Hydrogen-Bonding in the Anhydrous Morpholinium Salts of the Three Isomeric Monoaminobenzoic Acids
Abstract The structures of the anhydrous morpholinium salts of the isomeric 2-aminobenzoic acid (anthranilic acid) (1), 3-aminobenzoic acid (2) and 4-aminobenzoic acid (3), with formula $ C_{4} $$ H_{10} $$ NO^{+} $ $ C_{7} $$ H_{8} $$ NO_{2} $−, have been determined. Crystals of 1 are monoclinic, s...
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Gespeichert in:
| Autor*in: |
Smith, Graham [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
2016 |
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| Anmerkung: |
© Springer Science+Business Media New York 2016 |
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| Übergeordnetes Werk: |
Enthalten in: Journal of chemical crystallography - Springer US, 1994, 46(2016), 5 vom: Mai, Seite 230-236 |
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| Übergeordnetes Werk: |
volume:46 ; year:2016 ; number:5 ; month:05 ; pages:230-236 |
| Links: |
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| DOI / URN: |
10.1007/s10870-016-0650-2 |
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| Katalog-ID: |
OLC2036727697 |
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| 520 | |a Abstract The structures of the anhydrous morpholinium salts of the isomeric 2-aminobenzoic acid (anthranilic acid) (1), 3-aminobenzoic acid (2) and 4-aminobenzoic acid (3), with formula $ C_{4} $$ H_{10} $$ NO^{+} $ $ C_{7} $$ H_{8} $$ NO_{2} $−, have been determined. Crystals of 1 are monoclinic, space group P$ 2_{1} $/c, with unit cell dimensions a = 11.0696(9), b = 7.8775(6), c = 13.0180(11) Å, β = 95.804(8)° and Z = 4. Compound 2 is orthorhombic, space group Pna$ 2_{1} $, with unit cell dimensions a = 9.3899(4), b = 16.6789(7), c = 7.4463(3) Å and Z = 4 and compound 3 is monoclinic, space group Cc, with unit cell dimensions a = 5.9233(6), b = 18.048(2), c = 10.5478(10) Å, β = 90.376(10)° and Z = 4. In all crystals, both morpholinium N–H atoms are involved in primary inter-species hydrogen-bonding interactions with carboxyl O-atom acceptors of the anions. Secondary N–H···O hydrogen bonds between the amine groups and carboxyl (1 and 3) or both carboxyl and morpholine O-atom acceptors in 2, including in 2 a three-centre asymmetric N–H···O,O’ chelate [$$ R_{1}^{2} $$(4)] motif, give two-dimensional layers (1 and 2) or a three-dimensional network structure (3). In 1, the interactions include a centrosymmetric cyclic $$ R_{4}^{4} $$(12) motif and in 2, a cyclic $$ R_{3}^{2} $$(11) motif but no π–π aromatic ring associations are present in any of the structures. Graphical Abstract The structures of the anhydrous morpholinium salts of the three isomeric monoaminobenzoic acids are reported, together with their hydrogen-bonding patterns. | ||
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10.1007/s10870-016-0650-2 doi (DE-627)OLC2036727697 (DE-He213)s10870-016-0650-2-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Smith, Graham verfasserin aut Hydrogen-Bonding in the Anhydrous Morpholinium Salts of the Three Isomeric Monoaminobenzoic Acids 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2016 Abstract The structures of the anhydrous morpholinium salts of the isomeric 2-aminobenzoic acid (anthranilic acid) (1), 3-aminobenzoic acid (2) and 4-aminobenzoic acid (3), with formula $ C_{4} $$ H_{10} $$ NO^{+} $ $ C_{7} $$ H_{8} $$ NO_{2} $−, have been determined. Crystals of 1 are monoclinic, space group P$ 2_{1} $/c, with unit cell dimensions a = 11.0696(9), b = 7.8775(6), c = 13.0180(11) Å, β = 95.804(8)° and Z = 4. Compound 2 is orthorhombic, space group Pna$ 2_{1} $, with unit cell dimensions a = 9.3899(4), b = 16.6789(7), c = 7.4463(3) Å and Z = 4 and compound 3 is monoclinic, space group Cc, with unit cell dimensions a = 5.9233(6), b = 18.048(2), c = 10.5478(10) Å, β = 90.376(10)° and Z = 4. In all crystals, both morpholinium N–H atoms are involved in primary inter-species hydrogen-bonding interactions with carboxyl O-atom acceptors of the anions. Secondary N–H···O hydrogen bonds between the amine groups and carboxyl (1 and 3) or both carboxyl and morpholine O-atom acceptors in 2, including in 2 a three-centre asymmetric N–H···O,O’ chelate [$$ R_{1}^{2} $$(4)] motif, give two-dimensional layers (1 and 2) or a three-dimensional network structure (3). In 1, the interactions include a centrosymmetric cyclic $$ R_{4}^{4} $$(12) motif and in 2, a cyclic $$ R_{3}^{2} $$(11) motif but no π–π aromatic ring associations are present in any of the structures. Graphical Abstract The structures of the anhydrous morpholinium salts of the three isomeric monoaminobenzoic acids are reported, together with their hydrogen-bonding patterns. Morpholine Aminobenzoic acids Hydrogen-bonding Enthalten in Journal of chemical crystallography Springer US, 1994 46(2016), 5 vom: Mai, Seite 230-236 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:46 year:2016 number:5 month:05 pages:230-236 https://doi.org/10.1007/s10870-016-0650-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_4012 AR 46 2016 5 05 230-236 |
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10.1007/s10870-016-0650-2 doi (DE-627)OLC2036727697 (DE-He213)s10870-016-0650-2-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Smith, Graham verfasserin aut Hydrogen-Bonding in the Anhydrous Morpholinium Salts of the Three Isomeric Monoaminobenzoic Acids 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2016 Abstract The structures of the anhydrous morpholinium salts of the isomeric 2-aminobenzoic acid (anthranilic acid) (1), 3-aminobenzoic acid (2) and 4-aminobenzoic acid (3), with formula $ C_{4} $$ H_{10} $$ NO^{+} $ $ C_{7} $$ H_{8} $$ NO_{2} $−, have been determined. Crystals of 1 are monoclinic, space group P$ 2_{1} $/c, with unit cell dimensions a = 11.0696(9), b = 7.8775(6), c = 13.0180(11) Å, β = 95.804(8)° and Z = 4. Compound 2 is orthorhombic, space group Pna$ 2_{1} $, with unit cell dimensions a = 9.3899(4), b = 16.6789(7), c = 7.4463(3) Å and Z = 4 and compound 3 is monoclinic, space group Cc, with unit cell dimensions a = 5.9233(6), b = 18.048(2), c = 10.5478(10) Å, β = 90.376(10)° and Z = 4. In all crystals, both morpholinium N–H atoms are involved in primary inter-species hydrogen-bonding interactions with carboxyl O-atom acceptors of the anions. Secondary N–H···O hydrogen bonds between the amine groups and carboxyl (1 and 3) or both carboxyl and morpholine O-atom acceptors in 2, including in 2 a three-centre asymmetric N–H···O,O’ chelate [$$ R_{1}^{2} $$(4)] motif, give two-dimensional layers (1 and 2) or a three-dimensional network structure (3). In 1, the interactions include a centrosymmetric cyclic $$ R_{4}^{4} $$(12) motif and in 2, a cyclic $$ R_{3}^{2} $$(11) motif but no π–π aromatic ring associations are present in any of the structures. Graphical Abstract The structures of the anhydrous morpholinium salts of the three isomeric monoaminobenzoic acids are reported, together with their hydrogen-bonding patterns. Morpholine Aminobenzoic acids Hydrogen-bonding Enthalten in Journal of chemical crystallography Springer US, 1994 46(2016), 5 vom: Mai, Seite 230-236 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:46 year:2016 number:5 month:05 pages:230-236 https://doi.org/10.1007/s10870-016-0650-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_4012 AR 46 2016 5 05 230-236 |
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10.1007/s10870-016-0650-2 doi (DE-627)OLC2036727697 (DE-He213)s10870-016-0650-2-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Smith, Graham verfasserin aut Hydrogen-Bonding in the Anhydrous Morpholinium Salts of the Three Isomeric Monoaminobenzoic Acids 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2016 Abstract The structures of the anhydrous morpholinium salts of the isomeric 2-aminobenzoic acid (anthranilic acid) (1), 3-aminobenzoic acid (2) and 4-aminobenzoic acid (3), with formula $ C_{4} $$ H_{10} $$ NO^{+} $ $ C_{7} $$ H_{8} $$ NO_{2} $−, have been determined. Crystals of 1 are monoclinic, space group P$ 2_{1} $/c, with unit cell dimensions a = 11.0696(9), b = 7.8775(6), c = 13.0180(11) Å, β = 95.804(8)° and Z = 4. Compound 2 is orthorhombic, space group Pna$ 2_{1} $, with unit cell dimensions a = 9.3899(4), b = 16.6789(7), c = 7.4463(3) Å and Z = 4 and compound 3 is monoclinic, space group Cc, with unit cell dimensions a = 5.9233(6), b = 18.048(2), c = 10.5478(10) Å, β = 90.376(10)° and Z = 4. In all crystals, both morpholinium N–H atoms are involved in primary inter-species hydrogen-bonding interactions with carboxyl O-atom acceptors of the anions. Secondary N–H···O hydrogen bonds between the amine groups and carboxyl (1 and 3) or both carboxyl and morpholine O-atom acceptors in 2, including in 2 a three-centre asymmetric N–H···O,O’ chelate [$$ R_{1}^{2} $$(4)] motif, give two-dimensional layers (1 and 2) or a three-dimensional network structure (3). In 1, the interactions include a centrosymmetric cyclic $$ R_{4}^{4} $$(12) motif and in 2, a cyclic $$ R_{3}^{2} $$(11) motif but no π–π aromatic ring associations are present in any of the structures. Graphical Abstract The structures of the anhydrous morpholinium salts of the three isomeric monoaminobenzoic acids are reported, together with their hydrogen-bonding patterns. Morpholine Aminobenzoic acids Hydrogen-bonding Enthalten in Journal of chemical crystallography Springer US, 1994 46(2016), 5 vom: Mai, Seite 230-236 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:46 year:2016 number:5 month:05 pages:230-236 https://doi.org/10.1007/s10870-016-0650-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_4012 AR 46 2016 5 05 230-236 |
| allfieldsGer |
10.1007/s10870-016-0650-2 doi (DE-627)OLC2036727697 (DE-He213)s10870-016-0650-2-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Smith, Graham verfasserin aut Hydrogen-Bonding in the Anhydrous Morpholinium Salts of the Three Isomeric Monoaminobenzoic Acids 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2016 Abstract The structures of the anhydrous morpholinium salts of the isomeric 2-aminobenzoic acid (anthranilic acid) (1), 3-aminobenzoic acid (2) and 4-aminobenzoic acid (3), with formula $ C_{4} $$ H_{10} $$ NO^{+} $ $ C_{7} $$ H_{8} $$ NO_{2} $−, have been determined. Crystals of 1 are monoclinic, space group P$ 2_{1} $/c, with unit cell dimensions a = 11.0696(9), b = 7.8775(6), c = 13.0180(11) Å, β = 95.804(8)° and Z = 4. Compound 2 is orthorhombic, space group Pna$ 2_{1} $, with unit cell dimensions a = 9.3899(4), b = 16.6789(7), c = 7.4463(3) Å and Z = 4 and compound 3 is monoclinic, space group Cc, with unit cell dimensions a = 5.9233(6), b = 18.048(2), c = 10.5478(10) Å, β = 90.376(10)° and Z = 4. In all crystals, both morpholinium N–H atoms are involved in primary inter-species hydrogen-bonding interactions with carboxyl O-atom acceptors of the anions. Secondary N–H···O hydrogen bonds between the amine groups and carboxyl (1 and 3) or both carboxyl and morpholine O-atom acceptors in 2, including in 2 a three-centre asymmetric N–H···O,O’ chelate [$$ R_{1}^{2} $$(4)] motif, give two-dimensional layers (1 and 2) or a three-dimensional network structure (3). In 1, the interactions include a centrosymmetric cyclic $$ R_{4}^{4} $$(12) motif and in 2, a cyclic $$ R_{3}^{2} $$(11) motif but no π–π aromatic ring associations are present in any of the structures. Graphical Abstract The structures of the anhydrous morpholinium salts of the three isomeric monoaminobenzoic acids are reported, together with their hydrogen-bonding patterns. Morpholine Aminobenzoic acids Hydrogen-bonding Enthalten in Journal of chemical crystallography Springer US, 1994 46(2016), 5 vom: Mai, Seite 230-236 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:46 year:2016 number:5 month:05 pages:230-236 https://doi.org/10.1007/s10870-016-0650-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_4012 AR 46 2016 5 05 230-236 |
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10.1007/s10870-016-0650-2 doi (DE-627)OLC2036727697 (DE-He213)s10870-016-0650-2-p DE-627 ger DE-627 rakwb eng 540 VZ 13 ssgn Smith, Graham verfasserin aut Hydrogen-Bonding in the Anhydrous Morpholinium Salts of the Three Isomeric Monoaminobenzoic Acids 2016 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Springer Science+Business Media New York 2016 Abstract The structures of the anhydrous morpholinium salts of the isomeric 2-aminobenzoic acid (anthranilic acid) (1), 3-aminobenzoic acid (2) and 4-aminobenzoic acid (3), with formula $ C_{4} $$ H_{10} $$ NO^{+} $ $ C_{7} $$ H_{8} $$ NO_{2} $−, have been determined. Crystals of 1 are monoclinic, space group P$ 2_{1} $/c, with unit cell dimensions a = 11.0696(9), b = 7.8775(6), c = 13.0180(11) Å, β = 95.804(8)° and Z = 4. Compound 2 is orthorhombic, space group Pna$ 2_{1} $, with unit cell dimensions a = 9.3899(4), b = 16.6789(7), c = 7.4463(3) Å and Z = 4 and compound 3 is monoclinic, space group Cc, with unit cell dimensions a = 5.9233(6), b = 18.048(2), c = 10.5478(10) Å, β = 90.376(10)° and Z = 4. In all crystals, both morpholinium N–H atoms are involved in primary inter-species hydrogen-bonding interactions with carboxyl O-atom acceptors of the anions. Secondary N–H···O hydrogen bonds between the amine groups and carboxyl (1 and 3) or both carboxyl and morpholine O-atom acceptors in 2, including in 2 a three-centre asymmetric N–H···O,O’ chelate [$$ R_{1}^{2} $$(4)] motif, give two-dimensional layers (1 and 2) or a three-dimensional network structure (3). In 1, the interactions include a centrosymmetric cyclic $$ R_{4}^{4} $$(12) motif and in 2, a cyclic $$ R_{3}^{2} $$(11) motif but no π–π aromatic ring associations are present in any of the structures. Graphical Abstract The structures of the anhydrous morpholinium salts of the three isomeric monoaminobenzoic acids are reported, together with their hydrogen-bonding patterns. Morpholine Aminobenzoic acids Hydrogen-bonding Enthalten in Journal of chemical crystallography Springer US, 1994 46(2016), 5 vom: Mai, Seite 230-236 (DE-627)182237877 (DE-600)1189288-2 (DE-576)039053679 1074-1542 nnns volume:46 year:2016 number:5 month:05 pages:230-236 https://doi.org/10.1007/s10870-016-0650-2 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-CHE SSG-OLC-GEO SSG-OLC-PHA SSG-OLC-DE-84 SSG-OPC-GGO GBV_ILN_70 GBV_ILN_4012 AR 46 2016 5 05 230-236 |
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Crystals of 1 are monoclinic, space group P$ 2_{1} $/c, with unit cell dimensions a = 11.0696(9), b = 7.8775(6), c = 13.0180(11) Å, β = 95.804(8)° and Z = 4. Compound 2 is orthorhombic, space group Pna$ 2_{1} $, with unit cell dimensions a = 9.3899(4), b = 16.6789(7), c = 7.4463(3) Å and Z = 4 and compound 3 is monoclinic, space group Cc, with unit cell dimensions a = 5.9233(6), b = 18.048(2), c = 10.5478(10) Å, β = 90.376(10)° and Z = 4. In all crystals, both morpholinium N–H atoms are involved in primary inter-species hydrogen-bonding interactions with carboxyl O-atom acceptors of the anions. Secondary N–H···O hydrogen bonds between the amine groups and carboxyl (1 and 3) or both carboxyl and morpholine O-atom acceptors in 2, including in 2 a three-centre asymmetric N–H···O,O’ chelate [$$ R_{1}^{2} $$(4)] motif, give two-dimensional layers (1 and 2) or a three-dimensional network structure (3). In 1, the interactions include a centrosymmetric cyclic $$ R_{4}^{4} $$(12) motif and in 2, a cyclic $$ R_{3}^{2} $$(11) motif but no π–π aromatic ring associations are present in any of the structures. 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Hydrogen-Bonding in the Anhydrous Morpholinium Salts of the Three Isomeric Monoaminobenzoic Acids |
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Hydrogen-Bonding in the Anhydrous Morpholinium Salts of the Three Isomeric Monoaminobenzoic Acids |
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hydrogen-bonding in the anhydrous morpholinium salts of the three isomeric monoaminobenzoic acids |
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Hydrogen-Bonding in the Anhydrous Morpholinium Salts of the Three Isomeric Monoaminobenzoic Acids |
| abstract |
Abstract The structures of the anhydrous morpholinium salts of the isomeric 2-aminobenzoic acid (anthranilic acid) (1), 3-aminobenzoic acid (2) and 4-aminobenzoic acid (3), with formula $ C_{4} $$ H_{10} $$ NO^{+} $ $ C_{7} $$ H_{8} $$ NO_{2} $−, have been determined. Crystals of 1 are monoclinic, space group P$ 2_{1} $/c, with unit cell dimensions a = 11.0696(9), b = 7.8775(6), c = 13.0180(11) Å, β = 95.804(8)° and Z = 4. Compound 2 is orthorhombic, space group Pna$ 2_{1} $, with unit cell dimensions a = 9.3899(4), b = 16.6789(7), c = 7.4463(3) Å and Z = 4 and compound 3 is monoclinic, space group Cc, with unit cell dimensions a = 5.9233(6), b = 18.048(2), c = 10.5478(10) Å, β = 90.376(10)° and Z = 4. In all crystals, both morpholinium N–H atoms are involved in primary inter-species hydrogen-bonding interactions with carboxyl O-atom acceptors of the anions. Secondary N–H···O hydrogen bonds between the amine groups and carboxyl (1 and 3) or both carboxyl and morpholine O-atom acceptors in 2, including in 2 a three-centre asymmetric N–H···O,O’ chelate [$$ R_{1}^{2} $$(4)] motif, give two-dimensional layers (1 and 2) or a three-dimensional network structure (3). In 1, the interactions include a centrosymmetric cyclic $$ R_{4}^{4} $$(12) motif and in 2, a cyclic $$ R_{3}^{2} $$(11) motif but no π–π aromatic ring associations are present in any of the structures. Graphical Abstract The structures of the anhydrous morpholinium salts of the three isomeric monoaminobenzoic acids are reported, together with their hydrogen-bonding patterns. © Springer Science+Business Media New York 2016 |
| abstractGer |
Abstract The structures of the anhydrous morpholinium salts of the isomeric 2-aminobenzoic acid (anthranilic acid) (1), 3-aminobenzoic acid (2) and 4-aminobenzoic acid (3), with formula $ C_{4} $$ H_{10} $$ NO^{+} $ $ C_{7} $$ H_{8} $$ NO_{2} $−, have been determined. Crystals of 1 are monoclinic, space group P$ 2_{1} $/c, with unit cell dimensions a = 11.0696(9), b = 7.8775(6), c = 13.0180(11) Å, β = 95.804(8)° and Z = 4. Compound 2 is orthorhombic, space group Pna$ 2_{1} $, with unit cell dimensions a = 9.3899(4), b = 16.6789(7), c = 7.4463(3) Å and Z = 4 and compound 3 is monoclinic, space group Cc, with unit cell dimensions a = 5.9233(6), b = 18.048(2), c = 10.5478(10) Å, β = 90.376(10)° and Z = 4. In all crystals, both morpholinium N–H atoms are involved in primary inter-species hydrogen-bonding interactions with carboxyl O-atom acceptors of the anions. Secondary N–H···O hydrogen bonds between the amine groups and carboxyl (1 and 3) or both carboxyl and morpholine O-atom acceptors in 2, including in 2 a three-centre asymmetric N–H···O,O’ chelate [$$ R_{1}^{2} $$(4)] motif, give two-dimensional layers (1 and 2) or a three-dimensional network structure (3). In 1, the interactions include a centrosymmetric cyclic $$ R_{4}^{4} $$(12) motif and in 2, a cyclic $$ R_{3}^{2} $$(11) motif but no π–π aromatic ring associations are present in any of the structures. Graphical Abstract The structures of the anhydrous morpholinium salts of the three isomeric monoaminobenzoic acids are reported, together with their hydrogen-bonding patterns. © Springer Science+Business Media New York 2016 |
| abstract_unstemmed |
Abstract The structures of the anhydrous morpholinium salts of the isomeric 2-aminobenzoic acid (anthranilic acid) (1), 3-aminobenzoic acid (2) and 4-aminobenzoic acid (3), with formula $ C_{4} $$ H_{10} $$ NO^{+} $ $ C_{7} $$ H_{8} $$ NO_{2} $−, have been determined. Crystals of 1 are monoclinic, space group P$ 2_{1} $/c, with unit cell dimensions a = 11.0696(9), b = 7.8775(6), c = 13.0180(11) Å, β = 95.804(8)° and Z = 4. Compound 2 is orthorhombic, space group Pna$ 2_{1} $, with unit cell dimensions a = 9.3899(4), b = 16.6789(7), c = 7.4463(3) Å and Z = 4 and compound 3 is monoclinic, space group Cc, with unit cell dimensions a = 5.9233(6), b = 18.048(2), c = 10.5478(10) Å, β = 90.376(10)° and Z = 4. In all crystals, both morpholinium N–H atoms are involved in primary inter-species hydrogen-bonding interactions with carboxyl O-atom acceptors of the anions. Secondary N–H···O hydrogen bonds between the amine groups and carboxyl (1 and 3) or both carboxyl and morpholine O-atom acceptors in 2, including in 2 a three-centre asymmetric N–H···O,O’ chelate [$$ R_{1}^{2} $$(4)] motif, give two-dimensional layers (1 and 2) or a three-dimensional network structure (3). In 1, the interactions include a centrosymmetric cyclic $$ R_{4}^{4} $$(12) motif and in 2, a cyclic $$ R_{3}^{2} $$(11) motif but no π–π aromatic ring associations are present in any of the structures. Graphical Abstract The structures of the anhydrous morpholinium salts of the three isomeric monoaminobenzoic acids are reported, together with their hydrogen-bonding patterns. © Springer Science+Business Media New York 2016 |
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