A Comparison Study of Physicochemical Properties and Stabilities of H-Shaped Molecule and the Corresponding Polymer
Abstract Rare attention has been paid to the comparison between a monomer and its corresponding polymer in terms of the optoelectronic characteristics. In this article, a model H-shaped molecule and its corresponding polymer, both of which exhibited similar properties including blue emission and sol...
Ausführliche Beschreibung
Autor*in: |
Feng, Quan-You [verfasserIn] |
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Format: |
Artikel |
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Sprache: |
Englisch |
Erschienen: |
2018 |
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Anmerkung: |
© Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag GmbH Germany, part of Springer Nature 2018 |
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Übergeordnetes Werk: |
Enthalten in: Chinese journal of polymer science - Chinese Chemical Society and Institute of Chemistry, CAS, 1985, 37(2018), 1 vom: 01. Juni, Seite 11-17 |
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Übergeordnetes Werk: |
volume:37 ; year:2018 ; number:1 ; day:01 ; month:06 ; pages:11-17 |
Links: |
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DOI / URN: |
10.1007/s10118-018-2152-5 |
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Katalog-ID: |
OLC2038274991 |
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520 | |a Abstract Rare attention has been paid to the comparison between a monomer and its corresponding polymer in terms of the optoelectronic characteristics. In this article, a model H-shaped molecule and its corresponding polymer, both of which exhibited similar properties including blue emission and solution processing, were designed and synthesized. Optoelectronic properties and various kinds of stability features, including the thermostabilities, spectral stabilities and amplified spontaneous emission characteristic of the monomer and polymer were investigated. In general, the corresponding polymer PH exhibited similar optoelectronic properties but deteriorated stabilities compared with its H-shaped monomer H-1 probably owing to the similar chemical structure but the wider molecular weight distribution and metal catalyst residue. Importantly, monomer H-1 displayed a comparable ASE threshold value with its polymer PH, suggesting that H-shaped fluorene-based small molecules may be more promising optical gain media in solid state amplifers and lasers. | ||
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10.1007/s10118-018-2152-5 doi (DE-627)OLC2038274991 (DE-He213)s10118-018-2152-5-p DE-627 ger DE-627 rakwb eng 540 660 VZ 660 670 VZ Feng, Quan-You verfasserin aut A Comparison Study of Physicochemical Properties and Stabilities of H-Shaped Molecule and the Corresponding Polymer 2018 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract Rare attention has been paid to the comparison between a monomer and its corresponding polymer in terms of the optoelectronic characteristics. In this article, a model H-shaped molecule and its corresponding polymer, both of which exhibited similar properties including blue emission and solution processing, were designed and synthesized. Optoelectronic properties and various kinds of stability features, including the thermostabilities, spectral stabilities and amplified spontaneous emission characteristic of the monomer and polymer were investigated. In general, the corresponding polymer PH exhibited similar optoelectronic properties but deteriorated stabilities compared with its H-shaped monomer H-1 probably owing to the similar chemical structure but the wider molecular weight distribution and metal catalyst residue. Importantly, monomer H-1 displayed a comparable ASE threshold value with its polymer PH, suggesting that H-shaped fluorene-based small molecules may be more promising optical gain media in solid state amplifers and lasers. Fluorene H-shape Stability Optoelectronic materials Li, Bin aut Zuo, Zong-Yan aut Xie, Song-Lin aut Yu, Meng-Na aut Liu, Bin aut Wei, Ying aut Xie, Ling-Hai aut Xia, Rui-Dong aut Huang, Wei aut Enthalten in Chinese journal of polymer science Chinese Chemical Society and Institute of Chemistry, CAS, 1985 37(2018), 1 vom: 01. Juni, Seite 11-17 (DE-627)130996939 (DE-600)1082856-4 (DE-576)026374684 0256-7679 nnns volume:37 year:2018 number:1 day:01 month:06 pages:11-17 https://doi.org/10.1007/s10118-018-2152-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4277 AR 37 2018 1 01 06 11-17 |
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10.1007/s10118-018-2152-5 doi (DE-627)OLC2038274991 (DE-He213)s10118-018-2152-5-p DE-627 ger DE-627 rakwb eng 540 660 VZ 660 670 VZ Feng, Quan-You verfasserin aut A Comparison Study of Physicochemical Properties and Stabilities of H-Shaped Molecule and the Corresponding Polymer 2018 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract Rare attention has been paid to the comparison between a monomer and its corresponding polymer in terms of the optoelectronic characteristics. In this article, a model H-shaped molecule and its corresponding polymer, both of which exhibited similar properties including blue emission and solution processing, were designed and synthesized. Optoelectronic properties and various kinds of stability features, including the thermostabilities, spectral stabilities and amplified spontaneous emission characteristic of the monomer and polymer were investigated. In general, the corresponding polymer PH exhibited similar optoelectronic properties but deteriorated stabilities compared with its H-shaped monomer H-1 probably owing to the similar chemical structure but the wider molecular weight distribution and metal catalyst residue. Importantly, monomer H-1 displayed a comparable ASE threshold value with its polymer PH, suggesting that H-shaped fluorene-based small molecules may be more promising optical gain media in solid state amplifers and lasers. Fluorene H-shape Stability Optoelectronic materials Li, Bin aut Zuo, Zong-Yan aut Xie, Song-Lin aut Yu, Meng-Na aut Liu, Bin aut Wei, Ying aut Xie, Ling-Hai aut Xia, Rui-Dong aut Huang, Wei aut Enthalten in Chinese journal of polymer science Chinese Chemical Society and Institute of Chemistry, CAS, 1985 37(2018), 1 vom: 01. Juni, Seite 11-17 (DE-627)130996939 (DE-600)1082856-4 (DE-576)026374684 0256-7679 nnns volume:37 year:2018 number:1 day:01 month:06 pages:11-17 https://doi.org/10.1007/s10118-018-2152-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4277 AR 37 2018 1 01 06 11-17 |
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10.1007/s10118-018-2152-5 doi (DE-627)OLC2038274991 (DE-He213)s10118-018-2152-5-p DE-627 ger DE-627 rakwb eng 540 660 VZ 660 670 VZ Feng, Quan-You verfasserin aut A Comparison Study of Physicochemical Properties and Stabilities of H-Shaped Molecule and the Corresponding Polymer 2018 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag GmbH Germany, part of Springer Nature 2018 Abstract Rare attention has been paid to the comparison between a monomer and its corresponding polymer in terms of the optoelectronic characteristics. In this article, a model H-shaped molecule and its corresponding polymer, both of which exhibited similar properties including blue emission and solution processing, were designed and synthesized. Optoelectronic properties and various kinds of stability features, including the thermostabilities, spectral stabilities and amplified spontaneous emission characteristic of the monomer and polymer were investigated. In general, the corresponding polymer PH exhibited similar optoelectronic properties but deteriorated stabilities compared with its H-shaped monomer H-1 probably owing to the similar chemical structure but the wider molecular weight distribution and metal catalyst residue. Importantly, monomer H-1 displayed a comparable ASE threshold value with its polymer PH, suggesting that H-shaped fluorene-based small molecules may be more promising optical gain media in solid state amplifers and lasers. Fluorene H-shape Stability Optoelectronic materials Li, Bin aut Zuo, Zong-Yan aut Xie, Song-Lin aut Yu, Meng-Na aut Liu, Bin aut Wei, Ying aut Xie, Ling-Hai aut Xia, Rui-Dong aut Huang, Wei aut Enthalten in Chinese journal of polymer science Chinese Chemical Society and Institute of Chemistry, CAS, 1985 37(2018), 1 vom: 01. Juni, Seite 11-17 (DE-627)130996939 (DE-600)1082856-4 (DE-576)026374684 0256-7679 nnns volume:37 year:2018 number:1 day:01 month:06 pages:11-17 https://doi.org/10.1007/s10118-018-2152-5 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_70 GBV_ILN_267 GBV_ILN_2018 GBV_ILN_4277 AR 37 2018 1 01 06 11-17 |
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Feng, Quan-You Li, Bin Zuo, Zong-Yan Xie, Song-Lin Yu, Meng-Na Liu, Bin Wei, Ying Xie, Ling-Hai Xia, Rui-Dong Huang, Wei |
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a comparison study of physicochemical properties and stabilities of h-shaped molecule and the corresponding polymer |
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A Comparison Study of Physicochemical Properties and Stabilities of H-Shaped Molecule and the Corresponding Polymer |
abstract |
Abstract Rare attention has been paid to the comparison between a monomer and its corresponding polymer in terms of the optoelectronic characteristics. In this article, a model H-shaped molecule and its corresponding polymer, both of which exhibited similar properties including blue emission and solution processing, were designed and synthesized. Optoelectronic properties and various kinds of stability features, including the thermostabilities, spectral stabilities and amplified spontaneous emission characteristic of the monomer and polymer were investigated. In general, the corresponding polymer PH exhibited similar optoelectronic properties but deteriorated stabilities compared with its H-shaped monomer H-1 probably owing to the similar chemical structure but the wider molecular weight distribution and metal catalyst residue. Importantly, monomer H-1 displayed a comparable ASE threshold value with its polymer PH, suggesting that H-shaped fluorene-based small molecules may be more promising optical gain media in solid state amplifers and lasers. © Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag GmbH Germany, part of Springer Nature 2018 |
abstractGer |
Abstract Rare attention has been paid to the comparison between a monomer and its corresponding polymer in terms of the optoelectronic characteristics. In this article, a model H-shaped molecule and its corresponding polymer, both of which exhibited similar properties including blue emission and solution processing, were designed and synthesized. Optoelectronic properties and various kinds of stability features, including the thermostabilities, spectral stabilities and amplified spontaneous emission characteristic of the monomer and polymer were investigated. In general, the corresponding polymer PH exhibited similar optoelectronic properties but deteriorated stabilities compared with its H-shaped monomer H-1 probably owing to the similar chemical structure but the wider molecular weight distribution and metal catalyst residue. Importantly, monomer H-1 displayed a comparable ASE threshold value with its polymer PH, suggesting that H-shaped fluorene-based small molecules may be more promising optical gain media in solid state amplifers and lasers. © Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag GmbH Germany, part of Springer Nature 2018 |
abstract_unstemmed |
Abstract Rare attention has been paid to the comparison between a monomer and its corresponding polymer in terms of the optoelectronic characteristics. In this article, a model H-shaped molecule and its corresponding polymer, both of which exhibited similar properties including blue emission and solution processing, were designed and synthesized. Optoelectronic properties and various kinds of stability features, including the thermostabilities, spectral stabilities and amplified spontaneous emission characteristic of the monomer and polymer were investigated. In general, the corresponding polymer PH exhibited similar optoelectronic properties but deteriorated stabilities compared with its H-shaped monomer H-1 probably owing to the similar chemical structure but the wider molecular weight distribution and metal catalyst residue. Importantly, monomer H-1 displayed a comparable ASE threshold value with its polymer PH, suggesting that H-shaped fluorene-based small molecules may be more promising optical gain media in solid state amplifers and lasers. © Chinese Chemical Society, Institute of Chemistry, Chinese Academy of Sciences and Springer-Verlag GmbH Germany, part of Springer Nature 2018 |
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title_short |
A Comparison Study of Physicochemical Properties and Stabilities of H-Shaped Molecule and the Corresponding Polymer |
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https://doi.org/10.1007/s10118-018-2152-5 |
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