 12. Dez., Seite 537-540 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:41 year:2010 number:4 day:12 month:12 pages:537-540 https://doi.org/10.1007/s10870-010-9916-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012 AR 41 2010 4 12 12 537-540 |
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10.1007/s10870-010-9916-2 doi (DE-627)OLC2036720994 (DE-He213)s10870-010-9916-2-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Chun, Hyungphil verfasserin aut A Square Grid Coordination Polymer from Tetrahedral Metal Ions and Angular Dicarboxylate Ligands 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2010 Abstract The title compound, {[$ NH_{2} $($ CH_{3} $)2]4[Zn($ C_{8} $$ H_{4} $$ O_{5} $)2]($ SO_{4} $)}n, is a coordination polymer based on mononuclear Zn($ O_{2} $C)4 unit and 5-hydroxyisophthalate linker. The 120° arrangement of the two carboxyl groups of the ligand effectively cancels out the tetrahedral coordination angles around $ Zn^{2+} $ ion and results in a two-dimensional (2D) square grid network. The surplus cations and anions balancing the extra charges of the framework form hydrogen bonds with carboxyl and hydroxyl groups of adjacent 2D layers. As a result, straight open channels are formed along a direction perpendicular to the 2D layers. Graphical Abstract The combination of tetrahedral $ Zn^{2+} $ ions and angular dicarboxylate ligands leads to square-grid type layers that form straight open channels by interlayer stacking. Coordination polymer Dicarboxylate Square grid Zn(II) Enthalten in Journal of chemical crystallography Springer US, 1994 41(2010), 4 vom: 12. Dez., Seite 537-540 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:41 year:2010 number:4 day:12 month:12 pages:537-540 https://doi.org/10.1007/s10870-010-9916-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012 AR 41 2010 4 12 12 537-540 |
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10.1007/s10870-010-9916-2 doi (DE-627)OLC2036720994 (DE-He213)s10870-010-9916-2-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Chun, Hyungphil verfasserin aut A Square Grid Coordination Polymer from Tetrahedral Metal Ions and Angular Dicarboxylate Ligands 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2010 Abstract The title compound, {[$ NH_{2} $($ CH_{3} $)2]4[Zn($ C_{8} $$ H_{4} $$ O_{5} $)2]($ SO_{4} $)}n, is a coordination polymer based on mononuclear Zn($ O_{2} $C)4 unit and 5-hydroxyisophthalate linker. The 120° arrangement of the two carboxyl groups of the ligand effectively cancels out the tetrahedral coordination angles around $ Zn^{2+} $ ion and results in a two-dimensional (2D) square grid network. The surplus cations and anions balancing the extra charges of the framework form hydrogen bonds with carboxyl and hydroxyl groups of adjacent 2D layers. As a result, straight open channels are formed along a direction perpendicular to the 2D layers. Graphical Abstract The combination of tetrahedral $ Zn^{2+} $ ions and angular dicarboxylate ligands leads to square-grid type layers that form straight open channels by interlayer stacking. Coordination polymer Dicarboxylate Square grid Zn(II) Enthalten in Journal of chemical crystallography Springer US, 1994 41(2010), 4 vom: 12. Dez., Seite 537-540 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:41 year:2010 number:4 day:12 month:12 pages:537-540 https://doi.org/10.1007/s10870-010-9916-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012 AR 41 2010 4 12 12 537-540 |
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10.1007/s10870-010-9916-2 doi (DE-627)OLC2036720994 (DE-He213)s10870-010-9916-2-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Chun, Hyungphil verfasserin aut A Square Grid Coordination Polymer from Tetrahedral Metal Ions and Angular Dicarboxylate Ligands 2010 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media, LLC 2010 Abstract The title compound, {[$ NH_{2} $($ CH_{3} $)2]4[Zn($ C_{8} $$ H_{4} $$ O_{5} $)2]($ SO_{4} $)}n, is a coordination polymer based on mononuclear Zn($ O_{2} $C)4 unit and 5-hydroxyisophthalate linker. The 120° arrangement of the two carboxyl groups of the ligand effectively cancels out the tetrahedral coordination angles around $ Zn^{2+} $ ion and results in a two-dimensional (2D) square grid network. The surplus cations and anions balancing the extra charges of the framework form hydrogen bonds with carboxyl and hydroxyl groups of adjacent 2D layers. As a result, straight open channels are formed along a direction perpendicular to the 2D layers. Graphical Abstract The combination of tetrahedral $ Zn^{2+} $ ions and angular dicarboxylate ligands leads to square-grid type layers that form straight open channels by interlayer stacking. Coordination polymer Dicarboxylate Square grid Zn(II) Enthalten in Journal of chemical crystallography Springer US, 1994 41(2010), 4 vom: 12. Dez., Seite 537-540 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:41 year:2010 number:4 day:12 month:12 pages:537-540 https://doi.org/10.1007/s10870-010-9916-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012 AR 41 2010 4 12 12 537-540 |
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A Square Grid Coordination Polymer from Tetrahedral Metal Ions and Angular Dicarboxylate Ligands |
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Abstract The title compound, {[$ NH_{2} $($ CH_{3} $)2]4[Zn($ C_{8} $$ H_{4} $$ O_{5} $)2]($ SO_{4} $)}n, is a coordination polymer based on mononuclear Zn($ O_{2} $C)4 unit and 5-hydroxyisophthalate linker. The 120° arrangement of the two carboxyl groups of the ligand effectively cancels out the tetrahedral coordination angles around $ Zn^{2+} $ ion and results in a two-dimensional (2D) square grid network. The surplus cations and anions balancing the extra charges of the framework form hydrogen bonds with carboxyl and hydroxyl groups of adjacent 2D layers. As a result, straight open channels are formed along a direction perpendicular to the 2D layers. Graphical Abstract The combination of tetrahedral $ Zn^{2+} $ ions and angular dicarboxylate ligands leads to square-grid type layers that form straight open channels by interlayer stacking. © Springer Science+Business Media, LLC 2010 |
| abstractGer |
Abstract The title compound, {[$ NH_{2} $($ CH_{3} $)2]4[Zn($ C_{8} $$ H_{4} $$ O_{5} $)2]($ SO_{4} $)}n, is a coordination polymer based on mononuclear Zn($ O_{2} $C)4 unit and 5-hydroxyisophthalate linker. The 120° arrangement of the two carboxyl groups of the ligand effectively cancels out the tetrahedral coordination angles around $ Zn^{2+} $ ion and results in a two-dimensional (2D) square grid network. The surplus cations and anions balancing the extra charges of the framework form hydrogen bonds with carboxyl and hydroxyl groups of adjacent 2D layers. As a result, straight open channels are formed along a direction perpendicular to the 2D layers. Graphical Abstract The combination of tetrahedral $ Zn^{2+} $ ions and angular dicarboxylate ligands leads to square-grid type layers that form straight open channels by interlayer stacking. © Springer Science+Business Media, LLC 2010 |
| abstract_unstemmed |
Abstract The title compound, {[$ NH_{2} $($ CH_{3} $)2]4[Zn($ C_{8} $$ H_{4} $$ O_{5} $)2]($ SO_{4} $)}n, is a coordination polymer based on mononuclear Zn($ O_{2} $C)4 unit and 5-hydroxyisophthalate linker. The 120° arrangement of the two carboxyl groups of the ligand effectively cancels out the tetrahedral coordination angles around $ Zn^{2+} $ ion and results in a two-dimensional (2D) square grid network. The surplus cations and anions balancing the extra charges of the framework form hydrogen bonds with carboxyl and hydroxyl groups of adjacent 2D layers. As a result, straight open channels are formed along a direction perpendicular to the 2D layers. Graphical Abstract The combination of tetrahedral $ Zn^{2+} $ ions and angular dicarboxylate ligands leads to square-grid type layers that form straight open channels by interlayer stacking. © Springer Science+Business Media, LLC 2010 |
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| title_short |
A Square Grid Coordination Polymer from Tetrahedral Metal Ions and Angular Dicarboxylate Ligands |
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https://doi.org/10.1007/s10870-010-9916-2 |
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