Partial oxidation of methane catalyzed by $ YBa_{2} $$ Cu_{3} $$ O_{x} $ in a solid state electrochemical reactor
Abstract The catalytic oxidation of methane was studied between 840 and 1110 K on a $ YBa_{2} $$ Cu_{3} $O* mixed-conducting electrode deposited on an yttria stabilized zirconia solid electrolyte. The lattice oxygen supplied electrochermically to the catalyst surface actively participated in the oxi...
Ausführliche Beschreibung
Gespeichert in:
| Autor*in: |
Gür, Turgut M. [verfasserIn] |
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| Format: |
Artikel |
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| Sprache: |
Englisch |
| Erschienen: |
1994 |
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| Schlagwörter: |
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| Systematik: |
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| Anmerkung: |
© J.C. Baltzer AG, Science Publishers 1994 |
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| Übergeordnetes Werk: |
Enthalten in: Catalysis letters - Baltzer Science Publishers, Baarn/Kluwer Academic Publishers, 1988, 23(1994), 3-4 vom: Mai, Seite 387-393 |
|---|---|
| Übergeordnetes Werk: |
volume:23 ; year:1994 ; number:3-4 ; month:05 ; pages:387-393 |
| Links: |
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| DOI / URN: |
10.1007/BF00811373 |
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OLC2040129812 |
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| 520 | |a Abstract The catalytic oxidation of methane was studied between 840 and 1110 K on a $ YBa_{2} $$ Cu_{3} $O* mixed-conducting electrode deposited on an yttria stabilized zirconia solid electrolyte. The lattice oxygen supplied electrochermically to the catalyst surface actively participated in the oxidation reaction, with CO as the major product, and $ CO_{2} $, $ CH_{3} $OH and HCHO as the minor products. The reaction rate was found to be of first order with respect to methane. The rate constant depended strongly on the electrochemically imposed bias. Under DC bias condition, the reaction rate was enhanced by as much as two orders of magnitude over that observed under open-circuit conditions. An Eley-Rideal mechanism for the interaction of $ CH_{4} $ with surface oxygen is proposed as the rate-determining step. | ||
| 650 | 4 | |a Electrochemical reactor | |
| 650 | 4 | |a methane oxidation | |
| 650 | 4 | |a zirconia electrolyte | |
| 650 | 4 | |a YBa | |
| 650 | 4 | |a Cu | |
| 650 | 4 | |a O | |
| 650 | 4 | |a catalytic electrode | |
| 650 | 4 | |a lattice oxygen | |
| 700 | 1 | |a Wise, Henry |4 aut | |
| 700 | 1 | |a Huggins, Robert A. |4 aut | |
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10.1007/BF00811373 doi (DE-627)OLC2040129812 (DE-He213)BF00811373-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Gür, Turgut M. verfasserin aut Partial oxidation of methane catalyzed by $ YBa_{2} $$ Cu_{3} $$ O_{x} $ in a solid state electrochemical reactor 1994 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © J.C. Baltzer AG, Science Publishers 1994 Abstract The catalytic oxidation of methane was studied between 840 and 1110 K on a $ YBa_{2} $$ Cu_{3} $O* mixed-conducting electrode deposited on an yttria stabilized zirconia solid electrolyte. The lattice oxygen supplied electrochermically to the catalyst surface actively participated in the oxidation reaction, with CO as the major product, and $ CO_{2} $, $ CH_{3} $OH and HCHO as the minor products. The reaction rate was found to be of first order with respect to methane. The rate constant depended strongly on the electrochemically imposed bias. Under DC bias condition, the reaction rate was enhanced by as much as two orders of magnitude over that observed under open-circuit conditions. An Eley-Rideal mechanism for the interaction of $ CH_{4} $ with surface oxygen is proposed as the rate-determining step. Electrochemical reactor methane oxidation zirconia electrolyte YBa Cu O catalytic electrode lattice oxygen Wise, Henry aut Huggins, Robert A. aut Enthalten in Catalysis letters Baltzer Science Publishers, Baarn/Kluwer Academic Publishers, 1988 23(1994), 3-4 vom: Mai, Seite 387-393 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:23 year:1994 number:3-4 month:05 pages:387-393 https://doi.org/10.1007/BF00811373 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2006 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4314 VA 2890 AR 23 1994 3-4 05 387-393 |
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10.1007/BF00811373 doi (DE-627)OLC2040129812 (DE-He213)BF00811373-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Gür, Turgut M. verfasserin aut Partial oxidation of methane catalyzed by $ YBa_{2} $$ Cu_{3} $$ O_{x} $ in a solid state electrochemical reactor 1994 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © J.C. Baltzer AG, Science Publishers 1994 Abstract The catalytic oxidation of methane was studied between 840 and 1110 K on a $ YBa_{2} $$ Cu_{3} $O* mixed-conducting electrode deposited on an yttria stabilized zirconia solid electrolyte. The lattice oxygen supplied electrochermically to the catalyst surface actively participated in the oxidation reaction, with CO as the major product, and $ CO_{2} $, $ CH_{3} $OH and HCHO as the minor products. The reaction rate was found to be of first order with respect to methane. The rate constant depended strongly on the electrochemically imposed bias. Under DC bias condition, the reaction rate was enhanced by as much as two orders of magnitude over that observed under open-circuit conditions. An Eley-Rideal mechanism for the interaction of $ CH_{4} $ with surface oxygen is proposed as the rate-determining step. Electrochemical reactor methane oxidation zirconia electrolyte YBa Cu O catalytic electrode lattice oxygen Wise, Henry aut Huggins, Robert A. aut Enthalten in Catalysis letters Baltzer Science Publishers, Baarn/Kluwer Academic Publishers, 1988 23(1994), 3-4 vom: Mai, Seite 387-393 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:23 year:1994 number:3-4 month:05 pages:387-393 https://doi.org/10.1007/BF00811373 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2006 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4314 VA 2890 AR 23 1994 3-4 05 387-393 |
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10.1007/BF00811373 doi (DE-627)OLC2040129812 (DE-He213)BF00811373-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Gür, Turgut M. verfasserin aut Partial oxidation of methane catalyzed by $ YBa_{2} $$ Cu_{3} $$ O_{x} $ in a solid state electrochemical reactor 1994 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © J.C. Baltzer AG, Science Publishers 1994 Abstract The catalytic oxidation of methane was studied between 840 and 1110 K on a $ YBa_{2} $$ Cu_{3} $O* mixed-conducting electrode deposited on an yttria stabilized zirconia solid electrolyte. The lattice oxygen supplied electrochermically to the catalyst surface actively participated in the oxidation reaction, with CO as the major product, and $ CO_{2} $, $ CH_{3} $OH and HCHO as the minor products. The reaction rate was found to be of first order with respect to methane. The rate constant depended strongly on the electrochemically imposed bias. Under DC bias condition, the reaction rate was enhanced by as much as two orders of magnitude over that observed under open-circuit conditions. An Eley-Rideal mechanism for the interaction of $ CH_{4} $ with surface oxygen is proposed as the rate-determining step. Electrochemical reactor methane oxidation zirconia electrolyte YBa Cu O catalytic electrode lattice oxygen Wise, Henry aut Huggins, Robert A. aut Enthalten in Catalysis letters Baltzer Science Publishers, Baarn/Kluwer Academic Publishers, 1988 23(1994), 3-4 vom: Mai, Seite 387-393 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:23 year:1994 number:3-4 month:05 pages:387-393 https://doi.org/10.1007/BF00811373 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2006 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4314 VA 2890 AR 23 1994 3-4 05 387-393 |
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10.1007/BF00811373 doi (DE-627)OLC2040129812 (DE-He213)BF00811373-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Gür, Turgut M. verfasserin aut Partial oxidation of methane catalyzed by $ YBa_{2} $$ Cu_{3} $$ O_{x} $ in a solid state electrochemical reactor 1994 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © J.C. Baltzer AG, Science Publishers 1994 Abstract The catalytic oxidation of methane was studied between 840 and 1110 K on a $ YBa_{2} $$ Cu_{3} $O* mixed-conducting electrode deposited on an yttria stabilized zirconia solid electrolyte. The lattice oxygen supplied electrochermically to the catalyst surface actively participated in the oxidation reaction, with CO as the major product, and $ CO_{2} $, $ CH_{3} $OH and HCHO as the minor products. The reaction rate was found to be of first order with respect to methane. The rate constant depended strongly on the electrochemically imposed bias. Under DC bias condition, the reaction rate was enhanced by as much as two orders of magnitude over that observed under open-circuit conditions. An Eley-Rideal mechanism for the interaction of $ CH_{4} $ with surface oxygen is proposed as the rate-determining step. Electrochemical reactor methane oxidation zirconia electrolyte YBa Cu O catalytic electrode lattice oxygen Wise, Henry aut Huggins, Robert A. aut Enthalten in Catalysis letters Baltzer Science Publishers, Baarn/Kluwer Academic Publishers, 1988 23(1994), 3-4 vom: Mai, Seite 387-393 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:23 year:1994 number:3-4 month:05 pages:387-393 https://doi.org/10.1007/BF00811373 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2006 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4314 VA 2890 AR 23 1994 3-4 05 387-393 |
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10.1007/BF00811373 doi (DE-627)OLC2040129812 (DE-He213)BF00811373-p DE-627 ger DE-627 rakwb eng 540 660 VZ VA 2890 VZ rvk Gür, Turgut M. verfasserin aut Partial oxidation of methane catalyzed by $ YBa_{2} $$ Cu_{3} $$ O_{x} $ in a solid state electrochemical reactor 1994 Text txt rdacontent ohne Hilfsmittel zu benutzen n rdamedia Band nc rdacarrier © J.C. Baltzer AG, Science Publishers 1994 Abstract The catalytic oxidation of methane was studied between 840 and 1110 K on a $ YBa_{2} $$ Cu_{3} $O* mixed-conducting electrode deposited on an yttria stabilized zirconia solid electrolyte. The lattice oxygen supplied electrochermically to the catalyst surface actively participated in the oxidation reaction, with CO as the major product, and $ CO_{2} $, $ CH_{3} $OH and HCHO as the minor products. The reaction rate was found to be of first order with respect to methane. The rate constant depended strongly on the electrochemically imposed bias. Under DC bias condition, the reaction rate was enhanced by as much as two orders of magnitude over that observed under open-circuit conditions. An Eley-Rideal mechanism for the interaction of $ CH_{4} $ with surface oxygen is proposed as the rate-determining step. Electrochemical reactor methane oxidation zirconia electrolyte YBa Cu O catalytic electrode lattice oxygen Wise, Henry aut Huggins, Robert A. aut Enthalten in Catalysis letters Baltzer Science Publishers, Baarn/Kluwer Academic Publishers, 1988 23(1994), 3-4 vom: Mai, Seite 387-393 (DE-627)130436550 (DE-600)644234-1 (DE-576)025720724 1011-372X nnns volume:23 year:1994 number:3-4 month:05 pages:387-393 https://doi.org/10.1007/BF00811373 lizenzpflichtig Volltext GBV_USEFLAG_A SYSFLAG_A GBV_OLC SSG-OLC-TEC SSG-OLC-CHE GBV_ILN_21 GBV_ILN_65 GBV_ILN_70 GBV_ILN_2006 GBV_ILN_2016 GBV_ILN_4012 GBV_ILN_4305 GBV_ILN_4314 VA 2890 AR 23 1994 3-4 05 387-393 |
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Gür, Turgut M. |
| doi_str_mv |
10.1007/BF00811373 |
| dewey-full |
540 660 |
| title_sort |
partial oxidation of methane catalyzed by $ yba_{2} $$ cu_{3} $$ o_{x} $ in a solid state electrochemical reactor |
| title_auth |
Partial oxidation of methane catalyzed by $ YBa_{2} $$ Cu_{3} $$ O_{x} $ in a solid state electrochemical reactor |
| abstract |
Abstract The catalytic oxidation of methane was studied between 840 and 1110 K on a $ YBa_{2} $$ Cu_{3} $O* mixed-conducting electrode deposited on an yttria stabilized zirconia solid electrolyte. The lattice oxygen supplied electrochermically to the catalyst surface actively participated in the oxidation reaction, with CO as the major product, and $ CO_{2} $, $ CH_{3} $OH and HCHO as the minor products. The reaction rate was found to be of first order with respect to methane. The rate constant depended strongly on the electrochemically imposed bias. Under DC bias condition, the reaction rate was enhanced by as much as two orders of magnitude over that observed under open-circuit conditions. An Eley-Rideal mechanism for the interaction of $ CH_{4} $ with surface oxygen is proposed as the rate-determining step. © J.C. Baltzer AG, Science Publishers 1994 |
| abstractGer |
Abstract The catalytic oxidation of methane was studied between 840 and 1110 K on a $ YBa_{2} $$ Cu_{3} $O* mixed-conducting electrode deposited on an yttria stabilized zirconia solid electrolyte. The lattice oxygen supplied electrochermically to the catalyst surface actively participated in the oxidation reaction, with CO as the major product, and $ CO_{2} $, $ CH_{3} $OH and HCHO as the minor products. The reaction rate was found to be of first order with respect to methane. The rate constant depended strongly on the electrochemically imposed bias. Under DC bias condition, the reaction rate was enhanced by as much as two orders of magnitude over that observed under open-circuit conditions. An Eley-Rideal mechanism for the interaction of $ CH_{4} $ with surface oxygen is proposed as the rate-determining step. © J.C. Baltzer AG, Science Publishers 1994 |
| abstract_unstemmed |
Abstract The catalytic oxidation of methane was studied between 840 and 1110 K on a $ YBa_{2} $$ Cu_{3} $O* mixed-conducting electrode deposited on an yttria stabilized zirconia solid electrolyte. The lattice oxygen supplied electrochermically to the catalyst surface actively participated in the oxidation reaction, with CO as the major product, and $ CO_{2} $, $ CH_{3} $OH and HCHO as the minor products. The reaction rate was found to be of first order with respect to methane. The rate constant depended strongly on the electrochemically imposed bias. Under DC bias condition, the reaction rate was enhanced by as much as two orders of magnitude over that observed under open-circuit conditions. An Eley-Rideal mechanism for the interaction of $ CH_{4} $ with surface oxygen is proposed as the rate-determining step. © J.C. Baltzer AG, Science Publishers 1994 |
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| container_issue |
3-4 |
| title_short |
Partial oxidation of methane catalyzed by $ YBa_{2} $$ Cu_{3} $$ O_{x} $ in a solid state electrochemical reactor |
| url |
https://doi.org/10.1007/BF00811373 |
| remote_bool |
false |
| author2 |
Wise, Henry Huggins, Robert A. |
| author2Str |
Wise, Henry Huggins, Robert A. |
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| up_date |
2024-07-04T01:19:17.479Z |
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