A Trinuclear Crystallochromic Cd(II) Complex with Zwitterionic Coordination Terminals: Network of Metalorganic Motifs Through C–H⋯N and Charge Promoted $ N^{∂+} $–H⋯N Associations in Solid State
Abstract In aqueous medium at pH 6, cadmium acetate dihydrate combines with 4,6-dimethylpyrimidine-2-thiol to form a centrosymmetric Cl, S-bridged complex having zwitterionic terminals. The zwitterionic nature of this complex is evidenced by its pH and conductance values in methanol solution. It cry...
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| Autor*in: |
Das, Asish K. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2014 |
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| Schlagwörter: |
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| Anmerkung: |
© Springer Science+Business Media New York 2014 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of chemical crystallography - Springer US, 1994, 44(2014), 4 vom: 20. Feb., Seite 177-184 |
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| Übergeordnetes Werk: |
volume:44 ; year:2014 ; number:4 ; day:20 ; month:02 ; pages:177-184 |
| Links: |
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| DOI / URN: |
10.1007/s10870-014-0496-4 |
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OLC2036726275 |
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| 245 | 1 | 0 | |a A Trinuclear Crystallochromic Cd(II) Complex with Zwitterionic Coordination Terminals: Network of Metalorganic Motifs Through C–H⋯N and Charge Promoted $ N^{∂+} $–H⋯N Associations in Solid State |
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| 520 | |a Abstract In aqueous medium at pH 6, cadmium acetate dihydrate combines with 4,6-dimethylpyrimidine-2-thiol to form a centrosymmetric Cl, S-bridged complex having zwitterionic terminals. The zwitterionic nature of this complex is evidenced by its pH and conductance values in methanol solution. It crystallizes in the space group $ P2_{1} $/c (Z = 4 asymmetric units, two molecules), each molecule being uncommonly characterized by a centric Cd(II)$ S_{2} $$ Cl_{2} $$ N_{2} $ as well as two acentric and anionic Cd(II)$ S_{3} $$ ClN_{2} $ coordination chromophores with counter cationic ligands. Relevant literature reports indicate a template relation between the structural designs of this complex and hydrated cadmium acetate, the metalorganic precursor. Packing of molecular motifs through weak C–H···N and strong charge-enhanced $ N^{δ+} $–H···N interactions generate the crystal structure with numerous screw–glide related small voids. Attempt has been made to rationalize the crystallochromic nature of the complex (pale green in solution, pale orange while crystalline) by time dependent DFT and ZINDO/S studies. Graphical Abstract In aqueous medium, cadmium acetate combines with 4,6-dimethylpyrimidine-2-thiol to form a centrosymmetric, trinuclear complex with zwitterionic terminals. The crystallochromic behaviour of this complex is investigated by quantum chemical treatment. | ||
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| 650 | 4 | |a Cadmium complexes | |
| 650 | 4 | |a Zwitterionic complexes | |
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| 700 | 1 | |a Slawin, Alexandra M. Z. |4 aut | |
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10.1007/s10870-014-0496-4 doi (DE-627)OLC2036726275 (DE-He213)s10870-014-0496-4-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Das, Asish K. verfasserin aut A Trinuclear Crystallochromic Cd(II) Complex with Zwitterionic Coordination Terminals: Network of Metalorganic Motifs Through C–H⋯N and Charge Promoted $ N^{∂+} $–H⋯N Associations in Solid State 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2014 Abstract In aqueous medium at pH 6, cadmium acetate dihydrate combines with 4,6-dimethylpyrimidine-2-thiol to form a centrosymmetric Cl, S-bridged complex having zwitterionic terminals. The zwitterionic nature of this complex is evidenced by its pH and conductance values in methanol solution. It crystallizes in the space group $ P2_{1} $/c (Z = 4 asymmetric units, two molecules), each molecule being uncommonly characterized by a centric Cd(II)$ S_{2} $$ Cl_{2} $$ N_{2} $ as well as two acentric and anionic Cd(II)$ S_{3} $$ ClN_{2} $ coordination chromophores with counter cationic ligands. Relevant literature reports indicate a template relation between the structural designs of this complex and hydrated cadmium acetate, the metalorganic precursor. Packing of molecular motifs through weak C–H···N and strong charge-enhanced $ N^{δ+} $–H···N interactions generate the crystal structure with numerous screw–glide related small voids. Attempt has been made to rationalize the crystallochromic nature of the complex (pale green in solution, pale orange while crystalline) by time dependent DFT and ZINDO/S studies. Graphical Abstract In aqueous medium, cadmium acetate combines with 4,6-dimethylpyrimidine-2-thiol to form a centrosymmetric, trinuclear complex with zwitterionic terminals. The crystallochromic behaviour of this complex is investigated by quantum chemical treatment. Thiolpyrimidine complexes Cadmium complexes Zwitterionic complexes Crystallochromic complexes Chattopadhyay, Asoke P. aut Fuller, Amy aut Slawin, Alexandra M. Z. aut Enthalten in Journal of chemical crystallography Springer US, 1994 44(2014), 4 vom: 20. Feb., Seite 177-184 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:44 year:2014 number:4 day:20 month:02 pages:177-184 https://doi.org/10.1007/s10870-014-0496-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012 AR 44 2014 4 20 02 177-184 |
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10.1007/s10870-014-0496-4 doi (DE-627)OLC2036726275 (DE-He213)s10870-014-0496-4-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Das, Asish K. verfasserin aut A Trinuclear Crystallochromic Cd(II) Complex with Zwitterionic Coordination Terminals: Network of Metalorganic Motifs Through C–H⋯N and Charge Promoted $ N^{∂+} $–H⋯N Associations in Solid State 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2014 Abstract In aqueous medium at pH 6, cadmium acetate dihydrate combines with 4,6-dimethylpyrimidine-2-thiol to form a centrosymmetric Cl, S-bridged complex having zwitterionic terminals. The zwitterionic nature of this complex is evidenced by its pH and conductance values in methanol solution. It crystallizes in the space group $ P2_{1} $/c (Z = 4 asymmetric units, two molecules), each molecule being uncommonly characterized by a centric Cd(II)$ S_{2} $$ Cl_{2} $$ N_{2} $ as well as two acentric and anionic Cd(II)$ S_{3} $$ ClN_{2} $ coordination chromophores with counter cationic ligands. Relevant literature reports indicate a template relation between the structural designs of this complex and hydrated cadmium acetate, the metalorganic precursor. Packing of molecular motifs through weak C–H···N and strong charge-enhanced $ N^{δ+} $–H···N interactions generate the crystal structure with numerous screw–glide related small voids. Attempt has been made to rationalize the crystallochromic nature of the complex (pale green in solution, pale orange while crystalline) by time dependent DFT and ZINDO/S studies. Graphical Abstract In aqueous medium, cadmium acetate combines with 4,6-dimethylpyrimidine-2-thiol to form a centrosymmetric, trinuclear complex with zwitterionic terminals. The crystallochromic behaviour of this complex is investigated by quantum chemical treatment. Thiolpyrimidine complexes Cadmium complexes Zwitterionic complexes Crystallochromic complexes Chattopadhyay, Asoke P. aut Fuller, Amy aut Slawin, Alexandra M. Z. aut Enthalten in Journal of chemical crystallography Springer US, 1994 44(2014), 4 vom: 20. Feb., Seite 177-184 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:44 year:2014 number:4 day:20 month:02 pages:177-184 https://doi.org/10.1007/s10870-014-0496-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012 AR 44 2014 4 20 02 177-184 |
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10.1007/s10870-014-0496-4 doi (DE-627)OLC2036726275 (DE-He213)s10870-014-0496-4-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Das, Asish K. verfasserin aut A Trinuclear Crystallochromic Cd(II) Complex with Zwitterionic Coordination Terminals: Network of Metalorganic Motifs Through C–H⋯N and Charge Promoted $ N^{∂+} $–H⋯N Associations in Solid State 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2014 Abstract In aqueous medium at pH 6, cadmium acetate dihydrate combines with 4,6-dimethylpyrimidine-2-thiol to form a centrosymmetric Cl, S-bridged complex having zwitterionic terminals. The zwitterionic nature of this complex is evidenced by its pH and conductance values in methanol solution. It crystallizes in the space group $ P2_{1} $/c (Z = 4 asymmetric units, two molecules), each molecule being uncommonly characterized by a centric Cd(II)$ S_{2} $$ Cl_{2} $$ N_{2} $ as well as two acentric and anionic Cd(II)$ S_{3} $$ ClN_{2} $ coordination chromophores with counter cationic ligands. Relevant literature reports indicate a template relation between the structural designs of this complex and hydrated cadmium acetate, the metalorganic precursor. Packing of molecular motifs through weak C–H···N and strong charge-enhanced $ N^{δ+} $–H···N interactions generate the crystal structure with numerous screw–glide related small voids. Attempt has been made to rationalize the crystallochromic nature of the complex (pale green in solution, pale orange while crystalline) by time dependent DFT and ZINDO/S studies. Graphical Abstract In aqueous medium, cadmium acetate combines with 4,6-dimethylpyrimidine-2-thiol to form a centrosymmetric, trinuclear complex with zwitterionic terminals. The crystallochromic behaviour of this complex is investigated by quantum chemical treatment. Thiolpyrimidine complexes Cadmium complexes Zwitterionic complexes Crystallochromic complexes Chattopadhyay, Asoke P. aut Fuller, Amy aut Slawin, Alexandra M. Z. aut Enthalten in Journal of chemical crystallography Springer US, 1994 44(2014), 4 vom: 20. Feb., Seite 177-184 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:44 year:2014 number:4 day:20 month:02 pages:177-184 https://doi.org/10.1007/s10870-014-0496-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012 AR 44 2014 4 20 02 177-184 |
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10.1007/s10870-014-0496-4 doi (DE-627)OLC2036726275 (DE-He213)s10870-014-0496-4-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Das, Asish K. verfasserin aut A Trinuclear Crystallochromic Cd(II) Complex with Zwitterionic Coordination Terminals: Network of Metalorganic Motifs Through C–H⋯N and Charge Promoted $ N^{∂+} $–H⋯N Associations in Solid State 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2014 Abstract In aqueous medium at pH 6, cadmium acetate dihydrate combines with 4,6-dimethylpyrimidine-2-thiol to form a centrosymmetric Cl, S-bridged complex having zwitterionic terminals. The zwitterionic nature of this complex is evidenced by its pH and conductance values in methanol solution. It crystallizes in the space group $ P2_{1} $/c (Z = 4 asymmetric units, two molecules), each molecule being uncommonly characterized by a centric Cd(II)$ S_{2} $$ Cl_{2} $$ N_{2} $ as well as two acentric and anionic Cd(II)$ S_{3} $$ ClN_{2} $ coordination chromophores with counter cationic ligands. Relevant literature reports indicate a template relation between the structural designs of this complex and hydrated cadmium acetate, the metalorganic precursor. Packing of molecular motifs through weak C–H···N and strong charge-enhanced $ N^{δ+} $–H···N interactions generate the crystal structure with numerous screw–glide related small voids. Attempt has been made to rationalize the crystallochromic nature of the complex (pale green in solution, pale orange while crystalline) by time dependent DFT and ZINDO/S studies. Graphical Abstract In aqueous medium, cadmium acetate combines with 4,6-dimethylpyrimidine-2-thiol to form a centrosymmetric, trinuclear complex with zwitterionic terminals. The crystallochromic behaviour of this complex is investigated by quantum chemical treatment. Thiolpyrimidine complexes Cadmium complexes Zwitterionic complexes Crystallochromic complexes Chattopadhyay, Asoke P. aut Fuller, Amy aut Slawin, Alexandra M. Z. aut Enthalten in Journal of chemical crystallography Springer US, 1994 44(2014), 4 vom: 20. Feb., Seite 177-184 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:44 year:2014 number:4 day:20 month:02 pages:177-184 https://doi.org/10.1007/s10870-014-0496-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012 AR 44 2014 4 20 02 177-184 |
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10.1007/s10870-014-0496-4 doi (DE-627)OLC2036726275 (DE-He213)s10870-014-0496-4-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Das, Asish K. verfasserin aut A Trinuclear Crystallochromic Cd(II) Complex with Zwitterionic Coordination Terminals: Network of Metalorganic Motifs Through C–H⋯N and Charge Promoted $ N^{∂+} $–H⋯N Associations in Solid State 2014 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2014 Abstract In aqueous medium at pH 6, cadmium acetate dihydrate combines with 4,6-dimethylpyrimidine-2-thiol to form a centrosymmetric Cl, S-bridged complex having zwitterionic terminals. The zwitterionic nature of this complex is evidenced by its pH and conductance values in methanol solution. It crystallizes in the space group $ P2_{1} $/c (Z = 4 asymmetric units, two molecules), each molecule being uncommonly characterized by a centric Cd(II)$ S_{2} $$ Cl_{2} $$ N_{2} $ as well as two acentric and anionic Cd(II)$ S_{3} $$ ClN_{2} $ coordination chromophores with counter cationic ligands. Relevant literature reports indicate a template relation between the structural designs of this complex and hydrated cadmium acetate, the metalorganic precursor. Packing of molecular motifs through weak C–H···N and strong charge-enhanced $ N^{δ+} $–H···N interactions generate the crystal structure with numerous screw–glide related small voids. Attempt has been made to rationalize the crystallochromic nature of the complex (pale green in solution, pale orange while crystalline) by time dependent DFT and ZINDO/S studies. Graphical Abstract In aqueous medium, cadmium acetate combines with 4,6-dimethylpyrimidine-2-thiol to form a centrosymmetric, trinuclear complex with zwitterionic terminals. The crystallochromic behaviour of this complex is investigated by quantum chemical treatment. Thiolpyrimidine complexes Cadmium complexes Zwitterionic complexes Crystallochromic complexes Chattopadhyay, Asoke P. aut Fuller, Amy aut Slawin, Alexandra M. Z. aut Enthalten in Journal of chemical crystallography Springer US, 1994 44(2014), 4 vom: 20. Feb., Seite 177-184 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:44 year:2014 number:4 day:20 month:02 pages:177-184 https://doi.org/10.1007/s10870-014-0496-4 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_2027 GBV_ILN_4012 AR 44 2014 4 20 02 177-184 |
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Das, Asish K. ddc 540 ssgn 13 misc Thiolpyrimidine complexes misc Cadmium complexes misc Zwitterionic complexes misc Crystallochromic complexes A Trinuclear Crystallochromic Cd(II) Complex with Zwitterionic Coordination Terminals: Network of Metalorganic Motifs Through C–H⋯N and Charge Promoted $ N^{∂+} $–H⋯N Associations in Solid State |
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A Trinuclear Crystallochromic Cd(II) Complex with Zwitterionic Coordination Terminals: Network of Metalorganic Motifs Through C–H⋯N and Charge Promoted $ N^{∂+} $–H⋯N Associations in Solid State |
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A Trinuclear Crystallochromic Cd(II) Complex with Zwitterionic Coordination Terminals: Network of Metalorganic Motifs Through C–H⋯N and Charge Promoted $ N^{∂+} $–H⋯N Associations in Solid State |
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a trinuclear crystallochromic cd(ii) complex with zwitterionic coordination terminals: network of metalorganic motifs through c–h⋯n and charge promoted $ n^{∂+} $–h⋯n associations in solid state |
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A Trinuclear Crystallochromic Cd(II) Complex with Zwitterionic Coordination Terminals: Network of Metalorganic Motifs Through C–H⋯N and Charge Promoted $ N^{∂+} $–H⋯N Associations in Solid State |
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Abstract In aqueous medium at pH 6, cadmium acetate dihydrate combines with 4,6-dimethylpyrimidine-2-thiol to form a centrosymmetric Cl, S-bridged complex having zwitterionic terminals. The zwitterionic nature of this complex is evidenced by its pH and conductance values in methanol solution. It crystallizes in the space group $ P2_{1} $/c (Z = 4 asymmetric units, two molecules), each molecule being uncommonly characterized by a centric Cd(II)$ S_{2} $$ Cl_{2} $$ N_{2} $ as well as two acentric and anionic Cd(II)$ S_{3} $$ ClN_{2} $ coordination chromophores with counter cationic ligands. Relevant literature reports indicate a template relation between the structural designs of this complex and hydrated cadmium acetate, the metalorganic precursor. Packing of molecular motifs through weak C–H···N and strong charge-enhanced $ N^{δ+} $–H···N interactions generate the crystal structure with numerous screw–glide related small voids. Attempt has been made to rationalize the crystallochromic nature of the complex (pale green in solution, pale orange while crystalline) by time dependent DFT and ZINDO/S studies. Graphical Abstract In aqueous medium, cadmium acetate combines with 4,6-dimethylpyrimidine-2-thiol to form a centrosymmetric, trinuclear complex with zwitterionic terminals. The crystallochromic behaviour of this complex is investigated by quantum chemical treatment. © Springer Science+Business Media New York 2014 |
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Abstract In aqueous medium at pH 6, cadmium acetate dihydrate combines with 4,6-dimethylpyrimidine-2-thiol to form a centrosymmetric Cl, S-bridged complex having zwitterionic terminals. The zwitterionic nature of this complex is evidenced by its pH and conductance values in methanol solution. It crystallizes in the space group $ P2_{1} $/c (Z = 4 asymmetric units, two molecules), each molecule being uncommonly characterized by a centric Cd(II)$ S_{2} $$ Cl_{2} $$ N_{2} $ as well as two acentric and anionic Cd(II)$ S_{3} $$ ClN_{2} $ coordination chromophores with counter cationic ligands. Relevant literature reports indicate a template relation between the structural designs of this complex and hydrated cadmium acetate, the metalorganic precursor. Packing of molecular motifs through weak C–H···N and strong charge-enhanced $ N^{δ+} $–H···N interactions generate the crystal structure with numerous screw–glide related small voids. Attempt has been made to rationalize the crystallochromic nature of the complex (pale green in solution, pale orange while crystalline) by time dependent DFT and ZINDO/S studies. Graphical Abstract In aqueous medium, cadmium acetate combines with 4,6-dimethylpyrimidine-2-thiol to form a centrosymmetric, trinuclear complex with zwitterionic terminals. The crystallochromic behaviour of this complex is investigated by quantum chemical treatment. © Springer Science+Business Media New York 2014 |
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Abstract In aqueous medium at pH 6, cadmium acetate dihydrate combines with 4,6-dimethylpyrimidine-2-thiol to form a centrosymmetric Cl, S-bridged complex having zwitterionic terminals. The zwitterionic nature of this complex is evidenced by its pH and conductance values in methanol solution. It crystallizes in the space group $ P2_{1} $/c (Z = 4 asymmetric units, two molecules), each molecule being uncommonly characterized by a centric Cd(II)$ S_{2} $$ Cl_{2} $$ N_{2} $ as well as two acentric and anionic Cd(II)$ S_{3} $$ ClN_{2} $ coordination chromophores with counter cationic ligands. Relevant literature reports indicate a template relation between the structural designs of this complex and hydrated cadmium acetate, the metalorganic precursor. Packing of molecular motifs through weak C–H···N and strong charge-enhanced $ N^{δ+} $–H···N interactions generate the crystal structure with numerous screw–glide related small voids. Attempt has been made to rationalize the crystallochromic nature of the complex (pale green in solution, pale orange while crystalline) by time dependent DFT and ZINDO/S studies. Graphical Abstract In aqueous medium, cadmium acetate combines with 4,6-dimethylpyrimidine-2-thiol to form a centrosymmetric, trinuclear complex with zwitterionic terminals. The crystallochromic behaviour of this complex is investigated by quantum chemical treatment. © Springer Science+Business Media New York 2014 |
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