Palladium-catalyzed cycloaromatization polymerization of enediynes
Abstract Bergman cyclization has shown great promise in constructing conjugated polymers. However, the application of this reaction in polymer science is still limited due to the harsh reaction condition and ill-defined structure of the achieved polymers. To this end, the cycloaromatization polymeri...
Ausführliche Beschreibung
Autor*in: |
Wang, Chonggang [verfasserIn] |
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Artikel |
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Sprache: |
Englisch |
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2017 |
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Anmerkung: |
© Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag GmbH Germany, part of Springer Nature 2018 |
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Übergeordnetes Werk: |
Enthalten in: Chinese journal of polymer science - Chinese Chemical Society and Institute of Chemistry, CAS, 1985, 36(2017), 2 vom: 01. Dez., Seite 237-243 |
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Übergeordnetes Werk: |
volume:36 ; year:2017 ; number:2 ; day:01 ; month:12 ; pages:237-243 |
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DOI / URN: |
10.1007/s10118-018-2088-9 |
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OLC2038273499 |
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520 | |a Abstract Bergman cyclization has shown great promise in constructing conjugated polymers. However, the application of this reaction in polymer science is still limited due to the harsh reaction condition and ill-defined structure of the achieved polymers. To this end, the cycloaromatization polymerization of enediynes catalyzed by a series of transition metal catalysts is investigated in this work, by taking advantage of the coordination chemistry of the enediyne with the transition metal complexes. According to the nuclear magnetic resonance (NMR), Fourier transform infrared (FTIR), ultraviolet-visble (UV-Vis) spectroscopies and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) analysis, the cycloaromatization polymerization of enediynes proceeds under milder conditions and in a more controlled manner in the presence of palladium(II) complexes, giving structurally regulated conjugated polymers in high yields. | ||
650 | 4 | |a Transition metal catalysis | |
650 | 4 | |a Enediyne | |
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650 | 4 | |a Bergman cyclization | |
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10.1007/s10118-018-2088-9 doi (DE-627)OLC2038273499 (DE-He213)s10118-018-2088-9-p DE-627 ger DE-627 rakwb eng 540 660 VZ 660 670 VZ Wang, Chonggang verfasserin aut Palladium-catalyzed cycloaromatization polymerization of enediynes 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract Bergman cyclization has shown great promise in constructing conjugated polymers. However, the application of this reaction in polymer science is still limited due to the harsh reaction condition and ill-defined structure of the achieved polymers. To this end, the cycloaromatization polymerization of enediynes catalyzed by a series of transition metal catalysts is investigated in this work, by taking advantage of the coordination chemistry of the enediyne with the transition metal complexes. According to the nuclear magnetic resonance (NMR), Fourier transform infrared (FTIR), ultraviolet-visble (UV-Vis) spectroscopies and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) analysis, the cycloaromatization polymerization of enediynes proceeds under milder conditions and in a more controlled manner in the presence of palladium(II) complexes, giving structurally regulated conjugated polymers in high yields. Transition metal catalysis Enediyne Polymerization Cycloaromatization Bergman cyclization Chen, Shudan aut Zhou, Hao aut Gu, Jinlou aut Hu, Aiguo aut Enthalten in Chinese journal of polymer science Chinese Chemical Society and Institute of Chemistry, CAS, 1985 36(2017), 2 vom: 01. Dez., Seite 237-243 (DE-627)130996939 (DE-600)1082856-4 (DE-576)026374684 0256-7679 nnns volume:36 year:2017 number:2 day:01 month:12 pages:237-243 https://doi.org/10.1007/s10118-018-2088-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4277 AR 36 2017 2 01 12 237-243 |
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10.1007/s10118-018-2088-9 doi (DE-627)OLC2038273499 (DE-He213)s10118-018-2088-9-p DE-627 ger DE-627 rakwb eng 540 660 VZ 660 670 VZ Wang, Chonggang verfasserin aut Palladium-catalyzed cycloaromatization polymerization of enediynes 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract Bergman cyclization has shown great promise in constructing conjugated polymers. However, the application of this reaction in polymer science is still limited due to the harsh reaction condition and ill-defined structure of the achieved polymers. To this end, the cycloaromatization polymerization of enediynes catalyzed by a series of transition metal catalysts is investigated in this work, by taking advantage of the coordination chemistry of the enediyne with the transition metal complexes. According to the nuclear magnetic resonance (NMR), Fourier transform infrared (FTIR), ultraviolet-visble (UV-Vis) spectroscopies and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) analysis, the cycloaromatization polymerization of enediynes proceeds under milder conditions and in a more controlled manner in the presence of palladium(II) complexes, giving structurally regulated conjugated polymers in high yields. Transition metal catalysis Enediyne Polymerization Cycloaromatization Bergman cyclization Chen, Shudan aut Zhou, Hao aut Gu, Jinlou aut Hu, Aiguo aut Enthalten in Chinese journal of polymer science Chinese Chemical Society and Institute of Chemistry, CAS, 1985 36(2017), 2 vom: 01. Dez., Seite 237-243 (DE-627)130996939 (DE-600)1082856-4 (DE-576)026374684 0256-7679 nnns volume:36 year:2017 number:2 day:01 month:12 pages:237-243 https://doi.org/10.1007/s10118-018-2088-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4277 AR 36 2017 2 01 12 237-243 |
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10.1007/s10118-018-2088-9 doi (DE-627)OLC2038273499 (DE-He213)s10118-018-2088-9-p DE-627 ger DE-627 rakwb eng 540 660 VZ 660 670 VZ Wang, Chonggang verfasserin aut Palladium-catalyzed cycloaromatization polymerization of enediynes 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract Bergman cyclization has shown great promise in constructing conjugated polymers. However, the application of this reaction in polymer science is still limited due to the harsh reaction condition and ill-defined structure of the achieved polymers. To this end, the cycloaromatization polymerization of enediynes catalyzed by a series of transition metal catalysts is investigated in this work, by taking advantage of the coordination chemistry of the enediyne with the transition metal complexes. According to the nuclear magnetic resonance (NMR), Fourier transform infrared (FTIR), ultraviolet-visble (UV-Vis) spectroscopies and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) analysis, the cycloaromatization polymerization of enediynes proceeds under milder conditions and in a more controlled manner in the presence of palladium(II) complexes, giving structurally regulated conjugated polymers in high yields. Transition metal catalysis Enediyne Polymerization Cycloaromatization Bergman cyclization Chen, Shudan aut Zhou, Hao aut Gu, Jinlou aut Hu, Aiguo aut Enthalten in Chinese journal of polymer science Chinese Chemical Society and Institute of Chemistry, CAS, 1985 36(2017), 2 vom: 01. Dez., Seite 237-243 (DE-627)130996939 (DE-600)1082856-4 (DE-576)026374684 0256-7679 nnns volume:36 year:2017 number:2 day:01 month:12 pages:237-243 https://doi.org/10.1007/s10118-018-2088-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4277 AR 36 2017 2 01 12 237-243 |
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10.1007/s10118-018-2088-9 doi (DE-627)OLC2038273499 (DE-He213)s10118-018-2088-9-p DE-627 ger DE-627 rakwb eng 540 660 VZ 660 670 VZ Wang, Chonggang verfasserin aut Palladium-catalyzed cycloaromatization polymerization of enediynes 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract Bergman cyclization has shown great promise in constructing conjugated polymers. However, the application of this reaction in polymer science is still limited due to the harsh reaction condition and ill-defined structure of the achieved polymers. To this end, the cycloaromatization polymerization of enediynes catalyzed by a series of transition metal catalysts is investigated in this work, by taking advantage of the coordination chemistry of the enediyne with the transition metal complexes. According to the nuclear magnetic resonance (NMR), Fourier transform infrared (FTIR), ultraviolet-visble (UV-Vis) spectroscopies and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) analysis, the cycloaromatization polymerization of enediynes proceeds under milder conditions and in a more controlled manner in the presence of palladium(II) complexes, giving structurally regulated conjugated polymers in high yields. Transition metal catalysis Enediyne Polymerization Cycloaromatization Bergman cyclization Chen, Shudan aut Zhou, Hao aut Gu, Jinlou aut Hu, Aiguo aut Enthalten in Chinese journal of polymer science Chinese Chemical Society and Institute of Chemistry, CAS, 1985 36(2017), 2 vom: 01. Dez., Seite 237-243 (DE-627)130996939 (DE-600)1082856-4 (DE-576)026374684 0256-7679 nnns volume:36 year:2017 number:2 day:01 month:12 pages:237-243 https://doi.org/10.1007/s10118-018-2088-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4277 AR 36 2017 2 01 12 237-243 |
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10.1007/s10118-018-2088-9 doi (DE-627)OLC2038273499 (DE-He213)s10118-018-2088-9-p DE-627 ger DE-627 rakwb eng 540 660 VZ 660 670 VZ Wang, Chonggang verfasserin aut Palladium-catalyzed cycloaromatization polymerization of enediynes 2017 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract Bergman cyclization has shown great promise in constructing conjugated polymers. However, the application of this reaction in polymer science is still limited due to the harsh reaction condition and ill-defined structure of the achieved polymers. To this end, the cycloaromatization polymerization of enediynes catalyzed by a series of transition metal catalysts is investigated in this work, by taking advantage of the coordination chemistry of the enediyne with the transition metal complexes. According to the nuclear magnetic resonance (NMR), Fourier transform infrared (FTIR), ultraviolet-visble (UV-Vis) spectroscopies and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) analysis, the cycloaromatization polymerization of enediynes proceeds under milder conditions and in a more controlled manner in the presence of palladium(II) complexes, giving structurally regulated conjugated polymers in high yields. Transition metal catalysis Enediyne Polymerization Cycloaromatization Bergman cyclization Chen, Shudan aut Zhou, Hao aut Gu, Jinlou aut Hu, Aiguo aut Enthalten in Chinese journal of polymer science Chinese Chemical Society and Institute of Chemistry, CAS, 1985 36(2017), 2 vom: 01. Dez., Seite 237-243 (DE-627)130996939 (DE-600)1082856-4 (DE-576)026374684 0256-7679 nnns volume:36 year:2017 number:2 day:01 month:12 pages:237-243 https://doi.org/10.1007/s10118-018-2088-9 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4277 AR 36 2017 2 01 12 237-243 |
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Abstract Bergman cyclization has shown great promise in constructing conjugated polymers. However, the application of this reaction in polymer science is still limited due to the harsh reaction condition and ill-defined structure of the achieved polymers. To this end, the cycloaromatization polymerization of enediynes catalyzed by a series of transition metal catalysts is investigated in this work, by taking advantage of the coordination chemistry of the enediyne with the transition metal complexes. According to the nuclear magnetic resonance (NMR), Fourier transform infrared (FTIR), ultraviolet-visble (UV-Vis) spectroscopies and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) analysis, the cycloaromatization polymerization of enediynes proceeds under milder conditions and in a more controlled manner in the presence of palladium(II) complexes, giving structurally regulated conjugated polymers in high yields. © Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag GmbH Germany, part of Springer Nature 2018 |
abstractGer |
Abstract Bergman cyclization has shown great promise in constructing conjugated polymers. However, the application of this reaction in polymer science is still limited due to the harsh reaction condition and ill-defined structure of the achieved polymers. To this end, the cycloaromatization polymerization of enediynes catalyzed by a series of transition metal catalysts is investigated in this work, by taking advantage of the coordination chemistry of the enediyne with the transition metal complexes. According to the nuclear magnetic resonance (NMR), Fourier transform infrared (FTIR), ultraviolet-visble (UV-Vis) spectroscopies and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) analysis, the cycloaromatization polymerization of enediynes proceeds under milder conditions and in a more controlled manner in the presence of palladium(II) complexes, giving structurally regulated conjugated polymers in high yields. © Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag GmbH Germany, part of Springer Nature 2018 |
abstract_unstemmed |
Abstract Bergman cyclization has shown great promise in constructing conjugated polymers. However, the application of this reaction in polymer science is still limited due to the harsh reaction condition and ill-defined structure of the achieved polymers. To this end, the cycloaromatization polymerization of enediynes catalyzed by a series of transition metal catalysts is investigated in this work, by taking advantage of the coordination chemistry of the enediyne with the transition metal complexes. According to the nuclear magnetic resonance (NMR), Fourier transform infrared (FTIR), ultraviolet-visble (UV-Vis) spectroscopies and matrix-assisted laser desorption/ionization time-of-flight mass spectrometry (MALDI-TOF MS) analysis, the cycloaromatization polymerization of enediynes proceeds under milder conditions and in a more controlled manner in the presence of palladium(II) complexes, giving structurally regulated conjugated polymers in high yields. © Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag GmbH Germany, part of Springer Nature 2018 |
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title_short |
Palladium-catalyzed cycloaromatization polymerization of enediynes |
url |
https://doi.org/10.1007/s10118-018-2088-9 |
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author2 |
Chen, Shudan Zhou, Hao Gu, Jinlou Hu, Aiguo |
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Chen, Shudan Zhou, Hao Gu, Jinlou Hu, Aiguo |
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doi_str |
10.1007/s10118-018-2088-9 |
up_date |
2024-07-03T18:14:09.135Z |
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